Experimental investigations on physico-mechanical properties of kaolinite clay soil stabilized at optimum silica fume content using clamshell ash and lime

This investigation examines the effect of clamshell ash (CSA) and lime additives on the physico-mechanical characteristics of kaolinite clay soil stabilized at the optimum silica fume content. Laboratory tests were performed to assess plasticity, shrink-swell characteristics, compaction characteristics, unconfined compressive strength (UCS), shear strength characteristics, mineralogical and morphological microstructure characteristics of stabilized soil specimens. The kaolinite clay soil was stabilized at its optimum silica fume content (6%) to produce the highest strength and was altered with three non-identical proportions of clamshell ash and lime (3%-9%). Cylindrical soil specimens, 76 mm in height and 38 mm in diameter, were moulded and treated for curing periods of 1, 7, 14, and 30 days to examine the strength of the altered soil. The findings revealed that, adding clamshell ash and lime significantly alters the plasticity, shrink-swell, maximum dry unit weights, and optimum moisture contents of the silica fume-stabilized soil. In terms of strength, the beneficial effects of CSA and lime additives were found to be more significant with more extended curing periods. Incremental increases in curing periods resulted in further enhancements in UCS, cohesion, and internal friction angle, indicating continued strength development over time. Microstructural analysis using field emission scanning electron microscopy and X-ray diffraction provided insights into the interparticle bonding mechanisms and microstructural changes induced by the addition of CSA and lime. The emergence of cementitious phases and pozzolanic responses between soil particles and stabilizers contributed to the densification and strengthening of the stabilized soil matrix. The findings of this study provide valuable insights into the potential of clamshell ash and lime additives to enhance the engineering properties of kaolinite clay soil stabilized with silica fume. These results have implications for sustainable soil stabilization practices, offering a promising approach to improve the performance of soils for various engineering applications, including construction and geotechnical projects.


Materials and methods
The materials examined in this study are kaolinite clay soil, silica fume, calcinated clamshell ash (CSA), and laboratory-grade hydrated lime utilized as the subsidiary alteration agent in the stabilization method.

Materials preparations and properties
Kaolinite clay is a mineral whose chemical composition is Al 2 Si 2 O 5 (OH) 4 .Kaolinite clay soil has a water-repellent polymer structure and tends to blend with moisture to form uniform clay.The kaolin powder's structure is platelike, fused by hydrogen bonds and secondary valence forces 19 .The engineering characteristics of the kaolinite soil are listed in Table 1.Silica fume was obtained from Scancem Materials Sdn.Bhd, Malaysia.It is known for its high pozzolanic value owing to its elevated silica content.The clamshells, predominantly composed of CaCO 3 , were cumulated from restaurants in Kuantan, Pahang, and around the east coast beach of Malaysia.These clamshells undergo calcination, resulting in the alteration of CaCO 3 to CaO.The air-dried clamshells were pulverized using a jaw crusher and then calcined at 800 °C for 1 h.The CSA exhibited a white color from the calcination process.It was subsequently stored in a desiccator for one day, allowing it to cool and preventing the hydration process between CSA and atmospheric moisture.The lime utilized in the study was a laboratory-grade hydrated lime supplied by CAO Industries; it was utilized owing to its compatible chemical compositions, which depleted the probability of variations in laboratory results.The chemical compositions of kaolinite clay, SF, CSA, and lime and their significant mineralogical identifications are listed in Tables 2 and 3.The morphological microstructures of all four (4) materials are illustrated in Fig. 1.
The CSA content was fixed similarly to the lime to maintain uniformity in investigating and comparing the effectiveness of CSA and lime on the silica fume-stabilized soil (SFSS).In the study, 6% of SF was admixed with 3%, 6%, and 9% of CSA and lime and were tested under eight (8) different tests as highlighted in section "Soil consistency tests" to section "X-ray fluorescence (XRF), X-ray diffraction (XRD), and field emission scanning electron microscopy (FESEM) test".Table 4 shows the sample mixture used in the study and Table 5 shows the sample used coherent to the test standard used in the study.In addition, Fig. 2 portrays the sample preparation for UCT and CIU test, while Fig. 3 portrays the experimental setup of kaolinite soil stabilization implemented in this study.

Soil consistency tests
The plasticity range of clay soil can be measured in numerical expression with consistency limits, as the moisture content of clay soil is also known as plastic consistency.Expansive clay was manufactured using the test method because its particle size range was finer than 63 µm.Clay and soil appear in four (4) states, depending on a specific moisture content: solid, semi-solid, plastic, and liquid.The consistency tests were conducted according to BS 1377: Part 2: 1990.The consistency tests were conducted on air-dried SFSS fraction passing 425 µm sieve.The LL, PL, and SL were based on BS 1377: Part 2: 1990.

Compaction test
Standard Proctor compaction test was used in accordance with BS 1377-2:1990 by utilizing a 2.5 kg hammer and 1-L capacity mould to determine the interconnection between the optimum moisture content (OMC) and the maximum dry density (MDD) for treated and untreated soft kaolin clay.Three (3) layers were compacted one by

Consolidated isotropic undrained (CIU) triaxial test
In this study, the consolidated isotropic undrained (CIU) triaxial test was utilized to evaluate the shear strength of the SFSS and SFSS altered with CSA and lime.The density of treated and non-treated soft clay was 1.74 kg/ cm 3 .Eventually, the CIU tests were performed according to BS 1377: Part 7: 1990.The samples utilized in the CIU test were prepared by compressing soil specimens with an optimal water content of the soils.The specimens were compressed in a cylindrical steel mould with dimensions of 76 mm height × 38 mm diameter and were treated for 1, 7, 14 and 30 days of curing in air tight container at room temperature of 25 °C.A total of three (3) samples were prepared for each of the mixtrue in CIU test.

