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Nanoparticles functionalized with photoresponsive molecules assemble into supracrystals on irradiation with UV light and disassemble on irradiation with visible light. These dynamic structures can trap small molecules from the surrounding solution and accelerate chemical reactions in repeated cycles. The artist's impression in the cover shows anthracene dimerization inside the supracrystal structure, with reactants going in and products coming out.
Developing useful methods to control light–matter interactions at the nanoscale requires an appreciation of the needs of industry and innovative approaches that go beyond plasmonics.
Predictions for the development of microelectronics provide a valuable example about the virtues of measured promises in nanotechnology, as Chris Toumey explains.
By taking advantage of the thermal gradient that is generated in plasmonic systems and by using an a.c. field, plasmonic tweezers can have a large radius of action and can trap and manipulate single nano-objects.
The light-powered assembly and disassembly of functionalized nanoparticles creates dynamic nanocavities with built-in selective uptake, reactivity and release.
The observation of single-photon emission at room temperature from defects in hexagonal boron nitride sheets opens new opportunities for quantum optics.
Nanostructured metamaterials fabricated on nanomembranes can be reconfigured by thermal, electric, magnetic and optical forces resulting in dynamically controlled optical properties.
Single-photon emission at room temperature can be achieved with hexagonal boron nitride due to electron and hole confinement in vacancy-related defects.
A molecular positioning device made from DNA origami can adjust the average distance between fluorescent molecules and reactive groups in steps as small as 0.04 nm.
A plasmonic tweezer combining thermal and electric fields can be used to create fast fluid motion for rapid and accurate positioning of single nanoparticles.
Nanoparticles can absorb most of the incoming light irrespective of incidence angle and polarization and condense it into a monochromatic emission in the presence of a dye.
Scanning tunnelling microscopy measurements suggest that resistive switching in TaOx, HfOx and TiOx can be caused by both the diffusion of oxygen vacancies and the migration of cations.
Using metal oxides for both the hole- and electron-transport layers in perovskite solar cells significantly improves their stability compared with devices containing organic transport layers.
Colloidal nanocrystals functionalized with light-responsive ligands can be cyclically assembled and disassembled to create nanoscale environments where chemical reaction rates are enhanced and stereoselectivities can be controlled.
A monovalent form of an engineered streptavidin can now be tethered to AFM cantilevers, representing a reliable anchoring tool with a well-defined pulling geometry for single-molecule force spectroscopy studies of proteins.
Suturing of ultrasmall blood vessels is now simplified through the use of a hydrogel that can act as a temporary stent on injection and can be removed through light irradiation.
Changxu Liu and Jianfeng Huang reflect on their experiences of a collaborative research project that was at a crossroads between physics and chemistry.