Proton exchange membrane fuel cells are promising candidates for a clean and efficient energy conversion in the future, the development of carbon based inexpensive non-precious metal ORR catalyst has becoming one of the most attractive topics in fuel cell field. Herein we report a Fe- and N- doped carbon catalyst Fe-PANI/C-Mela with graphene structure and the surface area up to 702 m2 g−1. In 0.1 M HClO4 electrolyte, the ORR onset potential for the catalyst is high up to 0.98 V and the half-wave potential is only 60 mV less than that of the Pt/C catalyst (Loadings: 51 μg Pt cm−2). The catalyst shows high stability after 10,000 cyclic voltammetry cycles. A membrane electrode assembly made with the catalyst as a cathode is tested in a H2-air single cell, the maximum power density reached ~0.33 W cm2 at 0.47 V.
The oxygen reduction reaction (ORR) on the cathode is an important process in proton exchange membrane fuel cells (PEMFCs). Because the cathodic activation and reduction of oxygen are much more difficult than the anodic activation and oxidation of hydrogen, relatively, large amounts of platinum catalyst must be used on the cathode to accelerate the ORR. Due to platinum's rarity and high cost, Pt catalyst loading is one of the most important factors hindering the commercialization of PEMFCs. Considerable attention has therefore been paid to overcome this problem by developing low-platinum and platinum-free catalysts for PEMFC cathodes1,2,3,4,5,6,7,8,9,10,11.
Nitrogen-doped carbon has been recognized as a promising type of cathode catalyst for PEMFCs since Gong et al.12 reported the high ORR activity of nitrogen-doped carbon nanotubes in 2009. Currently, investigating doped carbon catalysts for ORR application is becoming one of the hottest topics in the fuel cell field. Many types of nitrogen-doped carbon materials, such as nitrogen-doped carbon nanotubes5,12, nitrogen-doped graphene13,14,15 and various metal-N4 complexes16,17, have been investigated for their ORR activity. The Dai group12,18 found that some metal-free doped carbon nanomaterials even showed ORR activity almost comparable to platinum catalysts' in an alkaline medium. However, there is still a long way to go before such materials have the activity and stability to make them viable replacements for platinum catalysts in practical applications, especially in acidic media.
To improve the performance of doped carbon catalysts, some researchers have investigated the addition of metal species and significantly enhanced performance has been achieved. Recently, Wu et al.3 reported a high-performance doped carbon catalyst prepared from a polyamine-supported microporous carbon template incorporating iron or cobalt. The catalyst showed high ORR activity (the ORR onset potential was ca. 0.93 V vs. RHE) and excellent stability for 700 h of long-term testing.
The Dodelet group reported Fe/Phen/BP catalyst19 and Fe/Phen/Z8 catalyst17, prepared by milling a mixture of carbon black BP (Black Pearl, Cabot) or the metal-organic framework material Z8, phenanthroline and ferrous acetate, followed by pyrolyzing the mixture twice, first in argon, then in ammonia. The catalysts showed excellent performance at the cathode of PEMFCs, the best being the Fe/Phen/Z8 catalyst, with a volumetric activity of 230 A cm−3 at 0.8 V (iR-free). They believed that the high activity may have resulted from the high density of active sites on the catalyst, possibly caused by the high micropore surface area of the support and the fact that many of the iron cations were coordinated by pyridinic nitrogen functionalities in the interstices of the graphitic sheets within the micropores. Choi et al.9 prepared two types of FeCo/EDA-carbon catalysts, using Ketjen Black 600 (ca. 1416 m2 g−1) and Ketjen Black 300 (ca. 823 m2 g−1) as the respective carbon supports. They found that the higher surface area may result in high active site density and thus in high activity. This suggestion was also supported by the work of Liang et al.20 and Wang et al.13.
In the present study, a high-performance doped carbon electrocatalyst was prepared by pyrolyzing a hybrid precursor in an Ar atmosphere. The precursor was made by impregnating melamine with a solution of FeCl3 and aniline, followed by polymerizing the aniline and covering the melamine with it. Interestingly, the prepared catalyst possesses a graphene structure and demonstrates a high surface area (up to ca. 702 m2 g−1), as well as high pyridinic-N and graphitic-N content, high activity in an acidic medium and high stability.