Results and discussion
The optimum silica fume content (OSFC) for the soil under examination was 6%, which was implemented to stabilize the kaolinite clay soil.The stabilization mechanism was altered by mixing 3%, 6%, and 9% CSA and lime.The influence of the alteration on the plasticity, shrink-swell characteristics, compaction characteristics, unconfined compressive strength (UCS), shear strength parameters, and mineralogical and morphological microstructure properties were examined as part of the study.
Effect of CSA and lime on the plasticity and shrink-swell properties of SFSS Figure 4 illustrates the alterations in consistency limits owing to the inclusion of CSA and lime in the stabilized soil with OSFC.The addition of CSA and lime to 6% of SFSS resulted in an initial depletion in the liquid and plastic limits, then increased at further inclusion of CSA and stabilized at further inclusion of lime proportion.The liquid limit and plastic limit diminished to the lowest value of 37.0% and 31.5% at 3% of CSA inclusion, while at 6% of lime inclusion, the liquid limit and plastic limit diminished to the lowest value of 33.2% and 28.3%.Coherent to that, it is evident that at 6% of SF content, CSA and lime modify the plasticity of the SFSS by modifying both the liquid and plastic limits of the stabilized soil.The outcome of the plasticity test discloses that plasticity is the lowest at 3% CSA and 6% lime at 5.5% and 4.9%, respectively, as opposed to a value of 6.6% of pure SFSS.The plasticity modifications of SFSS induced by CSA and lime inclusion were affected by the cation interchange that exists between the SFSS and positive cations in the CSA and lime.In SFSS, the addition of CSA and lime causes cation exchange processes that drastically modify the soil's plasticity.Cation exchange refers to the transfer of positively charged ions (cations) between the SFSS and the additional components.CSA and lime produce calcium (Ca 2+ ) ions, which replace other cations found in the soil, including as sodium (Na + ) and potassium (K + ).This exchange lowers the concentrations of sodium and potassium ions in the soil, reducing its flexibility.Furthermore, aluminum (Al 3+ ) ions from CSA may replace other cations, altering soil characteristics.Lime dissociates into calcium (Ca 2+ ) and hydrogen (H + ) ions, with the hydrogen ions displacing other cations and causing soil flocculation, hence decreasing flexibility.Overall, the cation exchange mechanism involving calcium, aluminum, and hydrogen ions has a significant impact on the flexibility of SFSS when stabilized with CSA and lime, resulting in improved engineering characteristics and stability.The depletion in plasticity properties of the SFSS was affected by substituting highly plastic SF-clay particles with unamiable CSA and lime molecules.At higher CSA and lime contents, the plasticity increases and becomes stable.This is because, when CSA comes into contact with water, it forms calcium silicate hydrate (CSH) gel and calcium aluminate silicate hydrate (CASH) gel due to its high concentration of calcium oxide (CaO) and lime (calcium hydroxide, Ca(OH) 2 ).These hydrated gels cover the gaps between soil particles, increasing cohesion and lowering soil flexibility.Furthermore, the extra lime content produces an excess of calcium ions, which participate in cation exchange activities, replacing exchangeable sodium and potassium ions in the soil.This exchange process further lowers soil plasticity by flocculating clay particles.As the lime level rises, surplus lime combines with soil particles to generate stable calcium silicate and calcium aluminate compounds, increasing soil stability while decreasing flexibility.As a result, at higher CSA and lime contents, the soil's plasticity initially  www.nature.com/scientificreports/increases due to the presence of excess lime and reactive materials, but then stabilizes as the soil undergoes hydration and chemical reactions, resulting in improved engineering properties and stability 41,42 .Hence, low CSA and lime contents are more efficacious in minimizing plasticity characteristics than higher percentages of CSA and lime with higher SF content.XRF analysis shows that CSA and lime contain substantial amounts of calcium oxide (CaO).The consistency limits results obtained in this study are in a good agreement with an investigation performed by Harichane et al. 12 .The utilization of pozzolanic materials can significantly modify the consistency limits of the clayey soils.James 43 and Bian et al. 44 validated that the inclusion of SiO 2 and CaO-based materials in SFSS soils causes flocculation, thus reducing the consistency limits of the soil.Moreover, due to the fact that SFSS is aluminosilicates, the response of CaO with the SFSS structure generates CSH and CAH, which equalize the ionic bond in the structure of SFSS minerals and reduce the exchange capacity of the cation for water molecules.According to Mohanty et al. 45 , the depletion in moisture retention capacity can be ascribed to the presence of stabilizing agents that coat the SFSS molecules, causing them to bind together and fill the voids within the soil matrix.This process leads to a decrease in pore space and moisture content.Additionally, the incorporation of clamshell ash (CSA) and lime changes the consistency limits of the soil-stabilizing system (SFSS) due to increased affinity for moisture.CSA and lime facilitate the cohesion and aggregation of SFSS particles, resulting in a coarser texture.Similar findings were reported by Alrubaye et al. 19 and Zaini and Hasan 26,40,46 .
As the soil undergoes drying, the molecules comprising the soil-stabilizing system (SFSS) exhibit proximity, leading to a decrease in moisture content.Despite this reduction in moisture, the volume of the SFSS mass remains relatively unchanged, as it assumes a solid-like behavior.This phase, characterized by a stabilized moisture content, is termed the shrinkage limit (SL), which profoundly influences the propensity of the SFSS to undergo shrinkage.Notably, a lower SL value correlates with a heightened capacity for shrinkage within the SFSS. Figure 5 highlights the shrink-swell characteristics of CSA and lime-altered SFSS.The inclusion of CSA and lime resulted in a minimal upsurge in the FSI of the stabilized soil.The FSI of the SFSS raised from 12.55 to 21.61 and 13.12% only, with a margin difference of 9.06% and 0.57% when the maximum proportion of CSA and lime were utilized.The results show that the FSI of the SFSS when CSA was utilized was significantly improved, while opposite results were obtained when lime was integrated into the SFSS.The integration between SFSS molecules with CSA and lime molecules resulted in the massive repository of calcium ions as CSA, and lime has substantial CaO content.The increase in swelling is attributed to the SFSS's elevated capacity for swelling upon exposure to water, stemming from its capability to absorb and retain water molecules.The integration of CSA and lime significantly influences the SL of the SFSS.The difference between the SL value observed in pure SFSS specimens and SFSS altered with CSA and lime exceeds 1%.
Nonetheless, the inclusion of CSA and lime significantly alters the shrinkage characteristics of SFSS to an enormous extent.In line with this, the elevation in shrinkage limit (SL) is ascribed to the aggregation of molecules resulting from clamshell ash (CSA) and lime modification.The silica fume-stabilized soil (SFSS), initially characterized by high plasticity, exists in a dispersed state.However, with the augmented absorption of ions due to the CSA and lime modification, the thickness of the double layer surrounding the SFSS molecules reduces, reducing repulsive forces between them.This phenomenon led to the formation of aggregated conglomeration in SFSS molecules.The formation of aggregated conglomerates enhances resistance against capillary uptake, impacting volumetric shrinkage and increasing the shrinkage void ratio as moisture content decreases.Consequently, the silica fume-stabilized soil (SFSS) composition stabilized with clamshell ash (CSA), and lime has notably endured within the aggregation domain.
Based on the aforementioned findings, the highest proportion of CSA and lime within the soil-stabilizing system (SFSS) led to the formation of a highly porous structure capable of retaining a significant volume of water around the soil molecules 47,48 , thus increasing the LL, PL, FSI (Free Swell Index), and SL value.The incorporation of CSA and lime into the stabilized soil-stabilizing system (SFSS) results in a structurally robust framework that effectively resists contraction, thereby contributing to an increase in the shrinkage limit (SL) 49 .Presently, the SFSS predominantly consists of non-swelling soil with reduced fine content, and the influence of the dispersed double-layer recession owing to the minimal presence of CSA and lime is negligible.Nevertheless, the increment percentages of CSA and lime in the SFSS led to a significant increment in PL and LL, while a slight marginal improvement in FSI and SL was ascribed to the emergence of calcium silicate hydrate (CSH) and calcium aluminate silicate hydrate (CASH) gel that withstands the large quantity of water.Hence, it can be inferred that the integration of CSA and lime into SFSS at multiple mix ratios can alter the plasticity and swellshrinkage properties of the soil, and the integration of CSA into the SFSS shows a higher alteration compared to the integration of lime into the SFSS.The shrink-swell characteristics results obtained in this study are aligned with an assessment performed by Gadouri 14 .The utilization of pozzolanic materials can significantly modify the shrink-swell characteristics of the clayey soils.

