Abstract
Developing quantum machines which can outperform their classical counterparts, thereby achieving quantum supremacy or quantum advantage, is a major aim of the current research on quantum thermodynamics and quantum technologies. Here, we show that a fastmodulated cyclic quantum heat machine operating in the nonMarkovian regime can lead to significant heat current and power boosts induced by the antiZeno effect. Such boosts signify a quantum advantage over almost all heat machines proposed thus far that operate in the conventional Markovian regime, where the quantumness of the systembath interaction plays no role. The present effect owes its origin to the timeenergy uncertainty relation in quantum mechanics, which may result in enhanced systembath energy exchange for modulation periods shorter than the bath correlationtime.
Introduction
The nonequilibrium thermodynamic description of heat machines consisting of quantum systems coupled to heat baths is almost exclusively based on the Markovian approximation^{1,2}. This approximation allows for monotonic convergence of the systemstate to thermal equilibrium with its environment (bath) and yields a universal bound on entropy change (production) in the system^{3}. Yet, the Markovian approximation is not required for the derivation of the Carnot bound on the efficiency of a cyclic twobath heat engine (HE): this bound follows from the second law of thermodynamics, under the condition of zero entropy change over a cycle by the working fluid (WF), in both classical and quantum scenarios. In general, the question whether nonMarkovianity is an asset remains open, although several works have ventured into the nonMarkovian domain^{4,5,6,7,8,9}. By contrast, it has been suggested that quantum resources, such as a bath consisting of coherently superposed atoms^{10}, or a squeezed thermal bath^{11,12,13}, may raise the efficiency bound of the machine. The mechanisms that can cause such a raise include either a conversion of atomic coherence and entanglement in the bath into WF heatup^{10,14,15}, or the ability of a squeezed bath to exchange ergotropy^{11,12,13,16} (alias nonpassivity or workcapacity^{17,18,19}) with the WF, which is incompatible with a standard HE. However, neither of these mechanisms is exclusively quantum; both may have classical counterparts^{20}. Likewise, quantum coherent or squeezed driving of the system acting as a WF or a piston^{21} may boost the power output of the machine depending on the ergotropy of the systemstate, but not on its nonclassicality^{13}.
Finding quantum advantages in machine performance relative to their classical counterparts has been one of the major aims of research in the field of quantum technology in general^{22,23,24}, and particularly in thermodynamics of quantum systems^{25}. Overall, the foregoing research leads to the conclusion that conventional thermodynamic description of cyclic machines based on a (twolevel, multilevel or harmonic oscillator) quantum system in arbitrary twobath settings may not be the arena for a distinct quantum advantage in machine performance^{20}. An exception should be made for multiple identical machines that exhibit collective, quantumentangled features^{26,27}).
Here, we show that quantum advantage is in fact achievable in a quantum heat machine (QHM), whether a heat engine or a refrigerator, whose energylevel gap is modulated faster than what is allowed by the Markov approximation. To this end, we invoke methods of quantum systemcontrol via frequent coherent (e.g., phaseflipping or levelmodulating) operations^{28,29}, as well as their incoherent counterparts (e.g., projective measurements or noiseinduced dephasing)^{30,31,32,33,34}. Such control has previously been shown, both theoretically^{30,31,35,36} and experimentally^{34,37}, to yield nonMarkovian dynamics that conforms to one of two universal paradigms: (i) quantum Zeno dynamics (QZD) whereby the bath effects on the system are drastically suppressed or slowed down; (ii) antiZeno dynamics (AZD) that implies the opposite, i.e., enhancement or speedup of the systembath energy exchange^{30,31,38}. It has been previously shown that QZD leads to the heating of both the system and the bath at the expense of the systembath correlation energy^{39}, whereas AZD may lead to alternating cooling or heating of the system at the expense of the bath or viceversa^{30,31}. In our present analysis of cyclic heat machines based on quantum systems, we show that analogous effects can drastically modify the power output, without affecting their Carnot efficiency bound. AZD is shown to bring about a drastic power boost, thereby manifesting genuine quantum advantage, as it stems from the timeenergy uncertainty relation of quantum mechanics.
Results
Model
We consider a quantum system \({\mathcal{S}}\) that plays the role of a working fluid (WF) in a quantum thermal machine, wherein it is simultaneously coupled to cold and hot thermal baths. The system is periodically driven or perturbed with time period \({\tau }_{{\rm{S}}}=2\pi /{\Delta }_{{\rm{S}}}\) by the timedependent Hamiltonian \({\hat{H}}_{{\rm{S}}}(t)\):
In order to have frictionless dynamics at all times, we choose \({\hat{H}}_{{\rm{S}}}(t)\) to be diagonal in the energy basis of \({\mathcal{S}}\), such that.
The system interacts simultaneously with the independent cold (c) and hot (h) baths via
where the bath operators \({\hat{B}}_{{\rm{c}}}\) and \({\hat{B}}_{{\rm{h}}}\) commute: \(\left[{\hat{B}}_{{\rm{c}}},{\hat{B}}_{{\rm{h}}}\right]=0\), and \(\hat{S}\) is a system operator. For example, for a twolevel system, \(\hat{S}={\hat{\sigma }}_{x}\), while \(\hat{S}=\hat{X}\) for a harmonic oscillator, in standard notations. We do not invoke the rotating wave approximation in the systembath interaction Hamiltonian Eq. (3). As in the minimal continuous quantum heat machine^{40}, or its multilevel extensions^{42}, we require the two baths to have nonoverlapping spectra, e.g., superOhmic spectra with distinct upper cutoff frequencies (see Fig. 1). This requirement allows \({\mathcal{S}}\) to effectively couple intermittently to one or the other bath during the modulation period \({\tau }_{{\rm{S}}}\), without changing the interaction Hamiltonian to either bath.
