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Micro-tubular solid oxide fuel cell based on a porous yttria-stabilized zirconia support


Solid oxide fuel cells (SOFCs) are promising electrochemical energy conversion devices owing to their high power generation efficiency and environmentally benign operation. Micro-tubular SOFCs, which have diameters ranging from a few millimeters to the sub-millimeter scale, offer several advantages over competing SOFCs such as high volumetric power density, good endurance against thermal cycling and flexible sealing between fuel and oxidant streams. Herein, we successfully realized a novel micro-tubular SOFC design based on a porous yttria-stabilized zirconia (YSZ) support using multi-step dip coating and co-sintering methods. The micro-tubular SOFC consisted of Ni-YSZ, YSZ and strontium-doped lanthanum manganite (LSM)–YSZ as the anode, electrolyte and cathode, respectively. In addition, to facilitate current collection from the anode and cathode, Ni and LSM were applied as an anode current collector and cathode current collector, respectively. Micro-crystalline cellulose was selected as a pore former to achieve better shrinkage behavior of the YSZ support so that the electrolyte layer could be densified at a co-sintering temperature of 1300°C. The developed micro-tubular design showed a promising electrochemical performance with maximum power densities of 525, 442 and 354 mW cm−2 at 850, 800 and 750°C, respectively.


The depletion of conventional fossil fuels coupled with the increasing amount of anthropogenic greenhouse gases in the earth's atmosphere has called for a move toward alternative energy sources and efficient energy utilization1,2,3. Solid oxide fuel cells (SOFCs), which convert chemical energy in hydrocarbon fuels directly into electricity, are regarded as the next generation of energy conversion devices owing to their high efficiency and low environmental impact4,5,6,7. Because SOFCs operate at a high temperature (typically 600–900°C), their exhaust heat can be used for combined-cycle and cogeneration applications, thereby achieving significantly high system efficiencies8,9,10,11. In addition to efficient power generation, reversible SOFCs have also shown promise for energy storage and fuel production from renewable electricity12,13,14. Although SOFCs were traditionally considered suitable only for stationary power generation due to their very high operating temperature (≥900°C) and long start-up and shutdown times, recent developments in low-temperature SOFC materials and improved thermal shock resistance have made them attractive also for mobile and portable applications7. Moreover, a dramatic reduction in the electrolyte resistance as a result of nanometer-scale ultrathin electrolytes15,16 is expected to provide new opportunities for a broader range of SOFC applications.

Among the different geometric designs of SOFCs, the micro-tubular design offers a number of advantages. A tubular design alleviates issues associated with high-temperature sealing between fuel and oxidant streams because the seals can be placed out of the high-temperature zones. Since the active surface area per unit volume is inversely proportional to the cell diameter, micro-tubular SOFCs possess a significantly high volumetric power density. Additionally, their smaller size also reduces the thermal gradients, thereby making micro-tubular SOFCs robust against thermal cycling. Consequently, the start-up and shutdown times for a single micro-tubular SOFC can be as low as a few seconds. In view of these advantages, micro-tubular SOFCs have received increased attention in recent years17,18.

In a micro-tubular SOFC, structural support is usually provided by one of the active layers: electrolyte, anode, or cathode. Anode-supported designs have been pursued the most extensively owing to several favorable characteristics of the commonly used Ni-based cermet anodes such as good mechanical strength, relatively high electrical conductivity and suitable properties for co-sintering with the electrolyte layer19,20,21,22. However, current collection from the inner electrode (i.e., bore side) of micro-tubular SOFCs has been identified to be a critical problem with any support component23,24,25,26. For the outer electrode, current can be tapped from the entire electrode surface using current collecting materials such as wires or meshes. However, due to the very small size of micro-tubular SOFCs, which ranges from a few millimeters to the sub-millimeter scale, the application of such current collectors is limited to only the exposed end/s of the inner electrode. This results in a longer current conduction path on the inner electrode side, thus increasing the ohmic resistance. This effect is more pronounced when the active cell length exceeds a few centimeters23. To overcome this issue, we have proposed a novel micro-tubular design based on an inert support27. In this design, a thin current collecting layer is coated on top of the inert support so that current can be collected from the whole inner electrode surface. Computational fluid dynamics (CFD) simulations performed in our previous study28 showed that the proposed design results in a significantly reduced ohmic resistance and better performance even for longer cells with active lengths of several centimeters and above. In addition to providing a better current collection efficiency, the proposed design also minimizes issues related to the performance degradation of anode-supported micro-tubular SOFCs under redox cycle conditions29,30. In the present study, we successfully realized the proposed design by fabricating a micro-tubular SOFC with a porous yttria-stabilized zirconia (YSZ) support using an in-house developed multi-step dip coating method31. The micro-structural features of the fabricated cell were characterized by scanning electron microscope (SEM) and energy dispersive X-ray (EDX) images and its electrochemical performance was evaluated using electrochemical impedance spectroscopy (EIS) and IV characteristic curves.


