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Volume 7 Issue 4, April 2012

The ability to study the distribution of electric charge inside molecules would be useful in many areas of science and technology. Now researchers at IBM Research-Zurich have used a technique called Kelvin probe force microscopy to image the charge distribution inside a single naphthalocyanine molecule on a surface. This molecule has two hydrogen atoms at its centre and four lobes that give it a cross shape. The IBM team shows that the two lobes parallel to the hydrogen atoms have a lower charge density than the other two lobes. This computer simulation shows the asymmetry in the electric field above the molecule and perpendicular to the surface: regions of high field are shown in red and yellow; regions of low field are shown in blue. The image measures just over 2 nm across.

Letters p227; News & Views p210

IMAGE: FABIAN MOHN, IBM RESEARCH-ZURICH

COVER DESIGN: ALEX WING

Thesis

  • Scanning probe microscopes feature prominently in the history of nanotechnology but, as a recent book on the subject makes clear, this history could have been very different. Chris Toumey explains.

    • Chris Toumey
    Thesis

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Research Highlights

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News & Views

  • A single-atom transistor has been made by positioning a phosphorus atom between metallic electrodes, also made of phosphorus, on a silicon surface.

    • Gabriel P. Lansbergen
    News & Views
  • The distribution of electric charge within a single naphthalocyanine molecule has been revealed by researchers using a combination of three types of microscopy and theoretical modelling.

    • Peter Grutter
    News & Views
  • Chemically modifying solid-state nanopores with a single nitrilotriacetic acid receptor allows the reversible detection of single proteins.

    • Li-Qun Gu
    • Brandon Ritzo
    • Yong Wang
    News & Views
  • A motor protein can be made to walk in either direction along a filamentous track by adjusting the concentration of calcium ions in the surrounding solution.

    • Wilhelm J. Walter
    • Stefan Diez
    News & Views
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Review Article

  • This article reviews the development of multifrequency force microscopy and examines its application in studies of proteins, the imaging of vibrating nanostructures, measurements of ion diffusion, and subsurface imaging in cells.

    • Ricardo Garcia
    • Elena T. Herruzo
    Review Article
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Letter

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Article

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Correction

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