Enhanced tribological properties of diesel-based engine oil through synergistic MoS2-graphene nanohybrid additive

This research explores the potential of microwave-synthesized MoS2-graphene nanohybrid as additives to enhance the tribological properties of diesel-based engine oil. The synthesis method offers significant advantages, reducing both synthesis time and energy consumption by 90–98% compared to conventional approaches. The synthesized nanohybrids are characterized through FESEM, EDX, XRD, and Raman spectroscopy to understand their morphology and functional group interactions. These nanohybrids are incorporated into 20W40 engine oil following synthesis, and a comprehensive assessment of their properties is conducted. This evaluation covers critical parameters like viscosity index, stability, volatility, as well as tribological properties, oxidation resistance, and thermal conductivity of the oil-nanohybrid system. Results demonstrate that adding just 0.05 wt% of MoS2-graphene nanohybrid leads to a remarkable 58.82% reduction in friction coefficient and a significant 36.26% decrease in the average wear scar diameter. Additionally, oxidation resistance improves by 19.21%, while thermal conductivity increases notably by 19.83% (at 100 °C). The study demonstrates the synergistic effects of these nanohybrids in reducing friction and wear, enhancing oxidation resistance, and improving thermal conductivity. In conclusion, this research highlights the potential of microwave-synthesized MoS2-graphene nanohybrid as promising tribological additives for diesel engine oils. Their successful integration could significantly enhance the performance and durability of critical mechanical components in diesel engines, representing a significant advancement in lubrication technology.

role in intercalation and lubrication properties.The MoS 2 is used extensively in solid lubrication, lubrication additives in oils, and self-lubricating polymer materials.Various forms of MoS 2 , such as flower-like microspheres and ultrathin nanosheets, have been synthesized and evaluated for their tribological properties.Tang et al. synthesized MoS 2 flower-like microspheres, which demonstrated superior anti-wear and friction-reducing properties when used as a lubrication additive compared to pure base oil 6 .Song et al. prepared ultrathin MoS 2 nanosheets as lubricating additives and found that their tribological and extreme pressure properties were significantly enhanced due to the good dispersion and ultrathin shape of the nanosheets 7 .MoS 2 's unique structural and mechanical properties enable it to reduce friction and wear and prevent deposition, making it an important additive in various industrial applications.Ongoing research is focused on developing innovative techniques to synthesize and utilize MoS 2 to enhance its tribological properties further and broaden its range of applications.For example, Song et al. synthesized MoS 2 /graphene oxide hybrid nanosheets and reported that they exhibited excellent tribological performance and could be potentially used as lubricant additives 8 .Moreover, Chen et al. synthesized a composite material of MoS 2 and boron nitride, which possessed superior tribological properties as a lubricating additive 9 .
Graphene, a two-dimensional material of carbon atoms arranged in a hexagonal lattice, possesses exceptional tribological properties that make it an attractive candidate for various industrial applications.Its high chemical inertness, extreme strength, and easy shear capability on its densely packed and atomically smooth surface are favourable attributes for its impressive friction and wear behavior.Numerous recent studies have explored graphene's potential as a solid or colloidal liquid lubricant.Liang et al. 10 demonstrated that in-situ exfoliated graphene exhibits exceptional friction-reducing and anti-wear properties.Huang et al. 11 reported that crumpled graphene balls could significantly improve the lubrication properties of polyalphaolefin (PAO) base oil as a high-performance additive, with tribological performance that surpasses that of other carbon additives, such as graphite and carbon black.The tribological behavior of graphene is also influenced by its surface functionalization, which can be tailored to enhance its lubrication properties.For instance, Tao Bai et al. synthesized polyurethane-graphene oxide and Fe 3 O 4 nanocomposites and observed a significant reduction in the coefficient of friction and wear rate compared to neat polyurethane 12 .
Molybdenum disulfide (MoS 2 ) and graphene have attracted significant attention in the field of tribology due to their unique mechanical and structural properties.MoS 2 , with its layered and two-dimensional structure, exhibits excellent tribological behavior as a solid lubricant due to its low friction and wear properties.On the other hand, graphene possesses exceptional mechanical strength, chemical stability, and easy shear capability on its densely packed and atomically smooth surface.Combining these two materials as a nanocomposite further enhances their tribological properties, making them a valuable additive in various industrial applications.The high shear strength of graphene and the layered structure of MoS 2 may result in a synergistic effect, reducing friction and wear.Due to their excellent mechanical and structural properties MoS 2 /graphene nanocomposites may emerge as promising materials for tribological applications.
In this research, we used an innovative approach to synthesize MoS 2 -graphene nanohybrid, employing a microwave synthesis platform.This technique has demonstrated a remarkable reduction in both synthesis time and energy consumption by approximately 90-98% compared to conventional synthesis techniques such as solvothermal, chemical vapor deposition (CVD), laser ablation, and others, as previously documented [13][14][15][16] .The primary objective of this study is to investigate and elucidate the underlying mechanisms responsible for the substantial performance enhancement of base oil upon incorporating MoS 2 -graphene nanohybrid additives.In pursuit of this objective, we have conducted a comprehensive examination of several key parameters, including the coefficient of friction (COF), average wear scar diameter (WSD), oxidation induction time (OIT), and thermal conductivity.Notably, this investigation represents a new effort, as no prior research has systematically explored all these crucial parameters in the context of hybrid nanoparticles.Our foremost aim is to understand the influence exerted by hybrid MoS 2 -graphene nanohybrid additives on the behavior of engine oil.This knowledge holds the potential to facilitate the development of advanced lubricants characterized by superior performance characteristics.The outcomes of this research endeavor are poised to yield valuable insights into enhancing engine oil performance by incorporating MoS 2 -graphene nanohybrid additives, specifically within the domain of diesel-based engine oil applications.Consequently, this research may pave the way for a more sustainable future, marked by a reduced carbon footprint and cost-effective maintenance practices within energy conservation and efficiency.

