Chemistry

  • Article | | open

    Simple, fast, and accurate detection of food freshness has great significance to food safety and business. Here, the authors develop cellulose-based ratiometric fluorescent materials with superior amine-response, which can be used for visual monitoring the freshness of shrimp and crab.

    • Ruonan Jia
    • , Weiguo Tian
    • , Haotian Bai
    • , Jinming Zhang
    • , Shu Wang
    •  & Jun Zhang
  • Article | | open

    Molecular motion has attracted a wide range of interest for different applications. Here, the authors develop nanoparticles with internal molecular motion upon near infrared absorption and use the nanoparticles for photoacoustic imaging and demonstrate this application in vivo.

    • Zheng Zhao
    • , Chao Chen
    • , Wenting Wu
    • , Fenfen Wang
    • , Lili Du
    • , Xiaoyan Zhang
    • , Yu Xiong
    • , Xuewen He
    • , Yuanjing Cai
    • , Ryan T. K. Kwok
    • , Jacky W. Y. Lam
    • , Xike Gao
    • , Pingchuan Sun
    • , David Lee Phillips
    • , Dan Ding
    •  & Ben Zhong Tang
  • Article | | open

    Membrane elongation is fundamental to autophagy and is controlled by an ubiquitin-conjugating cascade orchestrated by ATG16L1. Here, the authors identify that the E3 ligase Gigaxonin regulates autophagosome formation by controlling ATG16L1 turnover.

    • Aurora Scrivo
    • , Patrice Codogno
    •  & Pascale Bomont
  • Article | | open

    Large-scale deletions of mitochondrial DNA (mtDNA) are associated with different human mitochondrial diseases and normal human ageing. Here the authors present a model for mtDNA formation based on generation sequencing analysis of patients samples and in vitro reconstituted mtDNA deletion using purified proteins.

    • Örjan Persson
    • , Yazh Muthukumar
    • , Swaraj Basu
    • , Louise Jenninger
    • , Jay P. Uhler
    • , Anna-Karin Berglund
    • , Robert McFarland
    • , Robert W. Taylor
    • , Claes M. Gustafsson
    • , Erik Larsson
    •  & Maria Falkenberg
  • Article | | open

    The photofixation and utilization of CO2 is considered to be a clean and green way to produce high-value-added commodity chemicals, but production of long chain chemicals through this process remains a challenge. Here, the authors develop a practical way for the photofixation of CO2 to long-chain chemicals via defect engineering.

    • Shichuan Chen
    • , Hui Wang
    • , Zhixiong Kang
    • , Sen Jin
    • , Xiaodong Zhang
    • , Xusheng Zheng
    • , Zeming Qi
    • , Junfa Zhu
    • , Bicai Pan
    •  & Yi Xie
  • Article | | open

    Investigation of a reaction scope usually starts with the optimization for a model substrate. Here, the authors apply a time-efficient multi-substrate screening approach to identify a general organocatalyst for the Diels–Alder reaction of cyclopentadiene with α,β-unsaturated aldehydes.

    • Hyejin Kim
    • , Gabriela Gerosa
    • , Jonas Aronow
    • , Pinar Kasaplar
    • , Jie Ouyang
    • , Julia B. Lingnau
    • , Paul Guerry
    • , Christophe Farès
    •  & Benjamin List
  • Article | | open

    Defect tolerance is important in order to ensure the mechanical integrity of synthetic materials and biological tissues. Here the authors demonstrate that toughening mechanisms provide soft collagenous tissues with high defect tolerance, with important implications for biomedical applications.

    • Kevin Bircher
    • , Manuel Zündel
    • , Marco Pensalfini
    • , Alexander E. Ehret
    •  & Edoardo Mazza
  • Article | | open

    SecB homologs can be associated with stress-responsive type II toxin–antitoxin (TA) systems and form tripartite toxin-antitoxin-chaperone systems (TAC). Here the authors provide structural insights into TACs by presenting the crystal structure of the M. tuberculosis TA-associated SecB chaperone in complex with the C-terminal ChAD (chaperone addiction) extension of the antitoxin HigA1.