Effect of CSA and lime on the compaction properties of SFSS
The dry unit weight and moisture content of SFSS with CSA and lime content are illustrated in Fig. 6.The MDD value of SFSS is 1.54 g/cm 3 with an OMC of 17.00%.The reduction of MDD is examined to be in the range of 1.42 g/cm 3 to 1.55 g/cm 3 with an OMC value ranging from 17.00 to 24.00%.Hasan et al. [50][51][52] have reported a similar result.It is examined that when the dosage of soil stabilizers increased, the MDD decreased while the OMC values increased.The upsurge in OMC was proportionately confined.As a result, the reduction in thickness of the double-layer ensued, leading to grain accumulation as sodium cations in the diffuse layer of SFSS are replaced by calcium ions 53 .The prevalence of silty soil type within the SFSS matrix promotes closely packed molecules, thereby inhibiting the formation of additional void volume.Coherently, as the attraction between soil molecules increases, the molecules move closer together, reducing MDD value.The MDD reduction observed in both SFSS combined with CSA, and lime can be attributed to hydration, dissociation, and pozzolanic reactions, which decrease the density of the soil matrix.The addition of CSA and lime altered the organization of SFSS molecules, resulting in a denser packing arrangement.This alteration in specific surface area necessitates water absorption to facilitate hydration and pozzolanic reactions among the fine particles, thereby initiating soil improvement.The reduction in MDD is directly dependent on the OMC.Consequently, the OMC of the stabilized sample experiences flocculation due to the adhesion capability of CSA and lime.A substantial amount of water is required to form calcium silicate hydrate (CSH) and calcium aluminate hydrate (CAH) molecules and for the pozzolanic response in the presence of SF.The compaction results obtained in this study are in a good agreement with a study conducted by Gadouri 14 .The utilization of additives can significantly alter the compaction characteristics of the soil.

