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In between the twin certainties of reject and accept lies a large range of decisions covered by the blanket term of Revise. Here we discuss how to deal with this uncertain result.
Radical intermediates are key species in many chemical transformations. Recent advances have provided a new suite of selective radical alkylation reactions. This Comment highlights pioneering studies using alkyl amines that act as radical precursors in a number of catalytic processes by their conversion to alkylpyridinium salts.
The preeminent Haber–Bosch process has been feeding humankind for more than one hundred years. Are electrochemical pathways for ammonia synthesis able to compete with it in the future? Electrocatalysts, electrolytes and novel cell design may be key.
Peer review has established itself as a crucial validation mechanism for modern science. Despite the disadvantages associated with its practice, it remains a powerful method to add value to scientific publications.
Establishing an efficient catalytic system for direct amidation reactions has remained a formidable challenge for years. This Comment will focus on potential new directions in the hope of moving this field forward.