Abstract
The recent discovery of pressure (p) induced superconductivity in the binary helimagnet CrAs has raised questions on how superconductivity emerges from the magnetic state and on the mechanism of the superconducting pairing. In the present work the suppression of magnetism and the occurrence of superconductivity in CrAs were studied by means of muon spin rotation. The magnetism remains bulk up to p 3.5 kbar while its volume fraction gradually decreases with increasing pressure until it vanishes at p
7 kbar. At 3.5 kbar superconductivity abruptly appears with its maximum Tc
1.2 K which decreases upon increasing the pressure. In the intermediate pressure region (3.5
p
7 kbar) the superconducting and the magnetic volume fractions are spatially phase separated and compete for phase volume. Our results indicate that the less conductive magnetic phase provides additional carriers (doping) to the superconducting parts of the CrAs sample thus leading to an increase of the transition temperature (Tc) and of the superfluid density (ρs). A scaling of ρs with
as well as the phase separation between magnetism and superconductivity point to a conventional mechanism of the Cooper-pairing in CrAs.
Introduction
The pressure-induced superconductivity in the binary helimagnet CrAs has recently attracted much attention1,2,3,4,5. At ambient pressure CrAs is characterized by a relatively high Néel temperature K6,7,8. TN decreases approximately by a factor of three for pressures (p) approaching
kbar, above which the magnetism completely disappears1,2,3. On the other hand superconductivity sets in for pressures exceeding
kbar thus revealing a range of
kbar where superconductivity and magnetism coexist.
The close proximity of superconductivity to magnetism, the similarity of the phase diagram of CrAs with that of some Fe-based superconductors, as well as the absence of the coherent Hebel-Slichter peak in the nuclear relaxation rate 1/T1T made the authors of Refs 1, 2, 3, 5 to suggest an unconventional pairing mechanism. It should be noted, however, that the similarity of the phase diagram does not necessarily requires a similar mechanism of Cooper-pairing. The Hebel-Slichter peak can also be suppressed in conventional s—wave superconductors. This is e.g. the case for superconductors in the strong coupling limit9, for superconductors having a spread of Tc over the sample, or for slight gap anisotropies10. Whether a coherence peak is present at all in the archetypical two-gap superconductor MgB2 is still subject of discussion11,12. One needs, therefore, a more detailed investigation of the superconducting response of CrAs as well as an understanding on how superconductivity emerges from a compound being initially in a strong magnetic state.
In this paper we report on muon spin rotation (μSR) studies of the magnetic and the superconducting properties of CrAs. We first discuss separately the magnetic and the superconducting responses as a function of pressure and concentrate later on the issue of coexistence between magnetism and superconductivity.
Results
Magnetism in CrAs
The magnetic response of CrAs powder samples was studied by zero field (ZF) and weak transverse field (wTF) μSR experiments. In the following we discuss the μSR data for three different pressure regions.
In the low-pressure region, kbar, spontaneous muon spin precession is clearly seen in the ZF μSR time spectra (see Fig. 1a) thus confirming that long range magnetic order is established below TN. The oscillating part of the signal is accurately described by a field distribution characterized by a minimum (Bmin) and a maximum (Bmax) cutoff field (see the inset in Fig. 1a), which is consistent with the observation of helimagnetic incommensurate magnetic order4,5,6,7,8. The relatively high values of the cutoff fields (
T and
T at p = 1 bar) are in agreement with the large moments
as obtained by means of neutron powder diffraction4. The wTF μSR experiments performed at ambient pressure and at p = 2.5 kbar show relatively sharp transitions to the magnetic state and prove that the magnetism occupies close to 100% of the sample volume (see Fig. 1b and Fig. Sup 3 in the Supplemental material). The hysteresis in TN signifies a first order magnetic phase transition.
Representative ZF and wTF μSR data.
(a) ZF μSR time-spectra of CrAs measured at T = 5 K and p = 1 bar. The solid line is a fit according to the theoretical field distribution caused by incommensurate helimagnetic order shown in the inset [see the Supplemental materials for details]. The minimum (Bmin) and the maximum (Bmax) cutoff fields are represented by vertical dashed lines. (b) and (c) depict the temperature evolution of the non-magnetic volume fraction f of CrAs obtained in the wTF μSR measurements at p = 2.5 and 5.55 kbar, respectively. Closed and open symbols correspond to the experimental data obtained with increasing and decreasing temperature (the sweeping rate is K/min, 5 minutes per data point). The clear hysteresis is indicative of a first order magnetic transition.