Effect of CSA and lime on the UCS of SFSS
Improvement of UCS for 6% of SFSS altered with CSA and lime is portrayed in Table 6.The findings show that the compressive strength of the SFSS elevates slowly with the increment of the CSA and lime content and curing days.The compressive strength of the SFSS altered with 3%, 6%, and 9% of CSA and lime significantly improved from 15.51 kN/m 2 at 1 day of curing to 93.54 kN/m 2 , 145.34 kN/m 2 and 189.75 kN/m 2 at 30 days of curing for CSA utilization and 27.17 kN/m 2 , 40.22 kN/m 2 , and 70.24 kN/m 2 at 30 days of curing for lime utilization.From the results, the utilization of 9% of CSA and 9% of lime at 30 days of curing periods led to the most significant enhancement in the UCS value of the SFSS.Identical observations were observed by Alrubaye et al. 19 , Zaini et al. 54 , and Türköz et al. 55 .Besides, it is noted that the enhancement of the UCS observed in SFSS soil is due to the 1.20 www.nature.com/scientificreports/loess matrix that potentially fills the macropores and enhances the cohesion between loess aggregates.Additionally, the SF alters the sample's inner structure, resulting in an increment in the shear strength.The chemical effects stem from reactive silica in the SF, capable of chemically reacting with the loess particles in an alkaline surrounding, thereby producing a binding material 56 .This chemical reaction is also positively correlated with the observed improvement in sample strength.The massive CaO content present in CSA and lime is crucial to initiate the hydration process for the generation of Ca(OH) 2 when reacting with water.The higher the Ca(OH) 2 production, the higher the pozzolanic response will occur.High production of CSH and CASH leads to the effective alterations and substantial strength improvement of kaolinite clay.However, the significant physiochemical responses governing the engineering characteristics of SFSS mixtures include cation exchange reactions, flocculation of kaolinite clay particles, pozzolanic response, and agglomeration.The agglomeration of soil molecules resulted from the charge neutralization effect of the CSA and lime, forming silica gel.This phenomenon increased shear resistance and particle contact within the soil.Furthermore, reactions such as cation dissociation and interchange contribute to rapid changes in soil workability, enhancing particle adhesion and improving the kaolinite clay's strength.The UCS results obtained in this study are in a good agreement with a study conducted by Aldaood et al. 11 .The utilization of additives can significantly alter the UCS value of the clayey soil.
In addition, the curing periods affect the inclusion of CSA and lime into the soil together with SF in the kaolinite clay stabilization process.As examined in Table 6, the ramification is notable at later curing periods.The increments in the specimens' curing periods resulted in the maximum value of UCS observed in SFSS altered with CSA and lime.Table 6 illustrates the influence of curing periods on the improvement of strength of the SFSS altered with CSA and lime.Based on the analysis, it can be clearly seen that the curing periods affect CSA and lime alteration on the SF-kaolinite clay stabilization.The CSA and lime-modified strength curves are significant compared to the strength curves of pure SFSS.The data depicted in the figure suggests that incorporating clamshell ash (CSA) and lime into the silica fume-stabilized soil (SFSS) has substantial positive ramifications on enhancing the long-term strength of the kaolinite clay soil.Additionally, it is evident from Table 6 that variations in curing periods notably influence the strength enhancement of CSA and lime-modified SFSS.
In this study, the strength improvement in percentage was also analyzed to portray the significant contribution of CSA and lime in improving the strength of the soil.Figure 7 illustrates the percentage strength improvement of CSA and lime content utilized to alter the SF stabilization activity.The analysis examined the effects of CSA and lime on strength improvement across four (4) contrasting curing periods.The strength improvement at 1 day of curing was represented as "instantaneous strength, " 7 days of curing as "premature strength, " 14 days www.nature.com/scientificreports/ of curing as "matured strength, " and 30 days of curing as "retarded strength." The original strength of SFSS was established as a control for evaluating the percentage of strength improvement owing to the inclusion of CSA and lime for 1, 7, 14, and 30 days of curing periods, which disclosed the extent of the strength improvement coherent to pure SFSS.CSA and lime integration into the SFSS emerged with the lowest instantaneous strength improvement of 72.83% with 3% ESA and 27.27% with 3% lime, while 6% SFSS altered with 9% CSA and 9% lime resulted in a substantial instantaneous strength improvement of 114.41% and 76.48% respectively.The increment in the curing periods resulted in a significant increase in premature strength, matured strength, and retarded strength observed in 9% of CSA and lime utilization with a maximum percentage of strength improvement of 450.61%, 177.71% for premature strength improvement, 973.36% and 224.42% for matured strength improvement, and 1123.25% and 352.82% for retarded strength improvement.Therefore, it is perspicuous that the inclusion of CSA and lime into the SFSS emerged in a 72%-115% of instantaneous strength improvement of CSA, 27%-77% of instantaneous strength improvement of lime, 325%-451% of premature strength improvement of CSA, 62%-178% of premature strength improvement of lime, 345%-974% of matured strength improvement of CSA, 70%-225% of matured strength improvement of lime, 503%-1124% of retarded strength improvement of CSA, and 75%-353% of retarded strength improvement of lime.The results obtained are consistent with the findings reported by Zaini and Hasan 26,40 .

