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ZEOLITE CATALYSTS

Active sites in the right places

Nature Synthesis volume 1, pages 757–758 (2022)Cite this article

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Bifunctional catalysts containing metal and acid sites are used industrially in alkane hydroconversion. Now, the nanoscale spatial separation of the two active sites is shown to promote hydroisomerization and inspires design principles for this type of catalyst.

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Fig. 1: The impact of metal–acid catalytic site intimacy on the selectivity of C7 isomers in the hydroisomerization of n-heptane.

References

  1. Zhou, W. et al. Chem. Soc. Rev. 48, 3193–3228 (2019).

    Article  CAS  PubMed  Google Scholar 

  2. Wu, S.-M., Yang, X.-Y. & Janiak, C. Angew. Chem. Int. Ed. 58, 12340–12354 (2019).

    Article  CAS  Google Scholar 

  3. Zhang, J. et al. Nat. Catal. 1, 540–546 (2018).

    Article  CAS  Google Scholar 

  4. Wu, J. et al. Chem. Commun. 56, 6297–6300 (2020).

    Article  CAS  Google Scholar 

  5. Liu, L. & Corma, A. Chem. Rev. 118, 4981–5079 (2018).

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  6. Cheng, K. et al. Angew. Chem. Int. Ed. 59, 3592–3600 (2020).

    Article  CAS  Google Scholar 

  7. Weisz, P. B. & Swegler, E. W. Science 126, 31–32 (1957).

    Article  CAS  PubMed  Google Scholar 

  8. Cheng, K. et al. Science 377, 204–208 (2022).

    Article  CAS  PubMed  Google Scholar 

  9. Michels, N.-L., Mitchell, S. & Pérez-Ramírez, J. ACS Catal. 4, 2409–2417 (2014).

    Article  CAS  Google Scholar 

  10. Medford, A. J. et al. J. Catal. 328, 36–42 (2015).

    Article  CAS  Google Scholar 

Download references

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Authors and Affiliations

  1. State Key Laboratory of Advanced Technology for Materials Synthesis and Processing & Shenzhen Research Institute & Joint Laboratory for Marine Advanced Materials in National Laboratory for Marine Science and Technology (Qingdao), Wuhan University of Technology, Wuhan, China

    Si-Ming Wu & Xiao-Yu Yang

  2. Department of Physical and Macromolecular Chemistry, Faculty of Sciences, Charles University, Prague, Czech Republic

    Jiří Čejka

  3. School of Engineering and Applied Sciences, Harvard University, Cambridge, MA, USA

    Xiao-Yu Yang

Authors
  1. Si-Ming Wu
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  2. Jiří Čejka
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  3. Xiao-Yu Yang
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Correspondence to Xiao-Yu Yang.

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The authors declare no competing interests.

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Wu, SM., Čejka, J. & Yang, XY. Active sites in the right places. Nat. Synth 1, 757–758 (2022). https://doi.org/10.1038/s44160-022-00168-4

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