In the intermediate pressure region ( kbar) the cutoff fields, which are proportional to the ordered moment, decrease continuously and reach at
kbar
T and
T (see Fig. Sup 1 in the Supplemental materials). This is consistent with a decrease of the ordered magnetic moment to
. The wTF μSR experiments reveal that the low temperature value of the non-magnetic fraction f gradually increases with increasing pressure (see Fig. 1b,c and Fig. Sup 3 in the Supplemental materials). Therefore in the intermediate pressure region the sample is separated into a magnetically ordered phase and a non-magnetic phase. The hysteresis in TN confirms that the magnetic transition remains of first order at all pressures (see Fig. 1c).
For pressures above 7 kbar the ZF μSR experiments prove the absence of any type of magnetic order as exemplified by the weakly damped wTF μSR time spectra.
Superconductivity in CrAs
The superconducting response of CrAs was studied in transverse field (TF) μSR experiments (applied field μ0H = 30 mT). From the experimental data we have extracted the magnetic penetration depth λ, which is related to the superfluid density ρs in terms of ρs = ns/m* ∝ λ−2 (ns charge carrier concentration and m* carrier effective mass). The magnetic penetration depth was determined from the Gaussian muon-spin depolarization rate σsc(T) ∝ λ−2(T), which reflects the second moment of the magnetic field distribution in the superconductor in the mixed state13. σsc is related to λ via
14 (
Wb is the magnetic flux quantum and
MHz/T is the muon gyromagnetic ratio).
The measured λ−2(T) and the internal field B(T) of CrAs for p = 4.06, 4.9, 5.8, 6.7, 8.6 and 10.3 kbar are shown in Fig. 2a,b. Note that λ−2 and B were derived from the fraction of the sample remaining in the non-magnetic state down to the lowest temperature (see Fig. 3a). Due to the strongly damped signal in the magnetic phase one is unable to measure any superconducting response in the magnetic fraction of the sample. We believe, however that superconductivity in CrAs cannot emerge in the magnetically ordered parts for two following reasons. First, Wu et al.1 have shown that the low-temperature diamagnetic susceptibility (χdia) of CrAs is nearly zero for pressures kbar, increases linearly in the range
and reaches its maximum value, close to the ideal χdia = −1/4π, for pressures exceeding 7.85 kbar. It follows almost exactly the pressure dependence of the non-magnetic fraction f as observed in our wTF and TF μSR experiments (see Fig. 3a). Second, the large magnetic moment and its weak reduction as a function of pressure (see Fig. 3b) require the separation of CrAs in superconducting and magnetic domains. This is e.g. the case for the so-called ‘245’ family of Fe-based superconductors15,16, which is characterized by the high value of both, magnetic moment (~3μB) and Néel temperature (TN ~ 500 K)17,18,19,20. Note that within the full pressure range studied here the value of the ordered magnetic moment in CrAs is only a factor of two smaller than that in ‘245’ superconductors.
The superfluid density and the diamagnetic shift at various pressures.
(a) Temperature evolution of the inverse squared magnetic penetration depth and (b) the internal field B obtained from the fit of 30 mT TF μSR data measured at p = 4.06, 4.9, 5.8, 6.7, 8.6 and 10.3 kbar. Solid lines in (a) are power law fits
with a common exponent n = 1.95(3) for all data sets.
Temperature-pressure phase diagram.
(a) Pressure dependence of the non-magnetic volume fraction f; (b) maximum cutoff field Bmax, which is proportional to the ordered moment ; (c) superconducting transition temperature Tc; and (d) the zero-temperature value of the inverse squared magnetic penetration depth
. The grey area represents the pressure region where magnetism and superconductivity coexist. The solid line in (b) is a linear fit with
(see the Supplemental materials).