Physiochemical and morphological characterization of MoS 2 -graphene nanohybrid
Figure 1 shows XRD and Raman spectra analysis of the physiochemical properties of MoS 2 , graphene nanoparticles, and synthesized MoS 2 -graphene nanohybrid.The diffraction peaks at 2θ = 14.5°, 33.0°, 39.3°, 58.5°, and 69.7° in Fig. 1a are connected to the (002), (100), (103), (110), and (201) peaks of the pure MoS 2 phase (JCPDS no.371492) 17,18 .The graphene diffraction peaks are depicted as a single major peak at 2θ = 24.6°from the (002).The hybrid nanoparticle had no additional peaks or substantial changes from the original MoS 2 or graphene diffraction spectra.The estimation of crystallite size in the MoS 2 -graphene nanohybrid was conducted using the Scherrer equation: Here D represents the crystallite size in nanometers, K is the Scherrer constant with a value of 0.9, λ denotes the wavelength of X-rays, β corresponds to the full width at half maximum (FWHM), and θ represents the peak (1) D = K βcosθ position.Applying Eq. (1), the calculated crystallite size of the MoS 2 -graphene nanohybrid was determined to be 94.46 nm.
The Raman spectra in Fig. 1b show the respective spectra for MoS 2 , Graphene and MoS 2 -graphene nanohybrid.The Raman spectrum of MoS 2 shows 2 strong peaks; the first (in 367 cm −1 ) is associated with the E 1 2g vibrational mode, whereas the second (in 406 cm −1 ) is associated with the A 1g mode.On the other hand, these modes correspond to in-plane vibrations of sulphur atoms in one direction, molybdenum atoms in the other, and out-of-plane vibrations (A 1g ) of sulphur atoms.The graphene phase also contributes to the Raman spectrum and the characteristic G and 2D peaks of graphene can be observed at around 1580 cm −1 and 2700 cm −1 , respectively.However, it was observed that only MoS 2 spectra were visible in the Raman spectra of the nanohybrid, while the spectra of graphene were not detected.This phenomenon can be attributed to the strong Raman scattering from MoS 2 compared to graphene.The electronic band structure of MoS 2 allows for strong resonance enhancement of the Raman signal.Thus, the Raman scattering from MoS 2 dominates over the Raman scattering from graphene.Moreover, the laser used in Raman spectroscopy cannot penetrate through the MoS 2 layers to excite the underlying graphene layers.The MoS 2 layers encapsulate the graphene layers, so the Raman signal from the graphene layers were not observed 19,20 .
Figure 2a-c depicts SEM images of MoS 2 -graphene nanohybrid at various magnifications, an EDX spectrum, and elemental mapping.The MoS 2 nanoparticles are shown to be consistently grown over graphene surfaces with curved edges that are uniformly faceted.The images show regions where the MoS 2 and graphene are in close proximity, indicating that they are well-dispersed and that there is good interfacial interaction between the two phases.The microwave synthesis platform has proven highly effective in producing a MoS 2 -graphene nanohybrid with intriguing characteristics.Moreover, the resulting hybrid exhibits flake sizes ranging from 100 to 150 nm, confirming the size in the nanometer range.This nano-sized structure imparts significant advantages, primarily promoting efficient reaction kinetics and reducing the likelihood of nanoparticle aggregation 21 .Furthermore, the microwave synthesis method enables the MoS 2 nanoparticles to encapsulate the surface of  www.nature.com/scientificreports/graphene sheets and intercalate between the MoS 2 layers.This unique feature creates an interlayer coupling effect between the hybrid layers, leading to intriguing synergistic properties.The encapsulation of graphene by MoS 2 and the intercalation between MoS 2 layers not only enhance the structural integrity of the nanocomposite but also facilitate interfacial interactions and promote interlayer charge transfer processes 22,23 .In Fig. 2, a highresolution Energy-Dispersive X-ray Spectroscopy (EDS) mapping composition analysis reveals a uniform and homogeneous distribution of Molybdenum (Mo), Sulphur (S), Carbon (C), and Oxygen (O) across the nanosheet of the MoS 2 -graphene nanohybrid.The EDS spectrum in Fig. 2d confirms the presence of Mo, S, C, and O elements within the hybrid MoS 2 -graphene structure.Furthermore, the corresponding quantitative surface analysis depicted in Fig. 2e demonstrates the consistent elemental distribution of these respective elements throughout the hybrid MoS 2 -graphene nanohybrid.

