Broadband perfect light trapping in the thinnest monolayer graphene-MoS2 photovoltaic cell: the new application of spectrum-splitting structure

The light absorption of a monolayer graphene-molybdenum disulfide photovoltaic (GM-PV) cell in a wedge-shaped microcavity with a spectrum-splitting structure is investigated theoretically. The GM-PV cell, which is three times thinner than the traditional photovoltaic cell, exhibits up to 98% light absorptance in a wide wavelength range. This rate exceeds the fundamental limit of nanophotonic light trapping in solar cells. The effects of defect layer thickness, GM-PV cell position in the microcavity, incident angle, and lens aberration on the light absorptance of the GM-PV cell are explored. Despite these effects, the GM-PV cell can still achieve at least 90% light absorptance with the current technology. Our proposal provides different methods to design light-trapping structures and apply spectrum-splitting systems.

can usually be adjusted by changing a characteristic parameter, such as the cavity length and the lattice constant of the photonic crystal. Therefore, employing a spectrum-splitting structure can focus sunlight with different wavelengths onto a light-trapping structure with different characteristic parameters to enhance light absorption through resonance in a wide frequency range.
A spectrum-splitting structure is widely applied in super-efficient photovoltaic cells [31][32][33][34][35] . This structure can reduce the thermal losses caused by the mismatch between the photon energy and the semiconductor's band gap by focusing light with different wavelengths on semiconductors with various band gaps [31][32][33][34][35] . Thermal losses may be reduced to approximately 10% by using 8-10 semiconductors with different band gaps to constitute a photovoltaic cell 32 . In our previous studies, we combined the spectrum-splitting structure and the resonance back-reflection light trapping structure to achieve broadband perfect absorption in a semiconductor film with a thickness of approximately 100 nm 36 . However, light localization is weak in the resonance back-reflection light trapping structure. Hence, perfect light absorption can hardly be achieved in a 1 nm thick medium layer. Demands on material mobility can be minimized by reducing the thickness of the medium layer to ~1 nm, and the energy band structure and optical properties of a ~1 nm semiconductor film can be controlled by adjusting structural and physical parameters such as stress. This process promotes the applications of energy band engineering in photovoltaic cells.
Several recent studies have explored the enhanced absorption of light in 2D materials such as graphene by using various optical microstructures [37][38][39][40][41][42][43][44][45][46][47][48][49] . In the present study, we combined an asymmetric photonic crystal microcavity with a wedge-shaped defect layer and spectrum-splitting structure. Using this structure produced a GM-PV cell that is three times thinner than the traditional photovoltaic cell and that exhibits a preferable light absorptance higher than 98% in a wide wavelength range. We also determined the effects of defect layer thickness, GM-PV cell position in the microcavity, incident angle, and lens aberration on the light absorption rate of the GM-PV cell to compare the calculation results and the actual outcome. Despite these effects, the light absorptance of the GM-PV cell can exceed 90% with the current technology. The study provides different methods to design light-trapping structures and apply spectrum-splitting systems.

Results
The effect of the common microcavity on the absorptance of the GM-PV cell is presented to understand the physical mechanism and show the advantages and disadvantages of traditional i-LTS. Figure 1(a) shows the structure of a common microcavity. The cyan layer, blue layer, and the red layer is the SiO 2 layer, ZnS layer, and the GM-PV cell layer, respectively. The defect layer with dielectric n c is in the middle of the cavity, and the GM-PV cell is at the center of the defect layer. The distributed Bragg reflectors (DBRs) in which two materials with different dielectric (n 1 and n 2 ) are alternately distributed are on both sides of the cavity with periodicities of M 1 and M 2 . n c = n 1 = 1.55 (e.g., SiO 2 ) and n 2 = 2.59 (e.g., ZnS) are used in the calculation. The corresponding layer thicknesses are d 1 = λ DBR /4n 1 and d 2 = λ DBR /4n 2 , where λ DBR is the center wavelength. All layers are nonmagnetic (μ = 1). For a direct comparison, the light absorptivities of the monolayer graphene, MoS 2 , and GM-PV cell were calculated. The refraction index of graphene can be expressed as = . +  Fig. 1(b). The absorptance of the GM-PV cell is approximately 10%, increases rapidly at short wavelengths, and reaches 30%. Previous studies reported that using an asymmetric microcavity can reduce reflection and enhance light absorption 39 . We calculated the absorptance at wavelengths of 470 and 610 nm [ Fig. 1(c,d)] as the periodicity of the DBRs on both sides of the microcavity varies. At 470 nm, the GM-PV cell exhibits a high absorptance, and the required Q-value is small. When M 1 = 2 and M 2 > 5, the absorption