Articles

  • Article |

    The semiconductor–electrolyte interface dominates the behaviour of semiconductor electrocatalysts. Inspired by ion-controlled electronics a universal self-gating phenomenon is now proposed to explain transport modulation during electrocatalytic reaction.

    • Yongmin He
    • , Qiyuan He
    • , Luqing Wang
    • , Chao Zhu
    • , Prafful Golani
    • , Albertus D. Handoko
    • , Xuechao Yu
    • , Caitian Gao
    • , Mengning Ding
    • , Xuewen Wang
    • , Fucai Liu
    • , Qingsheng Zeng
    • , Peng Yu
    • , Shasha Guo
    • , Boris I. Yakobson
    • , Liang Wang
    • , Zhi Wei Seh
    • , Zhuhua Zhang
    • , Minghong Wu
    • , Qi Jie Wang
    • , Hua Zhang
    •  & Zheng Liu
  • Article |

    Organic radical molecules violating the Aufbau principle are shown to reach high luminescence quantum yield and photostability, with potential applications for deep-red and near-infrared light-emitting sources.

    • Haoqing Guo
    • , Qiming Peng
    • , Xian-Kai Chen
    • , Qinying Gu
    • , Shengzhi Dong
    • , Emrys W. Evans
    • , Alexander J. Gillett
    • , Xin Ai
    • , Ming Zhang
    • , Dan Credgington
    • , Veaceslav Coropceanu
    • , Richard H. Friend
    • , Jean-Luc Brédas
    •  & Feng Li
  • Article |

    A RAB5A-mediated, epidermal growth factor-dependent activation of endosomal ERK1/2 is identified as a key molecular route for a solid-to-liquid-like phase transition, sufficient to overcome kinetic and proliferation arrest in normal mammary epithelial assemblies and to promote collective invasion in breast carcinoma.

    • Andrea Palamidessi
    • , Chiara Malinverno
    • , Emanuela Frittoli
    • , Salvatore Corallino
    • , Elisa Barbieri
    • , Sara Sigismund
    • , Galina V. Beznoussenko
    • , Emanuele Martini
    • , Massimiliano Garre
    • , Ines Ferrara
    • , Claudio Tripodo
    • , Flora Ascione
    • , Elisabetta A. Cavalcanti-Adam
    • , Qingsen Li
    • , Pier Paolo Di Fiore
    • , Dario Parazzoli
    • , Fabio Giavazzi
    • , Roberto Cerbino
    •  & Giorgio Scita
  • Article |

    Molecular sieving separates larger from smaller molecules, but all molecules smaller than the pore adsorb, hindering selectivity. Here, a MOF is reported with both molecular sieving and gate-opening, separating intermediate-sized molecules from larger and smaller analogues.

    • Dong-Dong Zhou
    • , Pin Chen
    • , Chao Wang
    • , Sha-Sha Wang
    • , Yunfei Du
    • , Hui Yan
    • , Zi-Ming Ye
    • , Chun-Ting He
    • , Rui-Kang Huang
    • , Zong-Wen Mo
    • , Ning-Yu Huang
    •  & Jie-Peng Zhang
  • Article |

    Liquid phase transmission electron microscopy reveals the growth pathway of 2D cobalt oxide and cobalt nickel oxide, in which 3D nanoparticles are formed first and then spread and transform into 2D nanosheets.

    • Juan Yang
    • , Zhiyuan Zeng
    • , Jun Kang
    • , Sophia Betzler
    • , Cory Czarnik
    • , Xiaowei Zhang
    • , Colin Ophus
    • , Chang Yu
    • , Karen Bustillo
    • , Ming Pan
    • , Jieshan Qiu
    • , Lin-Wang Wang
    •  & Haimei Zheng
  • Article |

    Local tuning of quantum dots embedded in a photonic waveguide can be achieved through the strain produced by laser heating of a thin layer of HfO2 deposited around the waveguide. The method is exploited to tune three quantum dots in resonance.

    • Joel Q. Grim
    • , Allan S. Bracker
    • , Maxim Zalalutdinov
    • , Samuel G. Carter
    • , Alexander C. Kozen
    • , Mijin Kim
    • , Chul Soo Kim
    • , Jerome T. Mlack
    • , Michael Yakes
    • , Bumsu Lee
    •  & Daniel Gammon
  • Article |

    Subnanometre Pt clusters show high catalytic activity, but can sinter and so reduce reactivity. Here, authors localize Pt clusters in one zeolite channel, preventing sintering and allowing highly stable and selective catalytic propane dehydrogenation.

