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Radical chemistry

Characterization of a secondary carbon-centred radical

Nature Synthesis volume 3, pages 677–678 (2024)Cite this article

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A diazapentadienyl radical featuring a disubstituted carbon centre is discovered allowing the isolation and structural characterization of a stable secondary carbon radical.

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Fig. 1: Synthesis, structural characterization, and reactivity of a secondary carbon-based radical.

References

  1. Kato, K. & Osuka, A. Angew. Chem. Int. Ed. 58, 8978–8986 (2019).

    Article  CAS  Google Scholar 

  2. Chen, Z., Li, X. Y. & Huang, F. Chem 7, 288–332 (2021).

    Article  CAS  Google Scholar 

  3. Gomberg, M. J. Am. Chem. Soc. 22, 757–771 (1900).

    Article  Google Scholar 

  4. Fessenden, R. W. & Schuler, R. H. J. Chem. Phys. 39, 2147–2195 (1963).

    Article  CAS  Google Scholar 

  5. Loh, Y. K. et al. Nat. Synth. https://doi.org/10.1038/s44160024-00516-6 (2024).

    Article  Google Scholar 

  6. Goettel, J. T., Gao, H., Dotzauer, S. & Braunschweig, H. Chem. Eur. J. 26, 1136–1143 (2020).

    Article  CAS  PubMed  Google Scholar 

  7. Loh, Y. K., Melaimi, M., Munz, D. & Bertrand, G. J. Am. Chem. Soc. 145, 2064–2069 (2023).

    Article  CAS  PubMed  Google Scholar 

  8. Dolai, R. et al. Chem. Eur. J. 29, e202202888 (2023).

    Article  CAS  PubMed  Google Scholar 

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  1. Twitter / X: @LabBraunschweig

Authors and Affiliations

  1. Institute for Inorganic Chemistry, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg, Germany

    Koushik Saha & Holger Braunschweig

  2. Institute for Sustainable Chemistry & Catalysis with Boron, Julius-Maximilians-Universität Würzburg, Am Hubland, Würzburg, Germany

    Koushik Saha & Holger Braunschweig

Authors
  1. Koushik Saha
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  2. Holger Braunschweig
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Correspondence to Holger Braunschweig.

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The authors declare no competing interests.

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Saha, K., Braunschweig, H. Characterization of a secondary carbon-centred radical. Nat. Synth 3, 677–678 (2024). https://doi.org/10.1038/s44160-024-00535-3

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