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Ferromagnetic films with perpendicular magnetic anisotropy (PMA) are of wide interest for applications in established and nascent technologies such as ultrahigh density magnetic hard drives 1 , MRAM 2 , superconducting spintronics 3 , and energy efficient spin-orbit torque memory 4 . PMA can be achieved in Pt/Co/Pt multilayer systems as a result of the interfacial anisotropy, however at a critical Co thickness, typically about 1 nm, the anisotropy will fall in-plane. Increasing the total ferromagnetic layer thickness further therefore involves adding additional interfaces to the multilayer. Having a multilayer structure introduces interfacial resistance and interfacial spin-flip scattering 5 , which are disadvantageous for applications such as ours which require the transport current perpendicular-to-plane [6][7][8] . Alternately, robust intrinsic PMA can be achieved in certain Co x Pt 100−x alloys and compounds at any thickness, without increasing the number of interfaces.
Here, we study the equiatomic Co 50 Pt 50 alloy, hereafter referred to as CoPt. Through growth at elevated temperatures it is possible to form the L1 1 and L1 0 chemically ordered compounds of CoPt as epitaxial films. Previous experimental studies of such compounds tend to use MgO substrates as the basis for high temperature epitaxial growth. Visokay and Sinclair report L1 0 crystal structure on MgO [001] substrates for growth temperatures above 520 • C 9 . Iwata et al. report growth of L1 1 crystal structure on MgO [111] substrates for a growth temperature of 300 • C 10 .
Early thin film studies of the chemically ordered CoPt (and the related FePt and FePd) compounds were motivated by the large out-of-plane anisotropy and narrow domain wall widths being candidate for high density storage mediums  . Recently, renewed interest in these compounds has been driven by the discovery of self-induced spin-orbit torque switching in these materials, which can be used as the switching mechanism for a low-dissipation magnetic memory 54-61 . our motivation for studying [111] CoPt is to incorporate this PMA ferromagnet in an all epitaxial heterostructure suitable for superconducting Josephson devices [6][7][8] or MRAM 2 . For these applications growth in the [111] direction is favourable. In Josephson junctions, the superconductor of choice is Nb, which can be grown epitaxially as a bcc structure in the [110] direction 62 . In MRAM, the seed layer of choice is Ta, which has almost identical structural properties to Nb. On Ta or Nb [110] layers, we know that Pt and Co will grow with [111] orientation 63  www.nature.com/scientificreports/ We fabricate and report the properties of three sets of samples. The first set is designed to determine the optimal growth temperature. Therefore, we fix the thickness d CoPt = 40 nm and vary the substrate heater temperature in the range from 27 to 850 • C . The next two sample sets are thickness series grown by varying the growth time at a fixed temperature and magnetron powers. The temperatures chosen for the thickness series are to produce either the L1 1 ( 350 • C ) or L1 0 ( 800 • C ) crystal structures. These temperatures are guided by the results of the first temperature series of samples. Thicknesses are varied over the range 1 nm ≤ d CoPt ≤ 128 nm.
On each sample set we report systematically on the structural and magnetic properties of the CoPt. Additionally, on the thickest 128 nm L1 1 and L1 0 samples we perform point contact Andreev reflection (PCAR) measurements with a Nb tip at 4.2 K to determine the spin polarisation. The use of Nb as the tip, the temperature of this measurement, and the ballistic transport regime probed are relevant for our proposed application of the CoPt in Josephson devices [6][7][8] .

Results and discussion
CoPt properties as a function of growth temperature. We expect that as the growth temperature is increased the CoPt will form initially a chemically disordered A1 alloy phase, followed by a chemically ordered L1 1 crystal structure, an intermediate temperature A1 phase, and finally a chemically ordered L1 0 crystal structure respectively. In order to map out the growth parameters we report on Al 2 O 3 (sub)/Pt (4 nm)/CoPt (40 nm)/ Pt (4 nm) sheet films grown at different set temperatures in the range from room temperature (RT) to 850 • C.