The absence of experimental points below K prevents us from drawing any conclusion about the possible gap symmetry in CrAs based on the λ−2(T) data. Therefore, they were fitted to a power law
with the common exponent n = 1.95(3) for all data sets. Values for the superconducting transition temperature Tc and the inverse squared zero-temperature magnetic penetration depth λ−2(0) obtained from these fits are plotted in Fig. 3c,d.
Interplay between magnetism and superconductivity
Figure 3 summarizes our results on the magnetism and superconductivity in CrAs as a function of pressure. CrAs remains purely magnetic up to kbar. Above this pressure and up to
kbar both, magnetic and superconducting responses are clearly detected in a set of ZF, wTF and TF μSR experiments. CrAs is phase separated into volumes where long range magnetic order is established below the Néel temperature TN and into non-magnetic volumes becoming superconducting below the critical temperature Tc. It is interesting to note that, besides the competition for the volume, there is no evidence for a competition between the magnetic and superconducting order parameter in CrAs. This is in contrast to various Fe-based and cuprate superconductors where it is generally observed. Indeed, the ordered magnetic moment stays almost constant, by changing less than 15% from 1.73μB at p = 1 bar to 1.47μB at
kbar, see Fig. 3b. TN, in their turn, evolves smoothly with pressure without showing any pronounced features at
kbar, i.e. where the non-magnetic phase starts to develop (see Refs 1, 2, 3,5).
Figure 3a,d demonstrate that the maximum value of the superfluid density is observed at the low pressure side of the phase separated region i.e. in the region where the non-magnetic volume fraction f is the smallest. With further increasing f, the superfluid density decreases until it saturates when
. By neglecting the pressure effect on the charge carrier mass m*, the superfluid density is simply proportional to the carrier concentration ρs ∝ ns. We may assume, therefore, that within the phase separated region carriers from the ‘less conductive’ magnetically ordered parts of the sample can be supplied to the ‘more conductive’ non-magnetic parts, which become superconducting at low temperatures. The effect of supplying additional carriers, which can be considered as “doping”, is expected to be the strongest if the magnetic volume fraction exceeds substantially the paramagnetic one (f
1), while it should decrease and even vanishes completely for f approaching 1. Figure 3a,d imply that this is exactly the case for CrAs. Effectively, the non-magnetic volume fraction f anticorrelates with the superfluid density ρs.
Correlation between Tc and λ−2
Figure 3c,d show that Tc and λ−2(0) have similar pressure dependences, which could point to a possible correlation between these quantities. The famous “Uemura line” establishes a linear relation between Tc and λ−2(0) for various families of underdoped cuprate high-temperature superconductors21,22. A similar linear relation was observed in recently discovered Fe-based superconductors23,24,25,26. In molecular superconductors λ−2(0) was found to be proportional to 27, while in some phonon mediated BCS superconductors
28. Figure 4 shows that in CrAs λ−2(0) the data scales as
thus suggesting that superconductivity in CrAs is most probably BCS like and is mediated by phonons.
Correlation between Tc and λ−2(0).
Superconducting critical temperature Tc versus inverse squared zero-temperature magnetic penetration depth λ−2(0) of CrAs. The red line is fit to CrAs data with the exponent n = 3.2(2). The black, green and blue lines are empirical relations for some phonon mediated BCS superconductors (n = 3.1, Ref. 28), cuprate and Fe-Based high-temperature superconductors (n = 1, Refs 21, 22, 23, 24, 25, 26) and molecular superconductors (n = 2/3, Ref. 27), respectively.
A further indication of conventional electron-phonon coupling in CrAs comes from the observed macroscopic phase separation of the magnetic and the superconducting phases. Following Ref. 29, the relative phase difference (θ) of the superconducting order parameter between different parts of Fermi surface or Fermi surface sheets may lead either to stabilization of microscopic coexistence of the magnetic and superconducting phases or drive both to repel each other. This happens because the staggered magnetic moment (M) plays in a superconductor the role of an intrinsic Josephson coupling with the free energy term (Δ1, Δ2 are the superconducting order parameters at different parts of the Fermi surface or Fermi surface sheets). If the superconducting order is a conventional one, (i.e. there is no internal phase change, θ = 0), this term increases the total energy, thus making both phases unlikely to coexist. On the contrary, if the phases are opposite such that θ = π the Josephson coupling term in the free energy is negative. As a result both the superconducting and the magnetic phases like to coexist. This explains why the magnetic and superconducting orders do coexist microscopically in some unconventional superconductors like ferropnictides, electron-doped cuprates and heavy-fermion systems where the order parameter has an internal phase shift. In CrAs, however, the phase diagram points towards an isotropic s—wave symmetry of the superconducting order parameter driven by electron-phonon interaction.
