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Photochemical Action of Ethylorthoformate

Abstract

Ciamician and Silber1 showed that when an ethyl alcohol solution of benzophenone is exposed to sunlight, the alcohol is oxidized to aldehyde and the ketone reduced to benzpinacol ; in the place of ethyl alcohol, isopropyl alcohol has frequently been used2. A large number of benzophenone derivatives react in the presence of alcohols as above3.

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References

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MUSTAFA, A. Photochemical Action of Ethylorthoformate. Nature 162, 856–857 (1948). https://doi.org/10.1038/162856a0

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