Physiochemical characterization of MoS 2 -graphene nanolubricant
The findings in Table 1 provide information regarding the density, kinematic viscosity, and viscosity index of a nanolubricant with different concentrations of the MoS 2 -graphene nanohybrid.The results from Table 1 indicate that the addition of the nanohybrid does not lead to any substantial alteration in the density of the engine oil.Based on the data presented in Table 1, it is observed that the addition of the MoS 2 -graphene nanohybrid leads to a slight decrease in the kinematic viscosity of the oil.This reduction in viscosity can be attributed to the lubricating effect of the MoS 2 -graphene nanohybrid, which effectively diminishes the friction between the oil molecules and the moving parts.Consequently, this reduction in frictional resistance facilitates the flow of the oil.The presence of the hybrid MoS 2 -graphene nanohybrid within the oil creates a lubricating boundary layer between the moving parts.This boundary layer acts as a protective barrier, minimizing direct metal-tometal contact and reducing the energy required for movement.In high shear rate environments, such as those encountered in engine components, the formation of this boundary layer becomes particularly significant [24][25][26] .
It can be seen that the MoS 2 -graphene nanohybrid increases the viscosity index in the nanolubricant compared to the SAE20W40.The viscosity index measures the lubricant's resistance to changes in viscosity with temperature changes.A higher viscosity index indicates that the lubricant will maintain its viscosity over a wider range of temperatures, which is crucial for engine protection and fuel efficiency 27 .The increase in the viscosity index reduces the tendency of the lubricant to thicken at low temperatures and thin at high temperatures.This improves the stability of the lubricant and ensures it provides effective engine protection even under extreme operating conditions 28 .
A zeta potential analysis is conducted to assess the stability of the MoS 2 -graphene nanohybrid-based nanolubricant in engine oil.This analysis is crucial as it measures the electrical charge of the dispersed nanoparticles within the engine oil, providing valuable insights into the stability of the nanoparticles.The measurement of zeta potential is a widely adopted method employed by researchers for studying nanolubricant stability 29,30 .Figure 3a illustrates the zeta potential values of the nanolubricant containing various concentrations of the MoS 2 -graphene nanohybrid before and after a period of 14 days.The zeta potential values indicate the dispersion intensity of  the nanoparticles in the engine oil, directly influencing the stability of the nanolubricant.Based on Fig. 3a, it can be observed that the majority of the nanolubricants investigated in this study exhibited zeta potential values exceeding 60 mV after 14 days of synthesis.These high zeta potential values indicate excellent stability of the MoS 2 -graphene nanohybrid in the engine oil.The increase in zeta potential values is due to the graphene in the nanocomposite having a high surface area and electrical conductivity, which provides a large number of active sites for surface interaction and electrostatic stabilization.The MoS 2 in the nanocomposite has a high surface energy and a polar surface, which can further enhance the surface interaction and electrostatic stabilization of the oil droplets 31 .This improves the charge distribution at the surface of the oil droplets, leading to higher zeta potential.The high zeta potential may prevent the droplets from agglomerating and sticking to engine components, which improves engine performance and prolongs engine life 32 .The increase in stability reduces the interfacial tension between the oil droplets and the engine components.This may improve the wetting ability of the oil, leading to better lubrication and reduced wear and tear.
The NOACK volatility test ASTM D5800 is a standard measure of the evaporation loss of lubricating oils under high-temperature conditions.In the NOACK volatility test, a nanolubricant sample is heated at 250 °C for 60 min with continuous airflow.The weight loss during this process evaluates the oil's volatility.The test simulates the engine operation conditions, where high temperatures can cause oil to evaporate and lead to oil thickening, deposits, and reduced engine performance.A lower mass loss in the NOACK test indicates that the oil is less prone to evaporation, which is desirable for engine protection and fuel efficiency.The Noack volatility study of nanolubricant with varying concentrations of MoS 2 -graphene nanohybrid is shown in Fig. 3b.The SAE20W40 evaporative loss was 12.25%, whereas the MoS 2 -graphene nanohybrid based nanolubricants evaporative loss ranged from 9.35 to 11.22%.This can be attributed to several mechanisms of the nanohybrid, which act as a heat sink, absorbing and dissipating the heat generated during engine operation, thereby reducing the evaporation of the lubricant.Furthermore, the nanohybrid reduces the vapor pressure of the nanolubricant engine oil 33 .The vapor pressure is a measure of the tendency of a fluid to evaporate.The MoS 2 -Graphene nanohybrid reduces the vapor pressure of the nanolubricant engine oil by adsorbing onto the metal surfaces and forming a protective layer that reduces the surface area available for evaporation.This can lead to a lower mass loss in the NOACK analysis and provides better engine protection 34 .www.nature.com/scientificreports/solid surfaces, and the lubricant molecules form a protective layer that prevents metal-to-metal contact.The MoS 2 -graphene nanohybrid is an excellent boundary lubricant because of its unique properties.Firstly, MoS 2 and graphene nanoparticles have a layered structure with weak van der Waals forces between the layers.This allows the nanoparticles to easily slide over each other, creating a low-friction surface.Secondly, graphene has a high surface area and may adsorb onto metal surfaces, providing additional lubrication and protection.When MoS 2 -graphene nanohybrid is added to nanolubricant engine oil, it forms a self-assembled layer on the metal surfaces due to its high affinity to metals 35,36 .This layer acts as a barrier between the surfaces and reduces friction by preventing metal-to-metal contact.The MoS 2 -graphene nanohybrid can also withstand high pressures and temperatures, commonly found in engine operation, without degrading or losing its lubricating properties.Additionally, the MoS 2 -graphene nanohybrid as an additive in the engine oil also reduces wear and tear on the engine parts, leading to longer engine life and improved performance.This is because the MoS 2 -graphene nanohybrid forms a protective tribofilm on the metal surfaces, which acts as a sacrificial layer that absorbs the wear and tear, thereby reducing the damage to the underlying metal surfaces 7,37 .When the nanohybrid concentration exceeds 0.05 wt%, the COF rises owing to nanoparticle aggregation.When nanoparticles cluster together, they can generate hard particles that behave as abrasives, increasing surface friction.

