Utilization of discarded face masks in combination with recycled concrete aggregate and silica fume for sustainable civil construction projects

The coronavirus (COVID-19) pandemic has not only had a severe impact on global health but also poses a threat to the environment. This research aims to explore an innovative approach to address the issue of increased waste generated by the pandemic. Specifically, the study investigates the utilization of discarded face masks in combination with recycled concrete aggregate (RCA) and Silica Fume (SFM) in civil construction projects. The disposable face masks were processed by removing the ear loops and nose strips, and then cutting them into small fibers measuring 20 mm in length, 5 mm in width, and 0.46 mm in thickness, resulting in an aspect ratio of 24. Various proportions of SFM and RCA were incorporated into the concrete mix, with a focus on evaluating the compressive strength, split tensile strength, and durability of the resulting material. The findings indicate that the addition of SFM led to improvements in both compressive and split tensile strength, while no significant impact on durability was observed.

The coronavirus (COVID-19) pandemic has not only had a severe impact on global health but also poses a threat to the environment.This research aims to explore an innovative approach to address the issue of increased waste generated by the pandemic.Specifically, the study investigates the utilization of discarded face masks in combination with recycled concrete aggregate (RCA) and Silica Fume (SFM) in civil construction projects.The disposable face masks were processed by removing the ear loops and nose strips, and then cutting them into small fibers measuring 20 mm in length, 5 mm in width, and 0.46 mm in thickness, resulting in an aspect ratio of 24.Various proportions of SFM and RCA were incorporated into the concrete mix, with a focus on evaluating the compressive strength, split tensile strength, and durability of the resulting material.The findings indicate that the addition of SFM led to improvements in both compressive and split tensile strength, while no significant impact on durability was observed.
The Coronavirus (COVID-19) pandemic has caused an enormous increase in the use of personal protective equipment (PPE) which includes facemasks and plastic gloves 1 .It was mandatory to wear a facemask in public in many countries.Facemask usage by the general population contributed to reducing the spreading of the disease but on another hand, it is causing an increase in pollution.The presence of these PPE i.e. facemasks in large amounts has been confirmed by the divers in the bed of the rivers and oceans [2][3][4] .An estimated amount of daily facemask use in Africa is 7 hundred million, while in Asia the daily facemask usage number shows 2.2 billion [5][6][7] .In June 2020 the monthly number of facemasks discharged to the environment was estimated to be 129 billion 8 .A total of 6.88 billion facemasks weighing approximately 206,407 tons are globally generated and then dumped into landfills daily 5 .Due to an increase in littering, these used facemasks can be found practically anywhere, including on streets, in parking lots, and in neighborhood parks.The light weight of the facemasks makes it possible for wind and rain to successfully transport them from the landfills or garbage bins into the city streets, rivers, and seas, where the plastic-based masks can break down into microplastics.The primary plastic material used in single-use surgical masks, polypropylene, is a thermoplastic polymer that takes more than 25 years to degrade in landfills 9 .However, when single-use surgical masks are flown into the water streams, they break down into microplastics that could reach our food supply [10][11][12] .As a result, the pandemic's impacts are not only having a significant negative impact on our economy but will also last long after the pandemic has passed.The non-biodegradable nature of the material of the facemask causes it to take more than 450 years to break down into the environment 13 .Since plastic fibers have several sustainability advantages over steel reinforcement, they have long drawn interest from the academic community and the building sector 14 .Due to its mechanical characteristics, such as tensile strength and Young's modulus, as well as its ease of manufacturing and high alkaline resistance, polypropylene fibers (PP) are widely employed across the concrete industry 15,16 .Previously Islam and Gupta (2016) analyzed polypropylene fiber-reinforced concrete in an experiment by adding these fibers between 0 and 0.3% (by volume of concrete) of polypropylene in the concrete mix.It was observed that the addition of polypropylene fibers by volume is causing a bit of drop in compressive strength throughout the testing period.Although the compressive strength decreased, the splitting tensile strength significantly increased when polypropylene fibers were added, increasing by 39% with the addition of 0.1% fibers by volume 17 .