is almost saturated. At 610 nm, the GM-PV cell exhibits a low absorptance, and the required Q-value is large. When M 1 = 3 and M 2 > 6, the absorption is basically saturated. The changes in absorptance with varying wavelengths are presented in Fig. 1(e). The maximum absorptance is 98.5%, and the full width at half maximum (FWHM) is 20.2 nm. In this structure, the absorptance is close to 1 is because interference can reduce the reflection, and light can be reflected in the microcavity for multiple times, causing a strong light localization [inset of Fig. 1 The resonance state in the microcavity is sensitive to the thickness of the defect layer and the incident angle. The calculated results are illustrated in Fig. 1(f-h). The resonant wavelength of the microcavity satisfies m i λ c /2 = L c cosθ′ , where L c = n c d c denotes the optical path of the microcavity, n c and d c are the refractive index and the thickness of the defect layer, respectively; m i is the positive integer; and θ′ = arcsinθ i /n c signifies the propagation angle of the light in the defect layer, where θ i is the incident angle. Thus, the resonant wavelength linearly increases as the defect layer thickness increases. Then, the resonant wavelength moves toward the direction of the short wave as the incident angle increases. Perfect absorption is mainly distributed at the photonic band gap (470-670 nm) because the thickness of the photonic crystals on both sides remains unchanged. The resonant wavelength also correlates with the propagation angle in the defect layer. The higher the refractive index of the defect layer, the smaller the propagation angle. Accordingly, minimal changes in the resonance peak occur as the incident angle varies. In the calculations, the resonance peak is sensitive to the incident angle when the refractive index of the defect layer is 1.55. The resonance absorption peak slightly shifts when the incident angle is 15°. Comparatively, the resonance peak shifts with a distance up to a FWHM when the incident angle is 30°.
Basing from the calculation results, we can conclude that the light absorption of the GM-PV cell in a common photonic crystal microcavity can only be enhanced at some specific wavelengths. In other words, the method cannot be directly applied in photovoltaic cells. However, the microcavity-based resonant wavelength linearly increases as the defect layer thickness increases. Therefore, a wedge-shaped defect layer is introduced, and sunlight with different wavelengths can be focused onto different positions in the microcavity through the spectrum-splitting structure. The resonance absorption of light can be achieved at the position where light is focused because of the appropriate thickness distribution of the defect layer [ Fig. 2(a)]. Accordingly, resonance-induced absorption enhancement can be realized in a broad frequency range. The spectrum-splitting Scientific RepoRts | 6:20955 | DOI: 10.1038/srep20955 structure is composed of a dense flint ZF13 prism and a low dispersion convex lens. The refractive index for ZF13 glass is Similarly, the DBRs on both sides of the microcavity are wedge-shaped to further increase the band gap [ Fig. 2(b)]. Figure 2(c) presents the calculation results, in which the periodicities of the upper and lower DBRs are 3 and 10, respectively. The slope of the wedge-shaped layer is about 1.4 × 10 −6 ; hence, the layers can be treated as parallel planes at each point. Thus, the transfer matrix method can be used in the calculation (Supplementary Information S1). Light with different wavelength incidents on different positions in the microcavity through the spectrum-splitting structure can achieve a resonance-induced absorption enhancement by adjusting the thickness of the defect layer. The calculated thickness distribution of the resonance defect layer is presented in the inset of Fig. 2(c). In this system, the absorptance of the GM-PV cell can exceed 98% at a wavelength of 500-670 nm (i.e., 670 nm at approximately the band gap of the monolayer MoS 2 ) by combining the spectrum-splitting structure and i-LTS. The absorptance of the GM-PV cell significantly decreases when the wavelength is less than 500 nm. This result can be attributed to the strong absorption of the GM-PV cell at short wavelengths and the large periodicity of the DBR. These features can suppress interference, increase reflection, and reduce absorptance [ Fig. 1(c)]. Nevertheless, shoulder-to-shoulder microcavities with different Q-values can be used in the design [inset of Fig. 2(d)] similar to the design of the shoulder-to-shoulder sub-batteries adopted in common spectrum-splitting systems. Light absorption at wavelengths less than 500 nm can be enhanced by reducing the periodicity of the upper DBR [ Fig. 2(d)]. The DBR can also be fabricated with parallel layers by using the shoulder-to-shoulder microcavities ( Supplementary Information S2). Some position might absorb less energy depending on the solar spectrum. However, different from the traditional photovoltaic cell with a spectrum-splitting structure, the GM-PV cell is utra-thin. The photo-generated electrons and holes can be collected rapidly by the electrode. The space charge accumulation is weak in the GM-PV cell.
