Abstract
We present characterizations of few-layer titanium trisulfide (TiS3) flakes which, due to their reduced in-plane structural symmetry, display strong anisotropy in their electrical and optical properties. Exfoliated few-layer flakes show marked anisotropy of their in-plane mobilities reaching ratios as high as 7.6 at low temperatures. Based on the preferential growth axis of TiS3 nanoribbons, we develop a simple method to identify the in-plane crystalline axes of exfoliated few-layer flakes through angle resolved polarization Raman spectroscopy. Optical transmission measurements show that TiS3 flakes display strong linear dichroism with a magnitude (transmission ratios up to 30) much greater than that observed for other anisotropic two-dimensional (2D) materials. Finally, we calculate the absorption and transmittance spectra of TiS3 in the random-phase-approximation (RPA) and find that the calculations are in qualitative agreement with the observed experimental optical transmittance.
Similar content being viewed by others
Introduction
The isolation of graphene and similar atomically-thin, van der Waals materials has sparked a strong research focus on this broad family which can be exfoliated from bulk layered crystals1,2,3. Despite this growing interest, the research focus has been mainly limited to graphene, boron nitride, and the Mo- and W- based transition metal dichalcogenides4,5,6,7. These materials, although very different, have largely isotropic in-plane optical and electrical properties. Reduced in-plane symmetry could lead to interesting anisotropic properties furthering the functionalities and applications of two-dimensional (2D) materials. In particular, anisotropic 2D materials would be appealing to fabricate passive optical polarizers and high mobility transistors that benefit from reduced backscattering from hot electrons8.
Recently, the layered materials black phosphorus (BP) and rhenium disulfide (ReS2) have shown promising in-plane anisotropy of their electrical and optical properties9,10,11. Harnessing the anisotropic properties of these materials has resulted in applications such as an integrated digital inverter12, and a linear-dichroic photodetector13. Exploration of other layered materials with stronger structural in-plane anisotropy would allow the opportunity to couple the advantages of 2D materials (flexibility, transparency, and large surface to volume ratio) with fully quasi-one dimensional (1D) properties. The transition metal trichalcogenides (with general formula MX3) are a prospective family of materials to achieve this goal due to their reduced in-plane bonding symmetry14. Fig. 1 shows the crystal structure of a single layer of titanium trisulfide (TiS3), the material under consideration in this study. Differences in the Ti-S bond length along the a (2.65 Å) and b (2.45 Å) axes lead to highly conducting 1D chains along the b-axis and results in strong anisotropic properties15,16. The red dashed lines mark the titanium, 1D chains in Fig. 1 which are also covalently bonded along the a-axis forming sheets that interact by van der Waals forces. Recent ab initio calculations predict an upper limit for b-axis electron mobilities of more than 10,000 cm2/Vs (higher than MoS217) and a-axis mobilities of more than an order of magnitude less15. To date, TiS3 has been exfoliated down to a single-layer (0.7 nm thick) and field-effect transistors and photodetectors have been demonstrated18,19,20,21 but a handling of the in-plane anisotropic properties of 2D, few-layer flakes is still lacking.
Here, specifically, we study the in-plane anisotropy of the electrical and optical properties of few-layer TiS3 flakes. Electrical transport, angle resolved polarization Raman spectroscopy, and optical transmission measurements are used to probe the anisotropic behavior of thin TiS3 specimens. We find that the electrical conductivity shows a marked anisotropy of Gmax/Gmin = 2.1 at room temperature and can reach Gmax/Gmin = 4.4 at low temperatures. We also note that the Raman spectra of thin flakes show strong in-plane anisotropy that can be used to identify the crystalline orientation of 2D, few-layer TiS3 samples. Interestingly, TiS3 displays strong linear dichroism, optical absorption that depends on the relative orientation between the materials lattice and incident linearly polarized light, with a magnitude much greater than that observed for BP and other anisotropic 2D materials. Finally, to better understand these findings we calculate the absorption and transmittance spectra in the random-phase-approximation (RPA)22,23,24 and find that the calculations are in qualitative agreement with our experimental findings.