    • Valérie Guillet
    • , Patricia Bordes
    • , Cécile Bon
    • , Julien Marcoux
    • , Virginie Gervais
    • , Ambre Julie Sala
    • , Suzana Dos Reis
    • , Nawel Slama
    • , Israel Mares-Mejía
    • , Anne-Marie Cirinesi
    • , Laurent Maveyraud
    • , Pierre Genevaux
    •  & Lionel Mourey
  • Article | | open

    Serine/threonine phosphatases such as PP1 associate with a large array of subunit proteins, such as ASPP (apoptosis-stimulating protein of p53) to achieve selective targeting. Here authors solved the crystal structure of the human ASPP2/PP1 complex and explain how ASPP2 can distinguish between PP1 isoforms.

    • M. Teresa Bertran
    • , Stéphane Mouilleron
    • , Yanxiang Zhou
    • , Rakhi Bajaj
    • , Federico Uliana
    • , Ganesan Senthil Kumar
    • , Audrey van Drogen
    • , Rebecca Lee
    • , Jennifer J. Banerjee
    • , Simon Hauri
    • , Nicola O’Reilly
    • , Matthias Gstaiger
    • , Rebecca Page
    • , Wolfgang Peti
    •  & Nicolas Tapon
  • Article | | open

    The amount of carbon stored in closed hidden reservoirs is unknown. Here the authors use a computational approach to study the evolution of carbon species and observe polymerization of carbon atoms at high pressures, illustrating the potential for a significant carbon reservoir in the Earth’s deep interior.

    • Natalia V. Solomatova
    • , Razvan Caracas
    •  & Craig E. Manning
  • Article | | open

    The fusion peptide (FP) of HIV envelope (Env) is critical in the cell entry process. Here, Kumar et al. present crystal structures of B41 SOSIP.664 Env trimer and show the dynamic nature of the FP and proximal region, which likely relates to conformational rearrangements required for membrane fusion.

    • Sonu Kumar
    • , Anita Sarkar
    • , Pavel Pugach
    • , Rogier W. Sanders
    • , John P. Moore
    • , Andrew B. Ward
    •  & Ian A. Wilson
  • Article | | open

    Objects with varied mechanical properties can be produced by additive manufacturing, but multimaterial control along all three axes of printing is still limited. Here the authors use wavelength control during vat polymerization and demonstrate printing of objects with spatial control of the composition and stiffness.

    • J. J. Schwartz
    •  & A. J. Boydston
  • Article | | open

    Organic cocrystals have interesting properties owing to synergistic effects of the individual components but development of effective growth methods for molecular cocrystals is still in its primary stage. Here the authors demonstrate a sublimation method which allows growing organic cocrystals with controlled morphology.

    • Xin Ye
    • , Yang Liu
    • , Qing Guo
    • , Quanxiang Han
    • , Chao Ge
    • , Shuangyue Cui
    • , Leilei Zhang
    •  & Xutang Tao
  • Article | | open

    Perylenediimide (PDI) radical anions show promise as photothermal agents for phototherapy, but are typically very unstable. Here the authors fabricate a PDI-based metal-organic framework where the PDI units become stable radical anions upon incorporation of amine vapors.

    • Baozhong Lü
    • , Yifa Chen
    • , Pengyu Li
    • , Bo Wang
    • , Klaus Müllen
    •  & Meizhen Yin
  • Article | | open

    Rydberg atoms can be created from photoexcitation of molecules using intense ultrafast laser pulses. Here the authors use a coincidence detection of electrons, ion and excited Rydberg atoms and their energy sharing to reveal the general mechanism of Rydberg state excitation in a dissociating H2 molecule.

    • Wenbin Zhang
    • , Xiaochun Gong
    • , Hui Li
    • , Peifen Lu
    • , Fenghao Sun
    • , Qinying Ji
    • , Kang Lin
    • , Junyang Ma
    • , Hanxiao Li
    • , Junjie Qiang
    • , Feng He
    •  & Jian Wu
  • Article | | open

    To realize efficient optoelectronic devices based on two-dimensional (2D) organic crystals, optimizing the photoelectrical response and growth of these materials at the 2D limit is vital. Here, the authors report enhanced internal photoresponse in large-area 2D crystals using a novel growth method.

    • Min Cao
    • , Cong Zhang
    • , Zhi Cai
    • , Chengcheng Xiao
    • , Xiaosong Chen
    • , Kongyang Yi
    • , Yingguo Yang
    • , Yunhao Lu
    •  & Dacheng Wei
  • Article | | open

    Coccolithophores are one of the most abundant phytoplankton and calcifying organisms, well-known to produce intricate calcareous exoskeletons made of coccoliths. Here the authors show, by using X-ray nanotomography, the dependence of the grid size on the calcite nucleation site number and on the mass of coccoliths.

