Skip to main content

Thank you for visiting nature.com. You are using a browser version with limited support for CSS. To obtain the best experience, we recommend you use a more up to date browser (or turn off compatibility mode in Internet Explorer). In the meantime, to ensure continued support, we are displaying the site without styles and JavaScript.

SCALING RELATIONS

Mechanochemistry breaks with expectations

Nature Catalysis volume 1, pages238–239(2018)Cite this article

Subjects

Tensile strain of a solid surface can result in either strengthening or weakening of bonds with adsorbates. Adsorption energies of different adsorbate/site combinations may be shifted in different directions — a striking violation of the Brønsted–Evans–Polanyi relation.

Access options

Rent or Buy article

Get time limited or full article access on ReadCube.

from$8.99

Rent or Buy

All prices are NET prices.

Fig. 1: Relating atomic-scale mechanical interactions to experimental signatures in the macroscopic world.

References

  1. 1.

    Mavrikakis, M., Hammer, B. & Norskov, J. K. Phys. Rev. Lett. 81, 2819–2822 (1998).

    Article  Google Scholar 

  2. 2.

    Gorsky, W. Physikal. Z. Sowjetunion 8, 457–471 (1935).

    Google Scholar 

  3. 3.

    Larché, F. & Cahn, J. W. Acta Metall. 21, 1051–1063 (1973).

    Article  Google Scholar 

  4. 4.

    Fratzl, P., Penrose, O. & Lebowitz, J. L. J. Stat. Phys. 95, 1429–1503 (1999).

    Article  Google Scholar 

  5. 5.

    Khorshidi, A., Violet, J., Hashemi, J. & Peterson, A. A. Nat. Catal. https://doi.org/10.1038/s41929-018-0042-4 (2018).

  6. 6.

    Deng, Q., Smetanin, M. & Weissmüller, J. J. Catal. 309, 351–361 (2014).

    CAS  Article  Google Scholar 

  7. 7.

    Kibler, L. A., El-Aziz, A. M., Hoyer, R. & Kolb, D. M. Angew. Chem. Int. Ed. 44, 2080–2084 (2005).

    CAS  Article  Google Scholar 

  8. 8.

    Weissmüller, J., Viswanath, R. N., Kibler, L. A. & Kolb, D. M. Phys. Chem. Chem. Phys. 13, 2114–2117 (2011).

    Article  Google Scholar 

  9. 9.

    Deng, Q., Gopal, V. & Weissmüller, J. Angew. Chem. Int. Ed. 127, 13173–13177 (2015).

    Article  Google Scholar 

  10. 10.

    Stafford, G. R. & Bertocci, U. J. Phys. Chem. C 113, 261–268 (2009).

    CAS  Article  Google Scholar 

  11. 11.

    Gokhshtein, A. Y. Doklady Akademii Nauk SSSR 187, 601–604 (1969).

    CAS  Google Scholar 

Download references

Author information

Affiliations

  1. Institut für Werkstoffphysik und Werkstofftechnologie, Technische Universität Hamburg, Hamburg, Germany

    Jörg Weissmüller

  2. Institut für Werkstoffforschung, Werkstoffmechanik, Helmholtz-Zentrum Geesthacht, Geesthacht, Germany

    Jörg Weissmüller

Authors
  1. Jörg Weissmüller
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Jörg Weissmüller.

Rights and permissions

Reprints and Permissions

About this article

Verify currency and authenticity via CrossMark

Cite this article

Weissmüller, J. Mechanochemistry breaks with expectations. Nat Catal 1, 238–239 (2018). https://doi.org/10.1038/s41929-018-0061-1

Download citation

Further reading

Search

Quick links

Nature Briefing

Sign up for the Nature Briefing newsletter — what matters in science, free to your inbox daily.

Get the most important science stories of the day, free in your inbox. Sign up for Nature Briefing