Results and Discussion
TiS3 samples are prepared by mechanical exfoliation of bulk TiS3 material which is synthesized by sulphuration of titanium disks (as reported in ref. 25). Recently, we have shown that by varying the temperature of the growth process, control over the morphology of the TiS3 bulk material can be achieved19. At a growth temperature of 400 °C the material grows in a sheet-like morphology permitting the isolation of few-layer, 2D flakes while at 500 °C it grows adopting a ribbon-like morphology, characteristic of the MX3 chalcogenides (M = Ti, Zr, Hf and X = S, Se, Te), with high aspect ratio. Figure 2(a) shows an optical image of a 6.4 nm (~9 layers) thick TiS3 nanosheet prepared by mechanical exfoliation of the material grown at 400 °C. In order to study the in-plane anisotropic electrical properties of the exfoliated flakes, 12 electrodes are created (using standard e-beam lithography, Ti/Au evaporation, and lift-off) to measure the electrical properties along different directions in rotational steps of 30 degrees. Figure 2(b) shows an AFM scan of the final device with 12 patterned electrodes.
The reduced thickness of the isolated TiS3 nanosheet allows us to study the electrical transport in a field-effect geometry, using the underlying 285 nm SiO2 as a gate dielectric and the heavily doped silicon as a gate electrode. We modulate the density of the charge carriers by applying a back gate voltage which makes it possible to estimate the field effect carrier mobility. Figure 2(c) shows transistor transfer curves (source-drain current acquired at fixed bias, 100 mV, while sweeping the back gate voltage) measured between two opposing electrodes. We set 0° (dashed white line in Fig. 2(b)) as the high conductance axis and plot the transfer curves for the next four pairs of electrodes in steps of 30° in a counterclockwise direction (0° to 120°). Along the b-axis, we estimate an electron mobility of 25 cm2/Vs from the measured transconductance using the standard linear regime, FET mobility calculation (unadjusted for contact resistance)26. Figure 2(d) shows a polar plot with the angular dependence of the conductance at gate voltages of −40 V, 0 V, and 40 V. The conductances for angles 0° through 120° correspond to the transfer curves in Fig. 2(c). The minimum (maximum) conductance directions are determined as the a-axis (b-axis) crystalline directions of the TiS3 nanosheets. These directions correspond to a conductance anisotropy of Gmax/Gmin = 2.1 as well as an anisotropy in the calculated mobilities of μb/μa = 2.3 (see Supporting Information, Figure S1 for a polar plot). The anisotropy in the conductance and mobility represents a more than 30% increase over reported anisotropy values for BP FET devices10,27,28. Furthermore, BP shows little change in its anisotropy with decreased temperature whereas we find that the anisotropy in TiS3 is strongly temperature dependent10. In Fig. 2(e,f) we plot the transfer curves and angle dependent conductances for the same device measured at a temperature of 25 K. The anisotropy in the mobility increases to μb/μa = (23 cm2/Vs)/(3 cm2/Vs) = 7.6 (see supplement figure S1 for polar plots) and we calculate an increase of the anisotropy in conductance to Gmax/Gmin = 4.4. Anisotropy values for our few-layer flake devices are slightly lower than the corresponding bulk values29,30. We speculate that current spreading and increased Coulomb interactions are the main causes which lead to a decrease in the anisotropy when compared with bulk values. Full temperature dependent measurements of nanosheets of thicknesses from bulk to few layers would help ascertain these discrepancies.
We further characterize the anisotropy of TiS3 by employing angle-resolved polarization Raman spectroscopy, as it has proven to be a very powerful tool to delineate the structural and vibrational properties of 2D materials31,32,33. Figure 3 shows Raman spectra acquired on a TiS3 ribbon grown at 500 °C under different polarization conditions. Note that we first select a nanoribbon to directly identify the crystalline b-axis which is the preferential growth axis. Fig. 3(a) shows 5 prominent peaks in the Raman spectra of an isolated nanoribbon sample exfoliated on to a Si/SiO2 substrate. While the peak at ~520 cm−1 is due to a Raman mode of the underlying silicon substrate, the other 4 peaks, (occurring at 177 cm−1, 300 cm−1, 371 cm−1, and 559 cm−1) correspond to Ag-type Raman modes of the TiS3 crystal and are in good agreement with the modes reported for bulk TiS334,35. While all the modes change in intensity with polarization angle (see Supporting Information for angle dependence of all modes), we find that the peak around 370 cm−1 is the most sensitive to the relative orientation between the b-axis and the polarization of the excitation laser (top panel of Fig. 3(a)). In fact, its intensity is strongly reduced when the polarization of the excitation is parallel to the b-axis. This is evident after rotating the substrate by ~90° and taking a second Raman spectra measurement with the sample now nearly parallel to the excitation/detection polarization (see bottom panel of Fig. 3(a)). This finding allows us to determine the crystalline orientation of exfoliated TiS3 nanosheets whose b-axis direction cannot be distinguished at a glance from the material morphology like in the case of the nanoribbons.