    • T. Beuvier
    • , I. Probert
    • , L. Beaufort
    • , B. Suchéras-Marx
    • , Y. Chushkin
    • , F. Zontone
    •  & A. Gibaud
  • Article | | open

    It is unclear whether CO2-stimulation of photosynthesis can propagate through slower ecosystem processes and lead to long-term increases in terrestrial carbon. Here the authors show that CO2-stimulation of photosynthesis leads to a 30% increase in forest regrowth over a decade of CO2 enrichment.

    • Anthony P. Walker
    • , Martin G. De Kauwe
    • , Belinda E. Medlyn
    • , Sönke Zaehle
    • , Colleen M. Iversen
    • , Shinichi Asao
    • , Bertrand Guenet
    • , Anna Harper
    • , Thomas Hickler
    • , Bruce A. Hungate
    • , Atul K. Jain
    • , Yiqi Luo
    • , Xingjie Lu
    • , Meng Lu
    • , Kristina Luus
    • , J. Patrick Megonigal
    • , Ram Oren
    • , Edmund Ryan
    • , Shijie Shu
    • , Alan Talhelm
    • , Ying-Ping Wang
    • , Jeffrey M. Warren
    • , Christian Werner
    • , Jianyang Xia
    • , Bai Yang
    • , Donald R. Zak
    •  & Richard J. Norby
  • Article | | open

    Adenovirus based (AdV) vectors are promising platforms for therapeutics and vaccines, but receptor usage of serotypes in clinical development remains unclear. Here, based on crystal structures and modeling, Baker et al. show that HAdV-D26/48 fiber knob protein interacts weakly with CAR but not with CD46 or DSG2.

    • Alexander T. Baker
    • , Alexander Greenshields-Watson
    • , Lynda Coughlan
    • , James A. Davies
    • , Hanni Uusi-Kerttula
    • , David K. Cole
    • , Pierre J. Rizkallah
    •  & Alan L. Parker
  • Article | | open

    Historical and future trends in net primary productivity (NPP) and its sensitivity to global change are largely unknown because of the lack of long-term, high-resolution data. Here the authors show that tree-ring isotopes can be used for inferring interannual variability and long-term changes in NPP.

    • Mathieu Levesque
    • , Laia Andreu-Hayles
    • , William Kolby Smith
    • , A. Park Williams
    • , Martina L. Hobi
    • , Brady W. Allred
    •  & Neil Pederson
  • Article | | open

    New photoluminescent strategies are required to realize high-performance ratiometric sensors for bio-sensing applications. Here, the authors demonstrate a fluorescence-thermally activated delayed fluorescence dual emission strategy for ratiometric sensors with high precision.

    • Xuping Li
    • , Gleb Baryshnikov
    • , Chao Deng
    • , Xiaoyan Bao
    • , Bin Wu
    • , Yunyun Zhou
    • , Hans Ågren
    •  & Liangliang Zhu
  • Article | | open

    Though designing conductive polymers for memory devices is attractive for future low-cost flexible electronics, a proof-of-concept device has yet to be realized. Here, the authors report a redox-gated polymer memristive processing unit with programmable multilevel storage and logic functionalities.

    • Bin Zhang
    • , Fei Fan
    • , Wuhong Xue
    • , Gang Liu
    • , Yubin Fu
    • , Xiaodong Zhuang
    • , Xiao-Hong Xu
    • , Junwei Gu
    • , Run-Wei Li
    •  & Yu Chen
  • Article | | open

    Quaternary contacts mediated by an extended heavy-chain framework region 3 (FR3) have been shown to improve binding to HIV envelope and virus neutralization for a few antibodies. Here, Liu et al. engraft such an FR3 loop onto several potent broadly neutralizing antibodies, resulting in improved neutralization activity and pharmacokinetics.