Tribological analysis of MoS 2 -graphene nanohybrid nanolubricant
The average wear scar diameters (WSD) MoS 2 -graphene nanohybrid in SAE20W40 diesel engine oil were measured using an optical profilometer in Fig. 4b.Without the inclusion of nanoparticles, the WSD of base oil was 444 µm with the addition of 0.05 wt% MoS 2 -graphene, the WSD of the nanolubricant was lowered by up to 36.26%.The MoS 2 -graphene nanohybrid is a highly effective lubricant additive that reduces the average wear scar diameter in nanolubricant engine oil.The MoS 2 -graphene nanohybrid is a highly effective lubricant additive that may reduce wear by several mechanisms.Firstly, the MoS 2 -graphene nanohybrid forms a self-assembled layer on the metal surfaces, which acts as a protective barrier that absorbs wear and tear.This layer reduces the amount of material that is removed from the metal surfaces, leading to a lower wear scar diameter.Secondly, the MoS 2 -graphene nanohybrid reduces wear by reducing friction between the metal surfaces.As discussed earlier, the MoS 2 -graphene nanohybrid is a highly effective boundary lubricant that reduces friction by forming a low-friction surface on metal surfaces 38 .This reduces the amount of mechanical wear that occurs during engine operation.Thirdly, the MoS 2 -graphene nanohybrid reduces wear by improving the thermal and chemical stability of the lubricant.The MoS 2 -graphene nanohybrid is highly resistant to thermal and chemical degradation, which may prolong the life of the lubricant and reduce the amount of wear that occurs due to thermal and chemical processes 39 .Figure 4c shows the schematic diagram of the lubrication mechanism of MoS 2 -graphene nanolubricant.
The wear scars on a ball bearing surface resulting from tribological testing were examined using FESEM, as shown in Fig. 5a,b.The FESEM images provided insights into the wear surfaces, allowing for a comparison between the wear scar formed on the ball bearing surface lubricated with base oil and the wear scar formed on the ball bearing surface lubricated with a nanolubricant containing 0.05 wt% hybrid MoS 2 -graphene nanohybrid.Figure 5a,b displays the FESEM image of the wear scar, highlighting a substantial difference between the two scenarios.The wear scar observed on the steel ball bearing surface lubricated solely with the base oil exhibited a significantly deeper and more pronounced scar compared to the wear scar formed on the ball bearing surface lubricated with the nanolubricant containing 0.05 wt% hybrid MoS 2 -graphene nanohybrid.This disparity suggests that the addition of nanoparticles, specifically the hybrid MoS 2 -graphene nanohybrid, exerted a mending effect on the wear surface 5 .The nanoparticles were hypothesized to deposit within the micro-cracks and defects present on the mating surfaces, thereby facilitating the repair and smoothening of the surface.This mending effect results in a smoother and more uniform surface, reducing the wear scar depth 40 .The presence of the hybrid MoS 2 -graphene nanohybrid was confirmed by examining the Elemental Dispersive X-ray (EDX) spectra.The EDX elemental spectrum revealed the detection of Mo, S, C, and O elements on the wear scar of the ball bearing lubricated with the nanolubricant containing 0.05 wt% hybrid MoS 2 -graphene nanohybrid.Conversely, no detection of the nanoparticle elements was observed on the wear scar of the ball bearing lubricated solely with the base oil (Fig. 5a).