Structure. In order to understand the magnetic phases of sputter deposited CoPt, it is necessary to understand the underpinning structure and the influence of the growth temperature. Therefore, the structural characteristics and film quality were investigated using X-ray diffraction (XRD) as a function of growth temperature. Figure 1a- Fig. 1d. In Fig. 1a, for a growth temperature of 350 • C , the additional feature at 2θ ≈ 40 • corresponds to the superimposed Pendellosung fringes and the Pt [111] structural peak (bulk Pt has a lattice constant of 3.92 Å). This additional Pt structural peak is present for growths up to 550 • C (see Supplemental Information online) which is within the expected optimal temperature range for sputter deposited Pt films on Al 2 O 3 64 . To maintain consistent Pt structure for CoPt growths at different temperatures, future work could grow the Pt layer at its optimum growth temperature. www.nature.com/scientificreports/ Using the Scherrer equation and the full widths at half maxima of the Gaussian fits to the CoPt [111] structural peaks, an estimation of the CoPt crystallite sizes can be made. The crystallite size determined by the main [111] structural peak is given in Fig. 1e. In the expected range of the ordered L1 1 crystal structure between 200 and 400 • C , the estimated CoPt crystallite size is 37 nm, which compared to the nominal thickness of 40 nm indicates that the CoPt has high crystallinity. On the other hand, at RT growth and intermediate temperatures between 400 and 800 • C , the estimated CoPt crystallite size is much lower, showing a minimum value of 22 nm at 700 • C where we expect A1 growth. Interestingly, the disorder in the A1 growth appears to affect both the chemical disorder (random positions of the Co and Pt atoms in the unit cell) and leads to a poorer crystallite size compared to the chemically ordered crystal structures. The disappearance of the Pendellosung fringes at these intermediate growth temperatures is related to the increased roughness of the A1 films. Finally, upon increasing the temperature further to 800 • C and 850 • C the crystallite size reaches a maximum of 49 nm. This value corresponds approximately to the entire thickness of the Pt/CoPt/Pt trilayer, indicating that the Pt buffer and capping layers have fully interdiffused into the CoPt layer. Figure 1f shows the CoPt c-plane space calculated from the center of the fitter Gaussian to the main [111] structural peak. At all temperatures the measured c-plane spacing is very close to the expected value based on single crystal studies 65 , indicating low out-of-plane strain. The trend with temperature, however, is non-monotonic and shows a discrete increase between the samples grown at 550 • C and 650 • C . The transition associated with the L1 0 crystal structure is expected to result in a transition from cubic to tetragonal crystal with a c/a = 0.979 in the single crystal 65 . In the single crystal study, however, the c-axis is in the [001] orientation. In our [111] orientated film, the small structural transition from cubic to tetragonal crystal structure is not expected to be visible in the [111] peak studied here. Nonetheless, Fig. 1f shows features consistent with the CoPt undergoing structural transitions.
X-ray reflectivity (XRR) is performed to further investigate the growth temperature dependent trends in the structural properties of the films. Figure 2a,c,e show the low angle XRR for selected growth temperatures along with the best fits to the data. The corresponding models are shown in Fig. 2b,d,f. Further XRR data are available in the Supplemental Information online. The fitting is performed using the GenX package 66 , which models each layer as a box with independent thickness, roughness, and density fitting parameters. Across 13 samples grown at varying temperatures, the average total sample thickness is 47.2 ± 0.3 nm, compared to a nominal total thickness of 48.0 nm, confirming the sputter rate calibration and that the growth temperature has not impacted the growth rate. For growth temperatures of 450 • C and below, the XRR is best modelled as a Pt/CoPt/Pt trilayer, for example Fig. 2a,b. At a growth temperature of 550 • C and above there is a clear change in the XRR. Modelling the data suggests that the interdiffusion has become so large that a trilayer model is no longer required. For the data shown in Fig. 2c-f, a single layer model is used to fit the reflectivity. Figure 2g shows the extracted roughness parameter on the top surface of the sample. The surface roughness shows temperature dependence corresponding to the underpinning structure of the CoPt film. For the optimal growth temperature to achieve the L1 1 crystal structure, the corresponding surface roughness is lowest. In the A1 growth regime, the disorder in the crystal structure evident in the XRD is also present in the film surface roughness. The lower roughness is recovered at higher temperatures at the optimal growth temperature for the L1 0 crystal structure. Figure 2h shows an extracted interfacial roughness parameter at the CoPt/Pt interface. We interpret this parameter as a measure of the interdiffusion between the layers. As expected, a clear trend is present where the interdiffusion between the layers increases with increasing temperatures. At the highest growth temperatures where a single layer model is used to fit the data, there is no interfacial roughness parameter to extract as the layer has completely interdiffused.