Effect of CSA and lime on the shear strength characteristics of SFSS
The experimental results of the CIU analysis propose that the cohesion and internal friction angle of SFSS are significantly affected by the inclusion of CSA and lime (see Fig. 8a,b).The cohesion of SFSS, when CSA and lime were integrated exhibits improvement and reaches its maximum value of 19.63 kN/m 2 and 15.10 kN/m 2 at 1 day of curing periods when 9% CSA and lime were utilized respectively.The cohesion value of SFSS steadily increased with the increment in curing periods and achieved its highest value of 21. www.nature.com/scientificreports/m 2 at 30 days of curing.The increase in the cohesion value of the SFSS was due to the reaction of cementitious material via hydration and the pozzolanic response process.The cohesion between SFSS molecules and the CSA and lime molecules increases through the chemical reaction.Furthermore, the small molecules of the soil stabilizers contribute to the packing of the soil matrix, emerging in a denser soil mixture.This densification is ascribed to the pozzolanic response, ultimately increasing the soil cohesion 37 .Comparable investigations have been assessed by Alrubaye et al. 18,19 and Zaini and Hasan 46 .Figure 8b highlights the influence of CSA and lime on the internal friction angle of SFSS.Based on the figure, the inclusion of CSA and lime at different proportions and curing periods increases the internal friction angle of the SFSS.The curing periods are essential in enhancing the internal friction angle of the SFSS.The increment of the internal friction angle value with an increasing percentage of CSA and lime in SFSS up to a maximum value of 43.52° and 33.48° at 30 days of curing can be elucidated by the collaborative impact of CSA and lime on the soil's mechanical characteristics.The maximum internal friction angle observed in all samples stabilized for 30 days of curing can be ascribed to the cation exchange activity and pozzolanic response between the SFSS-CSA and SFSS-lime.CSA and lime contain high calcium carbonate content and engage in a pozzolanic reaction with SiO 2 contained in during stabilization.This chemical interaction gives rise to the formation of CASH and CSH.As the concentration of these compounds rises with higher proportions of CSA and lime, the cementation between soil particles is intensified.Throughout this process, the bonding between the particles becoming stronger, coupled with microstructural changes induced by the additives, fosters a more stable and interconnected soil matrix.The particles in CSA and lime further contribute to improved particle packing, filling void spaces, and enhancing the interlocking of soil grains.The cumulative effect of these mechanisms results in increased soil strength, translating into a higher internal friction angle.This phenomenon signifies an augmented resistance to shear and improved frictional characteristics within the stabilized soil, highlighting the effectiveness of CSA and lime in fortifying the engineering characteristics of the soil matrix.The cohesion and internal friction angle results obtained in this study are aligned with a study conducted by Harichane et al. 12 .The utilization of additives can significantly improve the shear strength parameters of the soil.

Effect of CSA and lime on the mineralogical and morphological microstructure characteristics of SFSS
The notable strengthening effects observed during lime stabilization can be attributed to establishing pozzolanic products, such as CSH and CAH minerals 43,57 .X-ray diffraction (XRD) analysis provided insights into the mineralogical changes in the soil-stabilizing system (SFSS) upon the addition of clamshell ash (CSA), and lime, as illustrated in Fig. 9.The predominant minerals in the SFSS included quartz, kaolinite, illite, and cristobalite, while the introduction of CSA introduced calcite and portlandite, and lime added calcite.The CSA and lime-altered SFSS exhibited a composition of kaolinite, quartz, calcite, cristobalite, and muscovite.XRD patterns revealed new peaks, portraying the emergence of mineralogical compounds based on the added materials.The depletion in peak intensities of quartz and kaolinite in the stabilized kaolinite clay can be ascribed to the development of cementitious bonding.Previous studies conducted by Zaini and Hasan 40 have examined the behaviour of silica fume (SF), eggshell ash (ESA), and lime stabilizers in kaolinite clay.Zaini and Hasan 40 identified recurring crystalline clay minerals, including kaolinite, illite, smectite, and montmorillonite.The presence of calcium oxide (CaO) in the calcite and portlandite minerals of CSA and lime augmented the strength potential of the soil-stabilizing system (SFSS).Upon hydration, CaO produces calcium hydroxide (Ca(OH) 2 ), which undergoes carbonation upon interaction with CO 2 in the environment, causing the emergence of calcium carbonate (CaCO 3 ).This  www.nature.com/scientificreports/carbonation mechanism enhances the bonding between soil molecules, contributing significantly to the strength of the SFSS and incorporating calcite and portlandite with wet clay particles in the presence of cristobalite results in the dissociation of calcium, silicate, aluminate, and hydroxide ions.The positive charges of calcium ions are absorbed by the negative charges of the SFSS, causing SFSS molecules to aggregate and ultimately enhancing cohesion among SFSS molecules, thereby increasing strength 58 .In line with this, it has been demonstrated that the inclusion of CSA and lime significantly alters pozzolanic responses, contributing to strength improvement.Consistent findings have also been documented by Alrubaye et al. 18 , Alrubaye et al. 19 , and Aldaood et al. 11 .Morphological microstructure analysis was conducted to assess the microstructural development in the matrix of SFSS (Fig. 10).The kaolinite clay displayed an uneven-shaped microstructure, while SF molecules exhibited a tiny spherical shape with a particle size of a thousand micrometres.CSA and lime particles had a bumpy, dispersed morphology with varying particle size distribution.The addition of CSA and lime resulted in morphological alterations, breaking the scabrous structure of SFSS into a lumpy structure.Needle-like crystals formed between the soil and cementitious molecules, creating a densely packed and stiffer soil structure.In the SFSS, SF particles showed limited reactivity and binding with the kaolinite clay molecules due to lower Ca(OH) 2 production during the hydration process.
In contrast, 6% SFSS with 9% of CSA and lime exhibited a dense matrix with cementitious compound formations.The appearance of unpigmented cementitious compounds on the surfaces of soil-stabilizing system (SFSS) particles signifies the onset of pozzolanic reactivity.The microstructural development showed aggregated arrangements due to flocculation, where Ca 2+ ions provided by CSA and lime reacted with alumina and silica in SFSS during the pozzolanic response.The integration of CSA and lime as additives in SFSS stabilization led to the flocculation of soil particles, reducing pore spaces and substantially increasing the strength of the SFSS.The morphology and size of ettringite crystals notably impacted the strength characteristics, with larger crystals demonstrating higher strength properties.Consequently, it can be inferred that the morphological microstructure of the altered soil aligns with the observed strength outcomes.In accordance with this, the amalgamation of www.nature.com/scientificreports/SFSS, clamshell ash (CSA), and lime at 6% and 9% effectively enhanced soil strength by fostering denser particle arrangements.