    • Qingbo Liu
    • , Yen-Ting Lai
    • , Peng Zhang
    • , Mark K. Louder
    • , Amarendra Pegu
    • , Reda Rawi
    • , Mangaiarkarasi Asokan
    • , Xuejun Chen
    • , Chen-Hsiang Shen
    • , Gwo-Yu Chuang
    • , Eun Sung Yang
    • , Huiyi Miao
    • , Yuge Wang
    • , Anthony S. Fauci
    • , Peter D. Kwong
    • , John R. Mascola
    •  & Paolo Lusso
  • Article | | open

    Abandoned and degraded agricultural lands undergo ecological succession that sequesters atmospheric CO2 as soil carbon, but at low rates. Here the authors show that restoration of high plant diversity provides a greenhouse gas benefit by greatly increasing the rate of soil carbon sequestration on such lands.

    • Yi Yang
    • , David Tilman
    • , George Furey
    •  & Clarence Lehman
  • Article | | open

    Finding new thermoelectric materials that can achieve high performance is vital to realizing the potential of future energy harvesting technology. Here, through computation methods, the authors identify two high-performance full-Heusler thermoelectric compounds with high intrinsic band degeneracy.

    • Jiangang He
    • , Yi Xia
    • , S. Shahab Naghavi
    • , Vidvuds Ozoliņš
    •  & Chris Wolverton
  • Article | | open

    No structural data have been available for RNA polymerase holoenzymes or transcription initiation complexes that contain extracytoplasmic σ factors. Here the authors report the crystal structures of transcription initiation complexes comprising Mycobacterium tuberculosis RNA polymerase, extracytoplasmic σ factor σL and promoter DNA.

    • Wei Lin
    • , Sukhendu Mandal
    • , David Degen
    • , Min Sung Cho
    • , Yu Feng
    • , Kalyan Das
    •  & Richard H. Ebright
  • Article | | open

    1T’ phases of transition metal dichalcogenides show promise for electrocatalysis, energy storage, and spintronic applications but are difficult to obtain. Here the authors synthesize 1T’ WSe2 few-layered nanosheets by kinetically-controlled colloidal synthesis, and test their electrocatalytic activity.

    • Maria S. Sokolikova
    • , Peter C. Sherrell
    • , Pawel Palczynski
    • , Victoria L. Bemmer
    •  & Cecilia Mattevi
  • Article | | open

    Oxidation of magnetite has broad implications in geochemistry and environmental science, but its reaction mechanisms are not fully understood yet. Here the authors use Bragg coherent diffractive imaging to show oxidative dissolution of magnetite inducing a rich array of strain and defect structures.

    • Ke Yuan
    • , Sang Soo Lee
    • , Wonsuk Cha
    • , Andrew Ulvestad
    • , Hyunjung Kim
    • , Bektur Abdilla
    • , Neil C. Sturchio
    •  & Paul Fenter
  • Article | | open

    The antitermination factor RfaH adopts two functional states where its C-terminal domain is folded either as an α-helical hairpin or β-barrel. Here the authors employ solution state NMR measurements to show that the C-terminal domain transforms into the β-barrel only upon binding to the elongation complex and refolds back after dissociation.

    • Philipp Konrad Zuber
    • , Kristian Schweimer
    • , Paul Rösch
    • , Irina Artsimovitch
    •  & Stefan H. Knauer
  • Article | | open

    Ubiquitination may control protein stability or function. Here the authors show that an ubiquitination enzyme, Hectd3, ubiquitinates Stat3 and Malt1 to modulate their function but not degradation in T cells, and thereby promoting the differentiation of pathogenic Th17 cells and susceptibility to a mouse model of multiple sclerosis.

    • Jonathan J. Cho
    • , Zhiwei Xu
    • , Upasana Parthasarathy
    • , Theodore T. Drashansky
    • , Eric Y. Helm
    • , Ashley N. Zuniga
    • , Kyle J. Lorentsen
    • , Samira Mansouri
    • , Joshua Y. Cho
    • , Mariola J. Edelmann
    • , Duc M. Duong
    • , Torben Gehring
    • , Thomas Seeholzer
    • , Daniel Krappmann
    • , Mohammad N. Uddin
    • , Danielle Califano
    • , Rejean L. Wang
    • , Lei Jin
    • , Hongmin Li
    • , Dongwen Lv
    • , Daohong Zhou
    • , Liang Zhou
    •  & Dorina Avram
  • Article | | open

    Exsolution is attractive for the preparation of catalytically active metal nanoparticles, but versatility is limited. Here the authors report a technique for selective exsolution through topotactic ion exchange, leading to an electrocatalyst for a solid oxide fuel cell with enhanced performance.

