Experimental investigation on the physical, microstructural, and mechanical properties of hemp limecrete

This paper investigates the hemp limecrete mechanical and microstructural performance of a new sustainable and environmental friendly building material. Several studies have investigated the hemp limecrete focusing on the non-structural applications. The newly developed hemp limecrete consists of high mechanical and microstructural properties. The specimens were prepared with varying lengths and proportions of hemp fibers with lime and tested for compressive strength, flexural strength, thermal conductivity and microstructural analysis like SEM and EDS. The study found that the optimal fiber content for making mortars was between 2 and 4%. This conclusion was reached after analyzing the influence of fiber length and ratio on the properties of the mortars. The dry unit weight decreased when the fiber content was higher than 4%. In terms of strength, the study found that the flexural strength of the hemp limecrete improved with an increase in fiber ratio, but the compressive strength decreased. However, with 2% hemp fiber, compressive strengths of 3.48 MPa and above were obtained. The study also highlighted the good thermal insulation properties and dimensional stability of hemp limecrete. These findings have important implications for the use of hemp limecrete as a sustainable building material. The results suggest that hemp limecrete has the potential to be a viable alternative to conventional concrete in specific applications, particularly in areas where environmental sustainability is a priority.

were positive.The study also emphasizes the influence of hemp shiv degradability on emissions, highlighting the material's environmental sensitivity.Moletti et al. 28 study examines the hygrothermal properties of hemp-lime, a sustainable building material made from lime-based binders and hemp shives.By conducting experiments over three years and using numerical simulations, the research demonstrates that the material's performance improves with maturation, primarily attributed to binder carbonation and reduced initial moisture content, as confirmed by XRD and TG-DTG analyses.Rotem et al. 29 study evaluates the environmental impact of lime hemp concrete (LHC) with unfired binders as a lime replacement compared to standard LHC and conventional building materials.In an arid region, it reveals that LHC with unfired binders can reduce energy consumption and CO 2 emissions by up to 90%, making it a highly sustainable construction option.
Several studies have been published on how hemp shive affects material qualities, was previously stated.Although this information is useful, it is incomplete since the studies cited above focus on a subset of the features of composites and a subset of the proportions of fiber based on cement.The impact of shive size on the composite's other characteristics, like porosity, density, microstructural analysis and thermal heat conductivity, has to be investigated further for lime hemp limecrete.In the present investigation, we examined these consequences for hemp limecrete.Basic features of the hemp limecrete were also examined, including compressive strength, flexural, thermal conductivity and water absorption to see how much impact fiber had on these characteristics of the hemp specimens.
This study introduces groundbreaking innovations in construction materials and sustainable building.It introduces hemp limecrete as an eco-friendly construction material, offering a sustainable alternative to traditional concrete.The study precisely identifies the optimal combination of fiber content (4%) and length (1 cm) for hemp limecrete, providing essential guidelines for effective usage.The manuscript employs a holistic approach by analyzing mechanical properties, thermal conductivity, and microstructure through SEM and EDS.Emphasizing sustainability, it highlights hemp limecrete as a promising eco-friendly material, aligning with global trends in sustainable construction.These innovations collectively position hemp limecrete as a revolutionary, environmentally conscious choice for the construction industry.

Research objective
The research objective of hemp limecrete is to investigate and optimize the mechanical, and physical properties of the material, as well as its potential for use as a sustainable and eco-friendly construction material.This may include studying factors such as the optimal ratio of hemp to lime, the effect of different additives or binders.Ultimately, the goal is to develop a durable and cost-effective alternative to traditional building materials that has a lower environmental impact.Previous researches have been done on Hemp cement mortar, the novelty of the research lies with the utilization of lime and hemp alone in the preparation of mortar with hemp.The findings provide important information for architects, engineers, and builders on the mechanical properties of hemp limecrete, and the optimal fiber content and length required for desirable results.With further research and development, hemp limecrete could play an increasingly significant role in the construction industry as a sustainable and environmentally friendly alternative to conventional building materials.

