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| Open Access3D-printed liquid metal polymer composites as NIR-responsive 4D printing soft robot
“The combination of stimuli responsive nanomaterials and 3D printing leads interesting applications in the fields of soft robots and actuators. Here, the authors present a 3D printing approach for the fabrication of liquid metal nanoparticles-polymer composites acting as light controlled soft robots which can lift weights, grasp and release items”.
- Liwen Zhang
- , Xumin Huang
- & Ruirui Qiao
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Article
| Open AccessUltrasonic barrier-through imaging by Fabry-Perot resonance-tailoring panel
Breakthrough ultrasonic imaging captures objects behind barriers. Leveraging Fabry-Perot resonance with a unique resonance-tailoring panel, our method allows imaging through high-impedance barriers helping to revolutionise underwater and brain imaging.
- Chung Il Park
- , Seungah Choe
- & Yoon Young Kim
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| Open AccessPeculiar transient behaviors of organic electrochemical transistors governed by ion injection directionality
Few studies have investigated the structural properties of organic mixed ionic-electronic conductors in relation to the transient device characteristics. Here, Kim et al. show that backbone-dependent molecular orientation affects ion injection directionality, which determines ion mobility and transient response.
- Ji Hwan Kim
- , Roman Halaksa
- & Myung-Han Yoon
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Article
| Open AccessHidden magnetism uncovered in a charge ordered bilayer kagome material ScV6Sn6
Recently, time-reversal symmetry-breaking charge order was demonstrated in the AV3Sb5 (A = K, Rb, Cs) family of kagome superconductors. Here the authors extend this observation to the recently discovered kagome material ScV6Sn6 and discuss differences and similarities to other charge-ordered kagome lattices.
- Z. Guguchia
- , D. J. Gawryluk
- & H. Luetkens
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| Open AccessProgrammable catalysis by support polarization: elucidating and breaking scaling relations
Can support polarisation introduce an extra degree of freedom in catalyst scaling relations? This research considers a computational approach for studying catalysts on polar supports and identifies the origin of broken scaling relations.
- Seongjoo Jung
- , Cristina Pizzolitto
- & Turan Birol
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| Open AccessThe two-qubit singlet/triplet measurement is universal for quantum computing given only maximally-mixed initial states
It has been conjectured that an alternative model of quantum computation—in which one only applies two-qubit singlet-vs-triplet measurements to almost any source of input qubits—is as powerful as the usual gate-based model. Here, the authors prove this conjecture, ending up with a model where computations are independent from the way in which one picks the axes of the Bloch sphere.
- Terry Rudolph
- & Shashank Soyuz Virmani
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Article
| Open AccessFunctional Janus structured liquids and aerogels
A combination of functional nanoparticles and liquid streaming can be used to generate structures for the fabrication of soft functional materials. In this study, authors demonstrate the creation of Janus-structured liquids with anisotropic and programmable distributions of nanoparticles by utilizing interfacial assembly and jamming of nanoparticles at the liquid-liquid interface.
- Ahmadreza Ghaffarkhah
- , Seyyed Alireza Hashemi
- & Mohammad Arjmand
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Article
| Open AccessUnexpected dynamics in femtomolar complexes of binding proteins with peptides
High binding affinities are usually obtained when ligands are rigidified. Here the authors present flexible peptides binding to Armadillo repeat proteins with femtomolar affinity. They demonstrate that the bound state is characterized by residual dynamics limiting entropic losses upon binding.
- Stefano Cucuzza
- , Malgorzata Sitnik
- & Oliver Zerbe
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Article
| Open AccessData-driven grading of acute graft-versus-host disease
Acute GVHD severity grading is based on target organ assessments. Here, the authors show that data-driven grading can identify 12 distinct grades with specific aGVHD phenotypes, which are associated with clinical outcomes, and that their method outperformed conventional gradings.
- Evren Bayraktar
- , Theresa Graf
- & Amin T. Turki
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Article
| Open AccessLabel-free identification of protein aggregates using deep learning
The authors use deep learning to detect and segment unlabeled and unaltered protein aggregates in living cells from transmitted-light images. The method provides a way to quantitatively study protein aggregation dynamics in a simple, fast and accurate way.