The change in microstructure of the YSZ support and electrolyte layers with respect to the co-sintering temperature in the range 1250–1400°C is shown in Fig. 1. When the co-sintering temperature increases, rapid growth of YSZ particles takes place due to the high sinterability of YSZ. As a result, the porosity of the support layer gradually decreases, thereby making it unsuitable for the diffusion of fuel gases. Conversely, an increased co-sintering temperature helps to achieve a perfectly dense electrolyte layer. Thus, it is important to carefully select the co-sintering temperature so that the support layer will retain its porosity and the electrolyte layer will be dense enough to prevent the gas crossover. Considering this fact, a co-sintering temperature of 1300°C was found to be optimum in the present study. The porosity and shrinkage of the pre-sintered YSZ support as functions of the co-sintering temperature are illustrated in Fig. 2. As shown, the support layer porosity was 37% for the sample co-sintered at 1300°C. This corresponded with a support layer shrinkage of ca. 19%. Yamaguchi et al.32 previously showed that a minimum shrinkage of the support layer of ca. 15% is necessary for obtaining a fully dense electrolyte layer. Thus, the shrinkage achieved for the YSZ support co-sintered at 1300°C was well above the minimum requirement. Additionally, it is to be noted that an open porosity of 35–40% is considered to be good enough for gaseous diffusion in SOFC components33.

Figure 1

Cross-sectional SEM micrographs showing YSZ support and electrolyte microstructures at different co-sintering temperatures.

(a–d) Support microstructure. (e–h) Electrolyte microstructure.

Figure 2

Variation of porosity and shrinkage of pre-sintered YSZ support with the co-sintering temperature.

A cross-sectional view of a fractured half cell co-sintered at 1300°C is shown in Fig. 3a. The YSZ support tube had a homogeneous structure with an inner diameter of ca. 2.4 mm and an outer diameter of ca. 3.6 mm. The fractured cross-section of a tested micro-tubular SOFC is illustrated in Fig. 3b. It can be seen that the different layers were well adhered to each other and the electrolyte layer was dense and free of pinholes. A close-up view of the cell cross-section and corresponding EDX mapping of Ni, Zr and La elements are shown in Fig. 3c. The positions and thicknesses of the different layers are clearly distinguishable in the elemental distribution. The thicknesses of the Ni anode current collector, Ni-YSZ anode, YSZ electrolyte, strontium-doped lanthanum manganite (LSM)–YSZ cathode and LSM cathode current collector were estimated to be 12, 10, 18, 6 and 80 μm, respectively.

Figure 3

Cross-sectional SEM and EDX micrographs.

(a) Half cell co-sintered at 1300°C. (b) Full cell after electrochemical testing. (c) Close-up view of (b) and elemental distribution of Ni, Zr and La.

Impedance spectra for the single cell at different temperatures are shown in Fig. 4a. For each impedance spectrum, two distinct arcs can be observed: one at higher frequencies (on the left) and the other at lower frequencies (on the right). It is to be noted that high-frequency intercepts in the impedance spectra were not observed due to the frequency limitation (upper limit of 20 kHz) of the impedance meter. An equivalent circuit with Rohm + R1||Q1 + R2||Q2 configuration (Fig. 4b) was used to fit these impedance spectra. Rohm represents ohmic resistance contributed by the cell components. R1||Q1 and R2||Q2 represent the high-frequency and low-frequency arcs, respectively, where R is the resistance and Q the constant phase element (CPE) of the corresponding arcs. The high-frequency resistance (R1) and the low-frequency resistance (R2) are attributed to activation and concentration polarization losses, respectively20,22,31,34. The contribution of different resistances to the total cell resistance at different temperatures is given in Table 1.

Table 1 Area-specific resistance values obtained from impedance spectra for single cell
Figure 4

(a) Impedance spectra for single cell. (b) Equivalent circuit used to fit the impedance spectra.

Figure 5 shows plots of voltage and power density versus the current density of the single cell. The open-circuit voltages (OCVs) obtained at 850, 800 and 750°C were 1.035, 1.046 and 1.057, respectively. These values, close to the theoretical ones, confirmed that the chosen co-sintering temperature (1300°C) was high enough for a gas-tight electrolyte layer to be achieved, as also indicated by the SEM micrographs in Fig. 3. The maximum power densities generated by the cell were 525, 442 and 354 mW cm−2 at 850, 800 and 750°C, respectively.

Figure 5

Power generation characteristics for single cell.


