The composition of an electrolyte has a significant effect on electrocatalytic reaction rates and product selectivities. One mechanism by which spectator alkali cations can dictate reaction kinetics is now better understood.
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References
Nørskov, J. K. et al. J. Electrochem. Soc. 152, J23 (2005).
McCrum, I. T. & Koper, M. T. M. Nat. Energy 5, 891–899 (2020).
Sheng, W., Gasteiger, H. A. & Shao-Horn, Y. J. Electrochem. Soc. 157, B1529 (2010).
Huang, B. et al. JACS Au 1, 1674–1687 (2021).
Singh, M. R., Kwon, Y., Lum, Y., Ager, J. W. III & Bell, A. T. J. Am. Chem. Soc. 138, 13006–13012 (2016).
Shah, A. H. et al. Nat. Catal. https://doi.org/10.1038/s41929-022-00851-x (2022).
Chen, X., McCrum, I. T., Schwarz, K. A., Janik, M. J. & Koper, M. T. M. Angew. Chem. 129, 15221–15225 (2017).
Goyal, A. & Koper, M. T. M. Angew. Chem. Int. Ed. 60, 13452–13462 (2021).
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McCrum, I.T. Cations in alkaline hydrogen electrocatalysis. Nat Catal 5, 846–847 (2022). https://doi.org/10.1038/s41929-022-00858-4
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DOI: https://doi.org/10.1038/s41929-022-00858-4
