News & Views |
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News & Views |
One dislocation at a time
The direct observation of enhanced dislocation mobility in iron by in situ electron microscopy offers key insights and adds to the ongoing debate on the mechanisms of hydrogen embrittlement.
- Vasily Bulatov
- & Wei Cai
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News & Views |
Ultrafast push for counterintuitive spintronics
Current-inducing switching of magnetization is crucial for future magnetic data processing technologies, but switching it with speed and energy efficiency remains challenging. Using femtosecond optical pulses, instead of conventional charge currents, is found to make spintronics not only ultrafast but also counterintuitive.
- Dmytro Afanasiev
- & Alexey V. Kimel
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News & Views |
Writing above the bandgap
Above-bandgap, nanosecond laser pulses enable the localized in situ writing of spin defects in prefabricated nanophotonic cavities. The approach preserves defect and cavity mode properties, key requirements towards cavity–emitter coupling in quantum networks.
- Sridhar Majety
- & Marina Radulaski
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Research Briefing |
Polymer actuation using a Joule-heating-induced ferroelectric phase transition
The output mechanical energy densities of ferroelectric polymers remain orders of magnitude smaller than those of piezoelectric ceramics and crystals, limiting their applications in soft actuators. But polymer composites subject to an electro-thermally driven ferroelectric phase transition under low electric fields are now shown to have giant actuation strains and large energy densities.
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Article |
Electro-thermal actuation in percolative ferroelectric polymer nanocomposites
Piezoelectric actuators play a critical role in precision positioning devices; however, materials with high actuation strain and mechanical energy density are rare. Here a composite of poly(vinylidene fluoride) and TiO2 demonstrates superior performance in these metrics, with the ferroelectric transition driven by Joule heating.
- Yang Liu
- , Yao Zhou
- & Qing Wang
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Article |
Extreme phonon anharmonicity underpins superionic diffusion and ultralow thermal conductivity in argyrodite Ag8SnSe6
Superionic materials are of interest for solid-state batteries or thermoelectrics, yet a clear understanding of the atomistic mechanisms is lacking. Here it is shown that transverse acoustic phonons persist above the superionic transition in argyrodite Ag8SnSe6, and that the free-Se sublattice controls fast Ag cation diffusion.
- Qingyong Ren
- , Mayanak K. Gupta
- & Jie Ma
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News & Views |
Smoke in the MOF liquid
An ultra-microporous metal–organic framework glass foam shows outstanding gas sieving properties for challenging gas mixtures.
- Chinmoy Das
- & Sebastian Henke
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News & Views |
Unlocked sieving potential
A strategy of using a high ligand/metal ion concentration ratio eliminates lattice defects in polycrystalline zirconium metal–organic framework membranes, enhancing their molecular sieving performance.
- Jun Lu
- & Huanting Wang
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Article |
Eliminating lattice defects in metal–organic framework molecular-sieving membranes
MOF membranes can present exceptional molecular-sieving properties, but lattice defects arising from incomplete cluster coordination can hinder this. Here a strategy for the elimination of lattice defects by increasing the ligand to secondary building unit ratio is proposed and demonstrated.
- Guozhen Liu
- , Yanan Guo
- & Nanping Xu
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News & Views |
A catalyst for low-temperature CO2 activation
A low-valence carbon-doped ruthenium oxide-based catalytic material achieved a catalytic trinity of superior activity, selectivity and stability during the conversion of carbon dioxide into methane at low temperatures.
- Xin Zhang
- & Abhishek Dutta Chowdhury
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Article |
Low-oxidation-state Ru sites stabilized in carbon-doped RuO2 with low-temperature CO2 activation to yield methane
Activating CO2 to form methane is a potential strategy for energy decarbonization, but to activate CO2 typically requires high temperatures. Here a ruthenium oxycarbonate is presented that forms by carbon interstitial doping of RuO2, and this catalyst enables CO2 activation at 50 °C.
- Carmen Tébar-Soler
- , Vlad Martin-Diaconescu
- & Avelino Corma
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Article |
Real-space observation of ultraconfined in-plane anisotropic acoustic terahertz plasmon polaritons
Employing terahertz nanoscopy, we image highly confined, in-plane anisotropic acoustic terahertz plasmon polaritons in monoclinic Ag2Te platelets placed above a Au layer, verifying a linear dispersion and elliptical isofrequency contour in momentum space.