Figure 1 shows TEM images of C-PANI, PANI/C-Mela and Fe-PANI/C-Mela. It is clear that the C-PANI (Figure 1a) prepared from pure polyaniline had a good graphite-like layer structure with BET surface area ca. 392 m2 g−1. However, once melamine was added to the precursor, the resulting PANI/C-Mela (Figure 1b) showed a slightly altered mixed structure, has some different from C-PANI; its ordering seems lower than that of C-PANI and the BET surface area of PANI/C-Mela is ca. 521 m2 g−1, implying that mixing melamine with the precursor affected the structure of the final samples. It is very important that further doping of the PANI/C-Mela system with Fe resulted in the formation of thin, transparent graphene-like nanosheets, as shown in Figure 1 (c, d, e and f). The surface area of the catalyst reached 702 m2 g−1, which is higher than that of the graphene-based carbon nitride catalyst reported by Yang et al21. (542 m2 g−1) and almost the same as that of graphene nanosheets prepared under ultralow exfoliation temperature (750 m2 g−1)22. Actually, this result of high surface area further confirms the catalyst's graphene structure. It seems that the Fe acted as the catalyst for the formation of graphene. It is interesting that we hardly observe the particles of iron or iron compound in TEM images of the Fe-PANI/C-Mela sample, although the results of XRD and XPS revealed its existence, we believe most iron has been removed in the process of acid leaching.
Figure 2a compares the Raman spectra of C-PANI, PANI/C-Mela and Fe-PANI/C-Mela. The ratios of the D band to G band integrated intensity (ID/IG) for the three samples are 2.35, 2.39 and 1.22, respectively. Figure 2b shows the FTIR spectra of C-PANI, PANI/C-Mela and Fe-PANI/C-Mela. According to the literature, the bands at ~1243.2, ~1225.2 and ~1215.0 cm−1, as well as the bands at ~1589.3, ~1569.9 and ~1575.7 cm−1, can be assigned to the coordination-bonded, pyridine-type C-N bond23 and to the stretching of the C-N bonds24. Clearly the bands of PANI/C-Mela and Fe-PANI/C-Mela are much stronger than those of C-PANI, implying that the catalysts containing melamine include more certain C-N bonds.
As shown in Figure 3, the XPS results reveal the chemical state of doped N and Fe elements in Fe-PANI/C-Mela catalyst. The N1S spectrum (Figure 3a) can be deconvoluted into five peaks at 398.2, 399.1, 399.6, 400.8 and 401.9 eV, which can be assigned to pyridinic N25, N-Fe compounds16, benzenoid amine (–NH–)26, graphitic N17,19,25,27 and oxidized nitrogen compounds28, with compositions of 24.2, 10.7, 5.9, 41.9 and 17.3 at%, respectively. Our catalyst clearly has high graphitic N content (41.9 at% in total doped nitrogen) and high pyridinic N content (24.2 at%).
Figure 3b shows the Fe 2p spectrum, it can also be deconvoluted into five peaks at 710.7, 713.6, 718.7, 722.9 and 725.2 eV. The photoelectron peaks at 725.2 eV is correspond to the binding energies of 2p 1/2 of Fe(III) and Fe(II) ion29, the peaks at 722.9 eV can be assigned to the binding energies of 2p 1/2 of Fe(II) ion30. The peak at 713.6 eV and 710.7 eV can be assigned to the 2p 3/2 of Fe(II) ion31 and Fe(III) ion32, respectively. The peak at 718.7 eV is a satellite peak for the above four peaks. Indicating the co-existing of Fe(II) and Fe(III) in the catalyst.
The XRD patterns shown in Figure 4 display the structures of the catalyst prepared at various conditions. Figure 4a shows the XRD patterns of Fe-PANI/C-Mela catalysts pyrolyzed at various temperatures. With the increase of pyrolysis temperature, the peaks of carbon at 2θ of 21.7 and 26.3 varied obviously (short dash in Figure 4a). The intensity of the peaks at 2θ of 26.3 gets strong with the increase of pyrolysis temperatures, indicating the changing of the structure of the carbon in catalyst. It should be point out that when the pyrolysis temperature is getting higher than 800°C, the six characteristic diffraction peaks ((220), (311), (400), (422), (511) and (440)) of Fe3O4 are emerged and get strong with the increase of pyrolysis temperatures, implying the formation of Fe3O4. However, once the pyrolysis temperature is increased to 850°C, five peaks at 29.8, 33.7, 43.4, 50.7 and 74.7° of 2θ become clear, the peaks at 29.8, 33.7 and 43.4° can be assigned to the (100), (101) and (102) planes of FeS respectively; and the peaks at 43.4, 50.7 and 74.7° can be assigned to the (111), (200) and (220) planes of austenite (CFe15.1), indicating the co-existence of Fe3O4, FeS and austenite in the sample prepared over 850°C. Actually, the strongest peak at 43.4° of 2θ, appeared in the patterns of samples prepared by pyrolyzing at 800, 850 and 900°C, is a piled-up peak of FeS (102), Fe3O4 (400) and CFe15.1 (111). It is interesting that CFe15.1 (200) peak at 2θ of 50.7° gets strongest at 900°C and is disappeared at 950°C, whilst the piled-up peak at 43.4° gets weak significantly, indicating that there are no CFe15.1 existed in the samples prepared over 950°C. As we will discuss later, the sample prepared at 900°C shows best activity, it means that maybe FeS and austenite CFe15.1, but not Fe3O4, promotes the performance of the Fe-PANI/C-Mela catalyst.