One of the key ingredients in concrete is aggregates, both coarse and fine which play a significant influence in determining the overall technical qualities of concrete.The massive depletion of non-renewable natural resources had negative economic and environmental effects as a result of the heavy use of natural resources brought on by the constant high demand for new infrastructure and buildings 18 .The demolition and construction debris is made up of a diverse range of resources, including recovered aggregate, reclaimed asphalt, crushed brick, crushed glass, and crushed rock [19][20][21] .The construction and demolition waste constitutes about 45% of globally generated waste 13 .A literature review made by Tam found out By comparing data from 24 significantly developed nations across five continents, the authors were able to demonstrate how eager these nations are to encourage and promote the use of various recycled aggregates 22 .These nations have done this by passing new laws and raising awareness in the media about the need to reduce landfills and the extraction and consumption of natural mineral resources 22 .Recycling concrete debris is becoming increasingly important and is one of the most promising solutions to both shortages of natural resources and recycling of solid waste product materials because concrete is the second most abundant material on Earth, the first most used in construction and infrastructure, and the primary customer of non-renewable materials 23 .Crushing these concrete chunks into small pieces results in Recycled concrete aggregate (RCA) which can be used for different application like Buildings, pavements and for other constructions.RCA of 20 mm nominal size is used generally in pavement applications [24][25][26] .
Ordinary Portland cement is widely used in the construction sector and is one of the main sources of CO 2 emissions, which harms the environment 11 .The emission of CO 2 from the usage of ordinary Portland cement (OPC) caused pollution to the environment and affects the health of all living beings 18 .The construction industry will soon take action on the problem of decreasing its carbon output, which now ranges from 25 to 40% of emissions and of which just the production of cement accounts for 7-8% 27 .By using green building materials during construction and renewable energy during building operations, attempts are being made to have the whole construction sector reach net-zero carbon emissions by the year 2050 27 .To replace ordinary Portland cement in concrete, alternative materials have been introduced to lower the consumption of OPC in concrete.
Silica Fume is a by-product produced from the manufacture of silicon metal or Ferrosilicon Alloys, which is widely available in the world.Additionally, the use of Silica Fume is more environmentally friendly and save cost compared to OPC 28 .Initially, the silica fume remains inert when added to concrete [29][30][31] .After the start of the reaction between water and Portland cement, hydration starts, and two chemical compounds are formed as a result of this primary reaction: calcium silicate hydrate (CSH) the strength producing crystallization, and a by-product calcium hydroxide (CH), this is also known as free lime whose basic purpose is only as filler for lining the available pores within concrete.Calcium hydroxide reacts with the silica fume resulting in a Pozzolanic reaction leading to the production of additional CSH in many of the voids around hydrated cement particles.This results in increased compressive strength, flexural strength 28 , and bonding strength 32 along with the formation of a denser matrix preferably in those areas which would have remained as small voids subject to possible ingress of deleterious materials.Silica fume increasing percentage reduces the porosity which increases the compressive strength 33 .
The previous studies on these wastes (SFM, RCA) show a decrease in the mechanical properties of concrete.However, this research carried out a series of experiments to reduce environmental waste and to evaluate different percentages of SFM and RCA for improving the mechanical properties of concrete by introducing silica fume as an additional binder into different mixes.Based on literature review and previous studies, none of the existing studies assessed these wastes in concrete with the use of Silica fume in different mixes according to the author's knowledge.To fill this research gap silica fume is introduced to increase the compressive strength as well as the density of concrete.Several tests have been carried out to check the compressive strength, tensile strength of the concrete under various mix designs.Moreover, concrete having optimum percentages of SFM and RCA, durability of the concrete have been tested as it is also been revealed by the previous studies that to improve durability of concrete use fibers 34,35 .