    • Sangwook Joo
    • , Ohhun Kwon
    • , Kyeounghak Kim
    • , Seona Kim
    • , Hyunmin Kim
    • , Jeeyoung Shin
    • , Hu Young Jeong
    • , Sivaprakash Sengodan
    • , Jeong Woo Han
    •  & Guntae Kim
  • Article | | open

    While methane has become an increasingly important chemical feedstock, its selective conversion to other chemicals has proven challenging. Here, authors demonstrate a photocatalyst based on earth-abundant elements that selectively converts methane to carbon monoxide under mild conditions.

    • Xiang Yu
    • , Vincent De Waele
    • , Axel Löfberg
    • , Vitaly Ordomsky
    •  & Andrei Y. Khodakov
  • Article | | open

    The search for peroxidase-like as well as other enzyme-like nanozymes mainly relies on trial-and-error strategies, due to the lack of predictive descriptors. Here, the authors fill this gap by investigating the occupancy of eg orbitals as a possible descriptor for the peroxidase-like activity of transition metal oxide nanozymes

    • Xiaoyu Wang
    • , Xuejiao J. Gao
    • , Li Qin
    • , Changda Wang
    • , Li Song
    • , Yong-Ning Zhou
    • , Guoyin Zhu
    • , Wen Cao
    • , Shichao Lin
    • , Liqi Zhou
    • , Kang Wang
    • , Huigang Zhang
    • , Zhong Jin
    • , Peng Wang
    • , Xingfa Gao
    •  & Hui Wei
  • Article | | open

    Processes for efficient production of primary, secondary or ternary aminated compounds are constant challenges for chemical and pharmaceutical industries. Here, the authors develop selective and sustainable amination chemistry widely applicable to chemical substrates via formic acid.

    • Hu Li
    • , Haixin Guo
    • , Yaqiong Su
    • , Yuya Hiraga
    • , Zhen Fang
    • , Emiel J. M. Hensen
    • , Masaru Watanabe
    •  & Richard Lee Smith Jr.
  • Article | | open

    The bandgap of mixed-halide perovskites can be continuously tuned by changing the halide ratio, but the crystals have poor photo-stability. Here the authors show that photoinduced phase separation is suppressed when perovskite nanocrystals are embedded in a non-perovskite endotaxial matrix.

    • Xi Wang
    • , Yichuan Ling
    • , Xiujun Lian
    • , Yan Xin
    • , Kamal B. Dhungana
    • , Fernando Perez-Orive
    • , Javon Knox
    • , Zhizhong Chen
    • , Yan Zhou
    • , Drake Beery
    • , Kenneth Hanson
    • , Jian Shi
    • , Shangchao Lin
    •  & Hanwei Gao
  • Article | | open

    While the conversion of CO2 to valuable, storable chemicals is attractive, there are few inexpensive and abundant catalysts that are also active and selective for liquid fuels. Here, the authors study copper selenide as a high-performing and efficient electrocatalyst for CO2 conversion to methanol.

    • Dexin Yang
    • , Qinggong Zhu
    • , Chunjun Chen
    • , Huizhen Liu
    • , Zhimin Liu
    • , Zhijuan Zhao
    • , Xiaoyu Zhang
    • , Shoujie Liu
    •  & Buxing Han
  • Article | | open

    Despite remarkable optical properties in lead halide perovskites, spin control in these materials is largely unexplored. Herein Belykh et al. study the coherent spin dynamics of electrons and holes in cesium lead bromide perovskites, and evidence interaction of electron and lattice nuclear spins.

    • Vasilii V. Belykh
    • , Dmitri R. Yakovlev
    • , Mikhail M. Glazov
    • , Philipp S. Grigoryev
    • , Mujtaba Hussain
    • , Janina Rautert
    • , Dmitry N. Dirin
    • , Maksym V. Kovalenko
    •  & Manfred Bayer
  • Article | | open

    High mass loading and fast charge transport are two crucial but often mutually exclusive characteristics of pseudocapacitors. Here, the authors address this challenge by making use of block copolymer phase separation in the synthesis of porous carbon fibres as carbon supports for pseudocapacitors.

    • Tianyu Liu
    • , Zhengping Zhou
    • , Yichen Guo
    • , Dong Guo
    •  & Guoliang Liu
  • Article | | open

    How the chromosome passenger complex (CPC) phosphorylates the kinetochores that can be a micron away to control mitotic events is unknown. Here the authors find that the CPC directly binds microtubules near inner centromeres, which controls its ability to phosphorylate kinetochores independently of tension generated by kinetochore microtubule attachments.