From Markovian to nonMarkovian dynamics
In what follows we assume weak systembath coupling, consistent with the Born (but not necessarily the Markov) approximation. Our goal is to examine the dynamics as we transit from Markovian to nonMarkovian timescales, and the ensuing change of the QHM performance as the period duration \({\tau }_{{\rm{S}}}\) is decreased. To this end, we have adopted the methodology previously derived in refs. ^{28,29,43,44}, to account for the periodicity of \({\hat{H}}_{{\rm{S}}}(t)\), by resorting to a Floquet expansion of the Liouville operator in the harmonics of \({\Delta }_{{\rm{S}}}=2\pi /{\tau }_{{\rm{S}}}\)^{40,45,46}. As explained below, we focus on systembath coupling durations \({\tau }_{{\rm{C}}}=n{\tau }_{{\rm{S}}}\) of the order of a few modulation periods, where \(n \;> \; 1\) denotes the number of periods. The timescales of importance are the modulation time period \({\tau }_{{\rm{S}}}\), the systembath coupling duration \({\tau }_{{\rm{C}}}\), the bath correlationtime \({\tau }_{{\rm{B}}}\) and the thermalization time \({\tau }_{{\rm{t}}h} \sim {\gamma }_{0}^{1}\), where \({\gamma }_{0}\) is the systembath coupling strength. We consider \(n\gg 1\) such that \({\tau }_{{\rm{C}}}\gg {\tau }_{{\rm{S}}},\,{\left(\omega +q{\Delta }_{{\rm{S}}}\right)}^{1}\), where \(\omega\) denotes the transition frequencies of the system \({\mathcal{S}}\), and \(q\) is an integer (see Methods “Floquet Analysis of the nonMarkovian Master Equation”). This allows us to implement the secular approximation, thereby averaging over the fastrotating terms in the dynamics. In the limit of slow modulation, i.e, \({\tau }_{{\rm{S}}}\gg {\tau }_{{\rm{B}}}\), we have \({\tau }_{{\rm{C}}}\gg {\tau }_{{\rm{B}}}\), which allows us to perform the Born, Markov and secular approximations, and eventually arrive at a timeindependent Markovian master equation for \({\tau }_{{\rm{C}}}\gg {\tau }_{{\rm{S}}},\,{\omega }^{1},\,{\tau }_{{\rm{B}}}\) (see Methods “Floquet Analysis of the nonMarkovian Master Equation”).
On the other hand, in the regime of fast modulation \({\tau }_{{\rm{S}}}\ll {\tau }_{{\rm{B}}}\), the Markov approximation becomes inapplicable for coupling durations \({\tau }_{{\rm{C}}}=n{\tau }_{{\rm{S}}} \;\lesssim\; {\tau }_{{\rm{B}}}\). This gives rise to the fastmodulation form of the master equation (see Methods. “Floquet Analysis of the nonMarkovian Master Equation” and “NonMarkovian dynamics of a driven twolevel system in a dissipative bath”):
For simplicity, unless otherwise stated, we consider \(\hslash ={k}_{{\rm{B}}}=1\). Here, for any modulation period \({\tau }_{{\rm{S}}}\), the generalized Liouville operators \({{\mathcal{L}}}_{j}\) of the two baths act additively on the reduced density matrix \({\rho }_{{\rm{S}}}(t)\) of \({\mathcal{S}}\), generated by the \(\omega\)spectral components of the Lindblad dissipators \({{\mathcal{D}}}_{j,\omega }\) (see below) for the \(j={\rm{c}},h\) bath acting on \({\rho }_{{\rm{S}}}(t)\). For a twolevel system, or an oscillator, \({\mathcal{D}}\) does not depend on \(\omega\)^{1}. For \({\rho }_{{\rm{S}}}(t)\) that is diagonal in the energy basis, which we consider below, the dynamics is dictated by the coefficients \({{\mathcal{I}}}_{j}(\omega ,t)\equiv {\rm{R}}e\left[{\tilde{{\mathcal{I}}}}_{j}(\omega ,t)\right]\) in Eq. (4), which express the convolution of the \(j\)th bath spectral response function \({G}_{j}(\nu )\) that has spectral width \(\sim {\Gamma }_{{\rm{B}}} \sim 1/{\tau }_{{\rm{B}}}\), with the sinc function, imposed by the timeenergy uncertainty relation for finite times (see Methods “NonMarkovian dynamics of a driven twolevel system in a dissipative bath”).
Our main contention is that overlap between the sinc function and \({G}_{j}(\nu )\) at \(t \sim {\tau }_{{\rm{C}}}\;\lesssim\; {\tau }_{{\rm{B}}}\) may lead to the antiZeno effect, i.e., to remarkable enhancement in the convolution \({{\mathcal{I}}}_{j}(\omega ,t)\), and, correspondingly, in the heat currents and power. One can stay in this regime of enhanced performance over many cycles, by running the QHM in the following twostroke nonMarkovian cycles:

i.
Stroke 1: we run the QHM by keeping the WF (system) and the baths coupled over \(n\) modulation periods, from time \(t=0\) to \(t=n{\tau }_{{\rm{S}}}={\tau }_{{\rm{C}}}\;\lesssim\; {\tau }_{{\rm{B}}}\) (\(n\gg 1\), \({\tau }_{{\rm{S}}}\ll {\tau }_{{\rm{B}}}\)). The \(n\) modulation periods of the WF are equivalent to \(n\) cycles of continuous heat machines studied earlier, which have been shown to exploit spectral separation of the hot and cold baths for the extraction of work^{40,46}, or refrigeration^{19,47}, in the Markovian regime (see Eq. (8)). By contrast, in the nonMarkovian domain a modulation period is not a cycle, since the timedependent heat currents and the WF state are not necessarily reset to their initial values at the beginning of each modulation period (see below).

ii.
Stroke 2: In order to reset the WF state and the heat currents to their initial (\(t=0\)) values in the nonMarkovian regime, we have to add another stroke: At \(t=n{\tau }_{{\rm{S}}}={\tau }_{{\rm{C}}}\), we decouple the WF from the hot and cold baths. One needs to keep the WF and the thermal baths uncoupled (noninteracting) for a timeinterval \({\overline{t}}\;\gtrsim\; {\tau }_{{\rm{B}}}\), so as to eliminate all the transient memory effects^{38}.
After this decoupling period, we recouple the WF to the hot and cold thermal baths and continue to drive the WF with the periodically modulated Hamiltonian Eq. (1). Thus, the setup is initialized after time \({\tau }_{{\rm{C}}}+\overline{t}\), provided we choose \(n\) to be such that \({\rho }_{{\rm{S}}}({\tau }_{{\rm{C}}}+\overline{t})={\rho }_{{\rm{S}}}(0)\), so as to close the steadystate cycle after \(n\) modulation periods, with the WF returning to its state at start of the cycle (see Fig. 2 and section “A minimal quantum thermal machine beyond Markovianity”). The QHM may then run indefinitely in the nonMarkovian cyclic regime.