The shrinkage behavior of the support layer is an important consideration for the fabrication of micro-tubular SOFCs. It plays a crucial role in determining the co-sintering temperature at which the electrolyte layer is fully densified, which successively affects the manufacturing steps involved and the microstructural characteristics of each layer. There are several factors responsible for the shrinkage behavior of the support layer such as pre-sintering temperature, type of pore former used and the support layer material itself. The excellent shrinkage of the YSZ support in the present study can be attributed to the use of micro-crystalline cellulose as the pore former. Compared with other pore formers such as graphite and polymethyl methacrylate (PMMA), cellulose is known to cause better shrinkage of the support tube because of its ability to expand by absorbing the solvents during the slurry preparation process35. Thus, the use of the cellulose pore former made it possible to lower the co-sintering temperature to 1300°C from the typical range of 1400–1500°C, which in turn helped to maintain the porosity of the YSZ support.

Compatibility among different SOFC components depends on the manufacturing methods used as well as their thermal, chemical and mechanical properties. In the developed micro-tubular design, the contact between the YSZ support layer and the Ni current collector layer was of particular importance because there is an appreciable difference between the coefficients of thermal expansion (CTEs) of the two materials (13.3 × 10−6 K−1 for Ni and 10.5 × 10−6 K−1 for YSZ at 1000°C)36 and poor contact between them may affect structural integrity of the whole cell. From the microstructural observations above, it is evident that the manufacturing method employed was effective in achieving a homogeneous and well-connected SOFC structure. A particular concern may arise regarding the long-term stability of the cell due to the grain growth and coarsening of Ni particles in both the anode and its current collector layer. However, these effects can be suppressed by adding low surface energy oxides to Ni/Ni-YSZ as well as through proper microstructure tailoring of these layers37.

The impedance spectra for the micro-tubular SOFC showed that the contribution of the ohmic resistance to the total cell resistance was very small due to improved current collection from both the electrodes. As listed in Table 1, the ohmic resistance was 0.043, 0.061 and 0.078 Ω cm2 at 850, 800 and 750°C, respectively. These values are close to the resistance of the YSZ electrolyte with the present thickness of 18 μm at the respective temperatures38. However, the concentration polarization of the cell was found to be relatively high despite a good porosity of the YSZ support layer. There could be a couple of possible reasons for the high concentration polarization. To ensure good mechanical strength of the cell, the YSZ support layer had a thickness of ca. 600 μm, which is fairly large compared to a thickness of 200–300 μm for the commonly used anode supports. The thick YSZ support may have resulted in a poor diffusion of gaseous species. In addition, it is likely that the diffusion of the gaseous species through the Ni current collector and Ni-YSZ anode layers also considerably added to the total concentration polarization, as indicated by the close-up views of their microstructures in Fig. 6. It is well known that the concentration polarization of anode-supported micro-tubular SOFCs is largely influenced by the anode microstructure22. In the present micro-tubular SOFC, both the Ni current collector and Ni-YSZ anode layers showed rather low porosity since their porosity was derived mainly from the reduction of NiO particles to Ni during electrochemical testing. Therefore, the microstructure optimization of these two layers seems to be important for minimizing the concentration losses. On the other hand, the activation polarization was observed to increase notably with decreasing operating temperature owing to the reduced electrocatalytic properties of the electrode materials, mainly the LSM-YSZ cathode39. Moreover, the LSM-YSZ cathode thickness (6 μm) is likely to have been rather small for high oxygen reduction activity. Although most of the LSM-YSZ cathode performance is achieved at a thickness as low as 2 μm, the resistance associated with YSZ grain boundaries has been found to be reduced with the increased cathode thickness40. Thus, the optimization of the LSM-YSZ cathode thickness may play a role in lowering down the activation polarization to some extent.

Figure 6

Close-up views of (a) Ni current collector microstructure and (b) Ni-YSZ anode microstructure.

Despite the above limitations, the micro-tubular SOFC showed promising power generation characteristics. The power densities obtained in the present study are comparable to those observed for anode-supported micro-tubular SOFCs with similar component materials and active cell lengths20,31,41. In addition, the maximum power density at 800°C (442 mW cm−2) was 31% higher than that of a tubular SOFC with a similar cell structure but with materials more favorable for intermediate temperature range (600–800°C)30. The better electrochemical performance of the present micro-tubular SOFC despite the use of all conventional materials is attributable to its significantly low ohmic and concentration polarization resistances compared to those of the cell reported in ref. 30.

