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| Open AccessAthermally photoreduced graphene oxides for three-dimensional holographic images
Owing to its electronic and optical properties, graphene holds potential for flat display systems. Here, Li et al. write wide-angle, full-colour, three-dimensional holographic images using subwavelength, multilevel index modulation of athermally reduced graphene oxide by a single femtosecond pulse.
- Xiangping Li
- , Haoran Ren
- & Min Gu
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Article
| Open AccessQuantum Hall resistance standards from graphene grown by chemical vapour deposition on silicon carbide
The quantum Hall effect in GaAs-based devices defines resistance standards accurate to within one part in 10−9 at magnetic fields close to 10 T. Here, Lafont et al. demonstrate such accuracies over an extended magnetic field range at 1.4 K in chemically vapour-deposited graphene on silicon carbide.
- F. Lafont
- , R. Ribeiro-Palau
- & W. Poirier
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| Open AccessVisualization of electrochemically driven solid-state phase transformations using operando hard X-ray spectro-imaging
Hard X-ray spectro-imaging using synchrotron radiation can be used to monitor electrochemical reactions. Here, the authors present X-ray absorption data and resolve phase evolution for the conversion of iron fluoride, a high-capacity Li-ion battery conversion cathode, with nanoscale resolution.
- Linsen Li
- , Yu-chen Karen Chen-Wiegart
- & Song Jin
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Article
| Open AccessTemperature-triggered chemical switching growth of in-plane and vertically stacked graphene-boron nitride heterostructures
Targeted synthesis of vertically stacked graphene (G) and hexagonal boron nitride (h-BN) heterostructures remains a challenge. Here, the authors achieve the selective, CVD growth of h-BN-G and G/h-BN through a temperature-triggered switching reaction.
- Teng Gao
- , Xiuju Song
- & Zhongfan Liu
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Radiation-mode optical microscopy on the growth of graphene
Real-time observation of graphene growth is likely to result in a greater understanding of growth mechanisms and ultimately enable improved growth control. Here, the authors propose a new technique for observing CVD grown graphene, which they term ‘radiation-mode optical microscopy’.
- Tomo-o Terasawa
- & Koichiro Saiki
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Long distance spin communication in chemical vapour deposited graphene
Although graphene promises long spin coherence lengths in spintronic devices, state-of-the-art performance has been limited to exfoliated flakes, limiting industrial scalability. Here, Kumalakar et al. demonstrate long-distance spin transport in large-scale chemical vapour-deposited graphene.
- M. Venkata Kamalakar
- , Christiaan Groenveld
- & Saroj P. Dash
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| Open AccessControlling band alignments by artificial interface dipoles at perovskite heterointerfaces
Controlling the alignment of bands at oxide interfaces is crucial for developing them into useful devices. By inserting charges into the interface to generate dipoles, Yajima et al. show tuning of the band alignment between SrRuO3/Nb:SrTiO3by 1.7 eV.
- Takeaki Yajima
- , Yasuyuki Hikita
- & Harold Y. Hwang
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| Open AccessPseudocapacitance of MXene nanosheets for high-power sodium-ion hybrid capacitors
Conventional sodium ion batteries have low energy and power densities. Here, the authors report the use of MXene Ti2C as a negative electrode for sodium ion energy storage, and show that the pseudocapacitance of the electrode allows the hybrid capacitors to achieve high electrochemical performance.
- Xianfen Wang
- , Satoshi Kajiyama
- & Atsuo Yamada
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Article
| Open AccessA photofunctional bottom-up bis(dipyrrinato)zinc(II) complex nanosheet
The creation of functional 2D bottom-up nanosheets woven from molecular components remains a large challenge. Here, a bottom-up nanosheet featuring a photofunctional bis(dipyrrinato)zinc(II) complex motif is synthesized using interfacial syntheses, enabling a photoelectric conversion system.
- Ryota Sakamoto
- , Ken Hoshiko
- & Hiroshi Nishihara
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Magnetoelectric quasi-(0-3) nanocomposite heterostructures
Magnetoelectric composites of magnetic and ferroelectric components are promising for their use in applications such as information storage. Here, the authors find that magnetic quasiparticles embedded in a ferroelectric film matrix show promising properties compared to the usual thin-film architectures.