In Fig. 3(b), the intensity of the 370 cm−1 Raman peak (measured on a 3 nm thick, about 4 layer thick TiS3 nanosheet) is displayed at different excitation polarization angles while keeping the detection polarization parallel to the horizontal axis (see Supporting Information for a direct comparison between Raman spectra for the nanoribbon in Fig. 3(a) and the nanosheet in Fig. 3(b) showing the same Ag-type modes). The minimum of the Raman peak intensity is reached when the excitations polarization forms an angle of 130° with the horizontal axis, indicating the direction of the b-axis in the thin TiS3 nanosheet. Below the polar plot, Fig. 3(b) also displays an optical image of the studied flake and an AFM image shown with the same orientation as the optical image. A zoom-in of the AFM image shows how the determined b-axis direction is parallel to the straight edges of the TiS3 nanosheet. In Figure S2, the reader will find polar plots, similar to Fig. 3(b), for a TiS3 nanoribbon and a TiS3 nanosheet acquired at different sample orientation angles showing that the minimum occurs when the polarization of the excitation is aligned with the b-axis.
The anisotropy in the optical properties of TiS3 is further characterized using transmission mode optical microscopy. A linear polarizer is placed between the microscope light source and the condenser lens. Transmission mode images are acquired while the polarizer is rotated in steps of ~3°. The transmission is then calculated by normalizing the intensity measured on the TiS3 by the intensity measured on the nearby bare substrate. Figure 4(a) shows a polar plot with the angular dependence of the transmission of a TiS3 nanosheet. Besides the angle values, Fig. 4(a) also displays the acquired optical images, highlighting the orientation of the excitation polarization with respect to the nanosheet. The polar-plot clearly shows a marked linear dichroism i.e., a variation in the optical absorption for different polarization angles, for the TiS3 nanosheet. The transmission reaches a minimum value when the excitation light is polarized along the elongated side of the flake, which corresponds to the b-axis. These absorption characteristics are analogous to that of a wire grid polarizer. The high conducting 1D chains of the TiS3 absorb light with a polarization that is parallel to the chain axis (b-axis). The reader can find similar measurements made on a nanoribbon, where the b-axis can be easily determined in the Supporting Information (see Figure S3). The ratio between the b-axis and the a-axis transmission can reach values as high as 30 and decreases for thinner flakes (see Supporting Information, Figure S4). For a direct comparison, we measure the transmission of multilayer BP and MoS2 flakes of similar absolute transmission which present transmission ratios of ≈1.4 and ≈1, respectively (see Figure S5 in the Supporting Information).
To better understand and reaffirm the linear dichroic behavior found in the optical transmission measurements, we perform density functional theory (DFT) calculations in combination with many-body techniques (see the Methods section) to calculate the absorption spectrum for bulk TiS3. Figure 4(b) shows the calculated absorption spectra for bulk TiS3 when the electric field is aligned parallel to the a-axis (black solid curve) and b-axis (black dashed curve). Across the visible wavelengths, the absorption is much larger when the excitation field is parallel to the b-axis than when it is parallel to the a-axis. The inset in Fig. 4(b) shows the calculated transmittance in the a–b plane for red (1.9 eV), green (2.4 eV), and blue (2.72 eV) excitations, agreeing qualitatively well with the experimental transmittance of the red, green, and blue channels in Fig. 4(a).
Conclusions
In summary, we present electrical and optical measurements of the in-plane anisotropy of a recently isolated 2D material, TiS3, with 1D-like properties. From electrical measurements we calculate an anisotropy in the in-plane conductivity of 2.1 at room temperature and 4.4 at a temperature of 25 K. Through Raman characterization, we find that the Raman mode at 370 cm−1 is sensitive to the orientation of the b-axis relative to that of the excitation polarization. This allows for simple identification of the high conductance b-axis in TiS3 nanosheets. Furthermore, through optical transmission measurements and DFT calculations we show that TiS3 exhibits strong linear dichroism where the ratio in the transmission between the b-axis and a-axis reaches values as high as 30. The strong anisotropic properties of TiS3 set it apart from the commonly studied 2D materials which have largely isotropic properties and makes it an interesting material for future applications.