- Khalid A. Ibrahim
- , Kristin S. Grußmayer
- & Aleksandra Radenovic
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Article
| Open AccessLearning few-shot imitation as cultural transmission
The modelling of human-like behaviours is one of the challenges in the field of Artificial Intelligence. Inspired by experimental studies of cultural evolution, the authors propose a reinforcement learning approach to generate agents capable of real-time third-person imitation.
- Avishkar Bhoopchand
- , Bethanie Brownfield
- & Lei M. Zhang
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Article
| Open AccessLithium carbonate-promoted mixed rare earth oxides as a generalized strategy for oxidative coupling of methane with exceptional yields
Lithium carbonate-promoted mixed rare earth oxides can be used as redox catalysts for OCM at 700 °C and achieve a single-pass C2+ yield up to 30.6%. The high activity is assigned to the peroxide and OH radicals induced by Pr4+ in the redox catalyst.
- Kun Zhao
- , Yunfei Gao
- & Fanxing Li
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Article
| Open AccessUltra-durable cell-free bioactive hydrogel with fast shape memory and on-demand drug release for cartilage regeneration
Achieving successful in vivo cartilage regeneration remains challenging. Here they present a cell-free, multiple hydrogen-bond crosslinked hydrogel loaded with tannic acid and Kartogenin with ultra-durable mechanical properties and stage-dependent drug release behavior to promote cartilage regeneration.
- Yuxuan Yang
- , Xiaodan Zhao
- & Xuesi Chen
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Article
| Open AccessIn situ observation of a stepwise [2 + 2] photocycloaddition process using fluorescence spectroscopy
Using highly sensitive and selective in situ techniques to investigate the dynamics of intermediates formation is key to better understand reaction mechanisms but investigating the early stages of solid-state reactions or transformations is still challenging. Here the authors use in situ fluorescence spectroscopy to observe the evolution of intermediates during a two-step [2 + 2] photocycloaddition process in a coordination polymer.
- Meng-Fan Wang
- , Yun-Hu Deng
- & Jian-Ping Lang
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Article
| Open AccessAnomalous efficiency elevation of quantum-dot light-emitting diodes induced by operational degradation
Quantum-dot light-emitting diodes may exhibit anomalous efficiency enhancement upon electrical stress, as revealed by the authors, resulting from the continuous deterioration of cathode contacts.
- Siyu He
- , Xiaoqi Tang
- & Yizheng Jin
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Article
| Open AccessNon-equilibrium dynamics of spin-lattice coupling
Experimental approaches that can directly measure spin-lattice coupling are rare. Here, authors report direct observation of the coupling of the phonon and magnon dynamics of a coherently driven electromagnon in a multiferroic hexaferrite using time-resolved X-ray diffraction. (277 characters in total).
- Hiroki Ueda
- , Roman Mankowsky
- & Urs Staub
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| Open AccessMetal-organic framework boosts heterogeneous electron donor–acceptor catalysis
Heterogeneous electron donor–acceptor (EDA) catalysis has seen limited progress to date. Here, the authors showcase a significant improvement in EDA interaction by employing a metal-organic framework (MOF) as the donor catalyst, underscoring the potential of MOFs in catalytic processes.
- Jiaxin Lin
- , Jing Ouyang
- & Yangjian Quan
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Article
| Open AccessA promising perovskite primary explosive
A primary explosive (DPPE-1) with a double perovskite structure and ignition function was reported. It is synthesized in a straightforward manner and has good stability, with a minimum primary charge of 5 mg.
- Yongan Feng
- , Jichuan Zhang
- & Jean’ne M. Shreeve
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Article
| Open AccessA fully integrated, standalone stretchable device platform with in-sensor adaptive machine learning for rehabilitation
Methods for the wireless, continuous monitoring and analysis of activities directly from the throat skin have not been developed. Here, the authors present a stretchable device platform that provides wireless measurements and machine learning-based analysis of vibrations and muscle electrical activities from the throat.
- Hongcheng Xu
- , Weihao Zheng
- & Libo Gao
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Article
| Open AccessLocal H2 release remodels senescence microenvironment for improved repair of injured bone
Senescence microenvironment inhibits tissue repair in elderly individuals. Here, the authors demonstrate that local H2 supply has anti-inflammation and anti-senescence effects, and develop a H2-releasing scaffold to enhance aging bone defect repair.