To associate the calculation results with practical production, the effects of GM-PV cell location in the microcavity, defect layer thickness, incident angle, and lens aberration on the absorptance of the GM-PV cell are further investigated. The calculation results are presented in Fig. 3. Other effects such as the influence of the fabrication tolerances of the photonic crystal ( Supplementary Information S3), outermost layer correction ( Supplementary  Information S4), and the tolerances of the photovoltaic cells position (Supplementary Information S5) are shown in the supplementary materials.
Light localization is the strongest at the center of the cavity. The absorptance of the GM-PV cell declines when it is off-center. Nevertheless, the absorptance at the off-center position is slightly affected because the light field is almost evenly distributed in the cavity. The absorptance of the GM-PV cell exhibits almost no variation at Δ Z = 10 nm, slightly varies at Δ Z = 20 nm, and significantly declines at Δ Z ≥ 30 nm. The absorptance change increases at short wavelengths. This result can be attributed to the fact that a thinner defect layer at short wavelengths leads to a greater relative deviation. A change in defect layer thickness influences the absorptance of the GM-PV cell. The resonant frequency of the microcavity varies as the defect layer thickness varies. Thus, the resonance-induced perfect absorption of the light incident on the cavity can no longer be achieved, i.e., the absorptance is reduced. The absorptance slightly changes when the variation amplitude of the defect layer thickness is 1 nm. The light absorptance at > 500 nm wavelengths significantly decreases when the variation amplitude of the thickness is 2 nm. However, it can still exceed 90%. The light absorptance at < 500 nm wavelengths shows almost no change because of the lower Q-value of the microcavity. The light localization becomes weaker and the FWHM increases as the Q-value decreases. The tolerance of film growth can be less than 1 nm or even as low as the thickness of an atomic layer because of the development of material growth techniques such as molecular beam epitaxy (MBE).
As described earlier, varying incident angles can change the resonant frequency of the microcavity. Nevertheless, the resonant frequency of the microcavity slightly varies when the incident angle slightly changes. The calculated results are presented in Fig. 3(c,d). The absorptance slightly changes when the variation amplitude of the incident angle is 5° but significantly declines when the incident angle is altered by 10°. The incident angle can be controlled at approximately 0.1° by using the ray tracing system 52 .
Aberration causes the appearance of a light spot after lens imaging. The wavelength perfectly matches with the thickness of the defect layer around the center of the light spot, whereas the wavelength in other positions cannot be matched properly, leading to a decline in absorptance. Figure 3(e,f) present the effects of aberration on the absorptance of the GM-PV cell. Larger lens diameter means larger light spot. Accordingly, mismatch becomes evident, and GM-PV cell absorptance is reduced. The effect of aberration on the absorptance of the GM-PV cell mainly depends on the Q-value and the light-splitting ability of the spectrum-splitting structure. Smaller Q-value means weaker light localization and larger FWHM. Accordingly, the effect of aberration is weak under this condition. In lenses with varying diameters, the absorptance variation at wavelengths less than 500 nm significantly differs from that at wavelengths higher than 500 nm. Figure 3(e,f) show that larger vertical angle of the prism means stronger light-splitting ability and smaller variation gradient. That is, the effect of aberration is minimal.

Discussion
Spectrum-splitting system. The spectrum-splitting structure can reduce the thermal losses caused by the mismatch between the photon energy and the semiconductor's band gap. It can also enhance the light-trapping efficiency via combined utilization with i-LTS. The introduction of the spectrum-splitting structure increases the flexibility of the design of the light-trapping structure. The design of the shoulder-to-shoulder battery can also be adopted. Various light-trapping structures can be selected for sub-batteries with different wavelengths and materials with different band gaps. In addition to the microcavity in the current study, other light-trapping structures can also be employed and combined with the spectrum-splitting structure. These structures include photonic crystal, plasma, and nano-semiconductor-column array with resonant frequencies that are continuously adjustable by some structural parameters. The spectrum-splitting structure studied in this article is composed of disperse prism and convex lens. The structure is simple and can be manufactured easily, which is beneficial to revealing the fundamental principles. However, the light-splitting efficiency is not high, and the system can reflect 15-20% of sunlight. In this case, a highly efficient spectrum-splitting structure should be adopted [32][33][34][35] . The disperse plane lens may be a potential choice 53 .

Light-trapping ability and technique precision.