    • Prasad Trivedi
    • , Anatoly V. Zaytsev
    • , Maxim Godzi
    • , Fazly I. Ataullakhanov
    • , Ekaterina L. Grishchuk
    •  & P. Todd Stukenberg
  • Article | | open

    Fire-derived organic matter (OM) is present throughout the environment, and its impact on nutrient cycling remains poorly understood. Here, the authors show that this pyrogenic OM can retain large quantities of ammonia through covalent bond formation, thereby exerting an important control on nitrogen cycling.

    • Rachel Hestrin
    • , Dorisel Torres-Rojas
    • , James J. Dynes
    • , James M. Hook
    • , Tom Z. Regier
    • , Adam W. Gillespie
    • , Ronald J. Smernik
    •  & Johannes Lehmann
  • Article | | open

    Renewable CO2 conversion to useful products presents a sustainable, carbon-neutral method to limit climate change, yet few materials can perform this complex chemistry. Here, authors prepare a polymer-TiO2-graphene composite that can take up CO2 and convert it to CH4 using light and water.

    • Shaolei Wang
    • , Min Xu
    • , Tianyou Peng
    • , Chengxin Zhang
    • , Tao Li
    • , Irshad Hussain
    • , Jingyu Wang
    •  & Bien Tan
  • Article | | open

    The emergence of applications requiring device-to-device interactivity has to the need to develop conducting electrodes with high optical transparency at low radiofrequencies. Here, the authors demonstrate conductive polymer electrodes with high transparency in the MHz-order frequency range.

    • Taehoon Kim
    • , Gwangmook Kim
    • , Hyeohn Kim
    • , Hong-Jib Yoon
    • , Taeseong Kim
    • , Yohan Jun
    • , Tae-Hyun Shin
    • , Shinill Kang
    • , Jinwoo Cheon
    • , Dosik Hwang
    • , Byung-wook Min
    •  & Wooyoung Shim
  • Article | | open

    Electrochromic technology has diverse cutting-edge applications, but it has never been used to overcome the critical problems in the field of surface-enhanced Raman scattering (SERS). Here, the authors demonstrate a generic electrochromic strategy for ensuring the reproducibility and renewability of SERS substrates.

    • Shan Cong
    • , Zhen Wang
    • , Wenbin Gong
    • , Zhigang Chen
    • , Weibang Lu
    • , John R. Lombardi
    •  & Zhigang Zhao
  • Article | | open

    Class F receptors are therapeutic targets in human disease and understanding their structural changes during receptor activation may provide important pharmacological insight. Here, the authors combine computational and experimental methods to identify a molecular switch in TM6/7 of Class F receptors that mediates receptor activation.

    • Shane C. Wright
    • , Paweł Kozielewicz
    • , Maria Kowalski-Jahn
    • , Julian Petersen
    • , Carl-Fredrik Bowin
    • , Greg Slodkowicz
    • , Maria Marti-Solano
    • , David Rodríguez
    • , Belma Hot
    • , Najeah Okashah
    • , Katerina Strakova
    • , Jana Valnohova
    • , M. Madan Babu
    • , Nevin A. Lambert
    • , Jens Carlsson
    •  & Gunnar Schulte
  • Article | | open

    Cryo-electron microscopy can determine the structure but not the nanomechanics of biological matter. Here the authors combine force spectroscopy in cryogenic conditions with computer simulations to characterize the properties of DNA simultaneously down to the sub-nm level.

    • Rémy Pawlak
    • , J. G. Vilhena
    • , Antoine Hinaut
    • , Tobias Meier
    • , Thilo Glatzel
    • , Alexis Baratoff
    • , Enrico Gnecco
    • , Rubén Pérez
    •  & Ernst Meyer
  • Article | | open

    Acrylics and acrylates have become important building blocks for the chemical industry, but their efficient synthesis remains a challenge. Here, the authors report the first example of the catalytic aerobic partial oxidation of allyl ether to its acrylate ester derivative using a Li ion promoted mesoporous manganese oxide under mild conditions.

    • Biswanath Dutta
    • , Ryan Clarke
    • , Sumathy Raman
    • , Timothy D. Shaffer
    • , Laura Achola
    • , Partha Nandi
    •  & Steven L. Suib