Biological and synthetic catalysts often utilize iron in high oxidation states (+IV and greater) to perform challenging molecular transformations. A coordination complex featuring an Fe(VII) ion has now been synthesized through sequential oxidations of nonheme iron–nitrido precursors.
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References
Hohenberger, J., Ray, K. & Meyer, K. Nat. Commun. 3, 720 (2012).
Krest, C. M. et al. J. Biol. Chem. 288, 17074–17081 (2013).
Banerjee, R., Jones, J. C. & Lipscomb, J. D. Annu. Rev. Biochem. 88, 409–431 (2019).
Kal, S., Xu, S. & Que, L. Jr Angew. Chem. Int. Ed. 59, 7332–7349 (2020).
McDonald, A. R. & Que, L. Coord. Chem. Rev. 257, 414–428 (2013).
Bucinsky, L. et al. Inorg. Chem. 56, 4752–4769 (2017).
Scepaniak, J. J. et al. Science 331, 1049–1052 (2011).
Thompson, N. B., Green, M. T. & Peters, J. C. J. Am. Chem. Soc. 139, 15312–15315 (2017).
Berry, J. F. et al. Science 312, 1937–1941 (2006).
Sharma, V. K. Coord. Chem. Rev. 257, 495–510 (2013).
Martinez, J. L. et al. Science 370, 356–359 (2020).
Keilwerth, M. et al. Nat. Chem. https://doi.org/10.1038/s41557-023-01418-4 (2024).
Keilwerth, M. et al. J. Am. Chem. Soc. 143, 1458–1465 (2021).
Cheng, J., Wang, L., Wang, P. & Deng, L. Chem. Rev. 118, 9930–9987 (2018).
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Fiedler, A.T., Devkota, L. Lifting iron higher and higher. Nat. Chem. 16, 481–482 (2024). https://doi.org/10.1038/s41557-024-01484-2
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DOI: https://doi.org/10.1038/s41557-024-01484-2