On the cosmic origins of membranes
Developing membranes would have been crucial for the origins of life. While their formation is debated, it is possible that the building blocks of our present-day cell membranes were formed in space.
Developing membranes would have been crucial for the origins of life. While their formation is debated, it is possible that the building blocks of our present-day cell membranes were formed in space.
Ni-catalysed chain-walking blossomed as an effective synthetic tool to functionalize C(sp3)–H bonds in hydrocarbon chains. This Review provides a detailed overview of the most recent advances in this field, focusing on site-selective and regioselective manipulations at previously out-of-reach C(sp3)–H sites.