Materials and methods
The hemp came from the company Diamond Hemp Santiago, Chile.It was planted on April 12, 2021, and after drying out was harvested on May 3, 2022.All of the hemp plants were collected, packed, and stashed and the hemp hay were run through a mechanical shredder, and the resulting fiber, fibres, and dust were all utilized in this study.Hemp consisted of 67% fiber, 32% fibres and 3% dust (0.5 mm) by weight.Hemp Fiber used in this study is shown at Fig. 1 and Tables 1, 2 provides the physical and chemical properties of hemp fiber.Three samples of hemp were weighed and dried in a cabinet at 103 °C.for 24 h to assess the moisture content of the material.The hemp samples' moisture content on average is 13.3% after drying.
Hydraulic lime is used in this investigation, the chemical composition of lime from XRD analysis is shown in Table 3.The mixes were prepared using water-to-lime ratios of 0.35.We've tailored the quantity of hemp strands to the quantity of lime.There are 2%, 4%, and 6% of fibres by weight of the lime.Mixture ratios and approximate amounts are shown in Table 4.The mixture contains fibres of varying lengths and proportions.CS is the control Specimen and the mix properties were denoted as 2P0.5L,where P denotes the percentage of fibre and L denoted the length of fibre.There are ten distinct combinations here, nine of which include fibre and one of which is a control specimen.For the production of the cube specimens, we utilized industry-standard steel moulds with dimensions of the cylinder samples, 300 mm long, and breadth 150 mm.It was found that surrounding the mould using plastic sheet foil made it much simpler to remove the specimen once it had been prepared (O'Dowd & Quinn, 2005) 2 .The hemp was combined with 150 ml of water in a mixer for 5 min.At the same time, lime is combined together with water in a different container to produce a binder mixture.Hemp was then mixed with the binder mixture in the mixer for another five minutes.Any obvious lumps were manually broken apart.The mixture was poured into the moulds and compacted with a 45 mm wooden stave.Then a second layer was laid down and tamped, followed by a third.The mixture has been poured into the mould.The process for filling cylinders was quite similar.Tamping was followed by 1 min of vibration (at 50 Hz) in the moulds.After 24 h of curing in an indoor atmosphere of about 20 °C, the specimens were taken out of the moulds.After curing the specimens were subjected to mechanical strength tests.As a preliminary test, the mortar flow diameters were measured as per the ASTM C 1437 standard 30 .Vibrating mortars have been used to fill the moulds in two levels.The ASTM C 349 31 and ASTM C 348 32 standards have been followed to determine the compressive and flexural strengths after 7 and 28 days.Flexural strength test performed on 40 × 40 × 160 mm prism samples.After curing for 28 days, the samples were dried at 50 °C for 3 days, and the capillarity test was conducted.The quantity of water absorbed by capillary action was measured at 1, 5, 10, 20, 30, 60, 120, 180, 240, 300, 360, and 1440 min

Dry bulk density (BD) of hemp limecrete
The Bulk density and porosity of hemp limecrete results were illustrated in Fig. 2. Bulk density values for fibrous mixtures can range anywhere from 1273 to 1407 kg/m 3 , on average.The Bulk density value of the fiber-free control mix is found to be 1323 kg/m 3 .The Bulk density of the mixes in which just 6% fibre included was found to be lower than that of the control mix, this is due to workability loss.When using 2 and 4% fibre, BD values are greater than the control specimen.Mortars' BD values increased with a rise in fibre ratio, as shown by a comparison of fibre ratios between 2 and 4%.The observed effects can be attributed to the fixed proportion of the mixing ratios, which are not volume-based.There has been a rise in the Bulk density values due to increase in the quantity of fibre.The addition of 6% fiber content made it challenging to place the mortars in the mold, which resulted in a hollow structure.Mortars with fiber lengths of 1 or 2 cm generally showed a decrease in bulk density values.On the other hand, using 4% fiber content and 2 cm long fibers led to BD values exceeding 1407 kg/ m 3 .Mixtures containing 6% fiber showed Bulk density values below 1296 kg/m 3 .The decrease in processability caused by an increase in fiber length resulted in non-uniform distribution, which led to a general decrease in Bulk density values.Based on Fig. 3, it was observed that the porosity values of the fiber-based mixtures had a range of 7.21-10.35%.As the fiber ratio in the mixtures increased, the corresponding apparent porosity values also increased.Additionally, increasing the length of the fiber used further increased the apparent porosity values of the mixtures.Mixture compositions with 2% fiber content had porosity values that were closest to the control specimen porosity value of 7.72%.Interestingly, even the use of shorter fiber lengths, such as 0.5 cm and 1 cm, resulted in porosity values lower than the reference mixture's porosity value.Mixture compositions that utilized 0.5 cm long fibers exhibited greater homogeneity compared to other mixtures, as evidenced by the spread diameter of 14.4 cm.This increased homogeneity led to a reduction in porosity values.Some studies have suggested that short fibers act as micro aggregates and reduce porosity.The addition of 4% and 6% fiber  www.nature.com/scientificreports/results in porosity values is above 8%.The lowest BD value is achieved with a combination of 6% fiber and 2 cm fiber length, although the resulting porosity value is greater than 10%.Olivito and Zuccarello found in their study that increasing the length of steel fibers results in a minor decrease in unit volume weight values.The unit weight of mixtures was observed to increase as the steel fiber ratio increased, according to a study by Olivito and Zuccarello 33 .On the other hand, Asasutjarit et al. found in their study that an increase in fiber length led to a decrease in the density of composites and an increase in water absorption values 34 .