Oxidation induction time and thermal conductivity analysis of MoS 2 -graphene nanolubricant
The oxidative induction time (OIT) measures the resistance of the lubricant to oxidation, which leads to the formation of deposits and sludge in the engine, reduced lubricant performance, and increased engine wear.Figure 6a depicts the OIT of a nanolubricant in engine oil with different concentrations of MoS 2 -graphene anohybrid.With the addition of 0.05 wt% of the nanohybrid, the OIT of the nanolubricant increased to 19.21%.The MoS 2 -graphene nanohybrid improved oxidative stability by several mechanisms.Initially, the nanohybrid neutralizes the reactive species generated during oxidation reactions.This inhibits oxidation reactions by forming a protective barrier that prevents oxygen from reaching the lubricant components 41 .Subsequently, the MoS 2 -graphene nanohybrid improves oxidative stability by reducing the metal catalyst effect.Metal catalysts such as copper, iron, and nickel accelerate oxidation reactions by promoting the formation of reactive species.The MoS 2 -graphene nanohybrid may form a self-assembled layer on the metal surfaces, which acts as a barrier that reduces the metal catalyst effect and slows down oxidation reactions 42,43 .Lastly, the nanohybrid improves oxidative stability by reducing deposits and sludge formation.It acts as a dispersant, preventing the accumulation of deposits and sludge by keeping the lubricant components suspended.When the nanohybrid concentration exceeds 0.05 wt%, the OIT deteriorates due to the aggregated nanoparticles that created localized hotspots within the oil, leading to increased oxidative reactions and decreased OIT.Aggregated particles may also hinder the access of antioxidant molecules to the oil, further reducing the oxidative stability of the nanolubricant.
The thermal conductivity of a lubricant plays a vital role in the efficiency of engine operation.In general, higher thermal conductivity leads to better heat dissipation, which can reduce the operating temperature of engine components, increase fuel efficiency, and prolong engine life.Figure 6b indicates that incorporating MoS 2 -graphene nanohybrid at various concentrations into SAE20W40-based diesel oil considerably enhanced engine oil thermal conductivity.In the present study, the incorporation of 0.05 wt% MoS 2 -graphene nanohybrid has been demonstrated to significantly enhance heat conductivity by 19.83% (at 100 °C).This enhancement can be attributed to the formation of a thin, continuous film of nanocomposite on the metal surfaces of engine components.The presence of this film promotes better thermal contact between the components and the lubricant, thereby facilitating efficient heat transfer from the engine components to the lubricant.Additionally, the MoS 2 -graphene nanohybrid contributes to the improved dispersion of the lubricant, resulting in enhanced heat transfer throughout the lubricant system.Consequently, utilizing this nanohybrid exhibits the potential to dissipate heat and improve overall thermal performance effectively.
The nanohybrid facilitates the formation of a network-like structure in the lubricant, known as percolation mechanism, which can increase the thermal conductivity of the oil.The MoS 2 in the nanohybrid acts as a bridge between the graphene layers, enhancing the thermal conductivity of the composite 44,45 .The thermal conductivity decreases drastically at 0.1 wt% nanohybrid concentration.The higher nanohybrid concentration causes it to aggregate, forming an insulating surface layer in the nanolubricant.These layers can act as thermal barriers, limiting heat transfer between the oil molecules and the nanoparticles, thus reducing the overall thermal conductivity 46 .