    • Lichen Liu
    • , Miguel Lopez-Haro
    • , Christian W. Lopes
    • , Chengeng Li
    • , Patricia Concepcion
    • , Laura Simonelli
    • , Jose J. Calvino
    •  & Avelino Corma
  • Article |

    Generation of hydrogen peroxide from water and dioxygen is promising for artificial photosynthesis but photocatalysts suffer from low efficiency. Resorcinol–formaldehyde resins exhibit stable H2O2 generation with more than 0.5% solar-to-chemical conversion efficiency.

    • Yasuhiro Shiraishi
    • , Takahiro Takii
    • , Takumi Hagi
    • , Shinnosuke Mori
    • , Yusuke Kofuji
    • , Yasutaka Kitagawa
    • , Shunsuke Tanaka
    • , Satoshi Ichikawa
    •  & Takayuki Hirai
  • Article |

    Low-dimensional tin-halide perovskites exhibit strong temperature dependence of luminescence decay time that translates into high sensitivity over a wide range of temperatures and as such can be used in high-resolution remote thermography.

    • Sergii Yakunin
    • , Bogdan M. Benin
    • , Yevhen Shynkarenko
    • , Olga Nazarenko
    • , Maryna I. Bodnarchuk
    • , Dmitry N. Dirin
    • , Christoph Hofer
    • , Stefano Cattaneo
    •  & Maksym V. Kovalenko
  • Article |

    Mobile micromachines with advanced configurations and functions self-assembled through designed dielectrophoretic interactions between structural and motor units.

    • Yunus Alapan
    • , Berk Yigit
    • , Onur Beker
    • , Ahmet F. Demirörs
    •  & Metin Sitti
  • Article |

    Foreign body response can result in failure of biomaterials in vivo. Solvent-free crystals containing anti-fibrotic drugs now show the potential for long-term inhibition of fibrosis on a number of implantable devices in rodents and non-human primates.

    • Shady Farah
    • , Joshua C. Doloff
    • , Peter Müller
    • , Atieh Sadraei
    • , Hye Jung Han
    • , Katy Olafson
    • , Keval Vyas
    • , Hok Hei Tam
    • , Jennifer Hollister-Lock
    • , Piotr S. Kowalski
    • , Marissa Griffin
    • , Ashley Meng
    • , Malia McAvoy
    • , Adam C. Graham
    • , James McGarrigle
    • , Jose Oberholzer
    • , Gordon C. Weir
    • , Dale L. Greiner
    • , Robert Langer
    •  & Daniel G. Anderson
  • Article |

    Macroscopic single crystals with controlled texture are formed from a self-assembled columnar discotic liquid crystal.

    • Xunda Feng
    • , Kohsuke Kawabata
    • , Matthew G. Cowan
    • , Gregory E. Dwulet
    • , Kristof Toth
    • , Lucas Sixdenier
    • , Amir Haji-Akbari
    • , Richard D. Noble
    • , Menachem Elimelech
    • , Douglas L. Gin
    •  & Chinedum O. Osuji
  • Article |

    High-throughput computation is especially useful for materials screening where synthesis is challenging. Here, it is used to construct a stability map of ternary nitrides, allowing discovery of stable compounds and providing insight into principles that govern nitride stability.

    • Wenhao Sun
    • , Christopher J. Bartel
    • , Elisabetta Arca
    • , Sage R. Bauers
    • , Bethany Matthews
    • , Bernardo Orvañanos
    • , Bor-Rong Chen
    • , Michael F. Toney
    • , Laura T. Schelhas
    • , William Tumas
    • , Janet Tate
    • , Andriy Zakutayev
    • , Stephan Lany
    • , Aaron M. Holder
    •  & Gerbrand Ceder
  • Article |

    Scanning quantum dot microscopy, based on the use of a single molecule attached to the tip of the cantilever of an atomic force microscope, is shown to provide quantitative maps of surface potential distribution with atomic resolution.

    • Christian Wagner
    • , Matthew. F. B. Green
    • , Michael Maiworm
    • , Philipp Leinen
    • , Taner Esat
    • , Nicola Ferri
    • , Niklas Friedrich
    • , Rolf Findeisen
    • , Alexandre Tkatchenko
    • , Ruslan Temirov
    •  & F. Stefan Tautz
  • Article |

    Scanning electron nanobeam diffraction is used to monitor the morphology of organic thin films with nanometre resolution, revealing information on the arrangement of crystalline domains useful for structure–property relationship understanding.