Conclusions
To conclude, the magnetic and the superconducting properties of CrAs as a function of pressure were studied by means of muon spin rotation. The bulk magnetism exists up to kbar, while the purely non-magnetic state develops for pressures above
kbar. In the intermediate pressure region (
kbar) the magnetic phase volume decreases continuously and superconductivity develops in parts of the sample remaining non-magnetic down to the lowest temperatures. Both, the superconducting transition temperature Tc and the zero-temperature superfluid density ρs(0) decrease with increasing pressure in the intermediate pressure region and saturate for p exceeding
kbar i.e. in the region where magnetism is completely suppressed.
Our results suggest that the pressure-induced transition of CrAs from a magnetic to a superconducting state is characterized by a separation in macroscopic size magnetic and superconducting volumes. The less conductive magnetic phase provides additional carriers (doping) to the superconducting parts of CrAs. This would naturally explain the substantial increase of both, the transition temperature Tc (from 0.9 K to 1.2 K) and the superfluid density ρs(0) (up to %), in the phase coexistence region. The superfluid density was found to scale with Tc as
, which, together with the clear phase separation between magnetism and superconductivity, points towards a conventional mechanism of the Cooper-pairing in CrAs.
Methods
Sample preparation
Two type of polycrystalline CrAs samples were used during our studies. The first type of sample was prepared by means of high-pressure synthesis. Overall details of the sample cell assembly and high-pressure synthesis process can be found in Ref. 30. The mixture of Cr (99.9%) and As (99.99%) powders in a molar ratio 1:1 was enclosed in a boron nitride (BN) crucible and placed inside a pyrophylite cube with a graphite heater. In a typical run, the sample was compressed to 15 kbar at room temperature. While keeping pressure constant, the temperature was ramped up to °C in 3 h, held there for a period of 9 h and then cooled down to the room temperature in 3 h. Afterwards, the pressure was released and the sample removed. On two such synthesized samples the ZF and wTF μSR experiments under ambient pressure were conducted.
The second type of polycristalline CrAs samples was synthesized by solid state reaction as described in31. The samples obtained by this method were used in ZF and wTF studies under ambient pressure and for all experimental studies under the pressure.
Pressure Cell
The pressure was generated in a piston-cylinder type of cell made of CuBe alloy, which is especially designed to perform muon-spin rotation experiments under pressure32. As a pressure transmitting medium 7373 Daphne oil was used. The pressure was measured in situ by monitoring the pressure shift of the superconducting transition temperature of In. The maximum safely reachable pressures at T = 300 and 3 K are 14 and 11 kbar, respectively32.
Muon-spin rotation (μSR)
μSR measurements at zero field (ZF) and field applied transverse to the initial muon-spin polarization were performed at the πM3 and μE1 beamlines (Paul Scherrer Institute, Villigen, Switzerland), by using the GPS and GPD spectrometers, respectively. At the GPS spectrometer, equipped with a continuous flow 4He cryostat, ZF and 3 mT weak transverse field (wTF) experiments at ambient pressure and down to temperatures 1.6 K were carried out. At the GPD spectrometer, equipped with an Oxford sorption pumped 3He cryostat (base temperature ~0.24 K) and continuous flow 4He cryostat (base temperature K), the ZF, 5 mT wTF and 30 mT transverse field (TF) μSR experiments under pressure up to ~10.3 kbar were conducted. All ZF and TF experiments were performed by stabilizing the temperature prior to recording the muon-time spectra. In the wTF experiments under pressure the temperature was swept up and down with the rate
K/min. The data were collected continuously. Each muon-time spectra was recorded during approximately 5 minutes.
