Solar fuels articles from across Nature Portfolio

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  • News & Views |

    Photocatalytic hydrogen peroxide synthesis is a green approach to produce this widely-used chemical and potential energy carrier, yet performance is often poor. A porphyrin-based photocatalyst is now shown to produce hydrogen peroxide by an unusual mechanism involving both photoexcited electrons and holes with promising efficiency.

    • Yuanxing Fang
    •  & Xinchen Wang
  • News & Views |

    Zero–gap CO/CO2 electrolyzers typically exhibit low energy conversion efficiency at high reactant conversion due to current losses associated with the parasitic production of H2. Now, an electrolyzer using an electrocatalyst in bulk heterojunction with a hydrophobic covalent organic framework has maintained high energy efficiency at near unity reactant conversion.

    • Ezra L. Clark
    Nature Energy 8, 119-120
  • News & Views |

    Electrochemical reduction of N2, mediated by Li, offers promise to decarbonize NH3 production, yet interfacial dynamics in such systems are poorly understood. Now, the morphology of the solid-electrolyte interphase layer formed during N2 reduction is revealed, opening opportunities to elucidate by-product formation mechanisms and improve NH3 selectivity.

    • Eric J. McShane
    •  & Matteo Cargnello
    Nature Energy 8, 115-116
  • News & Views |

    Electroreduction of N2 to ammonia is a possible alternative to the Haber–Bosch process, but the competing hydrogen evolution reaction typically limits yields. Now, electrochemical protocols combining two molecular catalysts are shown to produce ammonia with adequate selectivity at moderate overpotentials under mild conditions.

    • Inke Siewert
    Nature Energy 7, 908-909