- Shengqiang Chen
- , Yuanman Yu
- & Qianjun He
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Article
| Open AccessProton and molecular permeation through the basal plane of monolayer graphene oxide
GO monolayers are presumed to invariably contain a large density of nanoscale pinholes. Here the authors present gas and proton transport measurements which show that GO monolayers can be pinhole-free over micrometer-scale areas.
- Z. F. Wu
- , P. Z. Sun
- & M. Lozada-Hidalgo
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| Open AccessA simeprevir-inducible molecular switch for the control of cell and gene therapies
Chemical inducer of dimerization (CID) modules can be used to effectively control biological processes; however, CID modules have been explored primarily in engineering cells for in vitro applications using inducers that have limited clinical utility. Here, the authors identify a CID module with favorable properties to enable rapid translation from in vitro applications to potential use in humans.
- Stacey E. Chin
- , Christina Schindler
- & Natalie J. Tigue
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Article
| Open AccessUniversal selective transfer printing via micro-vacuum force
Transfer printing of inorganic semiconductors is essential for high-performance flexible electronics. Here, Park et al. report the micro-vacuum assisted selective transfer to integrate inorganic thin-film semiconductors on unusual substrates.
- Sang Hyun Park
- , Tae Jin Kim
- & Keon Jae Lee
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Article
| Open AccessMulti-client distributed blind quantum computation with the Qline architecture
Multi-client demonstrations of blind quantum computation are still missing, due to their high resource overhead. Here, the authors fill this gap, by proposing a more scalable solution based on a recently introduced linear quantum network structure with high modularity, and demonstrating it in the two-client case.
- Beatrice Polacchi
- , Dominik Leichtle
- & Elham Kashefi
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Article
| Open AccessReal-data-driven real-time reconfigurable microwave reflective surface
The authors demonstrate how flexible metasurfaces powered by artificial neural network can dynamically manipulate the EM scattering behavior from an arbitrary surface - an ultimate ambition for many EM stealth and communication problems.
- Erda Wen
- , Xiaozhen Yang
- & Daniel F. Sievenpiper
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| Open AccessCryogenic multiplexing using selective area grown nanowires
The authors demonstrate a large ensemble of quantum dots which is characterized using a cryogenic multiplexer-demultiplexer circuit based on selective area growth nanowires, establishing the feasibility of scaling future quantum circuits.
- Dāgs Olšteins
- , Gunjan Nagda
- & Thomas S. Jespersen
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Article
| Open AccessOptimal free-surface pumping by an undulating carpet
Pumping fluids at small scales near fluid-fluid interfaces remains challenging. Pandey et al. present a pump that drives interfacial flow by traveling waves on a deformable boundary.
- Anupam Pandey
- , Zih-Yin Chen
- & Sunghwan Jung
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Article
| Open AccessLocal probe-induced structural isomerization in a one-dimensional molecular array
Achieving unit-by-unit isomerization within a molecular array poses a significant challenge in chemistry. Here, the authors demonstrate tip-induced stereoisomerization of dehydroazulene and diradical units in three-dimensional organometallic compounds on Ag(111).
- Shigeki Kawai
- , Orlando J. Silveira
- & Adam S. Foster
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| Open AccessOverlapping speckle correlation algorithm for high-resolution imaging and tracking of objects in unknown scattering media
Imaging moving objects within scattering media is important for a wide range of fields but remains challenging in many practical scenarios. Here, the authors present an overlapping speckle correlation algorithm for imaging and tracking particles in unknown media with limited prior sample knowledge.
- Yaoyao Shi
- , Wei Sheng
- & Youwen Liu
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Article
| Open AccessSelf-activated superhydrophilic green ZnIn2S4 realizing solar-driven overall water splitting: close-to-unity stability for a full daytime
A superhydrophilic green hollow ZnIn2S4 was fabricated to realize unassisted photocatalytic overall water splitting. This work could provide an innovative aperture for efficient solar-driven green hydrogen production to achieve carbon neutrality.
