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| Open AccessCurrent-induced skyrmion generation and dynamics in symmetric bilayers
The creation of practical devices based on magnetic skyrmions depends on the development of methods to create and control stable individual skyrmions. Here, the authors present a bilayer device that uses dipolar interactions to stabilize skyrmions that can be manipulated using electric currents.
- A. Hrabec
- , J. Sampaio
- & S. Rohart
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| Open AccessDynamic contrast-enhanced photoacoustic imaging using photothermal stimuli-responsive composite nanomodulators
Photoacoustic imaging becomes an enabling technology that is designed for clinic diagnosis of disease. Here, Chenet al. report an imaging contrast agent—plasmonic nanoparticles caged in hydrogel subject to reversible volume change depending on temperature, which exhibits tunable photoacoustic signal.
- Yun-Sheng Chen
- , Soon Joon Yoon
- & Stanislav Emelianov
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| Open AccessTowards colloidal spintronics through Rashba spin-orbit interaction in lead sulphide nanosheets
Exploring the Rashba spin splitting in colloidal materials enables spintronic device with low cost and high flexibility. Here, the authors report Rashba spin splitting in colloidal PbS nanosheets and demonstrate a mechanism for selectively exciting the carriers with different spin states.
- Mohammad Mehdi Ramin Moayed
- , Thomas Bielewicz
- & Christian Klinke
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| Open AccessTailoring protein nanomechanics with chemical reactivity
Post-translational modifications modulate nanomechanics of proteins. Here the authors use single-molecule force-clamp spectroscopy supported by density functional theory calculations to show how reactive low-weight molecular thiol compounds directly affect mechanical protein folding.
- Amy E. M. Beedle
- , Marc Mora
- & Sergi Garcia-Manyes
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| Open AccessCascaded spintronic logic with low-dimensional carbon
Spintronics, graphene, and carbon nanotubes are potential components of next-generation high performance computers. Here, the authors propose and theoretically evaluate a spintronic logic family composed solely of carbon materials with the potential for a 100 × improvement in energy efficiency.
- Joseph S. Friedman
- , Anuj Girdhar
- & Alan V Sahakian
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| Open AccessProbing intermediates of the induction period prior to nucleation and growth of semiconductor quantum dots
Growth of colloidal semiconductor quantum dots involves several stages, including an enigmatic induction period preceding nucleation. Here, the authors identify two distinct intermediates in the induction period, mapping their evolution from precursors all the way to either magic-size clusters or quantum dots.
- Mingyang Liu
- , Kun Wang
- & Kui Yu
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| Open AccessThree-dimensional crossbar arrays of self-rectifying Si/SiO2/Si memristors
Memristors are key structural units of complex memory and computing systems, yet most currently available memristors are based on materials that are not compatible with silicon technology. Here, the authors demonstrate a CMOS-compatible, self-rectifying memristor and arrays entirely based on p-Si/SiO2/n-Si.
- Can Li
- , Lili Han
- & Qiangfei Xia
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| Open AccessRapid visualization of grain boundaries in monolayer MoS2 by multiphoton microscopy
Atomically thin transition metal dichalcogenides can be grown on large scale using chemical vapour deposition which, however, determines presence of grain boundaries. Here, the authors report that third-harmonic generation imaging provides excellent sensitivity and fast speed for grain boundary visualization in MoS2.
- Lasse Karvonen
- , Antti Säynätjoki
- & Zhipei Sun
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| Open AccessLight-driven liquid metal nanotransformers for biomedical theranostics
Liquid metals are excellent candidate materials for biomedicine, owing to their intriguing optical properties and chemical stability. Here, the authors design multifunctional theranostic liquid metal nanocapsules that, upon irradiation, generate heat and reactive oxygen species and change shape to release drugs.
- Svetlana A. Chechetka
- , Yue Yu
- & Eijiro Miyako
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| Open AccessGiant electron-hole transport asymmetry in ultra-short quantum transistors
By utilizing electron-hole asymmetry in ultra-short single-walled carbon nanotube (SWCNT) transistors, McRaeet al., develop ‘two-in-one’ SWCNT quantum devices that can switch from behaving as quantum-dot transistors for holes to quantum buses for electrons by changing the transistor’s gate voltage
- A. C. McRae
- , V. Tayari
- & A. R. Champagne
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| Open AccessReal-time visualization of clustering and intracellular transport of gold nanoparticles by correlative imaging
The interaction of nanoparticles intracellularly has been investigated widely but the mechanisms of such interactions are not fully understood. Here, the authors utilize a semi-quantitative technique to assess the intracellular transportation and clustering potential of nanoparticles in real-time.