By contrast, in the limit of long WFbaths coupling duration \({\tau }_{{\rm{C}}}=n{\tau }_{{\rm{S}}}\gg {\tau }_{{\rm{B}}}\), the \({\rm{s}}inc\) functions take the form of deltafunctions, and therefore, as expected, the integral Eq. (4) reduces to the standard form obtained in the Markovian regime, given by
A minimal quantum thermal machine beyond Markovianity
Here, we consider as the QHM a twolevel system (TLS) WF with states \(\left0\right\rangle\) and \(\left1\right\rangle\), interacting with a hot and a cold thermal bath, described by the Hamiltonian
The Pauli matrices \({\hat{\sigma }}_{j}\) (\(j=x,y,z\)) act on the TLS, the operator \({\hat{B}}_{{\rm{c}}}\) (\({\hat{B}}_{{\rm{h}}}\)) acts on the cold (hot) bath, and \({\hat{H}}_{{\rm{B}}}\) denotes the bath Hamiltonian. The resonance frequency \(\omega (t)\) of the TLS is sinusoidally modulated by the periodiccontrol Hamiltonian
where the relative modulation amplitude is small: \(0\;<\;\lambda \ll 1\). The periodic modulation Eq. (7) gives rise to Floquet sidebands (denoted by the index \(q=0,\pm 1,\pm 2,\ldots\)) with frequencies \({\omega }_{q}=\left({\omega }_{0}+q{\Delta }_{{\rm{S}}}\right)\) and weights \({P}_{q}\), which diminish rapidly with increasing \( q\) for small \(\lambda\) (see Methods “NonMarkovian dynamics of a driven twolevel system in a dissipative bath”)^{29,40,44}.
A crucial condition of our treatment is the choice of spectral separation of the hot and cold baths, such that the positive sidebands (\(q\;> \; 0\)) only couple to the hot bath and the negative sidebands (with \(q\;<\;0\)) sidebands only couple to the cold bath. This requirement is satisfied, for example, by the following bath spectral functions:
which ensures that for small \(\lambda\), only the \(q=1\) harmonic exchanges energy with the hot bath at frequencies \(\pm {\omega }_{1}=\pm \left({\omega }_{0}+{\Delta }_{{\rm{S}}}\right)\), while the \(q=1\) harmonic does the same with the cold bath at frequencies \(\pm {\omega }_{1}=\pm \left({\omega }_{0}{\Delta }_{{\rm{S}}}\right)\). We neglect the contribution of the higher order sidebands (\( q \,> \; 1\)) for \(0\;<\;\lambda \ll 1\), for which \({P}_{q}\to 0\)^{19,29,40,44,46}. Further, we impose the KuboMartinSchwinger (KMS) detailedbalance condition
where \({\beta }_{j}=1/{T}_{j}\).
For simplicity, in what follows, \({G}_{{\rm{h}}}(\omega )\) and \({G}_{{\rm{c}}}(\omega )\) are assumed to be mutually symmetric around \({\omega }_{0}\), i.e., they satisfy
where \(\alpha\) is a realpositive number and \(0\le \nu \,< \,{\omega }_{0}\) (see Methods “Steady states in the antiZeno dynamics (AZD) regime”).
The WF is first coupled to the thermal baths at an initial time \({t}_{{\rm{in}}}\) (\({t}_{{\rm{in}}}\gg {\tau }_{{\rm{t}}h}\;> \; 0\)). Irrespective of the value of \({\tau }_{{\rm{S}}}\), at large times \(t+{t}_{{\rm{i}}n}\gg {\tau }_{{\rm{t}}h}\), and under the condition of weak WFbaths coupling, one can arrive at a timeindependent nonequilibrium steadystate \({\rho }_{{\rm{S}}}\to {\rho }_{{\rm{ss}}}\) in the energydiagonal form (see Methods “Steady states in the antiZeno dynamics (AZD) regime”):
One can then decouple the WF and the baths, such that they are noninteracting for a timeinterval exceeding \({\tau }_{{\rm{B}}}\) so as to eliminate all memory effects, then recouple them again at \(t=0\), keeping \({\rho }_{{\rm{S}}}={\rho }_{{\rm{ss}}}\), and run the QHM in a cycle (as described in the Section “From Markovian to nonMarkovian dynamics”).
In general, owing to the finite widths (\(\sim 1/{\tau }_{{\rm{C}}}\)) of \({{\mathcal{I}}}_{{\rm{h}},{\rm{c}}}({\omega }_{q},t)\) in the frequency domain for short coupling times (\({\tau }_{{\rm{C}}}\;\lesssim\; {\tau }_{{\rm{B}}}\)), the WF would be driven away from \({\rho }_{{\rm{ss}}}\), as follows from Eq. (4), causing \({\rho }_{{\rm{S}}}(t)\) to evolve with time within the timeinterval \(0\;<\; t\le {\tau }_{{\rm{C}}}\). However, in order to generate a cyclic QHM operating in the steadystate, we focus on cycles consisting of \(n\) modulation periods that satisfy
so that
The above conditions Eq. (12) and (13), along with the KMS condition Eq. (9), imply that
Equation (14), in turn, guarantees that Eq. (11) yields the steadystate even at short times, and thus eliminates any time dependence in \({\rho }_{{\rm{S}}}\) (see Fig. 2). For a QHM operating in the steadystate,
remains zero even during decoupling from, and recoupling with the hot and cold baths. This ensures that the system remains in its steadystate \({\rho }_{{\rm{ss}}}\) throughout the cycle.
Equations (12)–(14) can be easily satisfied for experimentally achievable parameters; e.g., \({\Delta }_{{\rm{S}}} \sim\) kHz, and \(n=10\) would imply \({T}_{{\rm{c}}}\gg \hslash {\Delta }_{{\rm{S}}}/2\pi n{k}_{{\rm{B}}} \sim 1{0}^{9}\) K. The number \(n=10\) was chosen to be around the minimal number \(n\) that allows for the validity of the secular approximation \({q}^{\prime}=q\) in Eq. (23) and hence for a simplification (Eq. (24)) in the master equation. This number should be made as low as possible, since by decreasing \(n\) we decrease the cycle duration \({\tau }_{{\rm{C}}}\) and hence increase the power boost, as explained above. Since this power boost is then maximized without changing the efficiency, as noted above, the performance is optimized for the chosen n.
From the First Law of thermodynamics, the QHM output power \(\dot{W}(t)\) is given in terms of the hot and cold heat currents \({J}_{{\rm{h}}}(t)\) and \({J}_{{\rm{c}}}(t)\), respectively, by^{19}
The possible operational regimes of the heat machine, i.e., its being a heat engine or a refrigerator^{19,40}, are determined by the signs of the WFbaths coupling durationaveraged \(\overline{{J}_{{\rm{h}}}}\), \(\overline{{J}_{{\rm{c}}}}\) and \(\overline{W}\). One can calculate the steadystate efficiency \(\eta\), average power output \(\overline{\dot{W}}\) and average heat currents \(\overline{{J}_{j}}\) (\(j={\rm{h}},{\rm{c}}\))
as a function of the modulation speed \({\Delta }_{{\rm{S}}}\), searching for the extrema of the functions in Eq. (16).
The heat currents \({J}_{{\rm{c}}}\) and \({J}_{{\rm{h}}}\), flowing out of the cold and hot baths, respectively, are obtained consistently with the Second Law^{19,40} in the form
where we have used \({P}_{\pm 1}={\lambda }^{2}/4\).