    • Ouliana Panova
    • , Colin Ophus
    • , Christopher J. Takacs
    • , Karen C. Bustillo
    • , Luke Balhorn
    • , Alberto Salleo
    • , Nitash Balsara
    •  & Andrew M. Minor
  • Article |

    Proton ceramic electrolysers can produce hydrogen directly from steam, but their development has suffered from limited electrical efficiency. A fully operational and stable BaZrO3-based tubular electrolyser with high hydrogen production rate is now reported.

    • Einar Vøllestad
    • , Ragnar Strandbakke
    • , Mateusz Tarach
    • , David Catalán-Martínez
    • , Marie-Laure Fontaine
    • , Dustin Beeaff
    • , Daniel R. Clark
    • , Jose M. Serra
    •  & Truls Norby
  • Article |

    Material depletion and accumulation at the crystallization front of organic semiconductors films induce the formation of large-area regular patterns, with a periodicity relevant to optoelectronic applications in the visible and near-infrared range.

    • John S. Bangsund
    • , Thomas R. Fielitz
    • , Trevor J. Steiner
    • , Kaicheng Shi
    • , Jack R. Van Sambeek
    • , Catherine P. Clark
    •  & Russell J. Holmes
  • Article |

    An antisymmetric and chiral long range interlayer magnetic exchange interaction is measured, with implications for spintronics and chiral magnetic devices.

    • Dong-Soo Han
    • , Kyujoon Lee
    • , Jan-Philipp Hanke
    • , Yuriy Mokrousov
    • , Kyoung-Whan Kim
    • , Woosuk Yoo
    • , Youri L. W. van Hees
    • , Tae-Wan Kim
    • , Reinoud Lavrijsen
    • , Chun-Yeol You
    • , Henk J. M. Swagten
    • , Myung-Hwa Jung
    •  & Mathias Kläui
  • Article |

    The mechanism of cytokinetic failure in the migrating zebrafish epicardium leading to multinucleated cells is shown to be driven by the interaction of the cytokinetic ring and the extracellular matrix through adhesion reinforcement by high traction forces.

    • Marina Uroz
    • , Anna Garcia-Puig
    • , Isil Tekeli
    • , Alberto Elosegui-Artola
    • , Juan F. Abenza
    • , Ariadna Marín-Llauradó
    • , Silvia Pujals
    • , Vito Conte
    • , Lorenzo Albertazzi
    • , Pere Roca-Cusachs
    • , Ángel Raya
    •  & Xavier Trepat
  • Article |

    Gold nanoparticles that passively deliver CRISPR machinery to blood repopulating cells have been developed and are shown to be capable of precise editing of multiple genetic loci of therapeutic interest without cytotoxicity or reduced fitness.

    • Reza Shahbazi
    • , Gabriella Sghia-Hughes
    • , Jack L. Reid
    • , Sara Kubek
    • , Kevin G. Haworth
    • , Olivier Humbert
    • , Hans-Peter Kiem
    •  & Jennifer E. Adair
  • Article |

    Crosstalk between microtubules and the actin cytoskeleton of cells is important in elucidating integrin-mediated adhesion and mechanotransduction. It is now shown that microtubule-mediated control of focal adhesions and podosomes occurs via KANK family proteins.

    • Nisha Bte Mohd Rafiq
    • , Yukako Nishimura
    • , Sergey V. Plotnikov
    • , Visalatchi Thiagarajan
    • , Zhen Zhang
    • , Shidong Shi
    • , Meenubharathi Natarajan
    • , Virgile Viasnoff
    • , Pakorn Kanchanawong
    • , Gareth E. Jones
    •  & Alexander D. Bershadsky
  • Article |

    The Alx3 transcription factor, expressed in prenatal tooth development, is shown to revitalize adult progenitor cells in decellularized scaffolds, leading to enhanced parenchymal dental pulp and vascularized stroma regeneration in vivo.