Conclusion
In conclusion, this research study successfully investigated the tribological behavior of hybrid MoS 2 -graphene nanohybrid in SAE20W40 diesel-based engine oil.The utilization of the advanced microwave synthesis platform proved to be highly efficient, significantly reducing synthesis time and energy consumption.The synthesis process resulted in the uniform growth of MoS 2 nanoparticles on the surface of Graphene nanoparticles through the interaction between their respective functional groups.The addition of 0.05 wt% hybrid MoS 2 -graphene nanohybrid in SAE20W40 diesel-based engine oil demonstrated remarkable improvements in various performance aspects.Specifically, a significant reduction of 58.82% in the coefficient of friction and 36.26% in the average wear scar diameter was observed compared to the base oil.Moreover, the nanolubricant exhibited notable enhancements in oxidation analysis by 19.21% and thermal conductivity by 19.83% at 100 °C.These findings confirm that the microwave synthesis of hybrid MoS 2 -graphene nanohybrid offers excellent potential as tribological additives in diesel-based engine oil.The synthesized nanoparticles significantly improve tribological performance, oxidation resistance, and thermal conductivity when incorporated into the engine oil.This research provides valuable recommendations for future studies to advance the application of hybrid MoS 2 -graphene nanohybrid.Key focal points include refining surface functionalization techniques to enhance compatibility with engine oil, conducting rigorous environmental impact assessments, and validating compatibility through thorough engine testing.Additionally, efforts should concentrate on assessing the scalability of nanoparticle synthesis for commercial production and exploring diverse industrial applications.These areas of emphasis are pivotal for realizing the full potential of hybrid MoS 2 -graphene nanohybrid in diverse applications.These advancements can potentially enhance the durability and efficiency of mechanical components in engine systems.The synergistic effects of the nanohybrid provide a promising avenue for future research and development of advanced lubricant formulations.