In order to study the steadystate QHM performances for different modulation frequencies, we consider the example of two nonoverlapping spectral response functions of the two baths displaced by \(\delta\) with respect to \({\omega }_{q}\), i.e., \({G}_{{\rm{h}}}(\nu )\) (\({G}_{{\rm{c}}}(\nu )\)) characterized by a quasiLorentzian peak of width \({\Gamma }_{{\rm{B}}}\), with the peak at \({\nu }_{{\rm{h}}}={\omega }_{0}+{\Delta }_{{\rm{S}}}+\delta\) (\({\nu }_{{\rm{c}}}={\omega }_{0}{\Delta }_{{\rm{S}}}\delta\)) (see Methods “QuasiLorentzian bath spectral functions”). Alternatively, we also consider the example of two nonoverlapping superOhmic spectral response functions \({G}_{{\rm{h}}}(\nu )\) and \({G}_{{\rm{c}}}(\nu )\) of the two baths, with their origins shifted from \(\nu =0\) by \({\nu }_{{\rm{h}}}={\omega }_{0}+{\Delta }_{{\rm{S}}}\delta\) and \({\nu }_{{\rm{c}}}={\omega }_{0}{\Delta }_{{\rm{S}}}+\delta\) respectively, for \(0\;<\;\delta \ll {\Delta }_{{\rm{S}}},{\omega }_{0},{\omega }_{0}{\Delta }_{{\rm{S}}}\) (see Methods “SuperOhmic bath spectral functions”). The dependence of \({\nu }_{{\rm{h}},{\rm{c}}}\) on \({\Delta }_{{\rm{S}}}\) amounts to considering baths with different spectral functions for different modulation frequencies, and ensures that any enhancement in heat currents and power under fast driving results from the broadening (rather than the shift) of the sinc functions, which are centered at \({\omega }_{0}\pm {\Delta }_{{\rm{S}}}\).
We plot quasiLorentzian bath spectral functions and the sinc functions in Fig. 3a, b, and the corresponding time averaged heat currents and power (see Eq. (17)) for the heat engine regime in Fig. 3c. We do the same for superOhmic bath spectral functions in Fig. 4a–c. The corresponding heat currents and powers for the refrigerator regimes are shown in Fig. 5a, b. The Markovian approximation: \({\rm{s}}inc(x)\propto \delta (x)\) in Eq. (4) reproduces the correct heat currents and power only in the limit of slow modulation (\({\tau }_{{\rm{C}}}\gg {\tau }_{{\rm{B}}}\)). By contrast, the Markovian approximation reproduces the exact efficiency for both slow and fastmodulation rates (see Fig. 6a). Thus, although the efficiency grows as \({\tau }_{{\rm{S}}}\) decreases, it is still limited by the Carnot bound.
AntiZeno dynamics
The performance of the QHM depends crucially on the relative width of the spectral function and the sinc functions. A slow modulation (\({\tau }_{{\rm{S}}}\gg {\tau }_{{\rm{B}}}\)) results in sinc functions, which are nonzero only over a narrow frequency range, wherein \({G}_{j}(\nu )\) can be assumed to be approximately constant, which leads to timeindependent \({{\mathcal{I}}}_{j}({\omega }_{q})\) and Markovian dynamics. On the other hand, fast modulation (\({\tau }_{{\rm{C}}}\;\lesssim\; {\tau }_{{\rm{B}}}\)) is associated with broad sinc functions, for which \({G}_{j}(\nu )\) is variable over the frequency range \(\sim \,{\tau }_{{\rm{C}}}^{1}\) for which the sinc functions are nonzero (see Figs. 3a, b and 4a, b). This regime is a consequence of the timeenergy uncertainty relation of quantum mechanics, and is associated with the antiZeno effect^{30,31}. This effect results in dynamically enhanced systembath energy exchange, which we dub antiZeno dynamics (AZD). Remarkably, in a QHM, appropriate choices of \({{\mathcal{I}}}_{{\rm{h}},{\rm{c}}}({\omega }_{q},t)\) may yield a power and heat currents boost whenever the sinc functions have sufficient overlap with \({G}_{{\rm{h}},{\rm{c}}}(\nu )\) (see Figs. 3c and 4c).
Importantly, we find that spectral functions peaked at frequencies sufficiently detuned from \({\omega }_{0}\pm {\Delta }_{{\rm{S}}}\) (i.e., \(\delta \;> \;{\Gamma }_{{\rm{B}}}\)) may increase the overlap with the sinc functions appreciably under fast modulation in the antiZeno regime, for \({\tau }_{{\rm{C}}}^{1},\delta \;\gtrsim\; {\Gamma }_{{\rm{B}}}\), thus resulting in substantial output power boost. This regime indicates that finite spectral width of the sinc functions may endow a HE with significant quantum advantage, arising from the timeenergy uncertainty relation, which is absent in the classical regime, be it Markovian or nonMarkovian. In the numerical examples shown here, the quantum advantage in the HEs powered by baths with quasiLorentzian (superOhmic) spectral functions can increase the power by a factor larger than two (seven) (see Figs. 3c and 4c), for the same efficiency (see Fig. 6a and Methods “Efficiency and coefficient of performance”).
Quantum refrigeration
AZD can lead to quantum advantage in the refrigerator regime as well, for modulation rates beyond the quantum speed limit^{42,48} (see Supplementary Note 1), by enhancing the heat current \({\overline{J}}_{{\rm{c}}}\), thus resulting in faster cooling of the cold bath. As for HE, numerical analysis shows that quasiLorentzian, as well as superOhmic bath spectral functions can lead to significant quantum advantage in the AZD regime (see Fig. 5). On the other hand, as for the efficiency in case of the HE, the coefficient of performance
is not significantly affected by the broadening of the sinc function, and on average remains identical to that obtained under slow modulation in the Markovian regime (see Fig. 6b and Methods “Efficiency and coefficient of performance”).
Discussion
We have explored the hitherto uncharted domain of quantum heat engines (QHEs) and refrigerator (QRs) based on quantum working fluids (WFs) intermittently coupled and decoupled from heat baths operating on nonMarkovian timescales. We have shown that for driving (control) faster than the correlation (memory) time of the bath, one may achieve dramatic output power boost in the antiZeno dynamics (AZD) regime.