    • Ling He
    • , Jian Zhou
    • , Mo Chen
    • , Chyuan-Sheng Lin
    • , Sahng G. Kim
    • , Yue Zhou
    • , Lusai Xiang
    • , Ming Xie
    • , Hanying Bai
    • , Hai Yao
    • , Changcheng Shi
    • , Paulo G. Coelho
    • , Timothy G. Bromage
    • , Bin Hu
    • , Nick Tovar
    • , Lukasz Witek
    • , Jiaqian Wu
    • , Kenian Chen
    • , Wei Gu
    • , Jinxuan Zheng
    • , Tzong-Jen Sheu
    • , Juan Zhong
    • , Jin Wen
    • , Yuting Niu
    • , Bin Cheng
    • , Qimei Gong
    • , David M. Owens
    • , Milda Stanislauskas
    • , Jasmine Pei
    • , Gregory Chotkowski
    • , Sainan Wang
    • , Guodong Yang
    • , David J. Zegarelli
    • , Xin Shi
    • , Myron Finkel
    • , Wen Zhang
    • , Junyuan Li
    • , Jiayi Cheng
    • , Dennis P. Tarnow
    • , Xuedong Zhou
    • , Zuolin Wang
    • , Xinquan Jiang
    • , Alexander Romanov
    • , David W. Rowe
    • , Songlin Wang
    • , Ling Ye
    • , Junqi Ling
    •  & Jeremy Mao
  • Article |

    Extreme electronic anisotropy is revealed in the high-temperature superconductor FeSe through tour de force experiments on detwinned crystals.

    • Tong Chen
    • , Youzhe Chen
    • , Andreas Kreisel
    • , Xingye Lu
    • , Astrid Schneidewind
    • , Yiming Qiu
    • , J. T. Park
    • , Toby G. Perring
    • , J Ross Stewart
    • , Huibo Cao
    • , Rui Zhang
    • , Yu Li
    • , Yan Rong
    • , Yuan Wei
    • , Brian M. Andersen
    • , P. J. Hirschfeld
    • , Collin Broholm
    •  & Pengcheng Dai
  • Article |

    Non-orthogonal magnetization switching is related to the shear strain associated with ferroelectric domains, with implications for magnetoelectric devices.

    • M. Ghidini
    • , R. Mansell
    • , F. Maccherozzi
    • , X. Moya
    • , L. C. Phillips
    • , W. Yan
    • , D. Pesquera
    • , C. H. W. Barnes
    • , R. P. Cowburn
    • , J.-M. Hu
    • , S. S. Dhesi
    •  & N. D. Mathur
  • Article |

    Porous molecular crystals are easy to fabricate but thought to have limited stability as they are bound by non-covalent interactions. Here, a porous crystal composed of C60 and phthalocyanine is demonstrated with stability to heat, acid, base and high pressures.

    • C. Grazia Bezzu
    • , Luke A. Burt
    • , Charlie J. McMonagle
    • , Stephen A. Moggach
    • , Benson M. Kariuki
    • , David R. Allan
    • , Mark Warren
    •  & Neil B. McKeown
  • Article |

    Electrostatic doping drives a transition from single condensate to two condensate superconductivity at the (110)-oriented LaAlO3/SrTiO3 interface.

    • G. Singh
    • , A. Jouan
    • , G. Herranz
    • , M. Scigaj
    • , F. Sánchez
    • , L. Benfatto
    • , S. Caprara
    • , M. Grilli
    • , G. Saiz
    • , F. Couëdo
    • , C. Feuillet-Palma
    • , J. Lesueur
    •  & N. Bergeal
  • Article |

    Magneto-optical spectroscopy shows that the dark exciton state in single formamidinium lead bromide perovskite nanocrystals is located below the bright exciton triplet. Slow bright-to-dark relaxation explains the intense brightness of the nanoparticles.

    • Philippe Tamarat
    • , Maryna I. Bodnarchuk
    • , Jean-Baptiste Trebbia
    • , Rolf Erni
    • , Maksym V. Kovalenko
    • , Jacky Even
    •  & Brahim Lounis
  • Article |

    The remote, non-volatile and reversible optical control of ferroic orders is challenging. Here, using laser illumination, multiple orders in epitaxial mixed-phase BiFeO3 are manipulated deterministically using a thermally driven flexoelectric effect.

    • Yi-De Liou
    • , Yu-You Chiu
    • , Ryan Thomas Hart
    • , Chang-Yang Kuo
    • , Yen-Lin Huang
    • , Yuan-Chih Wu
    • , Rajesh V. Chopdekar
    • , Heng-Jui Liu
    • , Arata Tanaka
    • , Chien-Te Chen
    • , Chun-Fu Chang
    • , Liu Hao Tjeng
    • , Ye Cao
    • , Valanoor Nagarajan
    • , Ying-Hao Chu
    • , Yi-Chun Chen
    •  & Jan-Chi Yang
  • Article |

    By exciting chiral plasmons within a nanohole by means of circularly polarized light pulses, orbital angular momentum can be imparted onto charged matter waves (here, electrons) and controlled at terahertz speed (femtosecond intervals).