Materials
For the experimentation, all reagents used in synthesizing hybrid MoS 2 -graphene nanohybrid were of analytical grade and employed without further purification.Ammonium molybdate tetrahydrate ((NH 4 )6Mo 7 O 24 .4H 2 O) was procured from Fisher Chemicals located in Chicago, USA, whereas thiourea (SC(NH 2 ) 2 ) was sourced from R&M Chemicals based in Dundee, UK.Graphene with a thickness of 8 nm and a specific surface area of approximately 80m 2 /g was obtained from Graphene Labs Inc, USA.The lubricant oil employed in the experimentation was diesel engine oil with API SAE20W40 CD/SE GL-4.The properties and specifications of the engine oil is shown in Table 2.

Synthesis of hybrid MoS 2 -graphene nanohybrid
The researchers utilized a microwave hydrothermal synthesis technique to synthesize a hybrid MoS 2 -graphene nanohybrid.In this experimental approach, a solution was prepared by gradually adding 3.7 g of ammonium molybdate tetrahydrate and 6.85 g of thiourea to 105 mL of deionized water.The mixture was stirred for 30 min to ensure homogeneity.Subsequently, 1 g of graphene powder was introduced, and the resulting mixture was subjected to sonication for 30 min.The solution was then transferred to a microwave synthesis platform (Milestone, flexiWAVE, Italy) and heated to 200 °C for 15 min.After heating, the sample was allowed to cool down to room temperature (26 °C) naturally.Subsequently, the sample was centrifugated, washed with distilled water and ethanol, and finally freeze-dried.The synthesis method of the hybrid MoS 2 -graphene nanohybrid is illustrated in Fig. 7.

The hybrid MoS 2 -Graphene nanolubricant formulation
Various concentrations of hybrid MoS 2 -graphene nanohybrid, including 0.005 wt%, 0.01 wt%, 0.05 wt%, and 0.1 wt%, were dispersed in 100 ml of SAE 20W40 engine oil.The mixture was then homogenized for 10 min using a high-shear lab mixer.To ensure that the nanoparticles were uniformly dispersed in the base oil and to prevent agglomeration, the samples were sonicated in an ultrasonic bath for 30 min.