Mechanical properties of mortars
Flexural strength and compressive strength outcomes of the hemp limecretes are shown in Figs. 4 and 5 for the 7 and 28-day.The flexure strength of the fiber-free mixture is 6.48 MPa.However, the 7 and 28-day flexural strength of the mortars do not show parallelism.The use of 6% 0.5 and 1 cm long fibers resulted in lower flexural strength than the reference mixture.Loss of workability have caused the reduction in flexural strength when using 0.5 and 1 cm fibers at 6% concentration.On the other hand, the use of 2 cm fibers increased the flexural strength, and generally, longer fibers resulted in higher flexural strength.The highest flexural strength was achieved with 2% fibers of 1 cm length, showing a 14.7% increase in strength compared to the control mix.However, increasing the fiber ratio caused a decrease in flexural strength.The flexural strength testing of the mortars are presented in Figs. 6 and 7.It is observed that the flexural strength of the mortars has significantly improved due to the increase in curing time.Unlike the 7-day strength results, an increase in the fiber ratio has led to an improvement in the 28-day flexural strength.However, the use of 6% fiber has still resulted in flexural strength values lower than 6.50 MPa.The 28-day flexural strength of all mixtures is higher than the reference mixture, with the highest strength achieved by the mixture containing 2 cm long fibers and 6% fiber content.The  www.nature.com/scientificreports/7-day strength of this mixture was 6.58 MPa, which increased by 23.6% on the 28th day.The flexural strength generally increased with an increase in fiber length and ratio up to 4%, but reductions were observed at 6% fiber content.The optimal fiber length was found to be 1 cm with a 4% fiber ratio.The flexural strength of the fiber-matrix interface improved due to the increased curing time, particularly for natural fibers such as hemp, which may require longer curing periods.SEM analysis can help further explore these findings.Jonathan et al. observed an increase in flexure strength with an increase in hemp fiber ratio, while an increase in fiber length led to a decrease in flexure strength 35 .
The compressive strengths of the mixtures decreased with increasing fiber content, except for the mixture containing 2% 0.5 cm long fibers, which showed a 4% increase in compressive strength compared to the control specimen.It has also been noted that consistency of the mixture affects fiber orientation and ultimately, flexure strength 36 .The compressive strength of the mortars generally increases with the fiber length of 1 cm.Mixtures produced from 0.5 and 2 cm long fibers have similar properties.However, the compressive strength remains below the reference mixture when the fiber content is 6%. Figure 5 illustrates that the compressive strength increases with the increase in curing time.All blends produced with 2% fiber showed higher compressive strength than the reference blend.Nevertheless, the compressive strength of the mortars decreases as the fiber ratio increases.The compressive strength of mixtures with 6% fiber content is generally below 3 MPa, although a fiber length of 1 cm typically increases compressive strength.Similar results were observed in a study 14,37 .The use of 4% fiber content has resulted in an increase in flexure strength, despite the high porosity values of the mixtures.Mixtures with 4% and 6% fiber content exhibited decreased compressive strength due to high porosity.However, the fibers acted as reinforcement, preventing crack propagation and leading to an increase in flexure strength.