In summary, a novel micro-tubular SOFC with a configuration of YSZ/Ni/Ni-YSZ/YSZ/LSM-YSZ/LSM was successfully fabricated using multi-step dip coating and co-sintering methods. The porosity of the YSZ support was maintained at 37% by adding micro-crystalline cellulose as a pore former and reducing the co-sintering temperature to 1300°C. With humidified H2 as the fuel and ambient air as the oxidant, the micro-tubular SOFC generated maximum power densities of 525, 442 and 354 mW cm−2 at 850, 800 and 750°C, respectively. These power densities are comparable to those of the conventional anode-supported micro-tubular SOFCs with similar component materials and active cell lengths. However, as suggested by the simulation study28, the present micro-tubular design could be expected to deliver a distinctly better performance for longer cells with active lengths exceeding several centimeters, where conventional designs suffer from the high ohmic loss associated with current collection from the inner electrode.


A YSZ support slurry was prepared by mixing 48 wt% YSZ (TZ-8Y, Tosoh Corp., Yamaguchi, Japan) and 12 wt% micro-crystalline cellulose (Avicel, Merck, Darmstadt, Germany) powders in a binary solvent of toluene and ethanol and ball-milling the mixture for 24 h. Polyvinyl butyral (PVB; Sigma Aldrich, St. Louis, USA), tallow propylene diamine (Diamin RRT, Kao Corp., Tokyo, Japan) and dioctyl phthalate (DOP; Sigma Aldrich) were used as binder, dispersant and plasticizer, respectively. The same solvents and organic additives were used for the other slurries. The YSZ support slurry was dip coated on a carbon rod (Ø 3 mm, length 40 mm) at a pulling rate of 2 mm s−1 several times until a desired thickness of the YSZ support layer was achieved. Each dip coating was followed by drying at 80°C for 5–10 min to remove the solvents. A NiO slurry was dip coated on top of the YSZ support as an anode current collector. The NiO slurry consisted of 27 wt% NiO (NiO-AFL, Kceracell, Kumsan-Kun, South Korea) and 1.5 wt% micro-crystalline cellulose. The YSZ/NiO bilayer was pre-sintered in air at 1000°C for 1 h using a heating profile discussed in our previous paper31.

Next, an anode slurry composed of 18 wt% NiO and 12 wt% YSZ was dip coated onto the pre-sintered YSZ/NiO bilayer and the sample was dried at 80°C for 1 h. This was followed by dip coating of an electrolyte slurry containing 30 wt% YSZ. The sample was then co-sintered in air at temperatures ranging from 1250 to 1400°C for 3 h at a heating rate of 5°C min−1. LSM-YSZ and LSM slurries were dip coated onto a half cell co-sintered at 1300°C as a cathode and cathode current collector, respectively. The LSM-YSZ slurry was prepared by mixing 20 wt% LSM (LSM-80F, Daiichi Kigenso Kagaku Kogyo, Osaka, Japan) and 20 wt% YSZ, whereas the LSM slurry consisted of 40 wt% LSM. The sample was finally sintered in air at 1150°C for 1 h at a heating rate of 5°C min−1. The active cathode length of the sample was 10 mm.

The electrochemical performance was evaluated by heating the micro-tubular SOFC sample in an electric furnace at three different temperatures: 850, 800 and 750°C. The sample was connected to the fuel supply tube with an alumina-based adhesive (Ceramabond 552, Aremco Products, NY, USA). The anodic and cathodic currents were collected using platinum wires as the current leads with platinum paste applied over the electrode surfaces for better electrical contact. Humidified H2 (3% H2O) at a flow rate of 20 cm3 min−1 and ambient air at a flow rate of 20,000 cm3 min−1 were used as the fuel and oxidant, respectively. The corresponding fuel utilization was estimated to be ca. 27 to 41%18. The NiO in the anode was reduced to Ni by exposing the sample to H2 for 30 min at 850°C before conducting the electrochemical measurements.

IV characteristic curves were obtained by varying the load current with an electronic load device (PLZ664WA, Kikusui Electronics Corp., Yokohama, Japan). EIS measurements were performed using an impedance meter (KFM2150, Kikusui Electronics Corp.) in the frequency range from 20 kHz to 200 mHz under a load current of 100 mA cm−2 and an AC perturbation of 10 mA cm−2.

An SEM equipped with an EDX analyzer (JSM-7001F, JEOL, Tokyo, Japan) was used to examine the SOFC microstructures. The porosity of the YSZ supports were determined by Archimedes' method with deionized water as the immersion medium.


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The authors gratefully acknowledge financial support from the Japan Society for the Promotion of Science (JSPS) in the form of a Grant-in-Aid for Scientific Research (number 23360434).

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D.P. and A.T. conceptualized the study and planned the experiments. D.P. performed the experiments. D.P. and A.T. discussed the results and prepared the manuscript.

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Panthi, D., Tsutsumi, A. Micro-tubular solid oxide fuel cell based on a porous yttria-stabilized zirconia support. Sci Rep 4, 5754 (2014).

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