- Yanxi Li
- , Zhongchang Wang
- & Dwight Viehland
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Rational design of a chalcogenopyrylium-based surface-enhanced resonance Raman scattering nanoprobe with attomolar sensitivity
Raman imaging offers great potential in biomedical imaging due to the combination of specificity and sensitivity. Here, the authors show nanoparticles functionalized with a chalcogenopyrylium reporter molecule, giving bright probes with low limits of detection for in vivoimaging.
- Stefan Harmsen
- , Matthew A. Bedics
- & Moritz F. Kircher
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A graphene field-effect transistor as a molecule-specific probe of DNA nucleobases
The development of improved DNA sequencing technologies relies on the ability to distinguish each of the four DNA nucleobases separately. Here, the authors fabricate a graphene field-effect transistor able to experimentally observe individual DNA nucleobases.
- Nikolai Dontschuk
- , Alastair Stacey
- & Jiri Cervenka
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Article
| Open AccessHigh-resolution vector microwave magnetometry based on solid-state spins in diamond
Microwave technology is crucial for communications and high-speed electronics. Wang et al. now use nitrogen-vacancy defects in diamond to measure the strength and orientation of the magnetic component of a microwave electromagnetic field on the nanoscale.
- Pengfei Wang
- , Zhenheng Yuan
- & Jiangfeng Du
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Unlocking Bloch-type chirality in ultrathin magnets through uniaxial strain
Magnetic domain walls can exhibit a variety of different spin textures. Chen et al. show that it is possible to switch these textures between left handed, right handed, cycloidal, helical and mixed domain wall structures by controlling uniaxial strain in iron/nickel bilayer thin films on tungsten.
- Gong Chen
- , Alpha T. N’Diaye
- & Andreas K. Schmid
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Formation of nickel cobalt sulfide ball-in-ball hollow spheres with enhanced electrochemical pseudocapacitive properties
While the synthesis of hollow structures of transition metal oxides is well established, the related sulfide chemistry remains challenging. Here, the authors report the synthesis of nickel cobalt sulfide ball-in-ball hollow spheres, via anion exchange, and evaluate their pseudocapacitive behaviour.
- Laifa Shen
- , Le Yu
- & Xiong Wen (David) Lou
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Article
| Open AccessCoherent creation and destruction of orbital wavepackets in Si:P with electrical and optical read-out
Impurity spins in silicon can be controlled with microwaves and then read-out electrically, offering a promising platform for quantum information applications. Here, the authors show that terahertz pulses can be used to address the orbital degree of freedom as well, which can also be detected electrically.
- K.L. Litvinenko
- , E.T. Bowyer
- & B.N. Murdin
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| Open AccessHumidity-enhanced wet adhesion on insect-inspired fibrillar adhesive pads
Many insects supply secretion via small tubes or pores to the end of their legs to be able to attach to a surface. Here, inspired by nature, Xue et al.fabricate adhesive pads with porous nanorod structure for oil delivery, which give rise to a 100-fold increase in adhesivity under humid conditions.
- Longjian Xue
- , Alexander Kovalev
- & Stanislav N. Gorb
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| Open AccessNanoscale probing of image-dipole interactions in a metallic nanostructure
An emitter near a surface induces an image dipole that alters the emission pattern and creates errors in single-particle imaging applications. Here, Ropp et al.show that an image dipole can distort the polarization and measured position of an emitter, and that these distortions can be corrected.
- Chad Ropp
- , Zachary Cummins
- & Edo Waks
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Triple-helical nanowires by tomographic rotatory growth for chiral photonics
Three-dimensional helical chiral metamaterials are required for nanophotonics but lack of full rotational symmetry has limited their use. Here, Esposito et al. combine chirality and isotropy, fabricating intertwined helical nanowires with 37% broadband circular dichroism with a high signal to noise ratio.