Figure 4b compared the XRD patterns of several samples pyrolyzed from various precursors, it is interesting that the sample C-Mela shows a strong and narrow diffraction peak at 2θ of 27.6°, which may be assigned to the carbon materials derived from melamine, indicating its high ordered structure. And we should point out that the shift of C (002) peaks, it shifts from 25.6 of C-PANI to 24.9 of PANI/C-Mela and 23.7 of Fe-PANI/C-Mela, indicates that the increase of inter-layer distances with the doping of melamine, which brings more nitrogen atoms in the catalyst and the further doping of Fe.
Activity and stability towards ORR
From Figure 5a we can see that the C-Mela prepared by pyrolyzation from pure melamine shows no ORR activity and the C-PANI shows only poor activity toward the ORR. However, the addition of melamine and iron to C-PANI is greatly enhances the ORR activity. The Fe-PANI/C-Mela catalyst exhibits unexpectedly high ORR activity, with an onset potential up to 0.98 V (vs. RHE), while its half-wave potential is only 60 mV less than that of JM 40 wt.% Pt/C (51 μg Pt cm−2) and its limited diffusion current is comparable to that of JM Pt/C. To our knowledge, the catalyst is among the best ones of reported doped carbon catalysts for ORR in an acidic medium so far. We found that the ratio of melamine to aniline in the precursors affects the catalytic activity, the optimal ratio being 1:2 by weight and the optimal Fe content being ca. 5 wt.% (see Figure S1, S2 in additional information).
Figure 5b shows the effect of pyrolysis temperature on the ORR activity of Fe-PANI/C-Mela catalyst. It is clearly that the optimal temperature is 900°C for our catalyst system, as higher or lower will yield inferior activity.
It is important that the Fe-PANI/C-Mela catalyst shows high stability. As shown in Figure 5c, its performance loss calculated from linear regression is in the range of 1.5 to 27.4% after 10,000 cycles of rotating disk electrode (RDE) testing, at 0.75 V it is ca. 27.4% and at 0.85 V it is ca. 26.5%. Furthermore, it is found that the lower the potential is, the lower the performance loss is. There are only ca. 14% and 1.5% performance loss at 0.65 and 0.55 V, respectively.
Single cell performance
Figure 6 shows the single-cell test results when Fe-PANI/C-Mela catalyst was used as the cathode catalyst of the membrane electrode assembly (MEAs). The open cell voltage (OCV) was ~0.96 V and the maximum power density was ~0.33 W cm−2 at 0.47 V in an H2-air fuel cell and it is reached the half that of the Pt/C single-cell. The current density reached ~400, ~640 and ~800 mA cm−2 at 0.6, 0.5 and 0.4 V, respectively. This is among the best ones of reported doped carbon catalysts for single PEMFC application in an H2-air fuel cell. It should be point out that the stability of Fe-PANI/C-Mela catalyst is still a serious problem, as shown in Figure 6(b), after a long term test of 100 hours, the performance of the single cell is degraded rapidly. The current density decreased to ~50, ~120 and ~230 mA cm−2 at 0.6, 0.5 and 0.4 V, respectively.
The ORR is a multi-electron charge transfer reaction with two main possible paths: one is one step direct pathway, involving four electrons transfer to produce H2O directly; another one is two steps indirect pathway, involving two electrons transfer to produce H2O2 in the first step and then the H2O2 get another two electrons to transform into H2O. Generally, the two electron process is less efficient than the four electron process and the H2O2 can make materials loss some ORR activity33 . Therefore, for the oxygen reduction at the cathode of PEM fuel cell, the catalyst, on which the oxygen can be reduced in one step four electron pathway, is the priority in the fuel cell field.
