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Molecular water oxidation catalysts based on first-row transition metal complexes

Nature Catalysis volume 5, pages 79–82 (2022)Cite this article

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The discovery of robust and efficient water oxidation catalysts based on first-row transition metal complexes is still a challenge. Here, we describe the underlying chemistry related to the deactivation pathways of first-row transition metal complexes and put forward a series of principles and basic checks to enable the development of robust catalysts.

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Fig. 1: Pathways that lead to high oxidation state active species.
Fig. 2: Potential species distribution involved in an aqueous solution of a 1TMC.
Fig. 3: Energy diagram for water oxidation and the competing ligand oxidation.

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Acknowledgements

Financial support from Ministerio de Ciencia e Innovación, FEDER and AGAUR through grants, PID2019-111617RB-I00, SO-CEX2019-000925-S and 2017-SGR-1631 is gratefully acknowledged.

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Authors and Affiliations

  1. Institut Català d’Investigació Química (ICIQ), Barcelona Institute of Science and Technology (BIST), Tarragona, Spain

    Marcos Gil-Sepulcre & Antoni Llobet

  2. Universitat Autònoma de Barcelona (UAB), Campus UAB, Barcelona, Spain

    Antoni Llobet

Authors
  1. Marcos Gil-Sepulcre
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  2. Antoni Llobet
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Correspondence to Antoni Llobet.

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Nature Catalysis thanks James D. Blakemore and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.

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Gil-Sepulcre, M., Llobet, A. Molecular water oxidation catalysts based on first-row transition metal complexes. Nat Catal 5, 79–82 (2022). https://doi.org/10.1038/s41929-022-00750-1

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