- Marco Esposito
- , Vittorianna Tasco
- & Adriana Passaseo
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Single-step deposition of high-mobility graphene at reduced temperatures
Current methods for depositing large-area, high-mobility graphene films are complicated by multiple processing steps and high temperatures. Here, the authors demonstrate a plasma chemistry that quickly produces high-mobility graphene on copper in a single step, at reduced temperatures (<420 °C).
- D.A. Boyd
- , W.-H. Lin
- & N.-C. Yeh
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Dynamically self-assembled silver nanoparticles as a thermally tunable metamaterial
Tunable metamaterials bring the promise of on-demand tailored optical properties, offering numerous device functionalities. Towards this aim, this study presents a tunable metamaterial based on dynamic self-assembly of nanoparticles coated with organic ligands, which also shows epsilon-near-zero behaviour.
- Wiktor Lewandowski
- , Martin Fruhnert
- & Ewa Górecka
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| Open AccessSub-nanosecond signal propagation in anisotropy-engineered nanomagnetic logic chains
Closely-spaced anisotropically-engineered single-domain nanomagnets may be exploited to encode and transmit binary information. Here, Gu et al. use time-resolved X-ray microscopy to image signal propagation at the intrinsic nanomagnetic switching limit in permalloy nanomagnet chains.
- Zheng Gu
- , Mark E. Nowakowski
- & Jeffrey Bokor
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| Open AccessReversed oxygen sensing using colloidal quantum wells towards highly emissive photoresponsive varnishes
Colloidal quantum wells have great potential as solution-processed light sources. Here, Lorenzon et al. demonstrate that such colloidal quantum wells can also be exploited as luminescent-sensing varnishes capable of detecting chemical agents through their reversible emission response.
- Monica Lorenzon
- , Sotirios Christodoulou
- & Sergio Brovelli
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Complete information acquisition in dynamic force microscopy
An often overlooked component of scanning probe microscopy involves information transfer from the tip–surface junction to a macroscopic measurement system. Here, the authors present an information–theory-based approach that relies on capturing the response at a wide-frequency band, allowing a complete and unbiased look at probing interaction.
- Alexei Belianinov
- , Sergei V. Kalinin
- & Stephen Jesse
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Surface modification-induced phase transformation of hexagonal close-packed gold square sheets
Phase transformations between different crystal structures in nanomaterials conventionally require extreme conditions, such as high pressure or high temperature. Here, the authors report the phase transformation of Au nanosheets by the exchange of surface ligands or coating of Ag at ambient conditions.
- Zhanxi Fan
- , Xiao Huang
- & Hua Zhang
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Topological proximity effect in a topological insulator hybrid
A topologically protected state can exist at the interface between a topological insulator and an ordinary insulator. Here, the authors use photoemission spectroscopy to show that the topological Dirac-cone state migrates from the surface of the topological insulator TlBiSe2to an attached bismuth film.
- T. Shoman
- , A. Takayama
- & Yoichi Ando
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| Open AccessSilane-catalysed fast growth of large single-crystalline graphene on hexagonal boron nitride
The growth of high-quality graphene directly on to dielectric substrates is of key importance for future electronic and optoelectronic applications. Here, the authors use silane-catalysed chemical vapour deposition to fabricate large graphene sheets, up to 20 μm in size, on hexagonal boron nitride.
- Shujie Tang
- , Haomin Wang
- & Mianheng Jiang
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| Open AccessExploitation of desilylation chemistry in tailor-made functionalization on diverse surfaces
Formation of stable and uniform self-assembled monolayers on surfaces is a prerequisite for bottom-up fabrication of many organic molecular devices. Here, the authors present a fabrication approach based on desilylation chemistry for modification and functionalization on various metal and carbon surfaces.
- Yongchun Fu
- , Songjie Chen
- & Shi-Xia Liu
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Mesoporous bismuth ferrite with amplified magnetoelectric coupling and electric field-induced ferrimagnetism
Bismuth ferrite is an important room temperature multiferroic material where magnetism and ferroelectricity are coupled. Here, the authors utilize a wet chemical synthesis method to create strained nanoporous bismuth ferrite with enhanced magnetoelectric coupling and elevated magnetic moments.