Thermal conductivity on hemp mortar
In order to determine the thermal conductivity of hemp limecrete, the study conducted thermal conductivity tests on three specimens of dimensions 160 mm × 40 mm × 40 mm.The tests were performed according to international standard ISO 8302 38 utilizing the heat flow meter method with a plate apparatus as shown in Fig. 8.The testing specimens are dried to a consistent mass at 60 °C before the experiment.The test was carried out with a hot plate set at 25 °C, a cooling plate at 0 °C, and an average temperature of 12.5 °C was obtained.The accuracy of  the absolute thermal conductivity measurement of the plate apparatus was determined to be within 2%.During the test, the heat moved through the sample in a path that was orthogonal to the direction in which the sample was being compacted.These tests provide important data for assessing the thermal insulation properties of hemp limecrete, which is a critical factor for its application as a sustainable building material.
The thermal conductivity of hemp limecrete with varying percentages of hemp was measured.The data shows that the thermal conductivity increases as the percentage of hemp increases, with the highest value of 0.27 W/ mK obtained for the sample with 6% hemp.The sample with 4% hemp also showed a relatively high thermal conductivity of 0.23 W/mK.The samples with lower percentages of hemp, 2% and control specimen had lower thermal conductivity values of 0.19 W/mK and 0.17 W/mK, respectively.It is worth noting that the thermal conductivity values for the 2% and 6% hemp samples were quite similar, with only a small difference of 0.08 W/ mK between them.These results suggest that adding hemp to lime can increase its thermal conductivity, which may have implications for its use in building insulation.However, it is also clear that the percentage of hemp used can have a significant impact on the thermal conductivity of the resulting composite, with higher percentages leading to higher values.The outcomes are consistent with those reported in the published research.Pavia and Walker 39 also utilized the similar binder to fiber, but their composites have density ranges from 508 to 627 kg/ m 3 .The results are line with evidence in the existing literature 40 .Using the same binder-to-fibers ratio as in the previous case, Walker and Pavia 39 obtained composites with a higher density have a higher thermal conductivity ranging from 0.107 to 0.128 W/(m K)).In other studies 41 , composite fibers with an average length less than 4 mm had a higher thermal conductivity coefficient than those with an length greater than 4 mm, eventhough the difference was small as well as the thermal permittivity ebbed and flowed is around 0.12 W/(m K).In additional investigations 41 , the composite comprising fibers with an average length less than 2 mm had a greater thermal conductivity coefficient than those with an length of 2 mm average, the difference in thermal conductivity coefficients were similar and modest.

SEM analysis
In order to investigate the microstructural characteristics of the specimens, a study using a scanning electron microscope (SEM) was carried out on 2, 4, and 6% hemp mortar with fiber lengths of 0.5, 1.0, and 2.0 mm.The acquired SEM images of lime-based hemp mortar are shown in Figs. 9, 10 and 11.The control specimen which depicts an unreinforced mortar is shown in Fig. 9.It reveals that there are almost no fractures in the limecrete on control Specimen.However, the hemp fiber reinforced limecrete specimen reveals a number of microscopic fractures and cavities.The presence of random fibers in the matrix generates a binding effect, increased toughness, and reduced shrinkage in composite materials, as reported by researchers [42][43][44] .Therefore, the introduction of hemp fibers into the mortar can lead to an improvement in both the compressive and tensile strengths of the specimens.
In the case of the 2% hemp limecrete, scanning electron microscopy analysis revealed that the hemp fibers were well distributed throughout the matrix, and that the lime binder had penetrated the fibers, creating a strong bond between the two components.The lime was observed to be present as a fine, crystalline structure within the matrix, which also helped to create a strong and durable composite material.The hemp fibers themselves were observed to be relatively uniform in size and shape, with a fibrous texture that allowed them to interlock with one another, providing additional strength to the material.
The addition of 4% hemp to limecrete resulted in a slight increase in the thermal conductivity of the composite compared to the 2% hemp composite.This is likely due to the increased density of the 4% hemp composite, which can lead to better thermal conductivity.Scanning electron microscopy analysis showed that the 4% hemp lime composite had a more homogeneous structure than the 2% hemp composite, likely due to the improved packing of the hemp particles in the mixture.This homogeneity can further improve the overall properties of the composite material.Additionally, the results of the SEM analysis demonstrated that the hemp particles were well distributed within the composite, indicating good adhesion between the hemp and the lime binder.These findings suggest that the addition of 4% hemp can lead to improved thermal conductivity and overall structural properties of hemp limecrete.
In the case of the 6% hemp limecrete, the reduction in compressive strength may be attributed to the higher percentage of hemp.Although hemp fibers can improve the durability and ductility of the material, too high of a concentration can negatively impact the strength.This may be due to the fact that hemp fibers are less stiff and strong than the lime binder, leading to weaker bonding between the fibers and matrix.Additionally, the higher concentration of hemp may have caused a less uniform distribution of fibers throughout the mortar, leading to weaker regions with a lower concentration of fibers.Overall, it is important to find a balance between the benefits of adding hemp fibers and the potential reduction in strength that may occur with higher concentrations.
The SEM analysis of the hemp mortar specimens revealed that there were a significant number of microcracks and voids present in the matrix.These microcracks are often the result of defects in the production process or improper handling.However, these cracks are not visible to the human eye.The hemp fibers can also be seen quite clearly in the limecrete, as shown in Fig. 9.The increasing amount of fibers in the matrix can lead the fibers to knock and overlap each other, which ultimately results in a loss of cohesion with the matrix and a weakened  composite material, as reported by previous research 45,46 .This circumstance can lead to a decline in the strength of the hemp fiber specimens.

