Inorganic chemistry

Inorganic chemistry is the study of the structure, properties and reactions of all chemical elements and compounds except for organic compounds (hydrocarbons and their derivatives).

Latest Research and Reviews

News and Comment

  • Comments and Opinion |

    Classical experiments from solid-state electrochemistry can be used to determine the charge of ions in solids. This Comment also clarifies how the charge of point defects fits with the standard picture of ionic charge, and highlights differences between these electrochemical experiments and methods that probe electrons directly.

    • Roger A. De Souza
    •  & David N. Mueller
  • Comments and Opinion
    | Open Access

    The activation of very inert small molecules generally requires highly reactive activating species, but the high energy of these species makes their regeneration, and thus also catalytic turnover of the reaction, difficult to achieve. Here, the authors highlight the formidable challenge of overcoming the tradeoff between activating power and catalytic turnover in the context of main-group ambiphiles.

    • Rian D. Dewhurst
    • , Marc-André Légaré
    •  & Holger Braunschweig
  • News and Views |

    White phosphorus is a prominent source of P atoms but has remained difficult to activate without using transition metals. Now, a bidentate ligand based on silicon(ii) donors has successfully stabilized a P2 moiety, and the resulting complex acts as a transfer reagent for P anions.

    • David Scheschkewitz
    Nature Chemistry 12, 785-787
  • Comments and Opinion
    | Open Access

    Water can form a vast number of topological frameworks owing to its hydrogen-bonding ability, with 19 different forms of ice experimentally confirmed at present. Here, the authors comment on open questions and possible future discoveries, covering negative to ultrahigh pressures.

    • Thomas Loerting
    • , Violeta Fuentes-Landete
    • , Christina M. Tonauer
    •  & Tobias M. Gasser