- S. Chen
- , P. L. Leng
- & R. Hillenbrand
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News & Views |
High-temperature superconductivity survives
In heavily hole-doped cuprates, superconductivity does not die by simply dissolving into a uniform metal due to the lack of pairing, but rather survives by shattering into nanoscale superconducting puddles.
- Yu He
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News & Views |
Flipping antiferromagnetism by light
Antiferromagnetism has a vanishing total magnetization and thus is extremely challenging to manipulate. Now, circularly polarized light is shown to efficiently detect, induce and switch a unique class of antiferromagnets.
- Youngjun Ahn
- & Liuyan Zhao
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Editorial |
Ferroelectrics forge forward
Ferroelectrics have already impacted scientific research and commercial applications, but they still show plenty of potential to surprise.
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News & Views |
Distinguishing atomic vibrations near point defects
Local vibrational modes at substitutional impurities in monolayer graphene are resolved with a sensitivity at the chemical bonding level, revealing the impacts of different chemical configurations and mass of impurity atoms on the defect-perturbed vibrational properties.
- Xingxu Yan
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Perspective |
Spherical ferroelectric solitons
Nanoscale ferroelectric topological solitons, such as polar bubbles, polar bubble skyrmions and hopfions, have garnered immense interest due to their emergent properties. This Perspective discusses how these structures form, advances in their study and how they can enable new devices and physics.
- Vivasha Govinden
- , Sergei Prokhorenko
- & Nagarajan Valanoor
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Perspective |
Lessons from hafnium dioxide-based ferroelectrics
The discovery of ferroelectric switching in ultrathin layers of hafnium dioxide has aroused significant interest for low-power non-volatile memory technologies. This Perspective discusses how lessons learned from hafnium dioxide-based ferroelectrics can be applied to other applications, and other binary oxides.
- Beatriz Noheda
- , Pavan Nukala
- & Mónica Acuautla
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Letter
| Open AccessProbing lithium mobility at a solid electrolyte surface
Understanding lithium dynamics in solid-state electrolytes used for Li-ion batteries can be challenging. Using nonlinear extreme-ultraviolet spectroscopies, a direct spectral signature of surface lithium ions showing a distinct blueshift relative to the bulk absorption spectra is observed in a prototypical solid-state electrolyte.
- Clarisse Woodahl
- , Sasawat Jamnuch
- & Michael Zuerch
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Letter |
Laser writing of spin defects in nanophotonic cavities
Using direct laser writing with a nanosecond pulsed laser operating at above-bandgap photon energies, we demonstrate the selective formation of spin defects in photonic crystal cavities in 4H-silicon carbide and their in situ characterization.
- Aaron M. Day
- , Jonathan R. Dietz
- & Evelyn L. Hu
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Article |
Imaging the strain evolution of a platinum nanoparticle under electrochemical control
Surface strain can be used in gas phase catalysis and electrocatalysis to control the binding energies of adsorbates on active sites, but in situ or operando strain measurements can be challenging. Coherent diffraction now allows strain inside individual Pt nanoparticles to be mapped and quantified under electrochemical control.
- Clément Atlan
- , Corentin Chatelier
- & Marie-Ingrid Richard
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Letter |
Compact spin-valley-locked perovskite emission
We report compact spin-valley-locked perovskite emitting metasurfaces where spin-dependent geometric phases are imparted into bound states in the continuum via Brillouin zone folding, simultaneously enabling chiral purity, directionality and large emission angles.
- Yang Chen
- , Jiangang Feng
- & Cheng-Wei Qiu
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Article |
Quantitative tests revealing hydrogen-enhanced dislocation motion in α-iron
Screw dislocations in α-iron move more easily in the presence of hydrogen, as evidenced by real-time imaging using quantitative transmission electron microscopy.
- Longchao Huang
- , Dengke Chen
- & Zhiwei Shan
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Article |
Layer-dependent correlated phases in WSe2/MoS2 moiré superlattice
The authors demonstrate electrical on/off switching of interlayer interactions in tungsten diselenide/molybdenum disulfide heterobilayers, the phase diagram of which contains layer-dependent correlated regions that reveal the role of strong correlations in interlayer exciton dynamics.
- Qinghai Tan
- , Abdullah Rasmita
- & Weibo Gao
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Article |
Tunable spin and valley excitations of correlated insulators in Γ-valley moiré bands
Electronic compressibility measurements of twisted double-bilayer WSe2 reveal correlated insulators with spin-polaron charged excitations, as well as close competition between moiré bands at Γ and K valleys.