In a μSR experiment nearly 100% spin-polarized muons are implanted into the sample one at a time. The positively charged muons thermalize at interstitial lattice sites, where they act as magnetic microprobes. The muon spin precesses about the local magnetic field B at the muon site with the Larmor frequency ωμ = γμB (γμ/2π = 135.5 MHz/T is the muon gyromagnetic ratio).
In pressure experiments a large fraction of the muons, roughly 50%, stop in the pressure cell walls adding a background contribution, which has to be separated from the sample signal in the data analysis. The detailed description of the data analysis procedure is given in the “Supplemental material” part.
Additional Information
How to cite this article: Khasanov, R. et al. Pressure-induced electronic phase separation of magnetism and superconductivity in CrAs. Sci. Rep. 5, 13788; doi: 10.1038/srep13788 (2015).
References
Wu, W. et al. Superconductitivy in the vicinity of the antiferromagnetic order in CrAs. Nat. Commun 5, 5508 (2014).
Kotegawa, H., Nakahara, S., Tou, H. & Sugawara, H. Superconductivity of 2.2 K under Pressure in Helimagnet CrAs. J. Phys. Soc. Jpn. 83, 093702 (2014).
Kotegawa, H., Tou, H., Sugawara, H. & Harima, H. Detection of an Unconventional Superconducting Phase in the Vicinity of the Strong First-Order Magnetic Transition in CrAs Using 75As-Nuclear Quadrupole Resonance. Phys. Rev. Lett. 114, 117002 (2015).
Keller, L. et al. Pressure dependence of the magnetic order in CrAs: A neutron diffraction investigation. Phys. Rev. B 91, 020409(R) (2015).
Shen, Y. et al. Structural and magnetic phase diagram of CrAs and its relationship with pressure-induced superconductivity. arXiv:1409.6615 (2015).
Watanabe, H., Kazama, N., Yamaguchi, Y. & Ohashi, M. Magnetic structure of CrAs and Mn-substituted CrAs. J. Appl. Phys. 40, 1128–1129 (1969).
Selte, K., Kjekshus, A., Jamison, W. E., Andresen, A. F. & Engebretsen, J. E. Magnetic structure and properties of CrAs. Acta Chem. Scand. 26, 1703–1714 (1971).
Boller, H. & Kallel, A. First order crystallographic and magnetic phase transition in CrAs. Solid State Comm. 9, 1699–1706 (1971).
Ohsugi, S. et al. Nuclear Relaxation Study in Strong Coupling Superconductors - A Comparison with High-Tc Superconductors. J. Phys. Soc. Jpn. 61, 3054–3057 (1992).
Stenger, V. A., Pennington, C. H., Buffinger, D. R. & Ziebarth, R. P. Nuclear Magnetic Resonance of A3C60 Superconductors. Phys. Rev. Lett. 74, 1649–1652 (1995).
Jung, J. K. et al. 11B NMR and relaxation in the MgB2 superconductor. Phys. Rev. B 64, 012514 (2001).
Baek, S. H. et al. NMR spectroscopy of the normal and superconducting states of MgB2 and comparison to AlB2 . Phys. Rev. B 66, 104510 (2002).
Zimmermann, P. et al. Muon-spin-rotation studies of the temperature dependence of the magnetic penetration depth in the Yba2Cu3Ox family and related compounds. Phys. Rev. B 52, 541–552 (1995).
Brandt, E. H. Flux distribution and penetration depth measured by muon spin rotation in high-Tc superconductors. Phys. Rev. B 37, 2349–2352 (1988).
Li, W. et al. Phase separation and magnetic order in K-doped iron selenide superconductor. Na. Phys. 8, 126–130 (2012).
Maletz, J. et al. Photoemission and muon spin relaxation spectroscopy of the iron-based Rb0.77Fe1.61Se2 superconductor: Crucial role of the cigar-shaped Fermi surface. Phys. Rev. B 88, 134501 (2013).
Shermadini, Z. et al. Coexistence of Magnetism and Superconductivity in the Iron-Based Compound Cs0.8(FeSe0.98)2 . Phys. Rev. Lett. 106, 117602 (2011).