- Thomas E. Quickel
- , Laura T. Schelhas
- & Sarah H. Tolbert
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| Open AccessNeutral particle mass spectrometry with nanomechanical systems
Mass spectrometry (MS) involves ionization of analytes with spectra dependent upon the mass-to-charge ratio. Here, the authors demonstrate that MS based on nanoelectromechanical systems gives results that are independent of the charge state and allow the mass spectrum of neutral species to be obtained.
- Eric Sage
- , Ariel Brenac
- & Sébastien Hentz
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A surface curvature oscillation model for vapour–liquid–solid growth of periodic one-dimensional nanostructures
Vapour-liquid-solid process is widely used to prepare a variety of one-dimensional nanostructures, but a quantitative understanding of the growth mechanism is missing. Here, Wang et al. show that the surface curvature oscillation of the liquid tip determines the growing process and thus the morphology.
- Hui Wang
- , Jian-Tao Wang
- & Xiao-Hong Zhang
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| Open AccessNitrogenated holey two-dimensional structures
There is currently interest in two-dimensional graphene-like materials incorporating heteroatoms. Here, the authors synthesize a solution-processable, holey two-dimensional network with C2N stoichiometry containing evenly distributed holes and nitrogen atoms, and use it to fabricate a field effect transistor.
- Javeed Mahmood
- , Eun Kwang Lee
- & Jong-Beom Baek
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Optically switchable transistors by simple incorporation of photochromic systems into small-molecule semiconducting matrices
Organic thin-film transistors can be photomodulated by incorporating photochromic molecules, but the state-of-the-art suffers from poor charge transport. Here, the authors improve charge mobility by three orders of magnitude by blending small conjugated molecules into diarylethene.
- Mirella El Gemayel
- , Karl Börjesson
- & Paolo Samorì
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Direct growth of large-area graphene and boron nitride heterostructures by a co-segregation method
Direct growth of graphene on h-BN is desired to improve device performance. Here, the authors demonstrate the direct growth of large-area and continuous graphene/h-BN vertical heterostructures via a co-segregation approach.
- Chaohua Zhang
- , Shuli Zhao
- & Zhongfan Liu
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10.5% efficient polymer and amorphous silicon hybrid tandem photovoltaic cell
Ultrathin film photovoltaic cells are a promising energy device, but suffer from low power conversion efficiency. Here, the authors construct a double-junction tandem cell using a hydrogenated amorphous silicon and a polymer as the front and back cell, respectively, which achieves 10.5% efficiency.
- Jeehwan Kim
- , Ziruo Hong
- & Yang Yang
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| Open AccessMolecular magnetic switch for a metallofullerene
Endohedral fullerenes are known to stabilize reactive radicals; however, the external magnetic manipulation of these species’ remains challenging. Here, the authors link a nitroxide radical to a paramagnetic fullerene system and are able to alter the spin behaviour of the fullerene via spin–spin interactions.
- Bo Wu
- , Taishan Wang
- & Chunru Wang
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| Open AccessFlexible suspended gate organic thin-film transistors for ultra-sensitive pressure detection
The development of wearable healthcare and intelligence systems require low-cost, large-area flexible electronic sensors. Here, Zang et al. report pressure sensors based on organic thin-film transistors in combination with a suspended-gate device geometry, which show high sensitivity up to 192 kPa−1.
- Yaping Zang
- , Fengjiao Zhang
- & Daoben Zhu
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| Open AccessFabrication of three-dimensionally interconnected nanoparticle superlattices and their lithium-ion storage properties
Three-dimensional nanoparticle superlattices are interesting, but their fabrication is generally limited to materials attainable as monodisperse colloidal nanoparticles. Here, the authors fabricate interconnected superlattices via self-assembly without the presynthesis of the constituent nanoparticles.
- Yucong Jiao
- , Dandan Han
- & Angang Dong
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Spin-torque-induced dynamics at fine-split frequencies in nano-oscillators with two stacked vortices
Magnetic vortices in nanodiscs possess potential applications based on their magnetic configuration and spin-torque-driven oscillation. Here, Sluka et al. show how the coupled gyration of two stacked vortices is split into discretized frequencies defined by their relative chirality and polarity.