Stabilization mechanism of CSA and lime in SFSS Stabilization
Cation exchange (CEC), flocculation, and pozzolanic reaction are necessary for stabilizing problematic and expansive soil.CEC and flocculation are short-term reactions triggered immediately when the chemical stabilizing agent is added to the untreated virgin soil.CEC and flocculation are the critical reactions that cause the alteration of plasticity characteristics of soil.The resulting soil will become friable, whereas the natural soil can be easily cut and moulded into shape when wetted.The reducing power of CEC is influenced by the adsorption affinity of cation, whereas Al > Ca > Mg > K = NH > Na > Li, pH of soil water, and types of clay minerals.Generally, kaolinite has the lowest CEC strength, while montmorillonite has the highest.Soil with high CEC value generally exhibits greater swelling properties than soil with lower CEC [59][60][61] .
According to Huang et al. 62 , the concentration of calcium ion (Ca 2+ ) and OH -from saturated Ca(OH) 2 affects the production of calcium silicate hydrate (CSH), with chemical formula CaSiO 3 H 2 O in the stabilized soil, and CSH is the main contributor to the strength of stabilized soil.When the concentration of Ca 2+ and OH -is low, the strength of stabilized soil is low due to the lack of CSH.Yu et al. 63 also deduced that CEC can decrease the saturation of Ca(OH) 2 , which increases the concentration of Ca 2+ and OH -and the production of CSH; thus, the strength of the stabilized soil improved.If the CEC of the soil sample is too high, Ca 2+ is exchanged by the other cations adsorbed on the soil particles, thus reducing the Ca 2+ concentration, and the stabilized soil strength is reduced due to insufficient CSH.
Flocculation is when the dispersed particles form larger clusters, come into contact, and adhere together.Generally, most soil particles are negatively charged, and due to the repelling charges theory, the soil particles are dispersed.When the stabilizer is introduced to the untreated clay soil, the cations are attracted by the negative charge of clay particles, causing them to stick together.Flocculation occurs as the repulsive force between the negative charge of clay particles is cancelled off when they are attracted by the stabilizer's Ca 2+ or magnesium ion (Mg 2+ ) and form a friable soil.Cementitious properties and pozzolanic reactions are crucial in stabilizing soft clay soil.The pozzolanic reaction, which is a slow process, primarily contributes to strength development.Typically, CaO and SiO 2 are recognized as cementitious material's principal constituents, both acting as binding agents when water is added.When hydration occurs, when water is added, the CaO will react with the water and form calcium hydroxide, Ca(OH) 2 , as shown in Eq. ( 1).
However, dissociation reactions lead to immediate changes in the plasticity and workability of the clay soil, as described in Eq. ( 2).Processes such as cation exchange, dispersion of clay soil particles, accumulation, and pozzolanic reactions are the primary physicochemical responses that affect the properties of SiO 2 -CaO soil mixtures.The presence of Ca 2+ ions in the stabilized clay soil reacts with water according to the chemical reaction pathways outlined in Eqs.(3 and 4).
Dissociation Reaction: Pozzolanic reaction: The continuous pozzolanic reaction produces gel-like calcium silicate hydrates (CSH) and threadlike calcium aluminate silicate hydrates (CASH), facilitating the bonding between stabilized clay soil particles and reinforcing soil strength.The prolonged pozzolanic reaction significantly influences the engineering properties of the soil, including porosity, hydraulic conductivity, and strength.Kaolinite clay has a low CEC due to its aluminosilicate composition, whereas CSA and SF have greater CEC values.The greater CEC of SFSS with CSA allows an adsorbtion of calcium (Ca 2+ ) and aluminum (Al 3+ ) ions from the surrounding solution, encouraging the production of CASH gel by the interaction of these ions with the clay's silicate components.The CASH gel functions as a binding agent, stabilizing the kaolinite clay while increasing its strength and durability.As a result, the CEC of SFSS with CSA is critical in promoting the development of CASH gel and improving the stability of stabilized kaolinite clay.According to Shao et al. 64 and Barman and Dash 5 , the pozzolanic reaction depends on two key factors: the maximum amount of Ca(OH) 2 that the pozzolan can react with and the surface area of the pozzolan.A larger surface area of the pozzolan results in higher pozzolanic reactivity.Clamshell ash (CSA) and lime primarily contain CaO, while silica fume (SF) consists of over 80% SiO 2 and is considered an artificial pozzolan primarily composed of silica glasses 65 .As pozzolans typically have low CaO content, lime or cement is often added due to their high CaO percentage.In this study, CSA and lime are utilized as the CaO source to replace cement in the chemical stabilization of soil.