Figure 7a shows the ORR curves of Fe-PANI/C-Mela catalyst at different rotation rates from 800 to 3600 rpm. Then four current density values corresponding to the potential of 0.55, 0.60, 0.65 and 0.70 V on every ORR curve were taken. According to the Koutecky-Levich equation as below,
Plot with J−1 versus ω−1/2 at each potential, we can obtain four J−1 − ω−1/2 lines derived from these potentials points (Figure 7b). In equation (1), the current density (J) consists of a kinetic part (J kin) and a diffusion part (J diff), ω is the angular velocity of the disk (ω = 2πN, N is the linear rotation rate) and B is a constant, its relation with electron transfer number n. Where n is the number of electrons transferred during the ORR, F is the Faraday constant (F = 96485 C mol−1), D is the diffusion coefficient of O2 in the 0.1 M HClO4 electrolyte (D = 1.93 × 10−5 cm2 s−1), C is the bulk concentration of O2 (C = 1.26 × 10−3 mol L−1), ν is the kinetic viscosity of the electrolyte (ν = 1.009 × 10−2 cm2 s−1)34.
According to the Koutecky–Levich equation, the slope of the Koutecky-Levich plots is the reverse of B. Thus, combining the equation (2), we calculated the electron transfer number n from the slope of each line, being 4.08, 4.04, 4.06 and 4.37, at 0.55, 0.60, 0.65 and 0.70 V, respectively, the average value is 4.14, demonstrating that the oxygen reduction on Fe-PANI/C-Mela catalyst followed the four-electrons transfer pathway.
According to the TEM Figure 1 (c, d, e and f), the catalyst Fe-PANI/C-Mela shows a thin, transparent graphene-like nanosheets. In addition, the Raman (Figure 2a) shows that the ratios of the D band to G band integrated intensity (ID/IG) from 2.35 and 2.39 of C-PANI and PANI/C-Mela, to 1.22 of Fe-PANI/C-Mela, indicates that the Fe-PANI/C-Mela has fewer sp3 carbon defects and more sp2 carbon, also clearly revealing the catalyst's graphene structure characteristics35. Furthermore, the XPS spectra (Figure 3), FTIR spectra (Figure 2b) and XRD spectra (Figure 4) reveal the doped of N and Fe in the Fe-PANI/C-Mela catalyst. It means that we prepared a doped graphene structured material with a facile method. Why the graphene structured material can be derived from melamine and polyaniline precursors with existence of Fe? We speculate that it may be related with the planar molecular structure of melamine and linear molecular structure of polyaniline and the Fe may be played as the catalyst for the formation of graphene structure.
Bezerra et al.36 have already presented a good review of the effects of pyrolysis temperature, actually, the optimal pyrolysis temperature depends on the adapted precursors. The temperature may affect both the formation and the density of active sites on the carbon materials.
We found that the pyrolysis temperature affected the structure of doped carbon and the existing status of iron significantly, as shown in Figure 4 and mentioned above, three types of iron, Fe3O4, CFe15.1 and FeS are co-existed in the catalyst and their ratio varied with the changing of pyrolysis temperature. At the optimal pyrolysis temperature of 900°C, the ratio of austenite CFe15.1 and FeS reached highest. implying that it may be the FeS and CFe15.1 but not the Fe3O4, play an important role in the formation of active sites, or join in the formation of active sites.
It should point out that XPS spectra just confirm the existence of Fe(II) and Fe(III), but not zerovalent iron, it may be caused by two reasons, one is that the zerovalent iron (CFe15.1) may be dispersed in the interior of the Fe-PANI/C-Mela nanoparticle, another is that its content may be lower than the detect limitation of XPS. It is found that the sample without of iron addition in the precursor presented very poor performance (See Figure S2). Thus, we can conclude that the iron plays an important role for improving the performance of our Fe-PANI/C-Mela catalyst.