- V. Sluka
- , A. Kákay
- & R. Hertel
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Controlling the direction of rectification in a molecular diode
The electronic coupling between the active components and electrodes in molecular electronics determines the device performance. Here, Yuan et al. show that a non-covalent coupling is sufficiently strong to induce molecular-based rectification, while weak enough to minimize leakage current.
- Li Yuan
- , Nisachol Nerngchamnong
- & Christian A. Nijhuis
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Self-biased reconfigurable graphene stacks for terahertz plasmonics
The unusual electronic and optical properties of graphene are finding increasing applications for terahertz and mid-infrared plasmonics. Here, the authors show how monolayers of graphene separated by thin dielectric layers can act as tunable structures for plasmonic device platforms.
- J.S. Gomez-Diaz
- , C Moldovan
- & J Perruisseau-Carrier
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| Open AccessSimultaneous observation of the quantization and the interference pattern of a plasmonic near-field
Mapping the field of surface plasmon polaritons is important to understand their fundamental properties and behaviour. Here, the authors show that ultrafast transmission electron microscopy can simultaneously obtain the spatial interference and quantization of nanowire-confined plasmonic fields.
- L Piazza
- , T.T.A. Lummen
- & F Carbone
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| Open AccessGate-controlled generation of optical pulse trains using individual carbon nanotubes
The photocurrent and luminescence of carbon nanotubes is governed by excitonic processes with diverse uses in nano-photonics. Here, Jiang et al.generate optical pulses from individual air-suspended carbon nanotubes under an application of square-wave gate voltages with control over pulse timing and duration.
- M Jiang
- , Y Kumamoto
- & Y. K. Kato
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Narrowband light detection via internal quantum efficiency manipulation of organic photodiodes
There is a growing interest in the development of narrowband photodiodes for full-color imaging and visible-blind near-infrared detection. Armin et al.show a sub-100 nm response by tuning the spectral bandwidth through regulating the charge collection efficiency in a thick organic bulk heterojunction.
- Ardalan Armin
- , Ross D. Jansen-van Vuuren
- & Paul Meredith
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Stable silicon-ionic liquid interface for next-generation lithium-ion batteries
Silicon is a promising anode material for lithium ion batteries, but suffers from structural degradation during operations. Here, the authors combine silicon with a room temperature ionic liquid to stabilize the electrode-electrolyte interface and achieve long-term cyclability.
- Daniela Molina Piper
- , Tyler Evans
- & Se-Hee Lee
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Silicon-chip mid-infrared frequency comb generation
Optical frequency combs in the mid-infrared are required for molecular gas detection applications but their realization in compact microresonator-based platforms is challenging. Here, Griffith et al. demonstrate on-chip broadband comb generation on a silicon microresonator spanning from 2.1 to 3.5 μm.
- Austin G. Griffith
- , Ryan K.W. Lau
- & Michal Lipson
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Crystalline silicon core fibres from aluminium core preforms
The integration of silicon optoelectronic devices in a fibre platform has great potential, but drawing such fibres is difficult. Using a simple, low cost and scalable method, Hou et al. fabricate a metre-long crystalline silicon-core, silica-clad fibre from a preform not containing elemental silicon.
- Chong Hou
- , Xiaoting Jia
- & Yoel Fink
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| Open AccessAn octave-spanning mid-infrared frequency comb generated in a silicon nanophotonic wire waveguide
Phase-coherent frequency combs in the mid-infrared have important potential applications but their fabrication remains challenging. Here, Kuyken et al. demonstrate an octave-spanning frequency comb in the mid-infrared using a highly nonlinear dispersion-engineered silicon waveguide on a silicon-on-insulator chip.
- Bart Kuyken
- , Takuro Ideguchi
- & Nathalie Picqué
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Self-assembled hydrogels utilizing polymer–nanoparticle interactions
Mouldable hydrogels find a variety of applications in the biomedical industry. Here, Appel et al. show a method to fabricate hydrogels through a self-assembly process based on the interaction between biopolymers and functional nanoparticles for multistage drug delivery in vivo.
- Eric A. Appel
- , Mark W. Tibbitt
- & Robert Langer