Abstract
CADMIUM oxide has an electrical conductivity considerably higher than is exhibited by other metallic oxides1, with the possible exception of Fe3O4. As an electronic semi-conductor it possesses unusual properties in that its thermo-electric power increases with increasing temperature2, while its conductivity decreases slowly with increasing temperature3. As a means of determining the nature of the conduction mechanism which leads to quasi-metallic properties in a semi-conducting oxide, the Hall coefficient R was measured as a function of temperature and oxygen pressure for specimens of cadmium oxide made from material of the kind used by Andrews2 and by Wright3. By this means the sign and concentration nf of the charge carriers can be determined.
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References
Meyer, W., Z. Elektrochem., 50, 274 (1944).
Andrews, J. P., Proc. Phys. Soc., 59, 990 (1947).
Wright, R. W. H., thesis, London (1949).
Hogarth, C. A., Phil. Mag., 39, 260 (1948).
von Baumbach, H. H., and Wagner, C., Z. phys. Chem., B, 22, 199 (1933).
von Baumbach, H. H., and Wagner, C., Z. phys. Chem., B, 24, 59 (1934).
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HOGARTH, C. Hall Constant of Cadmium Oxide. Nature 167, 521–522 (1951). https://doi.org/10.1038/167521a0
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DOI: https://doi.org/10.1038/167521a0
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