Cost analysis
In the quest for cost-effective strategies in civil engineering substructure development, navigating within the constraints of limited funding allocated for civil infrastructure construction and maintenance is imperative.To assess the efficacy of the proposed soil stabilization materials introduced in this study compared to conventional www.nature.com/scientificreports/cement-based soil treatment, a cost-benefit analysis emerges as a pivotal parameter for decision-making amid many alternatives.Accordingly, the pertinent literature was surveyed to gather precise unit prices of commodities, utilities, excavation, and in-place stabilization.Operational costs beyond these parameters were excluded from consideration.Table 7 presents the unit prices of materials and operations for soil stabilization.Leveraging the insights gleaned from this table, the soil stabilization process of the soil-stabilizing system (SFSS) was scrutinized and depicted in Fig. 11.Table 7 shows that the unit price for cement as soil stabilizer is lower than SF, with a margin difference of RM0.47 per kg (C-SF).Due to the data source found on the CSA and the material was self-collected, the CSA price was considered RM0.Hence, compared to CSA, cement's unit price is slightly higher, with a margin difference of RM0.55.The unit price of materials between cement and hydrated lime are RM0.55 and 0.53, respectively.The unit price shown in Table 7 is crucial to determine the total cost required to stabilize the kaolinitic clay soil using ideal percentages and combinations of SF, CSA, and lime.Based on the proposed percentages, the quantity of stabilizers needed to stabilize the kaolinitic clay soil must be calculated to calculate the total cost for soil stabilization.Hence, Table 8 shows the quantity of soil stabilizers needed to stabilize the assumed quantity of soil.Based on Table 8, the total soil assumed to be stabilized in this study was equal to 10,000 kg (10 m 3 ), as discussed by Tripathi et al. 68 .
Based on the total soil needed to be stabilized, the quantity of soil stabilizers was calculated and tabulated in Table 8.In order to compare the cost between the traditional stabilizers and the proposed stabilizers, four (4) samples that utilized cement stabilizers were tallied with the seven (7) types of proposed stabilizers.C6Cm sample was compared with the CS6 sample, the C9Cm sample was compared with the CS6Cs3 and CS6L3 sample, the C15Cm sample was compared with the CS6Cs6 and CS6L6 sample, and the C15Cm sample was compared with the CS6Cs9 and CS6L9 sample.In this study, 10 m 3 of soil is assumed to be stabilized.Coherent to the unit price of materials and operations for soil stabilization, the total cost projected for the conventional and proposed soil stabilizers is shown in Table 9. Figure 11 compares the total cost between cement and the soil stabilizers used in the study.The OMC of the cement was selected to be 7% based on the research conducted by Kulanthaivel et al. 69 .
Based on Table 9 and Fig. 11, the comparison is made between C6Cm with CS6 (denoted with red colour), C9Cm with CS6Cs3 and CS6L3 (denoted with green colour), C12Cm with CS6Cs6 and CS6L6 (denoted with pink colour), and C15Cm with CS6Cs9 and CS6L9 (denoted with purple colour).The table and figure show that the total cost of stabilization for cement utilization as a soil stabilizer is cheaper than SF stabilizer, with a 6.96% www.nature.com/scientificreports/cost increment (margin cost difference of RM63.03).Meanwhile, the utilization of CSA with SFSS is cheaper than cement, with a margin cost difference of RM102.03,RM267.41, and RM431.22,respectively.Conversely, the utilization of lime with SFSS resulted in higher increment of the total cost of stabilization lime utilization when compared to cement, with an increment cost of RM57.74,RM51.84 and RM45.95, respectively.Therefore, it can be concluded that utilizing CSA in SFSS can reduce the total cost of soil stabilization up to 10.06% (with 3% CSA utilization), 22.51% (with 6% CSA utilization), and 31.99% (with 9% of CSA utilization), while utilizing lime SFSS can increase the total cost of stabilization up to 5.37% (with 3% lime utilization), 4.20% (with 6% lime utilization), and 3.30% (with 9% of lime utilization) compared to the utilization of cement as soil stabilizing agent.Nevertheless, due to the cost-effectiveness of CSA utilization in SFSS, this material is an ideal choice for stabilizing problematic and expansive soil [70][71][72] .