- Benjamin A. Foutty
- , Jiachen Yu
- & Benjamin E. Feldman
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Article |
A soft co-crystalline solid electrolyte for lithium-ion batteries
Alternative solid electrolytes with enhanced thermal and chemical stability are key for advancing lithium batteries. A soft solid electrolyte with improved stability and ionic conductivity, overcoming several limitations of conventional materials, is now reported.
- Prabhat Prakash
- , Birane Fall
- & Michael J. Zdilla
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Article |
Tailoring planar slip to achieve pure metal-like ductility in body-centred-cubic multi-principal element alloys
This work shows that by designing appropriate alloying elements in a body-centred-cubic high-entropy alloy, local chemical order and lattice distortion can be tuned, which influences the evolution of planar-slip bands, realizing pure-metal-like tensile ductility at gigapascal yield strength.
- Liang Wang
- , Jun Ding
- & En Ma
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Article |
Covalent organic framework atropisomers with multiple gas-triggered structural flexibilities
Soft porous crystals combine high crystallinity with structural transformability, potentially enabling applications. Here, an atropisomeric covalent organic framework is reported, which demonstrates different structural transformations upon exposure to different gases.
- Chengjun Kang
- , Zhaoqiang Zhang
- & Dan Zhao
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Article |
High-efficiency stretchable light-emitting polymers from thermally activated delayed fluorescence
We synthesized stretchable electroluminescent polymers capable of reaching a near-unity theoretical quantum yield through thermally activated delayed fluorescence. Their polymers show 125% stretchability with 10% external quantum efficiency and demonstrate a fully stretchable organic light-emitting diode.
- Wei Liu
- , Cheng Zhang
- & Sihong Wang
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News & Views |
Atomic heteroepitaxy for topological superconductivity
Epitaxial topological heterostructures of (Bi,Sb)2Te3/graphene/gallium have been achieved using molecular-beam epitaxy, providing the opportunity to access Majorana zero modes in electrical transport when combined with van der Waals tunnel junctions.
- Faxian Xiu
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Article |
Observation of anti-damping spin–orbit torques generated by in-plane and out-of-plane spin polarizations in MnPd3
The authors address spin–orbit torques and magnetization switching in MnPd3/CoFeB hetrostructures.
- Mahendra DC
- , Ding-Fu Shao
- & Shan X. Wang
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News & Views |
A magnetic field for each electron
The arrangement of magnetic ions between layers of NbS2 affects it as though a giant magnetic field is applied in different directions for electrons moving with opposite velocities. This discovery goes beyond the reach of conventional magnets, and opens up the way to custom-made effective fields engineered to guide materials into new territory.
- Jasper van Wezel
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Research Briefing |
Revealing the origin of local atomic disorder in energy materials
Spectroscopic and structural measurements often give conflicting results about the role of disorder in determining the properties of energy materials. A hybrid neutron scattering technique is used to measure atomic correlations in time and space for cubic GeTe, revealing that anisotropic elastic interactions mimic disorder but the time-averaged structure is crystalline.
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News & Views |
Measuring the potential of zero charge
A second-harmonic generation approach enables the direct measurement of the potential of zero charge at electrochemical interfaces.
- Jan Rossmeisl
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News & Views |
Artificial neuron transmits chemical signals
An artificial neuron architecture based on antiambipolar organic electrochemical transistors shows responses to biological ions and neurotransmitters akin to real neurons with comparable speed. The soft and more biocompatible nature of organic semiconductors could enable applications in brain–machine interfaces and in vivo sensing.
- Shinya E. Chen
- , Rajiv Giridharagopal
- & David S. Ginger
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News & Views |
Tunnelling electrons locally ignite excitons
Using low-temperature scanning tunnelling microscopy on a MoSe2/few-layer graphene heterostructure enables localized exciton generation and mapping with atomic-scale spatial resolution.
- Libai Huang
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Letter |
Ambipolar charge-transfer graphene plasmonic cavities
Employing an oxidation-activated charge transfer strategy to oxidize transition-metal dichalcogenides into transition-metal oxides, the authors imprint plasmonic cavities with laterally abrupt doping profiles and nanoscale precision demonstrating plasmonic whispering-gallery resonators.
