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| Open AccessThermoelectric coupling effect in BNT-BZT-xGaN pyroelectric ceramics for low-grade temperature-driven energy harvesting
Pyroelectric energy harvesting has received increasing attention due to its ability to convert low-grade waste heat into electricity. Here, authors report an enhanced thermoelectric coupling BNT-BZT-xGaN pyroelectric energy harvester by facilitating resonance vibration between Ga and Ti, O atoms.
- Meng Shen
- , Kun Liu
- & Kui Yao
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Article
| Open AccessMolecular imprinting-based indirect fluorescence detection strategy implemented on paper chip for non-fluorescent microcystin
Fluorescence analysis is a fast and sensitive method for the trace detection of environmental toxins, but it remains challenging to develop a fluorescence method for detecting nonfluorescent toxins. Here, the authors report an indirect fluorescent sensing strategy for the rapid, selective and sensitive detection of the non-fluorescent microcystin as a model target.
- Bowei Li
- , Ji Qi
- & Lingxin Chen
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Article
| Open AccessMass spectrometry imaging for biosolids characterization to assess ecological or health risks before reuse
Mass spectrometry imaging is a suitable tool for the analysis of non-cohesive materials. Here, authors show that it can be used to detect persistent organic pollutants (POPs) and heavy metals (HMs) in biosolids using small amounts of material with speed and safety.
- Claire Villette
- , Loïc Maurer
- & Dimitri Heintz
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| Open AccessIndustrial source identification of polyhalogenated carbazoles and preliminary assessment of their global emissions
Recognition on sources of polyhalogenated carbazoles is needed to understand their environmental accumulation. Here, release of polyhalogenated carbazoles from 13 industries including 122 plants is identified and estimated.
- Yuxiang Sun
- , Lili Yang
- & Guorui Liu
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Article
| Open AccessTriboelectric-induced ion mobility for artificial intelligence-enhanced mid-infrared gas spectroscopy
Isopropyl alcohol can play a significant role in anti-virus diagnosis but generally yields limited response in conventional detection. Here, authors propose a methodology of AI-enhanced ion mobility and mid-infrared spectroscopy for accurate gas identification despite presence different carbon-based gases.
- Jianxiong Zhu
- , Shanling Ji
- & Chengkuo Lee
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| Open AccessPredictability of fossil fuel CO2 from air quality emissions
The historical changes in country emissions of greenhouse gases and air quality pollutants are classified together as a function of economic development, providing valuable guidance to emission scenario development.
- Kazuyuki Miyazaki
- & Kevin Bowman
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Article
| Open AccessEmissions and fate of organophosphate esters in outdoor urban environments
The authors show how city design and climate both influence the release of chemicals to the world, and suggest that we can help reduce impacts on people and ecosystems by reducing emissions and using green space to trap and degrade chemicals.
- Timothy F. M. Rodgers
- , Amanda Giang
- & Amandeep Saini
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Article
| Open AccessDeficiency and excess of groundwater iodine and their health associations
Both iodine deficiency and excess could cause thyroid disorders. By creating a national map of groundwater iodine throughout China, the authors reveal the spatial responses of diverse health risks to iodine in continental groundwater.
- Ruoqi Ma
- , Mingquan Yan
- & Jinren Ni
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| Open AccessHigh activity and selectivity of single palladium atom for oxygen hydrogenation to H2O2
Nanosized Pd-based catalysts are widely used in the direct hydrogen peroxide (H2O2) synthesis from H2 and O2, while the selectivity and yield of H2O2 remain inferior. Here, a remarkable H2O2 yield of 115 mol/gPd/h and H2O2 selectivity higher than 99% are reported using a Pd single-atom catalyst for the direct synthesis of H2O2.
- Shiming Yu
- , Xing Cheng
- & Ge Chen
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Article
| Open AccessGlobal analysis and prediction of fluoride in groundwater
A global fluoride hazard prediction map was created using machine learning and over 400,000 fluoride measurements, this shows ~180 million people are potentially affected by chronic fluoride exposure worldwide, mostly in Asia and Africa.
- Joel Podgorski
- & Michael Berg
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Article
| Open AccessNext-generation biomonitoring of the early-life chemical exposome in neonatal and infant development
Exposure to synthetic and natural toxicants is a major risk factor in the etiology of disease. Here, authors describe the development of a method to quantify >80 xenobiotics and apply it to assess early-life exposure in vulnerable infants.
- Thomas Jamnik
- , Mira Flasch
- & Benedikt Warth
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Article
| Open AccessHost-guest liquid gating mechanism with specific recognition interface behavior for universal quantitative chemical detection
In field, visual, chemical detection is of use for a wide range of possible applications. Here, the authors report on the creation of a host-guest liquid gating mechanism where detection of the target host triggers gate opening allowing for gas through the liquid gate, which can be used for visual detection.
- Huimeng Wang
- , Yi Fan
- & Xu Hou
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Article
| Open AccessThe world-wide waste web
The 2001–2019 web of international waste trade is investigated, allowing the identification of countries at threat of improper handling and disposal of waste. Chemical tracers are used to identify the environmental impact of waste in these countries.
- Johann H. Martínez
- , Sergi Romero
- & Ernesto Estrada
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Article
| Open AccessSingle amino acid bionanozyme for environmental remediation
In the context of enviromental applications, refining enzymes into more minimalist structures could ease production costs, improve stability, and improve reusability. Here, the authors report a single amino acid bionanozyme that can catalyze the rapid oxidation of environmentally toxic phenolic contaminates and serves as a tool to detect biologically important neurotransmitters similar to the laccase enzyme.