Energy dispersive spectrometer (EDS)
The energy dispersive spectrometer (EDS) analysis was conducted on three different hemp limecrete specimens containing 2%, 4%, and 6% hemp, respectively.The weight concentration of elements such as oxygen, calcium, silicon, and aluminum were found to be higher in all Hemp limecrete specimens as compared to traditional limecrete.The EDS analysis also identified the presence of calcium silicate hydrate with a Ca/Si ratio of 1.02 and 2.49 in the 4% and 6% hemp limecrete specimens, respectively.The elemental composition is provided in Table 5.
Figure 12 of EDS images shows the weight concentration of elements in the 2% hemp limecrete specimen.Oxygen (O) was the most abundant element, accounting for 51.35% of the total weight, followed by calcium (Ca) at 42.17%.Carbon (C) accounted for 5.13%, while silicon (Si) and aluminum (Al) made up only 0.31% and 0.58%, respectively.Potassium (K), magnesium (Mg), and sulfur (S) were present in trace amounts.
Figure 13 of EDS image shows the weight concentration of elements in the 4% hemp HLM specimen.Oxygen (O) was again the most abundant element, accounting for 55.7% of the total weight, followed by calcium (Ca) at 4.07%.Carbon (C) accounted for 38.5%, while silicon (Si) and aluminum (Al) made up only 0.82% and 0.34%, respectively.Magnesium (Mg), potassium (K), and sulfur (S) were present in trace amounts.
Figure 14. of EDS images shows the weight concentration of elements in the 6% hemp lime mortar specimen.Oxygen (O) was the most abundant element, accounting for 57.95% of the total weight, followed by calcium (Ca) at 7.52%.Carbon (C) accounted for 32.44%, while silicon (Si) and aluminum (Al) made up 1.03% and 0.36%, respectively.Magnesium (Mg), potassium (K), and sulfur (S) were again present in trace amounts.The high  presence of elements such as calcium, silicon, and aluminum, in addition to the organic content of the hemp fibers, contributes to the unique mechanical properties of hemp limecrete.The increase in hemp content in the HLM specimens was found to increase the weight concentration of C, Si, and Mg, while decreasing the weight concentration of Ca.
The SEM and EDS analyses of the 2, 4, and 6% hemp mortar specimens reveal the presence of microcracks and voids in the matrix.The introduction of hemp fibers into the mortar leads to an improvement in both the compressive and tensile strengths of the specimens.However, an increasing amount of fibers in the matrix can lead to a decline in the strength of the specimens.The chemical composition analysis of the hemp fiber-limecrete specimens reveals the high presence of elements such as C, Ca, Si, and Al, which improves the bond characteristics of the mortar.These findings can be useful in the development of hemp fiber mortar.

Conclusion
In conclusion, hemp limecrete has shown promising results in terms of its mechanical and physical properties.The use of hemp shivs as an aggregate in lime-based binder has led to a lightweight and breathable material.Additionally, hemp fibers can be added to the mixture to further enhance its mechanical properties, such as compressive and flexural strength.The optimal fiber length for hemp limecrete has been found to be 1 cm, with an optimum fiber ratio of 4%.

Figure 2 .
Figure 2. Results of bulk density and porosity of hemp limecrete.

Figure 3 .
Figure 3. Casting and curing of specimens.

Table 1 .
Physical properties of hemp.

Table 2 .
Chemical properties of hemp.

Table 3 .
Chemical composition of lime in percentage.

Table 4 .
Mix ratios and quantities of materials.

Table 5 .
Elemental concentration in spceimens of hemp lime fiber mortar.