- Brian S. Y. Kim
- , Aaron J. Sternbach
- & D. N. Basov
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Article |
The role of the electrolyte in non-conjugated radical polymers for metal-free aqueous energy storage electrodes
Redox-active non-conjugated radical polymers are promising candidates for metal-free aqueous batteries but their energy storage mechanism in an aqueous environment remains unclear. The role of the electrolyte in such polymers for designing metal-free aqueous energy storage electrodes is now elucidated.
- Ting Ma
- , Cheng-Han Li
- & Jodie L. Lutkenhaus
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Article |
Resolving the polar interface of infinite-layer nickelate thin films
Nickelate superconductivity has so far been limited to thin films, raising questions about the role of the polar substrate–film interface. Here the authors utilize advanced characterization techniques to reveal the interfacial atomic structure and its relevance for superconductivity.
- Berit H. Goodge
- , Benjamin Geisler
- & Lena F. Kourkoutis
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Article |
Scalable manufacturing of high-index atomic layer–polymer hybrid metasurfaces for metaphotonics in the visible
The authors propose a method for the scalable manufacturing of metalenses using deep-ultraviolet argon fluoride immersion lithography and wafer-scale nanoimprint lithography, opening a route towards their low-cost, high-throughput mass production.
- Joohoon Kim
- , Junhwa Seong
- & Junsuk Rho
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Article |
Growth of single-crystal black phosphorus and its alloy films through sustained feedstock release
Subcentimetre-size black phosphorous and its alloy films have been achieved on conventional substrates through sustained feedstock release design, and exhibit high crystalline quality and composition-dependent bandgap tunability.
- Cheng Chen
- , Yuling Yin
- & Jun He
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Article |
Magnetic detection under high pressures using designed silicon vacancy centres in silicon carbide
Optically detected magnetic resonance of nitrogen vacancy centres in diamond enables the detection of pressure-induced phase transitions, but interpreting their magnetic resonance spectra remains challenging. Here the authors propose implanted silicon vacancy defects in 4H-SiC for in situ magnetic phase detection at high pressures.
- Jun-Feng Wang
- , Lin Liu
- & Guang-Can Guo
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Review Article |
Hydrogels for RNA delivery
RNA-based therapeutics hold promise for the treatment of several diseases. This Review provides an overview of hydrogels for RNA delivery, discussing how the chemical nature and physical properties of hydrogels can be explored for tailored RNA loading and release, and highlighting the use of these materials in biomedical applications.
- Ruibo Zhong
- , Sepehr Talebian
- & Jinjun Shi
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Review Article |
Coherent antiferromagnetic spintronics
This Review discusses the field of antiferromagnetic spintronics with a focus on coherent effects.
- Jiahao Han
- , Ran Cheng
- & Shunsuke Fukami
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Article |
Single-atom vibrational spectroscopy with chemical-bonding sensitivity
Vibrational spectroscopy now allows for the exploration of lattice vibrational properties at the chemical-bond level, revealing the impact of chemical-bonding configurations and atomic mass on local phonon modes in graphene with a new level of sensitivity.
- Mingquan Xu
- , De-Liang Bao
- & Wu Zhou
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Article |
Tip-induced excitonic luminescence nanoscopy of an atomically resolved van der Waals heterostructure
Tip-induced excitonic luminescence nanoscopy of an atomically resolved van der Waals heterostructure.
- Luis E. Parra López
- , Anna Rosławska
- & Guillaume Schull
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Letter |
Observation of a massive phason in a charge-density-wave insulator
We report the observation of narrowband terahertz emission from a quasi-one-dimensional charge-density-wave insulator, (TaSe4)2I. The origin of the emitted radiation is interpreted as a phason that obtains mass due to the long-range Coulomb interaction.
- Soyeun Kim
- , Yinchuan Lv
- & Fahad Mahmood
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Letter |
Single-crystalline van der Waals layered dielectric with high dielectric constant
Large-size single-crystal van der Waals layered Bi2SeO5 has been synthesized with a high dielectric constant and high breakdown field strength for two-dimensional electronics applications.
- Congcong Zhang
- , Teng Tu
- & Hailin Peng
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Article |
Axion optical induction of antiferromagnetic order
The authors demonstrate control of antiferromagnetic order using helical light.
- Jian-Xiang Qiu
- , Christian Tzschaschel
- & Su-Yang Xu