Material and methods
The basic material that is taken under consideration to investigate is concrete consisting of SFM fibers (Polypropylene).In this research new Single use facemasks were used due to COVID-19 precautions.In this section firstly different properties of the materials (SFM, RCA, Silica Fume, and Concrete) are presented, in the second part of the section, a description and composition for the concrete experimental research are given.To verify properties, 3 samples of each result are tested during research and all the numeral findings shows the average result of those 3 samples.

Shredded face mask (SFM)
To carry out this research, new disposable surgical face masks were employed, featuring polypropylene fibers arranged in a random orientation and subsequently compressed and were fused into a pattern of small, closely spaced welds.Before using a single-use face mask in concrete, preparation of the masks is a must.Initially, the ear straps and all other metal parts were removed manually.Then the masks were cut down into smaller sizes manually.The fibers can be used in two forms i.e., short fibers and long fibers.In this research short fibers were used due to their easiness in handling and dispersion having length, width, and thickness of 20 mm, 5 mm, and 0.46 mm respectively.The aspect ratio is the length-to-diameter ratio of fiber, for short fibers, the aspect ratio ranges from 20 to 60, while for long fibers it is more than 200.According to Naaman (2003), the aspect ratio of a fiber with a non-circular cross-section can be calculated as: where l is the length, d FIER is the equivalent diameter, A is the cross-sectional area, and Ψ is the perimeter of the fiber cross-section.The aspect ratio was approximately 24 36 .
The Density of a single-use Facemask was found by taking a cylinder filled with water up to 600 ml and then a 30gm (0.030 kg) of facemask sample was immersed in the cylinder for 24 h, after 24 h all the air voids were removed from the cylinder and the water level reached to 680 ml.The volume change was recorded to be 80 ml (0.00008 m 3 ), from the formula of mass per unit volume, the Density was achieved as shown in Table 1.The procedure for calculating density is explained in Figs. 1 and 2.

Recycled concrete aggregates (RCA)
This research work was carried out by using materials that include water, cement, and aggregates.RCA was brought from the demolished road shoulders for sewage work in Abbottabad and was reduced to a nominal size of 19 mm by crushing the old concrete junks manually.The strength of the old concrete junks was in the range of 20-25 MPa.It is known that normal concrete is composed of 75% of coarse aggregates for which some mechanical and physical properties are required to be determined.These properties of natural and recycled concrete aggregates were determined according to the relevant ASTM standards shown in Table 2

Silica fume
Taking into consideration the effects of silica fume in enhancing the properties of concrete, along with protecting the environment by using this by-product in the construction industry rather than its disposal to the environment, an addition of 10% by weight of ordinary Portland cement in the mix was used which was taken from factory "Construction Chemicals & Services" located in Rawalpindi, Pakistan.A large proportion of the silica fume particles (95%) are finer than 1 µm.This nature and particle size of silica fume allows the concrete mix to become denser by filling the voids that are caused by using the SFM fibers.The reduction in porosity is more when silica fume was added up to a 10% level.Above 10%, the reduction in porosity is negligible.

Concrete
Generally, concrete is composed of 75% coarse aggregates whose properties are defined in Table 3.The rest 25% includes water, cement, and fine aggregates.Water from COMSATS University Abbottabad was used for concrete production and curing.Ordinary Portland cement was used whose physical and chemical properties are given in Table 4 and the specific gravity was 3.15.Natural aggregates were brought from Thandiani near Abbottabad.The properties of aggregate are presented in Table 3.With a target compressive strength of 25 MPa, recommended slump value of 20-30 mm, and maximum aggregate size of 19 mm having a W/C ratio of 0.62, the control concrete mix design based on the ACI method was formed.Samples were formed in which the natural aggregates were replaced by 15%, 25%, and 50% RCAs.RCAs absorb more water than natural aggregates.Due to higher water absorption of the RCA, an excessive amount of water in the mixture was taken into account.Additionally, Silica fume was used 10% by weight of cement and SFMs as 1%, 2%, and 3% by volume of concrete.All the trail mixes and control sample mix design is given in Table 5.