Conclusions
Various laboratory tests were performed to examine the effect of using CSA and lime on SFSS at various percentages and curing periods.The examination involved investigating the strength, plasticity, shrink-swell behaviours, compaction characteristics, and mineralogical and microstructural characteristics of kaolinite clay soil stabilized at OSFC and altered using CSA, an agricultural waste collected from the food service industry and lime.Therefore, the conclusions can be drawn as follows: (a) Adding clamshell ash (CSA) and lime reduces the plasticity of the stabilized soil with increasing dosages.However, CSA and lime modification significantly impacted the shrink-swell behaviour of the silica fume stabilized soil (SFSS).The results regarding plasticity and shrink-swell behaviour indicate that when suf- www.nature.com/scientificreports/ficient silica fume (SF) content is present, CSA and lime modification significantly alter the behaviour of the stabilized soil.(b) Alteration of OSFC-stabilized soil using CSA and lime emerged in the improvement of the strength of the modified soil.Curing periods significantly affect the strength of the SFSS altered with CSA and lime.The maximum strength benefit is accomplished at 30 days of curing with an enormous increase of 114.41% and 76.48% in instantaneous strength, 450.61% and 177.71% in premature strength, 973.36% and 224.42% in matured strength, and 1123.25% and 352.82% in retarded strength.Hence, CSA and lime alterations can substantially improve the strength of OSFC-stabilized soil, and the maximum enhancement is seen in retarded strengths.(c) The CIU test conducted on SFSS and SFSS altered with CSA and L shows noticeable cohesion and internal friction angle value alterations.The utilization of CSA and lime at 3%, 6%, and 9% cured at 1, 7, 14 and 30 days shows a significant increase in cohesion value and internal friction angle, with the maximum value recorded when 9% of CSA and lime were utilized and cured at 30 days of curing.(d) The X-ray diffraction (XRD) analysis reveals a notable prevalence of matrix disturbance, accompanied by the formation of cementitious compounds such as calcium silicate hydrate (CSH), calcium aluminate hydrate (CAH), and ettringite.This signifies a progressive improvement in strength over time.The enhanced strength is attributed to developing a coating around the soil particles, in addition to flocculation.Field emission scanning electron microscope (FESEM) images of the silica fume stabilized soil (SFSS) altered with clamshell ash (CSA) and lime depict the evolution of a dense matrix with cementitious compounds formed within the soil matrix.(e) The SFSS altered with 3%-9% CSA as the environment-friendly and cost-effective method can reduce 10%-40% of the total cost of stabilization while utilizing 3%-9% of lime resulted in an increment of the total cost of stabilization around 3%-5% compared to stabilizing the soil with cement.(f) Consequently, the study concludes that the incorporation of clamshell ash (CSA) and lime significantly influenced the engineering properties and enhanced the strength of the silica fume stabilized soil (SFSS).
The high content of calcium oxide, silicon dioxide, and aluminium oxide in the SFSS modified with CSA and lime contributed to the most substantial alterations and the maximum improvement in engineering properties and shear strength of the SFSS.(g) The improvement in strength and densification of stabilized soil matrix through the formation of cementitious phases and pozzolanic responses involves several key mechanisms.When lime and clamshell ash are admixed with the soil with a presence of water, a reaction occurred to form calcium silicate hydrates (CSH) and calcium aluminate silicate hydrate (CASH).These compounds act as binders, creating bridges between soil molecules and encouraging cohesion within the soil matrix.Additionally, pozzolanic reactions occur between the silica fume and lime, further enhancing the generation of CSH and filling voids within the soil structure.This process increases the interlocking of soil particles, reducing void spaces and enhancing the overall compactness and strength of the soil.Moreover, the pozzolanic responses contribute to the long-term durability of the stabilized soil by reducing hydraulic conductivity and increasing resistance to chemical attack and environmental degradation.Overall, the effects of cementitious phase formation and pozzolanic responses lead to substantial improvements in the mechanical properties and stability of the stabilized soil matrix, making it more suitable for various engineering applications.(h) This research has important applicability in real-world engineering projects and can help with numerous elements of infrastructure development and environmental sustainability.Optimized combinations of silica fume, clamshell ash, and lime can be utilized to increase the strength and durability of road pavements, particularly in locations with expanding clay soils.Engineers can apply the findings to road construction projects by using stabilized soil mixes as sub-base or base materials, lowering pavement failure rates and maintenance costs.

Figure 5 .
Figure 5.Effect of CSA and lime on the shrink-swell characteristics of 6% SFSS.

Figure 9 .
Figure 9. XRD pattern of SFSS with CSA and lime inclusion.

Table 1 .
Geotechnical characteristics of kaolinite clay.

Table 2 .
Compositions of untreated soil and soil stabilizers.
Vol:.(1234567890) Scientific Reports | (2024) 14:10995 | https://doi.org/10.1038/s41598-024-61854-1www.nature.com/scientificreports/Swelling potential test A free swell test was performed per ASTM D 4546 to determine the increase in soil volume without applying external pressure by submerging it in water.The test was carried out by passing a 10-g typical oven-dry sample through a 425-micron sieve.

Table 5 .
Sample coding coherent to the test standard utilized in the study.

and field emission scanning electron micros- copy (FESEM) test XRF
analysis was conducted utilizing Bruker S8 Tiger X-ray Fluorescence (XRF) analyzer and fully followed the ASTM E1621-13.The Bruker D8 Advance Diffractometer performed the XRD analysis of SFSS and SFSS, which was altered with CSA and lime at position 2-theta (2θ) with compliance to ASTM C1365-18.The FESEM analysis was done on SFSS, and SFSS was altered with CSA and lime in a FESEM model ZEISSEVO 50.

Table 6 .
UCS of 6% SFSS modified with CSA and lime at various curing days.

Table 7 .
The unit price of materials and operations for soil stabilization.*The rate was referred to Selangor State rate = RM2.86 / m 3 .

Table 8 .
Quantity of soil stabilizers needed to stabilize the assumed quantity of soil.Cm, Cement; C, Kaolinite Clay; S, Silica Fume; Cs, Clamshell Ash; L, Lime; Quantity of Soil based on 10 m 3 Volume = 10 000 kg.

Table 9 .
Cost analysis of projected soil to be stabilized using conventional soil stabilizers and proposed soil stabilizers.