Characterizations
This study utilized various analytical and characterization methods to investigate the properties and performance of hybrid MoS 2 -graphene nanohybrid as a lubricant additive.The size, morphology, and elemental compositions of the nanohybrid were determined using field emission scanning electron microscopy and energy-dispersive X-ray spectroscopy (FESEM and EDX).X-ray diffraction (XRD) with Cu Kα radiation (U = 45 kV, I = 27 mA, and λ = 1.54 nm) was employed to study the crystallinity and phase structure of the samples, while Raman spectroscopy was used to analyze the molecular interactions using a 532 nm laser.Additionally, the density, kinematic viscosity, and viscosity index of the samples were measured with a viscometer (Viscometer SWM 3000), and Zetasizer was used to determine the dispersion stability.The Noack volatility test was performed using Thermogravimetric Analysis (TGA).In the NOACK volatility test, nanolubricant engine oil is heated at 250 °C for 60 min with constant airflow.The resulting weight loss the oil's volatility characteristics, offering insights into its performance under high-temperature conditions.Tribological analysis was conducted using a four-ball tribotester (Ducom TR-30L) to measure the coefficient of friction (COF) and average wear scar diameter (WSD) of the hybrid MoS 2-Graphene based nanolubricant at various nanoparticle concentrations.Carbon chromium steel balls (Hardness (H), HRC: 65, Density (ρ), gm/ cm: 37.79 Surface roughness (Ra), μm: 0.022) were employed, and the rotational speed, applied load, time, and temperature were set to 12,000 rpm, 392.5 N, 3600 s, and 75 °C, respectively, in accordance with ASTM 4172-94.The wear scar images on the metal balls were studied using FESEM and EDX.
Furthermore, oxidation analysis was performed using High-Pressure Differential Scanning Calorimeter (HP-DSC) to determine the oxidation induction time (OIT) of MoS 2 -graphene based nanolubricant with various nanohybrid concentrations.The procedure was carried out at 500 psi, an isothermal temperature of 200 °C, a flow rate of 50 ml/min, and ramping rate of 10 °C/min.The thermal conductivity of the MoS 2-graphene based nanolubricant with different nanohybrid concentrations was evaluated using laser flash analysis (LFA Hyper-Flash).The sample was filled in the sample ring, and the upper and lower sealing discs were sprayed with graphite to promote black body absorption.The sample was heated from room temperature to 120 °C at a rate of 10 °C/ min in a nitrogen environment.

Figure 3 .
Figure 3. (a) The zeta potential analysis, (b) the NOACK Volatility analysis of nanolubricant with various concentrations of MoS 2 -graphene nanohybrid.

FigureFigure 4 .
Figure 4a presents the coefficient of friction (COF) values obtained for the nanolubricant containing different concentrations of the MoS 2 -graphene nanohybrid in engine oil.The COF represents the frictional resistance experienced during lubricated sliding.Upon examination of Fig. 4a, it is evident that the COF of the pure SAE20W40 base oil was measured at 0.0946.When incorporating the MoS 2 -graphene nanohybrid into the base oil, significant reductions in COF are observed.The COF values for the nanolubricant with 0.1 wt%, 0.05 wt%, 0.01 wt%, and 0.005 wt% concentrations of the MoS 2 -graphene nanohybrid were determined to be 21.69%,58.82%, 25.98%, and 17.19% lower, respectively, compared to the base oil.The reduction in COF is due to a highly effective boundary lubrication mechanism.Boundary lubrication occurs when the lubricant film is in direct contact with the

Figure 5 .
Figure 5. FESEM image of wear scar and corresponding EDX elemental spectrum of (a) of base oil without additive, (b) base oil with 0.05 wt% hybrid MoS 2 -graphene nanohybrid.

Table 1 .
Density, kinematic viscosity and viscosity index of the nanolubricant with various concentrations of MoS 2 -graphene nanohybrid.

Table 2 .
The properties and specifications of SAE20W40 diesel based engine oil used in this experiment.