Compressive strength test
The compressive strength tests were performed on cylindrical shape samples of dimensions (diameter and height) 150 mm and 300 mm according to ASTM-C39.The samples were tested on different curing Days i.e. 7, 14, and 28 days.The samples were subjected to loading until it breaks and the corresponding strengths were noted down as shown in Fig. 3.

Splitting tensile strength
Acquiring the results from the compressive strength test, the specimens with the highest compressive strength were subjected to diametral loading to get the splitting tensile strength for 28 days according to ASTM C496.The specimen of cylindrical shapes having standard dimensions i.e. 150 mm in diameter and 300 mm in height, were subjected to loading along the diameter of the specimen until it's splitting apart under a loading rate of 1.2-2.4MPa/min as shown in Fig. 4.

Durability
For durability of concrete, the samples were investigated according to ASTM-D3744 in aggressive Sulfuric Acid attack.Sulfuric Acid solution with a concentration of 5% was used for determining the resistance of samples for a total exposure period of 24 h.The loss in strength was investigated and visual assessment was also evaluated of the degraded samples as shown in Fig. 5.

Compressive strength
It is concluded from Fig. 6 and Table 6 that the compressive strength increases as the percentage of SFM increases from 0 to 1% and gives maximum strength by using 1% SFM which can be attributed to the crack-resistant properties or bridging effect of the fibers present in the Facemask 37 .Further increasing the SFM percentage causes a decrease in the strength due to the increasing pores.This variability in the strengths can be shown in percentage as loss or gain in the table below which shows that the strength increases by 9.97% when using the facemask fibers at 1% and 10% silica fume by weight of cement.The increasing facemask percentages to 2% and 3% increases the voids and porosity of concrete making it less dense, hence a decrease in the compressive strength occurred.
The attained compressive strengths of different percentages of SFM showed that the optimum percentage of SFM is 1% that gave us maximum compressive strength, In further trials, 1% SFM and different percentages of RCA along with 10% additional Silica Fume by weight of cement were used.It is concluded from Fig. 7 in which the error bars has also been incorporated based on the standard deviation and Table 7 that 1% SFM and 0% RCA have given maximum compressive strength of 25.8 MPa.Increasing RCA percentages from 0 to 50% leads to a decrease in strength which can be attributed to the weak and porous nature of RCA as compared to natural aggregate, but all these strengths lie within the allowable limits for Rigid Pavement i.e. minimum 20 MPa.So, to move to the economical side, a high percentage of RCA ≤ 50% can be used.

Splitting tensile strength
The specimen with the highest compressive strength in Table 7 was subjected to loading and compared with the control specimen.From Fig. 8 it can be concluded that split tensile strength increased effectively as compared to that of the normal sample having no SFM fibers, this increase in strength was attributed to the reinforcing, crack resistance, and bridging effect caused by SFM fibers 37,38 .This improvement of tensile strength is also due to more

Durability test
Concrete samples were examined under a harsh sulfuric acid attack to determine their durability.Test samples having RCA at 0%, 15%, 25%, and 50% were compared to control samples, which had SFM at the optimal amount.For a total exposure time of 24 h, samples were exposed to a 5% sulfuric acid solution to test their resistance.Investigation of the strength loss and evaluation of the degraded samples based on visual inspection was also conducted.The results of the durability test were reported in Fig. 9 and Table 8.It was found that no particular strength loss occurred.The maximum strength loss was 0.7 MPa out of 25.8 MPa which is not a major issue.
During the visual inspection, the concrete color slightly changed from normal color to light color as shown in Figure as the research carried out by Anish Banerjee also indicates that concrete color deteriorates in acidic environment 39 .

