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Crystal Structure of Orthorhombic Cobalt Molybdate

Abstract

IN petroleum refinery practice de-sulphurization is carried out by catalysts consisting of an η - or γ-type alumina impregnated with cobalt and molybdenum oxides. However, the nature of the cobalt and molybdenum compound or compounds present on the catalyst is quite unknown, and a search through the literature reveals that there is almost no information on the formula and crystal structure of cobalt molybdate. A mineral paterite is known which is quoted as having the formula CoMoO4 1.

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References

  1. Killeffer, D. H., and Ling, A., “Molybdenum Compounds” (Interscience Publishers, 1952).

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  2. Wyckoff, R. W. G., “Crystal Structures” (Interscience Publishers).

  3. Keeling, R. O., Acta Cryst., 10, 209 (1957).

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  4. Howells, E. R., Phillips, D. C., and Rogers, D., Acta Cryst., 3, 210 (1950).

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SMITH, G. Crystal Structure of Orthorhombic Cobalt Molybdate. Nature 188, 306–308 (1960). https://doi.org/10.1038/188306b0

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