Abstract
THERE have very recently been two recalculations of the graphite–diamond equilibrium, one by Liljeblad1 and the other by Berman and Simon2, who also included a brief historical survey. Liljeblad did not make use of the most recent experimental data, whereas in the second paper the latest published material was incorporated as well as new measurements of the expansion coefficient of diamond, made by one of us (J. T.). Fig. 1 shows the two calculated equilibrium curves; while Liljeblad's curve goes through a maximum of about 62,000 atm. near 3,000° K., Berman and Simon arrived at a linear extrapolation above 1,200° K., which follows the equation: P (atm.) = 7,000 + 27 T (°K.)
This is a preview of subscription content, access via your institution
Access options
Subscribe to this journal
Receive 51 print issues and online access
$199.00 per year
only $3.90 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
Similar content being viewed by others
References
Liljeblad, R., Arkiv för Kemi, 8, 423 (1955).
Berman, R., and Simon, F. E., Z. Electrochem., 59, 333 (1955) (Volmer Widmungsheft).
Bundy, F. P., Hall, H. T., Strong, H. M., and Wentorf, R. H., Nature, 176, 51 (1955).
Joly, J., Sci. Trans. Roy. Dublin Soc., 6, 283 (1897).
Krishnan, K. S., Proc. Ind. Acad. Sci., 24A, 33 (1946).
Röntgen, W. C., Münchener Ber., 381 (1912).
Bijl, D., and Pullan, H., Physica, 21, 285 (1955).
Grüneisen, E., “Handbuch der Physik.”, 10, 1 (1926).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
BERMAN, R., THEWLIS, J. The Graphite–Diamond Equilibrium. Nature 176, 834–836 (1955). https://doi.org/10.1038/176834b0
Issue Date:
DOI: https://doi.org/10.1038/176834b0
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.