Let us revisit our findings, using as a benchmark the Markovian regime under periodic driving: In the latter regime, detailedbalance of transition rates between the WF levels, as well as the periodic driving (modulation) rate, determine, according to the First and Second Laws of thermodynamics, the heat currents between the (hot and cold) baths, and thereby the power produced or consumed. In our present treatment, the Markovian regime is recovered under slow modulation, such that the WFbaths coupling duration \({\tau }_{{\rm{C}}}\) exceeds the bath correlationtime \({\tau }_{{\rm{B}}}\). Then, the Markovian approximation is adequate for studying the operation of the QHE or the QR. By contrast, under fast modulations, such that \({\tau }_{{\rm{C}}}=n{\tau }_{{\rm{S}}}\;\lesssim\; {\tau }_{{\rm{B}}}\), the working fluid interacts with the baths over a broad frequency range of the order of \(\sim {\tau }_{{\rm{C}}}^{1}\), according to the timeenergy uncertainty relation in quantum mechanics. The frequencywidth over which systembath energy exchange takes place can lead to antiZeno dynamics (AZD). The resultant quantum advantage is then especially pronounced for bath spectral functions that are appreciably shifted by \(\delta \;> \;{\Gamma }_{{\rm{B}}} \sim {\tau }_{{\rm{B}}}^{1}\), from the centers of the sinc functions that govern the systembath energy exchange rates.
We have explicitly restricted the results to mutually symmetric bath spectral functions (e.g., the experimentally common Lorentzian or Gaussian spectra), in order to ensure timeindependent steadystates of the WF. Yet this requirement is not essential, since the WF steadystate may be timedependent as long as it is periodic so as to allow for cyclic operation. The AZD^{28,29,30,31,32,33,34,35} can arise for any bath spectra of finite width \(\sim 1/{\tau }_{{\rm{B}}}\), as long as \(n{\tau }_{{\rm{S}}}\;\lesssim\; {\tau }_{{\rm{B}}}\). One can therefore operate a thermal machine provided stroke 1 of the cycle is in the AZD regime and achieve a quantum advantage without additional restrictions on the bath spectral functions (see Methods “Thermal machines with arbitrary (asymmetric) spectral functions”).
The QHM discussed here is driven by external modulation. As previously shown both theoretically^{28,29,30,31,32,35} and experimentally^{34,37}, periodic perturbations of the TLS state can increase its relaxation rate in the nonMarkovian antiZeno regime. The reason for the power boost is that at the nonMarkovian stage of the evolution, which occurs on short timescales, the sinc factors in the convolutions with \(G(\omega )\), as in Eq. (32), are sufficiently broad so as to modify the convolutions and hence the relaxation rates in Eq. (34) in comparison with the Markovian case, where these sinc functions are spectrally narrow enough to be approximated by deltafunctions. Under the conditions chosen in the paper, this modification leads to an increase in the TLS relaxation rates and hence to a power boost. This boost is of quantum nature, since the broadening of the sinc factors is due to the quantum timeenergy uncertainty relation that may lead to the violation of energy conservation at short times. The quantum mechanical timeenergy uncertainty relation employed here reflects the fact that the Scrödinger equation for a twolevel system coupled to a bath renders the energy transfer probability from the twolevel system to the bath and back oscillatory in time. Such oscillation leads at short times (comparable to the required cycle period) to sinclike deviation from deltafunction energy conservation. Classical description of analogous processes, even beyond the Markovian approximation, does not involve discrete energy levels and hence no oscillations of the systembath transfer rate that deviates from energy conservation. Thus, the effects discussed here are inherently quantum mechanical.
The nonMarkovian effect in the present context is quantified by the spectral widths of the sinc functions compared to the bathresponse \(G(\omega )\) spectral width \(1/{\tau }_{{\rm{B}}}\). If the cycle duration is kept fixed, then the nonMarkovian effect scales with the spectral width of \(G(\omega )\). Hence, superOhmic bath spectra with their salient cutoff provide realistic examples of the nonMarkovian effects described here. Such bath spectra should be contrasted with the flatter and broader Ohmic spectra. Yet, nonMarkovian dynamics does not necessarily imply a quantum advantage, as discussed in Supplementary Note 2.
The predicted power boost relies on transient dynamics: the heat fluxes change with time within \(t={\tau }_{C}\) in the nonMarkovian AZD regime, even when the WF state hardly changes during that timeinterval. Yet it is essential that we incorporate this transient dynamics within steadystate cycles by decoupling the WF from the baths, allowing the bathcorrelations to vanish within \({\tau }_{{\rm{B}}}\) and then recoupling the WF again to the baths when they have all resumed their initial states. These cycles can be repeated without restriction, thereby allowing us to operate the QHM with quantumenhanced performance even for long times, despite the reliance on transient dynamics within the stroke 1 of each cycle.
The quantum advantage of AZD, at zero energetic cost (see Supplementary Note 3), manifests itself in the form of higher output power, for the same efficiency, in the QHE regime (\({\Delta }_{{\rm{S}}}\;<\;{\Delta }_{{\rm{q}}sl}\)), as compared to that obtained under Markovian dynamics in the limit of large \({\tau }_{{\rm{C}}}\), all other parameters remaining the same. Alternatively, in the QR regime (\({\Delta }_{{\rm{S}}}\;> \;{\Delta }_{{\rm{q}}sl}\)), AZD may lead to quantum advantage over Markovian dynamics in the form of higher heat current \({\overline{J}}_{{\rm{c}}}\), or, equivalently, higher cooling rate of the cold bath, for the same coefficient of performance. The latter effect leads to the enticing possibility of quantumenhanced speedup of the cooling rate of systems as we approach the absolute zero, and raises questions regarding the validity of the Third Law of Thermodynamics in the quantum nonMarkovian regime, if we expect the vanishing of the cooling rate at zero temperature as a manifestation of the Third Law^{47,49,50}.
The QHE power boost in the antiZeno regime results from a corresponding increase in the rates of heatexchange and entropy production, arising from the TLS relaxation by both baths. This is the reason that the efficiency, i.e., the ratio of the work output to the heat input, is unchanged, i.e., is the same as in the standard Markovian regime. Yet, all parameters being equal, the QHM rate of operation (as measured by the power output) speeds up in the antiZeno regime, which constitutes a practical quantum advantage.
One can extend the analysis discussed here to Otto cycles^{42,51}: Fast periodic modulation during the nonunitary strokes of an Otto cycle can speedup the thermalization through AZD, thereby allowing quantumenhanced performance. Interestingly, fast modulation in the Otto cycle can yield enhanced power or refrigeration rate, even in the Markovian regime^{52}.