Theoretically, the light-trapping ability is no limitation in i-LTS combined with the spectrum-splitting structure. However, the practical light-trapping ability is limited to the technique precision. The light-trapping ability of an interference structure can be measured by the Q-value. Larger Q-value means stronger light-trapping ability. Although the Q-value of optical microstructures without absorption can reach up to 10 8 , the light-trapping ability is limited by the processing technique. Basing from the definition of Q-value Q = ω 0 /Γ , we can conclude that greater Q-values mean smaller FWHM. Meanwhile, smaller FWHM indicates higher demands on the processing precision. For example, with the assumption that the resonant wavelength of the microcavity is λ c = 2L c = 2n c d c , resonant wavelength will be changed by Δ λ c = 2n c Δ d c if d c is varied to d c + Δ d c because of processing errors, and the absorptance will be reduced by 50% if Δ λ c reaches half of the FMHM. Thus, after considering processing precision, the light-trapping ability based on the microcavity can be increased by at most two to three times than the results of the study. In addition, obtaining the perfect absorption in monolayer graphene with microcavity is difficult to obtain because the light absorption of monolayer graphene is only about 2.3% 40,41 . Transparent electrode. On the basis of the strong light localization in i-LTS, the light absorptance of the transparent electrode can be enhanced. Thus, the extinction coefficient of the transparent electrode should be low. The primary problem with the transparent electrode in the traditional photovoltaic cell is that it is required to maintain a small degree of light absorption within the entire spectral region of sunlight. However, different transparent electrodes can be used on sub-batteries by adopting the shoulder-to-shoulder design of the sub-batteries after using the spectrum-splitting structure. These transparent electrodes are only required to exhibit minimal light absorption within a specific frequency range, i.e., the difficulty in the design of the transparent electrode can be significantly reduced.
Materials. This study investigated the light-trapping ability of the thinnest photovoltaic cell (i.e., the graphene-MoS 2 photovoltaic cell) that features the combination of a spectrum-splitting structure and i-LTS. The requirements on material mobility can be minimized because the thickness of the working medium layer is only 1 nm. This phenomenon promotes the application of low-mobility materials, such as noncrystalline materials and organic materials, in photovoltaic cells. When the quantum tunneling effect is considered, an insulating medium with a low barrier height can be used to prepare an absorption medium. In particular, when the thickness of the working medium is reduced to a few nanometers, the energy band structure and optical properties can be adjusted by changing physical and structural parameters, such as stress. Furthermore, the estimated external quantum efficiency can be increased to larger than 80% by using shoulder-to-shoulder cells consisting of different band gap materials ( Supplementary Information S6). This step can largely promote the application of energy-band engineering in photovoltaic cells.
Feasibility of the experiments. The structures can achieve a high light absorptance after considering the present technique precision. The combined utilization of microcavity and traditional semiconductor microstructures, such as quantum well, is mature. The combined utilization of microcavity and 2D materials remains a challenge, but a photonic crystal microcavity that contains graphene has been produced [40][41][42][43] . The primary difficulty in fabricating this product is integrating i-LTS with a spectrum-splitting structure to establish a wedge-shaped medium layer. Prineas et al. promoted the growth of 210 wedge-shaped semiconductor layers through MBE to reduce the speed of light 54 . Wedge-shaped microcavities are also widely used in experimental studies of light-matter interactions, such as laser-plasma interactions, cavity polaritons, and Purcell effect 55-57 . Limitations. Similar to the traditional spectrum-splitting structure-based photovoltaic cells, the proposed photovoltaic cell is applicable only under direct sunlight. Under indirect sunlight, the conversion efficiency is significantly reduced and the utilization ratio of the scattered sunlight is low. A solar tracker and a feedback mechanical system should be used. In regions with a short period of direct sunlight exposure, the GM-PV cell should be used simultaneously with traditional photovoltaic cells.
In conclusion, broadband perfect absorption can be achieved in the 1 nm-thick GM-PV cell by combining spectrum-splitting structure and i-LTS. The achieved light absorptance exceeds the fundamental limit of nanophotonic light trapping in solar cells. The light absorptance of the GM-PV cell manufactured with the current technology can still exceed 90% regardless of layer thickness errors, the position deviation of the GM-PV cell in the microcavity, deviation of incident angle, and lens aberration. This study not only provides different way to design light-trapping structures and apply spectrum-splitting systems but also have significant applications in the development of optoelectronic devices, such as photoelectric detectors.

Methods
The modified transfer matrix method is used to model the absorption of GM-PV cell in the photonic crystal micro-cavity. For actual convex lens with aberrations, each of the refraction of light through the prism and lens is solved numerically using Snell's law.