Abstract
POTASSIUM, rubidium and cæsium form dark blue, hexagonal tungsten bronzes MexWO3, where the alkali content, which is probably somewhat variable, corresponds to values1 of x of about 0.3. The crystal structure of these compounds, which are isomorphous, has been established on the basis of an X-ray investigation of a single crystal of the rubidium bronze.
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References
Magnéli, A., and Blomberg, B., Acta Chem. Scand., 5, 372 (1951).
Magnéli, A., Nova Acta Regiae Soc. Sci. Upsaliensis, [4], 14, No. 8 (1950).
Wells, A. F., “Structural Inorganic Chemistry” (2nd edit., Oxford, 1950).
Magnéli, A., Arkiv Kemi, 1, 223 (1949).
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MAGNÉLI, A. Tungsten Bronzes containing Six-membered Rings of WO6 Octahedra. Nature 169, 791–792 (1952). https://doi.org/10.1038/169791a0
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DOI: https://doi.org/10.1038/169791a0
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