Finally, in the regime of ultrafast modulation with \({\tau }_{{\rm{C}}}^{1}\gg {\Gamma }_{{\rm{B}}},\delta\), quantum Zeno dynamics sets in, leading to vanishing heat currents and power, thus implying that such a regime is incompatible with thermal machine operation (see Fig. 7, Supplementary Note 2 and Supplementary Fig. 1). While Zeno dynamics has commonly been associated with measurements^{30,53,54,55}, both the Zeno and the antiZeno effects occur under various frequent perturbations, such as phase flips and nonselective (unread) measurements. Generally speaking, to observe the discussed effects, it is sufficient to repeatedly perform cycles of coupling the system (herethe WF) with another system (herea bath), then destroying or sharply changing the coherence between the two. This sharp change can be effected in different ways, e.g., by a measurement of the system (which can be readout or not) or, as in our case, by abruptly decoupling the WF and the baths, which gives rise to Zeno or antiZeno dynamics^{28,29,30,31,32,33}. In contrast to previous studies, here the Zeno or antiZeno dynamics of the WF arises by an external periodic field, and therefore not around the frequency \({\omega }_{0}\) of the unperturbed system, as in previous cases, but at multiple sideband frequencies \({\omega }_{0}+q{\Delta }_{{\rm{S}}}\).
The Markovian approximation suffices to find the correct efficiency (for a QHE) or the coefficient of performance (for a QR), even in the nonMarkovian regimes, for mutually symmetric bath spectral functions (see Eq. (10)). This guarantees that the efficiency always remains below the Carnot bound, even under fast modulations (see Fig. 6).
Our scenario is conceptually different from that in which work is produced by a QHE on an external quantum system and quantum effects arise from the interaction between the quantum WF and the external quantum system^{56}. Such quantum effects are absent in our case, where work input in the QHE is provided by a classical field.
Experimental scenarios where the predicted AZD quantum advantage may be tested are diverse. Since nonMarkovianity in general, and AZD in particular, require nonflat bath spectral functions, suitable candidates for the hot and cold baths are microwave cavities and waveguides in which dielectric gratings are embedded, with distinct cutoff and bandgap frequencies^{19,57} and the WF is a qubit whose level distance is modulated by fields. The required qubit modulations are then compatible with MHz periodic driving of superconducting transmon qubits^{58,59} or NVcenter qubits in diamonds^{60}. One can effectively decouple the WF from the thermal baths in stroke 2 by abruptly changing the resonance frequency of the twolevel WF from \({\omega }_{0}\) to \(\tilde{\omega }\), thus rendering the WF strongly offresonant with the thermal baths, so that \({G}_{{\rm{h}}}\left(\tilde{\omega }\right)\approx {G}_{{\rm{c}}}\left(\tilde{\omega }\right)=0\)), thereby precluding any energy flow between the baths and the WF. We can recouple the WF with the thermal baths by reverting this frequency back to \({\omega }_{0}\), and then modulating it periodically, so as to generate either Markovian or nonMarkovian antiZeno dynamics, as discussed above^{34}.
The AZD regime was experimentally observed in nuclear magnetic resonance= setups^{34}. Micro/nanoscale heat machines have been experimentally realized, for a trapped calcium ion as the WF^{61}; nanomechanical oscillators WF powered by squeezed thermal bath^{12}; atomic heat machines assisted by quantum coherence^{62}; or a nuclear spin \(1/2\) as the WF in a quantum Otto cycle^{63}.
The novel effects and performance trends of QHE and QR in the nonMarkovian time domain, particularly the antiZeno induced power boost, open new, dynamically controlled pathways in the quest for genuine quantum features in heat machines, which has been a major motivation of quantum thermodynamics in recent years^{10,11,12,13,21,25,41,64,65,66,67,68}.
Methods
Floquet analysis of the nonMarkovian master equation
Let us consider the differential nonMarkovian master equation for the system density operator \({\rho }_{{\rm{S}}}(t)\) in the interaction picture^{29}:
Here \({\rho }_{{\rm{B}}}={\rho }_{{\rm{B}}c}\otimes {\rho }_{{\rm{B}}h}\), where \({\rho }_{{\rm{B}}j}\) is the density operator of bath \(j\). In the derivation of Eq. (19) we have assumed that Tr\([{\hat{B}}_{j},{\rho }_{{\rm{B}}j}]=0\). We consider commuting bath operators \(\left[{\hat{B}}_{{\rm{c}}}(t),{\hat{B}}_{{\rm{h}}}({t}^{{\prime} })\right]=0\), such that the two baths act additively in Eq. (19). Below we focus on only one of the baths and omit the labels \(c/h\) for simplicity. We then have
where \(q\) are integers and \(\omega\) are transition frequencies of the system \({\mathcal{S}}\).
One can use Eq. (20) to write the first term on the r.h.s. of Eq. (19) as
In the limit of times of interest, i.e., times larger than the period of driving \({\tau }_{{\rm{S}}}\) and the effective periods of the system, \(t\gg {\tau }_{{\rm{S}}},{(\omega +q{\Delta }_{{\rm{S}}})}^{1}\), the terms with the fast oscillating factor before the integral in Eq. (21) become small and can be neglected, i.e., the secular approximation becomes applicable, such that
which generally holds only for
as long as \(\left({q}^{{\prime} }q\right){\Delta }_{{\rm{S}}}\) is not close to \(\left({\omega }^{{\prime} }\omega \right)\) for any \(q,{q}^{{\prime} },\omega ,{\omega }^{{\prime} }\). Condition (23) gives us
where \(\mu =ts\), and
In the limit of slow modulation, such that \(t=n{\tau }_{{\rm{S}}}\gg {\tau }_{{\rm{B}}}\), one can perform the Markov approximation, thereby extending the upper limit of the integral in time in Eq. (24) to \(t\to \infty\), which finally results in the timeindependent Markovian form^{1}
On the other hand, in the limit of \(t \sim n{\tau }_{{\rm{S}}}\;\lesssim\; {\tau }_{{\rm{B}}}\), the Markovian approximation becomes invalid, and one gets
Progressing similarly as above, one can arrive at similar expressions for other terms in Eq. (19) as well.
