Organometallic chemistry

Organometallic chemistry is the study of the synthesis, structure and reactivity of chemical compounds that contain metal-carbon bonds. These compounds are often used as homogeneous catalysts.

Latest Research and Reviews

News and Comment

  • News and Views |

    A comprehensive chemical space of potential inorganic ternary metal nitrides has been explored by computational methods as a guideline for their experimental synthesis and discovery.

    • Ralf Riedel
    •  & Zhaoju Yu
    Nature Materials 18, 664-665
  • Comments and Opinion |

    Radical intermediates are key species in many chemical transformations. Recent advances have provided a new suite of selective radical alkylation reactions. This Comment highlights pioneering studies using alkyl amines that act as radical precursors in a number of catalytic processes by their conversion to alkylpyridinium salts.

    • Duanyang Kong
    • , Patrick J. Moon
    •  & Rylan J. Lundgren
    Nature Catalysis 2, 473-476
  • News and Views |

    Gold — long presumed to be an inert metal — has been increasingly shaking this image over the past couple of decades, mostly through electrophilic behaviour. Now, a two-coordinate gold complex has been shown to exhibit nucleophilic reactivity, with the insertion of CO2 into its polarized Auδ−–Alδ+ bond.

    • Didier Bourissou
    Nature Chemistry 11, 199-200