Bao, W. et al. A Novel Large Moment Antiferromagnetic Order in K0.8Fe1.6Se2 Superconductor. Chin. Phys. Lett. 28, 086104 (2011).
Wang, M. et al. Spin waves and magnetic exchange interactions in insulating Rb0.89Fe1.58Se2 . Nat. Commun. 2, 580 (2011).
Li, C.-H., Shen, B., Han, F., Zhu, X. & Wen, H.-H. Transport properties and anisotropy of Rb1−xFe2−ySe2 single crystals. Phys. Rev. B 83, 184521 (2011).
Uemura, Y. J. et al. Universal Correlations between Tc and ns/m* (Carrier Density over Effective Mass) in High-Tc Cuprate Superconductors. Phys. Rev. Lett. 62, 2317–2320 (1989).
Uemura, Y. J. et al. Basic similarities among cuprate, bismuthate, organic, Chevrel-phase and heavy-fermion superconductors shown by penetration-depth measurements. Phys. Rev. Lett. 66, 2665–2668 (1991).
Luetkens, H. et al. Field and Temperature Dependence of the Superfluid Density in LaFeAsO1−xFx Superconductors: A Muon Spin Relaxation Study. Phys. Rev. Lett. 101, 097009 (2008).
Khasanov, R. et al. Muon spin rotation studies of SmFeAsO0.85 and NdFeAsO0.85 superconductors. Phys. Rev. B 78, 092506 (2008).
Goko, T. et al. Superconducting state coexisting with a phase-separated static magnetic order in (Ba,K)Fe2As2, (Sr,Na)Fe2As2 and CaFe2As2 . Phys. Rev. B 80, 024508 (2009).
Pratt, F. L. et al. Enhanced superfluid stiffness, lowered superconducting transition temperature and field-induced magnetic state of the pnictide superconductor LiFeAs. Phys. Rev. B 79, 052508 (2009).
Pratt, F. L. & Blundell, S. J. Universal Scaling Relations in Molecular Superconductors. Phys. Rev. Lett. 94, 097006 (2005).
Khasanov, R. et al. Correlation between the transition temperature and the superfluid density in BCS superconductor NbB2+x. Phys. Rev. B 77, 064506 (2008).
Fernandes, R. M. & Schmalian, J. Competing order and nature of the pairing state in the iron pnictides. Phys. Rev. B 82, 014521 (2010).
Zhigadlo, N. D. et al. High-pressure flux growth, structural and superconducting properties of LnFeAsO (Ln = Pr, Nd, Sm) single crystals. Phys. Rev. B 86, 214509 (2012).
Saparov, B., Mitchell, J. E. & Sefat A. S. Properties of Binary Transition-Metal Arsenides (TAs). Supercond. Sci. Technol. 25, 084016 (2012).
Andreica, D. Magnetic phase diagram in some Kondo-lattice compounds. Ph.D. thesis, ETH-Zurich (2001).
Acknowledgements
Part of this work was performed at the Swiss Muon Source (SμS) Paul Scherrer Insitute, Villigen, Switzerland. The work of IE was supported by the Focus Program 1458 ‘Eisen-Pniktide’ of the DFG and by the German Academic Exchange Service (DAAD PPP USA no. 57051534). IE acknowledges the support of the Russian Federation Government Program of Competitive Growth of Kazan (Volga region) Federal University. The work at the Oak Ridge National Laboratory was supported by the Department of Energy, Office of Science Basic Energy Sciences, Materials Science and Engineering Division (AS); also partially by the LDRD program (MS). The authors acknowledge helpful discussions with Lukas Keller, Jonathan White and Matthias Frontzek.
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R.K. has performed the experiment, analyzed the data and wrote the paper. Z.G. and H.L. have taken part in μSR experiments. N.D.Z., M.A.S. and A.S.S. prepared the samples. I.E. has provided the theoretical description. Z.G., I.E., H.L., A.A., P.K.B., Ch.R., A.S.S. and E.M. took part in discussions and preparation of the manuscript.
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Khasanov, R., Guguchia, Z., Eremin, I. et al. Pressure-induced electronic phase separation of magnetism and superconductivity in CrAs. Sci Rep 5, 13788 (2015). https://doi.org/10.1038/srep13788
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