NonMarkovian dynamics of a driven twolevel system in a dissipative bath
The nonMarkovian master equation followed by the TLS WF subjected to the Hamiltonian Eq. (6) is (see Eq. (19))
where we have removed the \(h,c\) indices for simplicity, and considered the dynamics due to a single bath. Here
\({\overline{A}}_{\downarrow }\), \({\overline{A}}_{\uparrow }\), and \(\overline{M}\) are the complex conjugates of \({A}_{\downarrow }\), \({A}_{\uparrow }\), and \(M\), respectively. The terms corresponding to \({\sigma }^{\pm }{\rho }_{{\rm{S}}}(t){\sigma }^{\pm }\) in Eq. (28) vanish for diagonal steadystate \({\rho }_{{\rm{S}}}(t)\to {\rho }_{{\rm{ss}}}\) (see Eq. (11)). Here, we focus on times longer than several modulation periods, i.e., \(t=n{\tau }_{{\rm{S}}}\gg {\tau }_{{\rm{S}}}\), when the fast oscillatory terms corresponding to \(q\;\ne\; {q}^{{\prime} }\) vanish as well, such that
We note that
The imaginary part in Eq. (31) acts on terms of the form \(i{\rm{I}}m[{\tilde{{\mathcal{I}}}}_{j}(\pm {\omega }_{q},t)]({\sigma }^{\mp }{\sigma }^{\pm }{\rho }_{{\rm{S}}}(t){\rho }_{{\rm{S}}}(t){\sigma }^{\mp }{\sigma }^{\pm })\), which vanish at large times when the offdiagonal elements \({\rho }_{{\rm{S}}}(t)\) approach zero for any initial state. On the other hand, the real part of Eq. (31) gives rise to terms of the form
In the limit of slow modulation such that \(t \sim n{\tau }_{{\rm{S}}}\gg {\tau }_{{\rm{B}}}\) (\(n\in {\mathbb{Z}},\,n\gg 1\)), the function \(\sin \left(\left[\nu \pm \left({\omega }_{0}+q{\Delta }_{{\rm{S}}}\right)\right]t\right)/\left[\nu \pm \left({\omega }_{0}+q{\Delta }_{{\rm{S}}}\right)\right]\) assumes a deltafunction centered at \(\nu =\pm \left({\omega }_{0}+q{\Delta }_{{\rm{S}}}\right)\), thus leading to the familiar Markovian form of master equation, with
On the other hand, in the antiZeno regime of fast modulation: \(t \sim n{\tau }_{{\rm{S}}}\;\lesssim\; {\tau }_{{\rm{B}}}\), \({{\mathcal{I}}}_{j}(\pm {\omega }_{q},t)\) is not given by Eq. (33), and one needs to consider the full form Eq. (32).
In particular, for a diagonal state \({\rho }_{{\rm{S}}}(t)={p}_{1}(t)\left1\right\rangle \left\langle 1\right+{p}_{1}(t)\left0\right\rangle \left\langle 0\right\), the dynamics Eq. (28)–Eq. (32) leads us to the rate equations
In the Zeno regime of ultrafast modulation, obtained in the limit of \(t \sim n{\tau }_{{\rm{S}}}\ll {\tau }_{{\rm{B}}}\), the integral \({\mathcal{I}}({\omega }_{q},t)\) vanishes (see Supplementary Fig. 1), thus leading to the Zeno effect of no dynamics.
Equations (19), (24), and (28) are of the type known as the differential master equation (DME). An alternative approach is based on the (less convenient) integrodifferential master equation (IME). The two equations are mathematically different and hence require different procedures for reducing them to the Markovian master equation (MME). However, the IME and the DME have the same validity conditions, i.e., generally similar accuracy. The IME and the DME follow from the exact expansions in the totally ordered and partially ordered cumulants, respectively, upon neglecting terms of order higher than \(2\) in the systembath coupling, which determines their accuracy^{1,35,69}.
The rates (Eq. (34)) can be negative when the modulation (or measurement) period is short enough to break the rotating wave approximation (RWA). Yet the probabilities \({p}_{0}(t)\), \({p}_{1}(t)\) are never negative, as detailed in refs. ^{31,35} and concisely proven in the next section.
NonMarkovian master equation with nonnegative probabilities
The nonMarkovian master equations (MEs) for an arbitrarily driven (controlled) twolevel system (TLS) presented in Eq. (34) have been derived and discussed in refs. ^{28,29,30,31,32} and experimentally verified in refs. ^{34,37}. These MEs involve the timedependent relaxation rates \({R}_{0}(t)\) and \({R}_{1}(t)\) which can take negative values, since the quantities \({{\mathcal{I}}}_{j}\), (32), are convolutions of a positive spectral response function \({G}_{j}(\nu )\) with a sinc function, which takes positive or negative values. As a result, the solutions of the MEs for the populations (probabilities) \({p}_{0}(t)\) and \({p}_{1}(t)\) of the TLS levels are not guaranteed to be nonnegative, i.e., to satisfy
Below we show that the inequalities (Eq. (35)) hold, at least, up to second order in the systembath coupling strength. This means that for a weak coupling, violations of (Eq.(35)) (if any) are negligibly small.
First, we note that at sufficiently long times, \(t\gg {\tau }_{{\rm{B}}}\), the MEs become Markovian and coincide with the Lindblad equation. In this case, the rates are constant and positive, \({R}_{0},{R}_{1}\ge 0\), as follows from Eq. (33). The inequalities Eq. (35) are now known to hold. Generally, the MEs are valid if the couplings of the TLS with the baths are sufficiently weak, so that
Consider now the short times, \(t\;{\lesssim }\;\tau_{{\rm{B}}}\), where the nonMarkovian effects are important. Since \({p}_{0}(t)+{p}_{1}(t)=1\), we rewrite
where \(w(t)={p}_{1}(t){p}_{0}(t)\) is the TLS population inversion. In terms of \(w(t)\), inequalities Eq. (35) are equivalent to
which we now prove.
The condition Eq. (36) implies that at times \({\lesssim }\;\tau_{{\rm{B}}}\), the relaxation can be approximated to first order in the relaxation rates. In this approximation, Eq. (34) yields
where
and
From (32) and (34), one can check that
From (39) we obtain
yielding Eq. (38). The second inequality in Eq. (43) follows from the assumption \( w(0) \le 1\) and the relation \( {J}_{}(t) \le {J}_{+}(t)\), resulting from Eqs. (40) and (42).
Steady states in the antiZeno dynamics regime
Now, we study the regimes that allow us to operate the setup with a timeindependent steadystate \({\rho }_{{\rm{ss}}}\) even inside the AZD regime. We note that for \(t\to \infty\), \({I}_{j}({\omega }_{q},t)\) reduces to the timeindependent form \(\pi {G}_{j}({\omega }_{q})\), thus leading us to the Eq. (11). On the other hand, for \(t \sim n{\tau }_{{\rm{S}}}\;\lesssim\; {\tau }_{{\rm{B}}}\), \({I}_{j}({\omega }_{q},t)\) includes contributions from \({G}_{j}({\omega }_{q}+\nu )\), where
Further, we consider \({\omega }_{0}\), \({T}_{{\rm{c}}},{T}_{{\rm{h}}}\), and \({\Delta }_{{\rm{S}}}\;<\;{\omega }_{0}\) large enough, such that \(1/t\ll {\omega }_{0}\pm {\Delta }_{{\rm{S}}},{T}_{{\rm{c}}},{T}_{{\rm{h}}}\). Therefore, in this limit the KMS condition gives us
This immediately leads us to
and consequently (see Eq. (11))
where we have considered the two sidebands \(q=1,1\) only.
