The link between oxygen redox and structural disorder in lithium-rich layered electrodes has been challenging to unravel. A theoretical framework for the link between structural disorder, subsequent bond rearrangements and redox chemistry has been proposed, providing guidance for the materials engineering of high-capacity electrodes.
This is a preview of subscription content, access via your institution
Access options
Access Nature and 54 other Nature Portfolio journals
Get Nature+, our best-value online-access subscription
$29.99 / 30 days
cancel any time
Subscribe to this journal
Receive 12 digital issues and online access to articles
$119.00 per year
only $9.92 per issue
Buy this article
- Purchase on Springer Link
- Instant access to full article PDF
Prices may be subject to local taxes which are calculated during checkout
References
Bauer, C. et al. Charging sustainable batteries. Nat. Sustain. 5, 176–178 (2020). A comment article that highlights the importance of developing sustainable batteries with high energy densities.
Li, W., Erickson, E. M. & Manthiram, A. High-nickel layered oxide cathodes for lithium-based automotive batteries. Nat. Energy 5, 26–34 (2020). A review article that presents the importance of cathode materials in attaining high energy densities.
Li, M. et al. Cationic and anionic redox in lithium-ion based batteries. Chem. Soc. Rev. 49, 1688–1705 (2020). A review article that presents the promise of lithium-rich layered oxide electrodes.
Assat, G. & Tarascon, J.-M. Fundamental understanding and practical challenges of anionic redox activity in Li-ion batteries. Nat. Energy 3, 373–386 (2016). A review article that examines the practical challenges of lithium-rich electrodes.
Eum, D. et al. Voltage decay and redox asymmetry mitigation by reversible cation migration in lithium-rich layered oxide electrodes. Nat. Mater. 19, 419–427 (2020). This paper reports a strategy to improve the structural reversibility of lithium-rich layered oxide electrodes.
Additional information
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
This is a summary of: Kim, B. et al. A theoretical framework for oxygen redox chemistry for sustainable batteries. Nat. Sustain. https://doi.org/10.1038/s41893-022-00890-z (2022).
Rights and permissions
About this article
Cite this article
Stabilizing oxygen redox chemistry for the realization of high-capacity batteries. Nat Sustain 5, 647–648 (2022). https://doi.org/10.1038/s41893-022-00891-y
Published:
Issue Date:
DOI: https://doi.org/10.1038/s41893-022-00891-y