Methods section
Synthesis of TiS3 bulk material
TiS3 has been synthetized by sulfuration of Ti discs (Goodfellow 99.9%, Ø = 10 mm) which had been previously etched in acid mixture (HF:HNO3, 4:30 wt%) to clean the surface of any oxide impurities. Sulfuration took place in a vacuum sealed ampoule with sulfur powder (Merk, 99.75%) enough to get the sulfur vapor pressure at 500 °C (∼2 bars) and 400 °C (∼0.5 bars) in order to get nanoribbons and nanosheets, respectively. Time of sulfuration was 20 hours. Method was described in ref. 25.
Fabrication and measurement of FET devices: Few-layer TiS3 nanosheets are isolated and exfoliated onto Si/SiO2 (285 nm) substrates using a viscoelastic stamp (PDMS). Individual nanosheets are selected by optical color contrast and Ti/Au electrodes are patterned using electron beam lithography, thin-film evaporation, and lift-off in warm acetone. Electrical measurements are performed in a Lakeshore probe station in vacuum.
Raman measurements
Raman measurements are performed in a Renishaw system with a 514 nm laser. All spectra are recorded at low powers to prevent laser-induced modification of the samples.
Optical Transmission measurements
A Nikon Eclipse Ci optical microscope equipped with a Canon EOS 1200D digital camera has been employed to perform the optical transmission measurements. A rotation stage with a linear polarizer has been placed between the illumination source and the microscope condenser to control the polarization of the incident light. In order to determine the polarization angle dependence of the transmission, the polarizer has been rotated in 3° steps and a transmission mode image has been acquired at each step. The transmission is then calculated by dividing the intensity transmitted through the bare substrate and that transmitted by the TiS3.
DFT calculations
Both for Ti and S, the exchange-correlation potential is described self-consistently within the generalized gradient approximation throughout the Perdew–Burke–Ernzerhof’s functional (PBE). For S a norm-conserving Martins–Troulliers’ pseudopotential is used, while for Ti a norm-conserving Goedecker–Hartwigsen–Hutter–Teter’s pseudopotential, including semi-core states for the valence electrons, is used36,37. We have relaxed the atomic positions and the unit cell vectors with a residual force after relaxation of 0.001 a.u. by starting from the atomic positions provided in ref. 17. The kinetic energy cutoff for the plane wave basis set is 180 Ry. The sampling of the Brillouin zone is 10 × 10 × 10 according to the Monkhorst–Pack scheme. First-principles electronic structure calculations and structure optimisation have been performed with the PWSCF code of the Quantum-ESPRESSO package38. As DFT tends to underestimate the electronic bandgap, we performed non-self-consistent G0W039,40 calculations in order to get accurate values for the electronic band structure. The local field effects in the screening calculations have been taken into account and we carefully converged the electronic quasi-particle gap. The G0W0 corrected DFT bands have been used to calculate the absorption spectra in the random-phase approximation (RPA). To construct the kernel in the RPA we have considered 30 valence and 120 conduction bands. The size of the response function has been carefully converged, hence local field effects corresponding to charge oscillations are accurately included. The plane-wave code Yambo41 is used to calculate the quasi-particle corrections and the optical properties in the RPA.
Additional Information
How to cite this article: Island, J. O. et al. Titanium trisulfide (TiS3): a 2D semiconductor with quasi-1D optical and electronic properties. Sci. Rep. 6, 22214; doi: 10.1038/srep22214 (2016).
References
Novoselov, K. et al. Two-dimensional atomic crystals. Proc. Natl. Acad. Sci. USA 102, 10451–10453 (2005).
Butler, S. Z. et al. Progress, challenges, and opportunities in two-dimensional materials beyond graphene. ACS Nano 7, 2898–2926 (2013).
Mak, K. F., Lee, C., Hone, J., Shan, J. & Heinz, T. F. Atomically Thin MoS_ {2}: A New Direct-Gap Semiconductor. Phys. Rev. Lett. 105, 136805 (2010).
Schwierz, F. Graphene transistors. Nat. Nanotechnol. 5, 487–496 (2010).
Radisavljevic, B., Radenovic, A., Brivio, J., Giacometti, V. & Kis, A. Single-layer MoS2 transistors. Nat. Nanotechnol. 6, 147–150 (2011).
Dean, C. et al. Boron nitride substrates for high-quality graphene electronics. Nat. Nanotechnol. 5, 722–726 (2010).
Georgiou, T. et al. Vertical field-effect transistor based on graphene-WS2 heterostructures for flexible and transparent electronics. Nat. Nanotechnol. 8, 100–103 (2013).