- Mengmeng Liu
- , Qian Li
- & Chunhai Fan
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| Open AccessOligolysine-based coating protects DNA nanostructures from low-salt denaturation and nuclease degradation
The instability of DNA nanostructures in physiological environments has hampered their use as therapeutics and diagnostic agents inin vivoapplications. Here, the authors show that coating DNA origami with oligolysine-PEG moieties improves their pharmacokinetic properties in mouse models.
- Nandhini Ponnuswamy
- , Maartje M. C. Bastings
- & William M. Shih
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| Open AccessAnapole nanolasers for mode-locking and ultrafast pulse generation
Here, the authors introduce the concept of nanocscale lasers based on a tightly confined anapole mode. Using first-principle calculations they show that the superposition of internal modes can generate radiation-less states that are scattering free, potentially overcoming the limitations of conventional nanolasers.
- Juan S. Totero Gongora
- , Andrey E. Miroshnichenko
- & Andrea Fratalocchi
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| Open AccessRapid mass production of two-dimensional metal oxides and hydroxides via the molten salts method
2D materials with exotic electronic properties are increasingly important for the development of low-dimensional electronic devices. Here, Huet al. have developed a fast and efficient method to synthesize 2D metal oxides and hydroxides, further enabling 2D electronics.
- Zhimi Hu
- , Xu Xiao
- & Jun Zhou
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| Open AccessUltrafast coherence transfer in DNA-templated silver nanoclusters
DNA-templated silver nanoclusters possess desirable optical properties, but their excited state dynamics remain poorly understood. Here the authors show that intracluster relaxations in such clusters are strongly coupled to a vibrational mode, resulting in ultrafast concerted transfer of population and coherence between excited states.
- Erling Thyrhaug
- , Sidsel Ammitzbøll Bogh
- & Donatas Zigmantas
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| Open AccessDirect observation of coherent energy transfer in nonlinear micromechanical oscillators
Energy drain on micromechanical resonators is always compensated by energy gain from external sources during operation. Here, Chenet al. show a strategy that can sustain stable oscillations by redistributing mechanical energy between coupled vibrational modes when the external energy supply is off.
- Changyao Chen
- , Damián H. Zanette
- & Daniel López
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| Open AccessScalable focused ion beam creation of nearly lifetime-limited single quantum emitters in diamond nanostructures
Interfacing spin quantum memories with photons requires the controlled creation of defect centre—nanocavity systems. Here the authors demonstrate direct, maskless creation of single silicon vacancy centres in diamond nanostructures, and report linewidths comparable to naturally occurring centres
- Tim Schröder
- , Matthew E. Trusheim
- & Dirk Englund
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| Open AccessIn situ dynamic tracking of heterogeneous nanocatalytic processes by shell-isolated nanoparticle-enhanced Raman spectroscopy
Rational design of heterogeneous catalysts requires molecular understanding of catalytic processes. Here, the authors attach PtFe and Pd nanocatalysts to Raman signal-enhancing Au-silica nanoparticles, allowing them to spectroscopically observe the active species and bonds involved in CO oxidation in real time.
- Hua Zhang
- , Chen Wang
- & Zhong-Qun Tian
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| Open AccessLong-term mutual phase locking of picosecond pulse pairs generated by a semiconductor nanowire laser
Although nanolasers have been an active field of research for over a decade, mode-locking on the nanoscale has not been achieved yet. Here, Mayeret al. show that semiconductor nanowire lasers can emit pairs of phase-locked picosecond pulses when the nanowires are incoherently pumped.
- B. Mayer
- , A. Regler
- & J. J. Finley
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| Open AccessDeterministic strain-induced arrays of quantum emitters in a two-dimensional semiconductor
The emergence of quantum emitters in 2D materials has led to the quest for methods and designs enabling their controllable spatial positioning. Here, the authors use strain engineering to fabricate a deterministic array of quantum emitters in WSe2with nanometre positioning accuracy.