- Pandeeswar Makam
- , Sharma S. R. K. C. Yamijala
- & Ehud Gazit
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Article
| Open AccessAmazon forests capture high levels of atmospheric mercury pollution from artisanal gold mining
The Peruvian Amazon is facing the highest known input of mercury pollution of any ecosystem globally. Intact forests located near artisanal gold mining are particularly at risk from this toxin.
- Jacqueline R. Gerson
- , Natalie Szponar
- & Emily S. Bernhardt
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Article
| Open AccessVisible colorimetric dosimetry of UV and ionizing radiations by a dual-module photochromic nanocluster
Radiation dosimeters that measure ionizing radiations over a broad range and allow for direct readout are desirable. Here, the authors present a dual-mode photochromic thorium-based metal-organic nanocluster that enables direct visible colorimetric dosimetry of UV, β-ray, and γ-ray radiation.
- Huangjie Lu
- , Jian Xie
- & Jian Lin
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| Open AccessLocal and global trace plutonium contributions in fast breeder legacy soils
This study proposes a method to differentiate between local plutonium-based contamination in soils versus trace plutonium stemming from global dispersion in the past, such as fallout from detonation and atmospheric testing of nuclear weapons.
- Chris Tighe
- , Maxi Castrillejo
- & Malcolm J. Joyce
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Article
| Open AccessParticle number-based trophic transfer of gold nanomaterials in an aquatic food chain
Biological fate of nanomaterials in organisms is an important topic, however, limitations of analytical techniques has hampered understanding. Here, the authors report on a study into the fate of model, gold nanoparticles in an aquatic food chain using an analytical workflow and range of analytical methods.
- Fazel Abdolahpur Monikh
- , Latifeh Chupani
- & Willie J.G.M. Peijnenburg
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Article
| Open AccessPervasive distribution of polyester fibres in the Arctic Ocean is driven by Atlantic inputs
Microplastics have spread across the globe and reached even the most remote locations, but an understanding of their origins remains largely elusive. Here the authors quantify and characterise microplastics across the North Pole, finding that synthetic fibers like polyester are dominant and likely sourced from the Atlantic Ocean.
- Peter S. Ross
- , Stephen Chastain
- & Bill Williams
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Article
| Open AccessMethane emissions from natural gas vehicles in China
The methane emissions from natural gas vehicles (NGVs) are unclear. Here the authors report high methane emissions from heavy-duty NGVs, and by using a scenario analysis show that strictly implementing the upcoming China VI standard could reduce GHG emissions by 509 Mt CO2eq for 2020-2030.
- Da Pan
- , Lei Tao
- & Mark A. Zondlo
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| Open AccessFast sulfate formation from oxidation of SO2 by NO2 and HONO observed in Beijing haze
How sulfur dioxide emitted through coal combustion is oxidized to sulfate particles during winter haze pollution events has been the subject of debate. Here, the authors show that rapid oxidation takes place by nitrogen dioxide and nitrous acid, producing nitrous oxide together with sulfate.
- Junfeng Wang
- , Jingyi Li
- & Daniel J. Jacob
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| Open AccessThe Red Sea Deep Water is a potent source of atmospheric ethane and propane
The Middle East is known to emit large amounts of non-methane hydrocarbon pollutants to the atmosphere, but the sources are poorly characterized. Here the authors discover a new source—deep water in the Red Sea—and calculate that its emissions exceed rates of several high gas-production countries.
- E. Bourtsoukidis
- , A. Pozzer
- & J. Williams
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| Open AccessFluorinated MOF platform for selective removal and sensing of SO2 from flue gas and air
Removal of SO2 from flue gas is of prime importance to avoid its poisoning of CO2-seperating agents. Here, the authors demonstrate that two fluorinated metal–organic frameworks selectively remove SO2 from synthetic flue gas and can sense SO2 with p.p.m.-level detection using quartz crystal microbalance transducers.
- M. R. Tchalala
- , P. M. Bhatt
- & M. Eddaoudi
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| Open AccessGlobal distribution of particle phase state in atmospheric secondary organic aerosols
Secondary organic aerosols (SOA) are important for climate and aerosol quality, but the phase state is unclear. Here, the authors show that SOA is liquid in tropical and polar air, semi-solid in the mid-latitudes, solid over dry lands and in a glassy solid phase state in the middle and upper troposphere.
- Manabu Shiraiwa
- , Ying Li
- & Ulrich Pöschl
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Article
| Open AccessGABAergic anxiolytic drug in water increases migration behaviour in salmon
Fish migration is influenced by various environmental factors such as chemicals in water. Here, Hellstrom et al. show that an anxiolytic drug in the benzodiazepine family, oxazepam, can promote migratory behaviour of Atlantic salmon smolts in both laboratory setting and river tributary in Sweden.
- Gustav Hellström
- , Jonatan Klaminder
- & Tomas Brodin
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Article |
Photochemical reflectance index as an indirect estimator of foliar isoprenoid emissions at the ecosystem level
Isoprene and monoterpenes, emitted by terrestrial plants, have an important role in both plant biology and environment, but they are poorly quantified at the ecosystem level. Peñuelas et al.show that the photochemical reflectance index can be used to indirectly estimate foliar isoprenoid emissions remotely.
- Josep Peñuelas
- , Giovanni Marino
- & Iolanda Filella