As shown in Figure 5a, the addition of melamine and iron to C-PANI is greatly enhances the ORR activity. The Fe-PANI/C-Mela catalyst exhibits unexpectedly high ORR activity which is comparable to that of a state-of-the-art JM Pt/C. This is attributed to the following three reasons. Firstly, the Fe-PANI/C-Mela catalyst has high graphitic N content (41.9 at% in total doped nitrogen) and high pyridinic N content (24.2 at%) as shown in Figure 3b. It has been acknowledged the graphitic N plays a crucial role in oxygen reduction37,38 and that pyridinic N and iron cations coordinated with N can also significantly increase ORR activity19,39,40, these may be the main reason that the catalyst presents high ORR activity. Secondly, the Fe (II) and zerovalent iron promotes the performance of the Fe-PANI/C-Mela catalyst, as we discussed before, the residual iron or iron compound can play an important role in enhancing the catalytic activity3,16,17,19. Thirdly, shown in Figure 4b that the shift of C (002) peaks, it shifts from 25.6 of C-PANI to 24.9 of PANI/C-Mela and 23.7 of Fe-PANI/C-Mela, indicates that the increase of inter-layer distances with the doping of melamine, which brings more nitrogen atoms in the catalyst and the further doping of Fe. This enlarged distance of graphene layers may benefit to the diffusion of ORR-related species and enhancement of the catalytic activity.
According to Figure 5c, the Fe-PANI/C-Mela catalyst shows high stability and the performance loss is comparable to that recently reported by Zelenay group3, their reported performance loss was 10 to 39% for their doped carbon catalyst after 10,000 RDE cycles. And our catalyst performance loss is in the range of 1.5 to 27.4%. These results reveal the good stability of our Fe-PANI/C-Mela catalyst towards the reduction of oxygen. We suggest that this good stability may be resulted from the stable graphene structure of the catalyst.
However, in H2-air single fuel cell, the performance and stability of the MEA with Fe-PANI/C-Mela as cathode catalyst are much bad than those of MEA with JM Pt/C catalyst as cathode catalyst. It is clearly that there is still a long way to go to make doped carbon catalyst meet the requirements for practical applications.
In summary, a novel nitrogen- and iron-doped carbon catalyst with a graphene structure, exhibiting high performance for the ORR in an acidic medium, was successfully prepared by pyrolysis with melamine and an iron-containing precursor. The addition of melamine improved the formation of particular C-N bonds and the further addition of iron gave the catalyst a graphene structure and a high surface area (702 m2 g−1). The catalyst showed excitingly high ORR activity and stability in RDE test in an acidic medium, which is almost comparable to that of JM Pt/C catalyst. The oxygen reduction on Fe-PANI/C-Mela catalyst followed the four-electron transfer pathway. However, the performance and durability of Fe-PANI/C-Mela catalyst In H2-air single fuel cell are still much lower than those of JM Pt/C catalyst.
Preparation of hybrid precursor Fe-PANI/C-Mela: In a typical approach, melamine (2.0 g, AR, >99.5%), aniline (4.0 mL, AR, >99.5%) and FeCl3·6H2O (1.5 g, AR, >99.0% the ratio of the Fe is 5 wt.% of the melamine and aniline) were first dispersed in 0.75 M HCl solution (120 mL) and the mixture was stirred in ice bath for 30 minutes. Afterwards, oxidant ammonium peroxydisulfate (10.0 g, AR, >98.0%) was added slowly as the polymerizing catalyst. After constant stirring for 24 hours below 10°C for the completely polymerization of aniline, the mixture was evaporated to remove the solvent, thus the hybrid precursor was obtained. Pyrolysis: the catalysts were prepared by a twice pyrolysis process, firstly, the hybrid precursor was pyrolyzed from 700–1000°C in an argon atmosphere for 1.0 hour, then the sample is leached in 0.5 M H2SO4 at 80°C for 10 hours, followed by thoroughly washing with de-ionized water. Finally, the catalyst was obtained by pyrolyzing the leached sample in an argon atmosphere for 3.0 hours at the same temperature; we denote the catalyst as Fe-PANI/C-Mela. (when the ratio of aniline: melamine was 1:2 by weight, denote Fe-PANI/C-Mela-1/2).
For comparison, we prepared a series of doped catalysts with almost same procedures, such as PANI/C-Mela, C-PANI and C-Mela prepared without addition of FeCl3·6H2O, prepared without addition of melamine and FeCl3 and prepared by pyrolyzing from pure melamine at 900°C, respectively.