Abudukelimu, A. et al. The effect of isotropic and anisotropic scattering in drain region of a ballistic channel diode. 10th IEEE International Conference on Solid-State and Integrated Circuit Technology (ICSICT) IEEE. Shanghai (2010, Nov).
Ho, C., Huang, Y., Tiong, K. & Liao, P. In-plane anisotropy of the optical and electrical properties of layered ReS2 crystals. J. Phys. Condens. Matter 11 5367 (1999).
Xia, F., Wang, H. & Jia, Y. Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics. Nat. Commun. 5, 4458 (2014).
Chenet, D. et al. In-Plane Anisotropy in Mono-and Few-Layer ReS2 Probed by Raman Spectroscopy and Scanning Transmission Electron Microscopy. Nano Lett. 15, 5667–5672 (2015).
Liu, E. et al. Integrated digital inverters based on two-dimensional anisotropic ReS2 field-effect transistors. Nat. Commun. 6, 6991 (2015).
Yuan, H. et al. Polarization-sensitive broadband photodetector using a black phosphorus vertical p–n junction. Nat. Nanotechnol. 10, 707–713 (2015).
Meerschaut, A. & Rouxel, J. In Crystal Chemistry and Properties of Materials with Quasi-One-Dimensional Structures 205–279 (Springer, 1986).
Dai, J. & Zeng, X. C. Titanium Trisulfide Monolayer: Theoretical Prediction of a New Direct‐Gap Semiconductor with High and Anisotropic Carrier Mobility. Angew. Chem. 54, 7572–7576 (2015).
Jin, Y., Li, X. & Yang, J. Single layer of MX3 (M = Ti, Zr; X = S, Se, Te): a new platform for nano-electronics and optics. Phys. Chem. Chem. Phys. 17, 18665–18669 (2015).
Cai, Y., Zhang, G. & Zhang, Y.-W. Polarity-reversed robust carrier mobility in monolayer MoS2 nanoribbons. J. Am. Chem. Soc. 136, 6269–6275 (2014).
Island, J. O. et al. Ultrahigh Photoresponse of Few‐Layer TiS3 Nanoribbon Transistors. Adv. Opt. Mater. 2, 641–645 (2014).
Island, J. O. et al. TiS3 transistors with tailored morphology and electrical properties. Adv. Mater. 27, 2595–2601 (2015).
Lipatov, A. et al. Few-layered titanium trisulfide (TiS3) field-effect transistors. Nanoscale 7, 12291–12296 (2015).
Molina-Mendoza, A. J. et al. Electronic Bandgap and Exciton Binding Energy of Layered Semiconductor TiS3 . Adv. Electron. Mater 1, 1500126 (2015).
Nozieres, P. & Pines, D. Electron interaction in solids. General formulation. Phys. Rev. 109, 741 (1958).
Ehrenreich, H. & Cohen, M. H. Self-consistent field approach to the many-electron problem. Phys. Rev. 115, 786 (1959).
Nozières, P. & Pines, D. Electron interaction in solids. Collective approach to the dielectric constant. Phys. Rev. 109, 762 (1958).
Ferrer, I. J., Maciá, M. D., Carcelén, V., Ares, J. R. & Sánchez, C. On the Photoelectrochemical Properties of TiS3 Films. Energy Procedia 22, 48–52 (2012).
Horowitz, G., Hajlaoui, R., Fichou, D. & El Kassmi, A. Gate voltage dependent mobility of oligothiophene field-effect transistors. J. Appl. Phys. 85, 3202–3206 (1999).
Liu, H. et al. Phosphorene: an unexplored 2D semiconductor with a high hole mobility. ACS Nano 8, 4033–4041 (2014).
Lu, W. et al. Probing the anisotropic behaviors of black phosphorus by transmission electron microscopy, angular-dependent Raman spectra, and electronic transport measurements. Appl. Phys. Lett. 107, 021906 (2015).
Gorlova, I. G., Zybtsev, S. G. e. & Pokrovskii, V. Y. Conductance anisotropy and the power-law current-voltage characteristics along and across the layers of the TiS3 quasi-one-dimensional layered semiconductor. JETP Lett. 100, 256–261 (2014).
Gorlova, I. et al. Magnetotransport and power-law I–V curves of the layered quasi one-dimensional compound TiS 3. Physica B 460, 11–15 (2015).
Ferrari, A. et al. Raman spectrum of graphene and graphene layers. Phys. Rev. Lett. 97, 187401 (2006).