- Artur Branny
- , Santosh Kumar
- & Brian D Gerardot
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| Open AccessInterface-driven formation of a two-dimensional dodecagonal fullerene quasicrystal
Quasicrystals promise exciting technological advances in optical devices, but their formation mechanism is yet not fully understood. Here, the authors describe a two-dimensional dodecagonal fullerene quasicrystal, forming on a Pt3Ti(111)-surface due to the complex adsorption-energy landscape.
- M. Paßens
- , V. Caciuc
- & S. Karthäuser
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| Open AccessSingle-molecule detection of dihydroazulene photo-thermal reaction using break junction technique
The conductance across single-molecule junctions is highly dependent on the electronic properties of the molecule in question. Here the authors use this fact to monitor a photo-thermal reaction by analysing break junction data, and observe significant differences compared to solution state behaviour.
- Cancan Huang
- , Martyn Jevric
- & Wenjing Hong
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| Open AccessLong-range ferrimagnetic order in a two-dimensional supramolecular Kondo lattice
Long-range magnetic order hardly ever emerges in a two-dimensional system due to the competition of fundamental magnetic interactions. Here, Girovskyet al. directly observe a long-range ferrimagnetic order emerging in a two-dimensional supramolecular Kondo lattice.
- Jan Girovsky
- , Jan Nowakowski
- & Nirmalya Ballav
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| Open AccessAntiferromagnetic CuMnAs multi-level memory cell with microelectronic compatibility
Devices based on antiferromagnetic materials have advantages of robustness to external magnetic fields and the potential for ultrafast operation. Here the authors present a multilevel antiferromagnetic memory cell that can be operated using standard electronic interfaces.
- K. Olejník
- , V. Schuler
- & T. Jungwirth
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| Open AccessDual-stimuli responsive and reversibly activatable theranostic nanoprobe for precision tumor-targeting and fluorescence-guided photothermal therapy
A number of nanomaterials for dual diagnostic and therapeutic application have a number of limitations including poor signal-to-noise ratio. Here, the authors developed dual stimuli-responsive and reversibly activatable nanoprobes for tumour targeting and fluorescence-guided photothermal therapy.
- Xu Zhao
- , Cheng-Xiong Yang
- & Xiu-Ping Yan
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Article
| Open AccessArtificial local magnetic field inhomogeneity enhances T2 relaxivity
The signal detected in magnetic resonance imaging comes from the relaxation of proton nuclear magnetization. Here, Zhouet al. introduce magnetic field inhomogeneity as a parameter to design iron oxide nanoparticle clusters to enhance the relaxation rate of nearby protons, thereby increasing image contrast.
- Zijian Zhou
- , Rui Tian
- & Xiaoyuan Chen
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| Open AccessNanometric holograms based on a topological insulator material
Holograms generally need to be as thick as a wavelength of light to introduce the necessary optical phase shifts that create true three-dimensional images. Here, Yueet al. use a high-index topological insulator material to create a resonant optical cavity and thin holograms to the nanometre scale.
- Zengji Yue
- , Gaolei Xue
- & Min Gu
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| Open AccessHeat guiding and focusing using ballistic phonon transport in phononic nanostructures
Heat conduction at the nanoscale is unlike macroscopic diffusion and phonons can travel in straight lines without dissipation. Here Anufrievet al. show that heat conduction can be spatially directed in nanostructured silicon and exploit this effect to concentrate heat into a focal point.
- Roman Anufriev
- , Aymeric Ramiere
- & Masahiro Nomura
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| Open AccessElectrostatic melting in a single-molecule field-effect transistor with applications in genomic identification
DNA hybridization of two single-strands to form a double-stranded helix is widely used for genomic identification applications. Here, Vernicket al. record duplex formation of 20-mer oligonucleotide using a single-molecule field-effect transistor, where DNA kinetics is affected by electrostatic bias.
- Sefi Vernick
- , Scott M. Trocchia
- & Kenneth L. Shepard
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| Open AccessEquilibrium oxygen storage capacity of ultrathin CeO2-δ depends non-monotonically on large biaxial strain
The surface oxygen storage capacity is an important metric of catalytic activity, but its dependence on strain is not well characterized. Here, the authors show the surface oxygen nonstoichiometry in coherently strained CeO2-δ films increases non-monotonically with biaxial strain.