Comparison with previous studies
In comparison to regular concrete, fiber concrete has advantages in terms of improving its compressive strength, split tensile strength, and ductility.According to previous research carried out by Cory High, the use of combined chopped basalt fiber and basalt fiber reinforced bars as additives caused a maximum increase in compressive strength of concrete at the age of 28 days up to 6% 40 .Another research on the basalt fiber was carried out by Biradar in which the maximum increase in the compressive strength at the age of 28 days was recorded up to 9% by using 0.3% fibers by volume of concrete 41 .Moreover, research by Sivakumar concluded that after using fibers of 0.6 kg/m 3 , the compressive strength for 28 days of Glass fiber reinforced concrete (GFRC), polyester, and nylon improved by 3%, 1.8%, and 6.3% respectively 28 .The research carried out by Pelisser determined that by using polyethylene terephthalate (PET) fibers by volume of concrete the maximum increase in compressive strength is recorded up to 1% at the age of 28 days 43 .All of the improvements in strength by using the above-mentioned fibers are less than the increase caused in compressive strength percentage by using 1% SFM fiber by volume of concrete.Due to this enhancement in mechanical properties, ease in availability, environment friendly (trash usage) Fig. 10, and cost-effectiveness of SFM fibers makes it is more suitable to be used in concrete and Rigid Pavement.The results of the previous works have been reported in Fig. 11.
In comparison to control sample, the split tensile strength increased as shown in Fig. 8 and this increase in strength was attributed to the reinforcing, crack resistance, and bridging effect caused by SFM fibers 44 .This increase in split tensile strength due to SFM fibers has also been observed by Shannon Kilmartin-Lynch 8 .
In comparison of the control sample of durability test, it was found out that specimen lost 0.7 MPa strength out of 25.8 Mpa.The total strength loss was recorded 2.71% when the specimens were exposed to 5% sulphuric acid solution.The research of Arash Arjomandi also indicates that with the rise in the time of exposure to acidic environment, the concrete strength declines as he also used 5% sulphuric acid solution to find durability of concrete having steel fibers and nylon granules 45 .

Conclusion
• From this study, it can be concluded that to control COVID-19 waste and due to non-biodegradable nature of the material of the SFM, it has been added to concrete in different percentages.• Among all the SFM percentages (0-3%), 1% SFM gives maximum compressive strength.However, a further increase in SFM percentage decrease the compressive strength.• To decrease construction demolition waste, Recycled Concrete Aggregates (RCA) is introduced to the mix in different percentages and Silica fume is used 10% by weight of cement in addition to counter the decrease in strength caused by RCA in concrete.• By introducing RCA (15%, 25%, and 50%) to the mix, the compressive strength decreased with the increasing percentages of RCA, but all these strengths lie within the limits of the required strength of rigid pavements i.e. 20Mpa.• Among all these samples having different percentages of SFM and RCA, samples having 1% SFM and 15% RCA gave the highest compressive strength.• SFM fibers increased the split tensile strength as compared to the sample having no SFM fibers, further increase of SFM fibers in the mix can increase split tensile strength but can cause a decrease in compressive strength.• Samples having 1% SFM and 15%, 25%, and 50% RCA were found durable as no significant decrease in strengths was observed when compared to the control sample.

Figure 9 .
Figure 9. Durability of various specimens containing various RCA percentages.

Figure 10 .Figure 11 .
Figure 10.Change of color of the specimens.

Table 2 .
Physical and mechanical properties of aggregates.

Table 3 .
Physical and mechanical properties of aggregates.

Table 4 .
Chemical compositions of the cement (%), and mechanical and physical properties.

) RCA% (%) Compressive strength (Mpa) 7 days 14 days 28 days
flexibility of SFM fibers as compared to RCA particles as these fibers are classified as short and discontinuous fibers which could provide good results in terms of strength and stiffness.