Ribeiro, H. B. et al. Unusual angular dependence of the Raman response in black phosphorus. ACS Nano 9, 4270–4276 (2015).
Lee, C. et al. Anomalous lattice vibrations of single-and few-layer MoS2 . ACS Nano 4, 2695–2700 (2010).
Galliardt, D., Nieveen, W. & Kirby, R. Lattice properties of the linear chain compound TiS3 . Solid State Commun. 34, 37–39 (1980).
Gard, P., Cruege, F., Sourisseau, C. & Gorochov, O. Single‐crystal micro‐Raman studies of ZrS3, TiS3 and several Zr1–xTixS3 compounds (0 < x ≤ 0.33). J. Raman Spectrosc. 17, 283–288 (1986).
Hartwigsen, C., Gœdecker, S. & Hutter, J. Relativistic separable dual-space Gaussian pseudopotentials from H to Rn. Phys. Rev. B 58, 3641 (1998).
Goedecker, S., Teter, M. & Hutter, J. Separable dual-space Gaussian pseudopotentials. Phys. Rev. B 54, 1703 (1996).
Giannozzi, P. et al. QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials. J. Phys.: Condens. Matter 21, 395502 (2009).
von der Linden, W. & Horsch, P. Precise quasiparticle energies and Hartree-Fock bands of semiconductors and insulators. Phys. Rev. B 37, 8351 (1988).
Engel, G. & Farid, B. Generalized plasmon-pole model and plasmon band structures of crystals. Phys. Rev. B 47, 15931 (1993).
Marini, A., Hogan, C., Grüning, M. & Varsano, D. Yambo: an ab initio tool for excited state calculations. Comput. Phys. Commun. 180, 1392–1403 (2009).
Momma, K. & Izumi, F. VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data. J. Appl. Crystallogr. 44, 1272–1276 (2011).
Acknowledgements
This work was supported by the Dutch Organization for Fundamental Research on Matter (NWO/OCW). R. D’A. and R. B. acknowledge financial support by the DYN-XC-TRANS (Grant No. FIS2013-43130-P), and NanoTHERM (Grant No. CSD2010-00044) of the Ministerio de Economia y Competitividad (MINECO), and Grupo Consolidado UPV/EHU del Gobierno Vasco (Grant No. IT578-13). R. B. acknowledges the financial support of the Ministerio de Educacion, Cultura y Deporte (Grant No. FPU12/01576). AC-G acknowledges financial support from the BBVA Foundation through the fellowship “I Convocatoria de Ayudas Fundacion BBVA a Investigadores, Innovadores y Creadores Culturales”, from the MINECO (Ramón y Cajal 2014 program, RYC-2014-01406) and from the MICINN (MAT2014-58399-JIN). MIRE Group thanks MINECO (MAT2011-22780) for financial support.
Author information
Authors and Affiliations
Contributions
A.C.G. conceived the project. J.O.I. and A.C.G. performed the experiments. R.B. and R.D. performed the calculations. M.B., J.M.C., J.R.A., C.S. and I.J.F. synthesized the bulk material. J.O.I., R.B., R.D., H.S.J.Z., I.J.F. and A.C.G. wrote the manuscript. All authors contributed though scientific discussion.
Corresponding authors
Ethics declarations
Competing interests
The authors declare no competing financial interests.
Supplementary information
Rights and permissions
This work is licensed under a Creative Commons Attribution 4.0 International License. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in the credit line; if the material is not included under the Creative Commons license, users will need to obtain permission from the license holder to reproduce the material. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/
About this article
Cite this article
Island, J., Biele, R., Barawi, M. et al. Titanium trisulfide (TiS3): a 2D semiconductor with quasi-1D optical and electronic properties. Sci Rep 6, 22214 (2016). https://doi.org/10.1038/srep22214
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/srep22214
This article is cited by
-
Highly-anisotropic carrier transport and optical properties of two-dimensional titanium trisulfide
Journal of Materials Science (2022)
-
In-plane anisotropic optical and mechanical properties of two-dimensional MoO3
npj 2D Materials and Applications (2021)
-
A graphene/TiS3 heterojunction for resistive sensing of polar vapors at room temperature
Microchimica Acta (2020)
-
Controlling electronic structure of single-layered \({\hbox {HfX}}_{3}\) (\(\hbox {X=S}\), Se) trichalcogenides through systematic Zr doping
Journal of Materials Science (2020)
-
Two-dimensional black arsenic for Li-ion battery applications: a DFT study
Journal of Materials Science (2019)
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.