- Wei-Kean Chong
- , Boon-Junn Ng
- & Siang-Piao Chai
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| Open AccessCu-mediated enantioselective C–H alkynylation of ferrocenes with chiral BINOL ligands
Ligands capable of accelerating and inducing enantioselectivity in C–H activations with base metal catalysts have remained elusive. Here, the authors report a ligand-accelerated enantioselective C–H alknylation, using a chiral BINOL ligand with a copper catalyst.
- Xin Kuang
- , Jian-Jun Li
- & Jin-Quan Yu
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Article
| Open AccessPhonon-enhanced nonlinearities in hexagonal boron nitride
Nonlinear optical processes like higher-order harmonic generation in solids depend on several factors. Here the authors explore the optical nonlinearity of hexagonal boron nitride and find that enhanced nonlinearity is due to electron-phonon and phonon-polariton couplings.
- Jared S. Ginsberg
- , M. Mehdi Jadidi
- & Alexander L. Gaeta
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Article
| Open AccessThe role of halogens in Au–S bond cleavage for energy-differentiated catalysis at the single-bond limit
Investigation of the reaction process at the single-bond interface is key to understanding the catalytic reaction mechanism. Here, the authors develop a STM-BJ method to monitor the catalytic process from the perspective of single-bond energy.
- Peihui Li
- , Songjun Hou
- & Xuefeng Guo
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Article
| Open AccessTough soldering for stretchable electronics by small-molecule modulated interfacial assemblies
“The interface mismatch of soft substrates and rigid silicon-based microelectronics frequently causes failures of integrated circuits. Here, the authors develop a stretchable solder based on liquid metal-polymer composites which enables seamless integration of electronic components with soft substrates, showcasing high conductivity and stretchability”.
- Liqing Ai
- , Weikang Lin
- & Xi Yao
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Article
| Open AccessAll electromagnetic scattering bodies are matrix-valued oscillators
The usual treatment of wave scattering theory relies on a formalism that does not easily allow for probing optimal spectral response. Here, the authors show how an alternative formalism, encoding fundamental principles of causality and passivity, can be used to make sense of complex scattered fields’ structures.
- Lang Zhang
- , Francesco Monticone
- & Owen D. Miller
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| Open AccessAutonomous nanorobots with powerful thrust under dry solid-contact conditions by photothermal shock
Optically trapping objects, marked by Nobel Prizes in 1997 and 2018 for applications in vacuum and liquids, remains challenging on solid surfaces. Here, the authors demonstrate a breakthrough by using photothermal-shock tweezers and explore nano-conventional robot applications
- Zhaoqi Gu
- , Runlin Zhu
- & Fuxing Gu
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Article
| Open AccessThermal and electrostatic tuning of surface phonon-polaritons in LaAlO3/SrTiO3 heterostructures
Phonon polaritons are promising for infrared applications while it is difficult to tune the phonon polariton properties. Here, authors report a thermal and electrostatic tuning of surface phonon polaritons in heterostructures of LaAlO3/SrTiO3.
- Yixi Zhou
- , Adrien Waelchli
- & Alexey B. Kuzmenko
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Article
| Open AccessExtent of carbon nitride photocharging controls energetics of hydrogen transfer in photochemical cascade processes
Savateev et al. investigate proton-coupled electron transfer from persistent graphitic carbon nitride radical to oxygen and imines. The results of their study find application in cascade photocatalysis – selective tetramerization of benzylic amines.
- Oleksandr Savateev
- , Karlo Nolkemper
- & Markus Antonietti
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Article
| Open AccessA self-stabilized and water-responsive deliverable coenzyme-based polymer binary elastomer adhesive patch for treating oral ulcer
The therapeutic benefits of biomaterials-based treatments for oral ulcer have been limited by the materials’ poor adhesion and short-time retention in oral cavity. Here, the authors report a polymer binary elastomer adhesive patch that allows water-responsive sustainable delivery of bioactive small molecules and durable adhesion to oral mucosal wounds to achieve efficient therapy of oral ulcer.
- Chunyan Cui
- , Li Mei
- & Wenguang Liu
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Article
| Open AccessMode attraction, rejection and control in nonlinear multimode optics
The authors introduce and demonstrate experimentally a novel fundamental property of nonlinear multimode optical systems, named mode rejection. This paves the way towards a more general idea of all-optical mode control and its related applications.