The condition
which holds for mutually symmetric bath spectral functions up to a multiplicative factor \({G}_{{\rm{h}}}({\omega }_{0}+x)\approx \alpha {G}_{{\rm{c}}}({\omega }_{0}x)\) for any real \(x\) and positive \(\alpha\) (see Supplementary Fig. 2), leads to the timeindependent steadystate \({\rho }_{{\rm{ss}}}\) with (see Eq. (11))
Efficiency and coefficient of performance
The efficiency in the heat engine regime is given by
while the coefficient of performance in the refrigerator regime takes the form
where we have defined
One can get the results of the Markovian (\({\tau }_{{\rm{C}}}\to \infty\)) limit by replacing \({{\mathcal{I}}}_{j}({\omega }_{q},t)\) by \({G}_{j}\left({\omega }_{q}\right)\).
Let us consider the integral:
where we have defined the variable \(x=\nu \left({\omega }_{0}+{\Delta }_{{\rm{S}}}\right)\), and taken into account that \({G}_{{\rm{h}}}(\nu )=0\) for \(0\;<\;\nu \le {\omega }_{0}\) (see Eq. (8)), and \(\sin \left(xt\right)/x\) is small for large \( x\).
Similarly, we have
where \(y=\left({\omega }_{0}{\Delta }_{{\rm{S}}}\nu \right)\), and we have taken into account that \({G}_{{\rm{c}}}(\nu )=0\) for \(\nu \ge {\omega }_{0}\) (see Eq. (8)), and \(\sin \left(yt\right)/y\) is small for large \( y\).
Clearly, for bath spectral functions related by Eq. (10), we have \({{\mathcal{I}}}_{{\rm{h}}}({\omega }_{0}{\Delta }_{{\rm{S}}},t)\approx \alpha {{\mathcal{I}}}_{{\rm{c}}}({\omega }_{0}+{\Delta }_{{\rm{S}}},t)\), which in turn results in the efficiency and the coefficient of performance in the nonMarkovian antiZeno dynamics regime being approximately equal to those in the Markovian dynamics regime (see Fig. 6).
QuasiLorentzian bath spectral functions
We focus on baths characterized by the spectral functions:
where we have considered the KMS condition, \(\Theta\) is the step function, \(N\in {\mathbb{Z}},\,N\;> \; 0\) denotes the number of peaks and \({\Gamma }_{{\rm{B}},r}=1/{\tau }_{{\rm{B}},r}\;> \; 0\) is the width of the \(r\)th peak. \({\delta }_{r}\) are the (real) Lamb self energy shifts, such that \({G}_{{\rm{h}}}\) (\({G}_{{\rm{c}}}\)) is peaked at \(\nu ={\omega }_{0}+\Delta +{\delta }_{r}\) (\(\nu ={\omega }_{0}\Delta {\delta }_{r}\)).
As seen from Eq. (53), we consider bath spectral functions with different resonance frequencies (\(={\omega }_{0}\pm {\Delta }_{{\rm{S}}}\pm {\delta }_{r}\)) for different modulation rates \({\Delta }_{{\rm{S}}}\). As mentioned in the main text, this ensures that the detuning between the \(r\)th resonance frequency of a bath spectral function, and the maximum of the corresponding sinc function, is always \({\delta }_{r}\), and is independent of the modulate rate \({\Delta }_{{\rm{S}}}\). For example, this can be implemented by choosing different baths for operating thermal machines with different modulation frequencies. Consequently, any enhancement in heat currents and power originate from the broadening of the sinc functions, rather than from the shift of the maxima of the sinc functions. Here \({c}_{r}\ge 0\) is the weight of the \(r\)th term in the sums in Eq. (53). A nonzero (but small) \(\epsilon \;> \; 0\) ensures that \({G}_{{\rm{c}}}(\nu )\) and \({G}_{{\rm{h}}}(\nu )\) vanish at \(\nu =0\), thus resulting in vanishing thermal excitations and entropy at the absolute zero temperature, as is demanded by the third law of thermodynamics^{47,50}. Since \({G}_{{\rm{c}}}(\nu ={\omega }_{0})={G}_{{\rm{c}}}(\nu ={\omega }_{0})=0\), the \(0\)th sideband (\(q=0\)) does not contribute to the dynamics. Supplementary Fig. 3 shows the quantum advantage obtained for bath spectral functions of the form Eq. (53) with \(N=2\) (doublepeaked functions).
For the singlepeaked case (\(N=1\)), the above functions Eq. (53) reduce to quasiLorentzian spectral functions of the form
The condition \(\delta =0\) results in the spectral functions and the sinc function attaining maxima at the same frequencies, viz., at \(\nu ={\omega }_{0}\pm {\Delta }_{{\rm{S}}}\).
SuperOhmic bath spectral functions
We also consider superOhmic bath spectral functions of the form
with the origin shifted from \(\nu =0\) by
Here \(s\;> \; 1\), and
ensures that \({G}_{{\rm{h}},{\rm{c}}}(\nu )\) is nonzero at the maxima of the sinc functions at \({\omega }_{0}\pm {\Delta }_{{\rm{S}}}\). As before, a small \(\epsilon \;> \; 0\) guarantees that \({G}_{{\rm{c}}}(\nu =0)=0\), and we consider \({\Delta }_{{\rm{S}}}\)dependent \({\nu }_{{\rm{h}}}\) and \({\nu }_{{\rm{c}}}\), to ensure that any enhancement in heat currents and power are due to the broadening of the sinc functions for fast modulations, rather than due to the shifting of the peaks of the sinc functions.
Thermal machines with arbitrary (asymmetric) spectral functions
We consider
where, as before, \(\alpha \;> \; 0\) and \(\tilde{\chi }(\nu )\) is an arbitrary real function of \(\nu\). We then have
and
In this case, we get a timedependent steadystate with
Therefore, the rate of change of \(w(t)\) with time is given by
One can still operate the setup as a cyclic thermal machine for a time \(t\le \tilde{t}\), as long as \(\chi (t)\) and \(\dot{\chi }(t)\) are small enough so as to ensure
where \({\dot{w}}_{{\rm{m}}ax}\) is the maximum value attained by \( \dot{w}(t)\) in the timeinterval \(0\le t\le \tilde{t}\).
Data availability
All relevant data are available to any reader upon reasonable request.
Code availability
All relevant codes are available to any reader upon reasonable request.
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We acknowledge the support of ISF, DFG (FOR 7024), EU (PATHOS, FET Open), QUANTERA (PACEIN), and VATAT.
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G.K. and V.M. conceived the idea. V.M. and A.G.K. performed the analytical calculations. V.M. did the numerical simulations. All authors contributed to the interpretations of the results and to the writing of the manuscript.
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Mukherjee, V., Kofman, A.G. & Kurizki, G. AntiZeno quantum advantage in fastdriven heat machines. Commun Phys 3, 8 (2020). https://doi.org/10.1038/s420050190272z
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DOI: https://doi.org/10.1038/s420050190272z
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