TEM images were rerecorded on a JEM-2100HR microscope (JEOL, Japan) operated at 200 kV. XRD was conducted on a TD-3500 powder diffractometer (Tongda, China) operated at 40 kV and 30 mA, using Cu-Kα radiation sources. Raman measurement was performed on a LabRAM Aramis Raman spectrometer (HJY, France) with a laser wavelength of 532 nm. Fourier transform infrared spectroscopy (FTIR) was recorded with a Tessor 27 (Bruke, Germany). X-ray photoelectron spectroscopy (XPS) was performed on an Axis Ultra DLD X-ray photoelectron spectrometer (Kratos, England) employing a monochromated Al-Ka X-ray source (hν = 1486.6 eV). Specific surface areas were measured by Brunauer-Emmett-Teller (BET) nitrogen adsorption-desorption on a TristarII 3020 (Micromeritics, USA) gas adsorption analyzer.
The ORR performances of the catalysts were evaluated on an electrochemical workstation (Ivium, Netherlands) at room temperature, using a three-electrode electrochemical cell. The work electrode was prepared with following procedures: 5 mg catalyst were dispersed ultrasonically in 1 mL Nafion/ethanol (0.25 wt.% Nafion) for 1.0 hour, then 20 μL catalyst dispersion was pipetted and spread on the glassy carbon electrode (5 mm inner diameter), followed by drying under an infrared bulb. A platinum wire and Ag/AgCl (3 M NaCl) (E[RHE] = E[Ag/AgCl] + 0.290 V in 0.1 M HClO4 electrolyte) were used as the counter and reference electrodes, respectively. ORR steady-state polarization measurements were conducted in oxygen-saturated 0.1 M HClO4 electrolyte with scanning rates of 10 mV s−1. For doped carbon catalysts, the loadings is 0.51 mg cm−2 and for JM Hispec 4100, Pt/C catalyst, the loadings is 51 μg Pt cm−2.
The Melamine-PANI-Fe has been investigated by continuous potential cycling in air-saturated 0.1 M HClO4 between 0.39 and 1.14 V with the scan rate at 0.10 V/s. And after some continuous cycles, the ORR steady-state polarization measurements were conducted in oxygen-saturated 0.1 M HClO4 electrolyte with scanning rates of 10 mV s−1 and rotation rate at 1600 rpm.
The fuel cell performance of the doped carbon catalyst as a cathode was tested at a single cell system. The MEAs with an active area of 5.0 cm2 were fabricated using the catalyst-sprayed membrane method reported previously by our research group41. First, the slurry of Fe-PANI/C-Mela catalyst was prepared by ultrasonically mixing of catalyst powders, isopropanol, 5 wt.% Nafion ionomer solution (DuPont, USA) for 1 hour. Then the slurry was sprayed on the one side of a pretreated Nafion 212 membrane (DuPont, USA) to form the cathode catalyst layer; Commercial Hispec 4100 Pt/C catalyst was used as an anode, the anode catalyst ink was prepared by the same method and sprayed on the another side of the membrane to form the anode catalyst layer. The dry Nafion content in both anode and cathode catalyst layer (CL) was 25 wt.%. The Fe-PANI/C-Mela catalyst loadings in the cathode were 4 mg cm−2 and Pt loadings in the anodes were 0.1 mg cm−2 respectively. Single fuel cell was assembled with the as-prepared MEAs and two pieces of gas diffusion layers on the both sides. H2 and air were used as the fuel and oxidant with 30 psi in the test process. Fuel cell polarization plots were recorded using fuel cell test stations (Arbin Instruments, USA). Pure hydrogen and air, humidified at 80°C, were fed to the anode and cathode, respectively, at flow rates of 300 cm3 min−1 (hydrogen) and 800 cm3 min−1 (air) using fully humidified gases.
The gas diffusion layers (GDLs) for anode and cathode were prepared by the following procedures41. In a typical approach, first, TGP-H-060 carbon paper (Toray, Japan) was hydrophobically treated by impregnating the paper with a Teflon dispersion and calcining at 400°C for 30 min; then, a slurry of carbon black and Teflon, with a composition of 85 wt.% carbon powder (Vulcan XC72, Cabot, USA) and 15 wt.% polytetrafluoroethylene (PTFE) (60%, Aldrich, USA), was sprayed onto the pretreated carbon paper, followed by calcining at 400°C for 30 min in air.
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This work was supported by the National Scientific Foundation of China (Project Numbers 21076089, 20876062, 26073040) and Doctoral Fund of Ministry of Education of China (20110172110012).
The authors declare no competing financial interests.
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Peng, H., Mo, Z., Liao, S. et al. High Performance Fe- and N- Doped Carbon Catalyst with Graphene Structure for Oxygen Reduction. Sci Rep 3, 1765 (2013). https://doi.org/10.1038/srep01765
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