    • G. M. Vanacore
    • , G. Berruto
    • , I. Madan
    • , E. Pomarico
    • , P. Biagioni
    • , R. J. Lamb
    • , D. McGrouther
    • , O. Reinhardt
    • , I. Kaminer
    • , B. Barwick
    • , H. Larocque
    • , V. Grillo
    • , E. Karimi
    • , F. J. García de Abajo
    •  & F. Carbone
  • Article |

    Oxide-supported isolated Pt-group metal atoms as catalytic active sites are of interest because of their unique reactivity. Isolated Pt species are now shown to adopt a range of local coordination environments and oxidation states in response to environmental conditions.

    • Leo DeRita
    • , Joaquin Resasco
    • , Sheng Dai
    • , Alexey Boubnov
    • , Ho Viet Thang
    • , Adam S. Hoffman
    • , Insoo Ro
    • , George W. Graham
    • , Simon R. Bare
    • , Gianfranco Pacchioni
    • , Xiaoqing Pan
    •  & Phillip Christopher
  • Article |

    Reversible and cooperative activation processes are important characteristics of biological enzymes and can be used in designing catalysts. Highly active TiO2 photocatalysts incorporated with site-specific single copper atoms are now shown to exhibit such a photoactivation process.

    • Byoung-Hoon Lee
    • , Sunghak Park
    • , Minho Kim
    • , Arun K. Sinha
    • , Seong Chan Lee
    • , Euiyeon Jung
    • , Woo Je Chang
    • , Kug-Seung Lee
    • , Jeong Hyun Kim
    • , Sung-Pyo Cho
    • , Hyungjun Kim
    • , Ki Tae Nam
    •  & Taeghwan Hyeon
  • Article |

    Hole and electron traps related to the presence of trace water are found in organic semiconductor thin films, at an energy offset of ~0.3–0.4 eV from the highest occupied and lowest unoccupied molecular orbitals, respectively.

    • Guangzheng Zuo
    • , Mathieu Linares
    • , Tanvi Upreti
    •  & Martijn Kemerink
  • Article |

    The structural foundation of self-assembled peptide materials is typically the β-sheet. Here the authors describe peptides made of three natural amino acids that self-assemble into helical-like superstructures with enhanced mechanical rigidity.

    • Santu Bera
    • , Sudipta Mondal
    • , Bin Xue
    • , Linda J. W. Shimon
    • , Yi Cao
    •  & Ehud Gazit
  • Article |

    Plasmonic catalysis is believed to be mediated by energy transfer from nanoparticles to adsorbed molecules. Localized surface plasmon resonance on gold nanoparticles excited by electron beam is shown to drive site-selective CO disproportionation at room temperature.

    • Wei-Chang D. Yang
    • , Canhui Wang
    • , Lisa A. Fredin
    • , Pin Ann Lin
    • , Lisa Shimomoto
    • , Henri J. Lezec
    •  & Renu Sharma
  • Article |

    Solution shearing of semiconducting polymers with a patterned blade induces improved alignment of the polymeric chains at the nano- and macroscale. This leads to increased charge transport in stretchable, roll-to-roll deposited organic transistors.

    • Jie Xu
    • , Hung-Chin Wu
    • , Chenxin Zhu
    • , Anatol Ehrlich
    • , Leo Shaw
    • , Mark Nikolka
    • , Sihong Wang
    • , Francisco Molina-Lopez
    • , Xiaodan Gu
    • , Shaochuan Luo
    • , Dongshan Zhou
    • , Yun-Hi Kim
    • , Ging-Ji Nathan Wang
    • , Kevin Gu
    • , Vivian Rachel Feig
    • , Shucheng Chen
    • , Yeongin Kim
    • , Toru Katsumata
    • , Yu-Qing Zheng
    • , He Yan
    • , Jong Won Chung
    • , Jeffrey Lopez
    • , Boris Murmann
    •  & Zhenan Bao
  • Article |

    Sensing hydrogen by the change in plasmonic response upon metal hydride formation is safe, but trace gas poisoning and low sensitivity can occur. Here, a PdAu alloy/polymer sensor is poison resistant and can sense 3 ppm H2 with a response time of 1 s.