- Chirranjeevi Balaji Gopal
- , Max García-Melchor
- & William C. Chueh
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| Open AccessHigh conductance values in π-folded molecular junctions
Foldamers are synthetic oligomers that adopt folded conformations through non-covalent intramolecular interactions. Here, Cariniet al. describe a family of foldamers with a large number of anthracene units that are able to transport charge efficiently at the single-molecule level.
- Marco Carini
- , Marta P. Ruiz
- & Aurelio Mateo-Alonso
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| Open AccessOptical determination of crystal phase in semiconductor nanocrystals
Identifying crystallographic phases in solution is not possible with standard diffraction methods. Here, Limet al. demonstrate the in situidentification of cubic and hexagonal phases of cadmium selenide nanocrystals using optical methods based on first-principles electronic theory.
- Sung Jun Lim
- , André Schleife
- & Andrew M. Smith
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| Open AccessTuning colloidal quantum dot band edge positions through solution-phase surface chemistry modification
The band edge positions of semiconductors decide their optoelectronic properties. Here, the authors establish a simple ligand exchange strategy to tune the band edge positions of colloidal PbS semiconductor quantum dots, revealing clear relationships between surface chemistry and band edge position.
- Daniel M. Kroupa
- , Márton Vörös
- & Matthew C. Beard
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| Open AccessPower generator driven by Maxwell’s demon
The study of Maxwell's demon provides a link between information thermodynamics and modern electronics. Using integrated nanometer-scale transistors in a single electron box configuration, Chidaet al., demonstrate the extraction of electrical power by Maxwell’s demon.
- Kensaku Chida
- , Samarth Desai
- & Akira Fujiwara
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| Open AccessInjection and controlled motion of conducting domain walls in improper ferroelectric Cu-Cl boracite
Conducting ferroelectric domain walls constitute a new class of functional material, but to achieve site-specific injection and annihilation of such walls is challenging. Here, McQuaidet al. report site-specific injection of such walls in Cu3B7O13Cl created by local point-stress and controlled by electric field.
- Raymond G.P. McQuaid
- , Michael P. Campbell
- & J. Marty Gregg
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| Open AccessControlling photophysical properties of ultrasmall conjugated polymer nanoparticles through polymer chain packing
Synthesis of small conjugated polymer nanoparticles (Pdots) with bright and stable fluorescence is an active challenge. Here, the authors introduce a strategy to fabricate ultrasmall Pdots with high fluorescence intensity by using twisted, rather than planar, conjugated polymers, lending new insight into the molecular design of Pdots.
- Hubert Piwoński
- , Tsuyoshi Michinobu
- & Satoshi Habuchi
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| Open AccessAbsorptive pinhole collimators for ballistic Dirac fermions in graphene
Shaping and guiding the flow of ballistic electrons is at the core of electron optics; however in graphene this is hindered by chiral tunneling. Here, the authors experimentally demonstrate an electron collimator based on hBN-encapsulated ballistic graphene, capable of emitting narrow electron beams.
- Arthur W. Barnard
- , Alex Hughes
- & David Goldhaber-Gordon
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| Open AccessUnderwater Leidenfrost nanochemistry for creation of size-tailored zinc peroxide cancer nanotherapeutics
Water can function as a sustainable reactor for the synthesis of size-controlled, functional nanoparticles. Here, the authors introduce an underwater Leidenfrost synthesis that reproduces the dynamic chemistry of the deep ocean, in which anticancer therapeutic ZnO2nanoclusters form in an overheated zone and migrate to colder water to continue growth.
- Mady Elbahri
- , Ramzy Abdelaziz
- & Moheb Abdelaziz
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| Open AccessReal-time atomistic observation of structural phase transformations in individual hafnia nanorods
The high-temperature tetragonal phase of HfO2 is technologically useful but difficult to stabilize at room temperature. Here, the authors observe in real-time the transformation of a HfO2nanorod from its room temperature to tetragonal phase, at 1000° less than its bulk temperature, suggesting that size confinement may kinetically trap this phase.
