Artistic impression of a mechanical arm and three differently shaped DNA nanostructures

Read our September issue

This month, a Comment on the role of computers in chemical education, a Thesis for scientific conference first-timers, a Perspective on chiral 2D materials, and a spirited In Your Element article.

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  • A Nobel medal in the foreground with some beakers and flasks in the background.

    The 2023 Nobel Prize in Chemistry has been awarded to Moungi G. Bawendi, Louis E. Brus and Alexei I. Ekimov for the discovery and synthesis of quantum dots. In recognition of this award, Nature Portfolio presents a collection of research, review and opinion articles that highlight the development of quantum dots over the past three decades.

  • A lab with robotic arms carrying out experiments

    The combination of techniques such as machine learning, artificial intelligence, robotics and automation can be used to accelerate chemical and materials synthesis. This Focus issue showcases developments in the automation and digitalization of synthesis, as well as highlights the challenges to be overcome in this area.

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    Nature Chemical Engineering is open for submissions. The journal will cover a broad range of systems and scales that significantly advance fundamental research, aid product and process development and explore new technological solutions, all in the context of core chemical engineering approaches. It will publish research, reviews and opinion articles.

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  • Multiple bonds between heavier main-group elements may exhibit different properties and reactivity compared with their second-row counterparts. Now it has been shown that a NHC-stabilized phosphasilyne, a heavier analogue of nitrile, undergoes thermal isomerization to yield a phosphasilenylidene; this represents a rare example of heavier nitrile–isonitrile isomerization.

    • Martin E. Doleschal
    • Arseni Kostenko
    • Shigeyoshi Inoue
    ArticleOpen Access
  • While Mo carbide catalysts have demonstrated excellent performance for CO2 conversion chemistry, these catalysts require harsh synthetic conditions and have poor reaction stabilities. Here flame-synthesized unsaturated Mo oxides are shown to undergo carburization during the reverse water–gas shift reaction, and reaction-induced Mo oxycarbide active sites provide excellent catalytic performance.

    • Xingtao Sun
    • Jiafeng Yu
    • Jian Sun
    Article
  • Simultaneous functionalization of reactive and inert remote sites presents a powerful approach to access complex molecules, yet it is hindered by precise remote C(sp3)–H activation. Now, the accurate translocation of functional groups and remote C–H desaturation has been achieved in parallel through combining functional group migration and cobalt-promoted hydrogen atom transfer.

    • Shengchun Wang
    • Xu Luo
    • Aiwen Lei
    Article
  • Zinc and manganese are commonly used reductants but their redox potentials in organic solvents have not been studied. Now, these redox potentials have been measured, revealing the impact of solvents and additives. The reductant potential substantially influences the performance of nickel-catalysed cross-electrophile coupling reactions, highlighting the merits of tunable electrochemical reduction.

    • Zhi-Ming Su
    • Ruohan Deng
    • Shannon S. Stahl
    Article
  • Although ammonia synthesis represents a major chemical industry, developing highly effective non-iron catalysts is a challenging task. Now it has been shown that anchoring fullerene onto non-iron transition metals separates and activates catalytic sites for hydrogen and nitrogen intermediates, boosting ammonia synthesis rates.

    • Yangyu Zhang
    • Xuanbei Peng
    • Su-Yuan Xie
    Article
  • The development of materials for efficient hydrogen storage is desirable. Now, hydrogen-bonded organic frameworks exhibiting both high volumetric and gravimetric hydrogen storage capacities have been synthesized; hydrogen-bonding interactions are key to guide the catenation of the structure, effectively minimizing the surface area loss in the supramolecular crystals.

    • Ruihua Zhang
    • Hilal Daglar
    • J. Fraser Stoddart
    Article
  • When one says the word alcohol to a non-chemist, it is typically in reference to ethanol, the first alcohol discovered. Chi Chen, Mahlet Garedew, and Stafford W. Sheehan toast ethanol’s past, present, and future.

    • Chi Chen
    • Mahlet Garedew
    • Stafford W. Sheehan
    In Your Element
  • Going to conferences to share and learn about the latest science is a key part of being a researcher. Shira Joudan reflects on presenting their group’s research for the first time and guiding students through their first conference experiences.

    • Shira Joudan
    Thesis
  • The role of computers in the chemical sciences is changing. Previously the domain of the theoretical or computational chemist, advanced digital skills, including data analysis, automation and simulation, are becoming extremely relevant to all. Here, we discuss the importance of integrating digital skills into an undergraduate chemistry programme and highlight some work currently being carried out to achieve this.

    • Andrew R. McCluskey
    • Miguel Rivera
    • Antonia S. J. S. Mey
    Comment
  • Nitric oxide is at the heart of myriad environmental and biological processes. Pokhraj Ghosh and Timothy Warren explore the molecular interconnections and wide-ranging impacts of this molecule which is critical for the health of our planet.

    • Pokhraj Ghosh
    • Timothy H. Warren
    In Your Element
  • In his previous Thesis, Bruce Gibb introduced us to the chemistry of Jupiter’s moons. Now, he takes us on a tour of NASA’s Europa Clipper, the spacefaring chemistry lab set to revolutionize our understanding of Jupiter’s most intriguing satellite.

    • Bruce C. Gibb
    Thesis

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