    • Ferry A. A. Nugroho
    • , Iwan Darmadi
    • , Lucy Cusinato
    • , Arturo Susarrey-Arce
    • , Herman Schreuders
    • , Lars J. Bannenberg
    • , Alice Bastos da Silva Fanta
    • , Shima Kadkhodazadeh
    • , Jakob B. Wagner
    • , Tomasz J. Antosiewicz
    • , Anders Hellman
    • , Vladimir P. Zhdanov
    • , Bernard Dam
    •  & Christoph Langhammer
  • Article |

    Generating electricity by low-grade thermal harvesting requires a low-cost technology. Here, by chemically treating wood, aligned cellulose molecular chains form that confine sodium ions in the sub-nanometre channels and enhance selective diffusion, generating differential thermal voltage of 24 mV K–1.

    • Tian Li
    • , Xin Zhang
    • , Steven D. Lacey
    • , Ruiyu Mi
    • , Xinpeng Zhao
    • , Feng Jiang
    • , Jianwei Song
    • , Zhongqi Liu
    • , Guang Chen
    • , Jiaqi Dai
    • , Yonggang Yao
    • , Siddhartha Das
    • , Ronggui Yang
    • , Robert M. Briber
    •  & Liangbing Hu
  • Article |

    Upon ultrafast irradiation, a (PbTiO3)/(SrTiO3) superlattice transforms into a complex supercrystal that contains periodicities of up to 30 nm in size and is stable in ambient. Creation and destruction, by heating, of the supercrystal is reversible.

    • V. A. Stoica
    • , N. Laanait
    • , C. Dai
    • , Z. Hong
    • , Y. Yuan
    • , Z. Zhang
    • , S. Lei
    • , M. R. McCarter
    • , A. Yadav
    • , A. R. Damodaran
    • , S. Das
    • , G. A. Stone
    • , J. Karapetrova
    • , D. A. Walko
    • , X. Zhang
    • , L. W. Martin
    • , R. Ramesh
    • , L.-Q. Chen
    • , H. Wen
    • , V. Gopalan
    •  & J. W. Freeland
  • Article |

    Although anionic redox in Li- and Na-rich transition metal oxides can enhance energy density of rechargeable batteries, anionic capacity is partly irreversible in discharge. A unified picture to clarify this irreversibility and to improve cycling performance is proposed.

    • Mouna Ben Yahia
    • , Jean Vergnet
    • , Matthieu Saubanère
    •  & Marie-Liesse Doublet
  • Article |

    High mobility and high carrier density are found in the Weyl semimetal NbAs. This is attributed to the low dissipation of disorder-tolerant Fermi arcs.

    • Cheng Zhang
    • , Zhuoliang Ni
    • , Jinglei Zhang
    • , Xiang Yuan
    • , Yanwen Liu
    • , Yichao Zou
    • , Zhiming Liao
    • , Yongping Du
    • , Awadhesh Narayan
    • , Hongming Zhang
    • , Tiancheng Gu
    • , Xuesong Zhu
    • , Li Pi
    • , Stefano Sanvito
    • , Xiaodong Han
    • , Jin Zou
    • , Yi Shi
    • , Xiangang Wan
    • , Sergey Y. Savrasov
    •  & Faxian Xiu
  • Article |

    The extracellular matrix surrounding cells plays a significant role in their behaviour. The spreading, mechanosensing and differentiation of mesenchymal stem cells are shown to be dependent on the early deposition and remodelling of local nascent proteins within degradable and viscoelastic hydrogels.

    • Claudia Loebel
    • , Robert L. Mauck
    •  & Jason A. Burdick
  • Article |

    The simultaneous high-pressure and high-temperature phase diagram of two MOFs, ZIF-4 and ZIF-62, is mapped. Crystalline, pressure- and temperature-amorphous, and liquid states are found, while melting temperature is found to decrease with pressure.

    • Remo N. Widmer
    • , Giulio I. Lampronti
    • , Simone Anzellini
    • , Romain Gaillac
    • , Stefan Farsang
    • , Chao Zhou
    • , Ana M. Belenguer
    • , Craig W. Wilson
    • , Hannah Palmer
    • , Annette K. Kleppe
    • , Michael T. Wharmby
    • , Xiao Yu
    • , Seth M. Cohen
    • , Shane G. Telfer
    • , Simon A. T. Redfern
    • , François-Xavier Coudert
    • , Simon G. MacLeod
    •  & Thomas D. Bennett