Fig. 1: Kinetics of CEES oxidation by O2 catalyzed by Bry/NOx with and without Cu(II). | Communications Chemistry

Fig. 1: Kinetics of CEES oxidation by O2 catalyzed by Bry/NOx with and without Cu(II).

From: A solvent-free solid catalyst for the selective and color-indicating ambient-air removal of sulfur mustard

Fig. 1

Conditions: 5.0 mM TBABr3, 10 mM p-TsOH, 10 mM TBANO3, 103 mM CEES, 70 mM 1,3-dichlorobenzene (1,3-DCB) internal standard, in MeCN under 1 atm. of air at ambient temperature (~22 °C). Red curve = 1.0 mM Cu(ClO4)2•6H2O, black curve = 0 mM Cu(ClO4)2•6H2O. These curves represent 10 turnovers based on NO3.

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