- Bethany M. Hudak
- , Sean W. Depner
- & Beth S. Guiton
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| Open AccessLipoprotein-biomimetic nanostructure enables efficient targeting delivery of siRNA to Ras-activated glioblastoma cells via macropinocytosis
Drug delivery in brain tumours is still a significant clinical concern. In this study, the authors develop a biomimetic lipoprotein nanoparticle for the efficient delivery of ATF5 siRNA inRas-activated brain cancer cells, where the nanoparticle is internalized by macropinocytosis in a Ras-dependent manner.
- Jia-Lin Huang
- , Gan Jiang
- & Xiao-Ling Gao
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| Open AccessScalable and efficient separation of hydrogen isotopes using graphene-based electrochemical pumping
Thousands of tons of water are processed every year for hydrogen isotope separation, using extremely costly technology. Here the authors demonstrate a fully-scalable graphene electrochemical pump, which promises to dramatically reduce the energy and capital costs.
- M. Lozada-Hidalgo
- , S. Zhang
- & A. K. Geim
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| Open AccessRETRACTED ARTICLE: Precise determination of graphene functionalization by in situ Raman spectroscopy
Raman spectroscopy is a versatile tool to gain insight into the functionalization of graphene-based materials, yet unequivocal assignment of the vibrational modes associated with covalent binding has so far remained elusive. Here, the authors succeed in an experimental and theoretical identification of this molecular fingerprint.
- Philipp Vecera
- , Julio C. Chacón-Torres
- & Andreas Hirsch
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| Open AccessAntibody-powered nucleic acid release using a DNA-based nanomachine
Responsive molecular machines can perform specific tasks triggered by environmental or chemical stimuli. Here, the authors show that antibodies can be used as inputs to modulate the binding of a molecular cargo to a designed DNA-based nanomachine, with potential applications in diagnostics and drug delivery.
- Simona Ranallo
- , Carl Prévost-Tremblay
- & Francesco Ricci
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| Open AccessQuantum-circuit refrigerator
Efficient on-demand cooling of the functional degrees of freedom in solid-state implementations of quantum information processing devices remains a challenge. Here the authors demonstrate direct cooling of a photonic mode of a superconducting resonator using voltage-controllable electron tunnelling.
- Kuan Yen Tan
- , Matti Partanen
- & Mikko Möttönen
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| Open AccessHighly selective covalent organic functionalization of epitaxial graphene
Organic functionalization is key to the development of graphene-based functional composites, yet selective covalent functionalization is hindered by graphene chemical inertness. Here, the authors demonstrate a versatile route to graphene covalent bonding with amino-terminated organic molecules.
- Rebeca A. Bueno
- , José I. Martínez
- & José A. Martín-Gago
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| Open AccessFabrication of MoSe2 nanoribbons via an unusual morphological phase transition
The unique electronic properties of two-dimensional materials are determined not only by their shape, but also the precise atomic arrangement of atoms along edges. Here, Chenet al. have developed a bottom-up epitaxial growth of MoSe2nanoribbons that controls both geometry and edge states.
- Yuxuan Chen
- , Ping Cui
- & Chih-Kang Shih
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| Open AccessProbing nanoscale oxygen ion motion in memristive systems
Ion transport in solid-state materials is a fundamental process for many modern technologies. Utilizing electrostatic force microscopy, Yanget al. directly visualize ion motion and verify the oxygen ion dynamics within HfO2—a common metal-oxide based memristive material.
- Yuchao Yang
- , Xiaoxian Zhang
- & Ru Huang
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| Open AccessMagnetotransport on the nano scale
Macroscopic magneto-transport measurements enable investigation of the transport properties of materials in the presence of magnetic fields, yet they do not allow access to atomic scale details. Here, the authors combine scanning tunneling potentiometry with magnetic fields to demonstrate nanoscale magneto-transport.
- Philip Willke
- , Thomas Kotzott
- & Martin Wenderoth
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| Open AccessCoulomb engineering of the bandgap and excitons in two-dimensional materials
Electronic bandgap tuning in semiconductors enables key functionalities in solid-state devices. Here, the authors present a strategy to control the bandgap of atomically thin WS2 and WSe2semiconductors via manipulation of the surrounding dielectric environment rather than by modifications of the materials themselves.
- Archana Raja
- , Andrey Chaves
- & Alexey Chernikov