- Kunhao Ji
- , Ian Davidson
- & Massimiliano Guasoni
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Article
| Open AccessCooperative Fe sites on transition metal (oxy)hydroxides drive high oxygen evolution activity in base
Fe-based oxyhydroxides are promising catalysts for oxygen evolution reactions. However, the dynamics of Fe sites require further investigation. Here, the authors report Fe oxyhydroxide clusters on nickel or cobalt oxyhydroxides as key active sites for water oxidation and reveal how these clusters are selectively formed under controlled electrochemical conditions.
- Yingqing Ou
- , Liam P. Twight
- & Shannon W. Boettcher
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Article
| Open AccessConfined Cu-OH single sites in SSZ-13 zeolite for the direct oxidation of methane to methanol
High yields of methanol are difficult to achieve with direct oxidation of methane to methanol. Here the authors report a high methanol space-time yield which is attributed to the confinement effect of 6-membered ring voids and the isolated Cu-OH single sites in SSZ−13 zeolite.
- Hailong Zhang
- , Peijie Han
- & Yong Wang
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Article
| Open AccessOcclusive membranes for guided regeneration of inflamed tissue defects
Symbiosis should be maintained during the oral regeneration period. Herein, authors develop an occlusive membrane that induces symbiosis, thereby improving the performance of guided bone generation therapy.
- Woojin Choi
- , Utkarsh Mangal
- & Jinkee Hong
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Article
| Open Access3D bioprinted multilayered cerebrovascular conduits to study cancer extravasation mechanism related with vascular geometry
Geometrical complexities of blood vessels alter biophysical behaviors of circulating tumor cells, influencing cancer metastasis. Here, the authors develop a 3D bioprinted in vitro brain blood vessel-on-a-chip to investigate continuities between vascular geometry and metastatic cancer development.
- Wonbin Park
- , Jae-Seong Lee
- & Dong-Woo Cho
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Article
| Open AccessCorrosion-resistant cobalt phosphide electrocatalysts for salinity tolerance hydrogen evolution
Seawater electrolysis for hydrogen production is limited by the poor salinity tolerance of catalysts. CoP was found to repel chlorine while attracting H2O molecules to form a thin layer on the catalyst surface, thus constructing a corrosion-resistant CoP/rGO@Ti catalyst for seawater splitting.
- Xinwu Xu
- , Yang Lu
- & Yibo He
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Article
| Open AccessThe unusual quadruple bonding of nitrogen in ThN
Nitrogen can form a maximum of three shared electron-pair bonds to complete its octet, suggesting the maximum bond order of nitrogen is three. Here, the authors report a joint photoelectron spectroscopy and quantum chemical study, showing a quadruple bond between nitrogen and thorium in thorium nitride.
- Zejie Fei
- , Jia-Qi Wang
- & Jun Li
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Article
| Open AccessSynchronous micromechanically resonant programmable photonic circuits
MEMS-based photonic integrated circuits (PICs) are often limited in speed by mechanical resonances. Here the authors report a programmable architecture for PICs which uses mechanical eigenmodes for synchronized, resonantly enhanced optical modulation.
- Mark Dong
- , Julia M. Boyle
- & Dirk Englund
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Article
| Open AccessDirect OC-CHO coupling towards highly C2+ products selective electroreduction over stable Cu0/Cu2+ interface
The electrosynthesis of multicarbon products from CO2 is a highly attractive way to utilize emitted CO2. Here, the authors report in situ formed Cu0/Cu2+ interfaces from copper phosphate-based electrocatalysts for promoting selectivity toward multicarbon products through OC-CHO coupling.
- Xin Yu Zhang
- , Zhen Xin Lou
- & Hua Gui Yang
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Article
| Open AccessNanoparticles exhibiting virus-mimic surface topology for enhanced oral delivery
The oral delivery of nano-drug delivery systems (Nano-DDS) remains challenging. Here the authors construct core–shell mesoporous silica nanoparticles with virus-like nanospikes and demonstrate the versatility of these nanoparticles as Nano-DDS to achieve efficient oral drug delivery by mimicking structural feature, chiral recognition, and gene encapsulation of viruses.
- Zhentao Sang
- , Lu Xu
- & Heran Li