Magnetic characterisation. The magnetisation versus field data are shown in Fig. 3 for Al 2 O 3 (sub)/Pt (4 nm)/ CoPt (40 nm)/Pt (4 nm) sheet film samples. Further magnetisation data for all samples in this study are available in the Supplemental Information online. The 350 • C , 550 • C , and 800 • C samples are plotted here as they are representative of the magnetic response of the L1 1 crystal structure, the chemically disordered A1 phase, and L1 0 crystal structure respectively. Magnetisation is calculated from the measured total magnetic moments, the areas of the sample portions, and the nominal thicknesses of the CoPt layer.
For the chemically ordered L1 1 crystal structure shown in Fig. 3a, the OOP hysteresis loop shows a wasp waisted behavior associated with the formation of magnetic domains at remanence. Such behavior is common in CoPt alloys and multilayer thin films 9 . The wasp waisted OOP hysteresis loop along with the low IP remanence and higher IP saturation field indicates that the 40 nm CoPt samples with the L1 1 crystal structure have strong PMA. We can estimate the effective anisotropy using the expression K eff = µ 0 M s H s /2 , where µ 0 is the vacuum permeability, M s the saturation magnetisation, and H s is the saturation magnetic field. We estimate from the hysteresis loop that H s in-plane is 0.8 T (based on when the magnetisation reaches 97.5% of the fitted saturation value), and therefore K eff = 0.4 ± 0.1 MJ/m 3 . The effective anisotropy includes the uniaxial and shape anisotropy.
For samples grown at intermediate temperatures with the chemically disordered A1 structure, the magnetism favours IP anisotropy at 40 nm, shown for growth at 550 • C in Fig. 3b.
For the chemically ordered L1 0 crystal structure shown in Fig. 3c, there is a significant increase in the coercivity and squareness ratio ( M r /M s ) for both the IP and OOP field orientations. The increased coercive field suggests that the L1 0 CoPt is magnetically hard compared to the L1 1 and A1 samples. The magnetisation of the L1 0 40 nm CoPt sample does not show clear IP or OOP anisotropy from these measurements.
The magnetisation vs growth temperature is shown in Fig. 3d. At growth temperatures below 550 • C the magnetisation remains approximately constant, however at higher temperatures the magnetisation begins to decrease with increasing temperature. The possible cause of this decrease is the higher growth temperature contributing to interdiffusion between the Pt and CoPt layers, creating magnetic dead layers. www.nature.com/scientificreports/ The saturation field and squareness ratio vs growth temperature are shown in Fig. 3e,f respectively. The general trends can be seen in the differences observed in the hysteresis loops of Fig. 3a-c. These trends allow us In the L1 0 crystal structure, Fig. 3c, the high squareness ratio for both field orientations suggests that the anisotropy axis of the material is neither parallel or perpendicular to the film. Instead, it is possible that the magnetic anisotropy is perpendicular to the layer planes, which are stacked in the [100] direction.
To further investigate the anisotropy, we pattern our L1 1 350 • C and L1 0 800 • C samples into Hall bars and perform angular dependent Hall resistivity, R xy (θ ), measurements (Fig. 4). The fabricated Hall bar and measurement geometry is shown in Fig. 4a. R xy (θ ) for the L1 1 350 • C and L1 0 800 • C Hall bars are shown in Fig. 4b,c, respectively. For the L1 1 350 • C sample with out-of-plane anisotropy, R xy (θ ) shows a plateau close to out-of-plane field and a uniform response for angles in between. The plateau is interpreted as an angle forming between the magnetisation and applied field because of the anisotropy axis 67 . In comparison, the L1 0 800 • C sample also shows a R xy (θ ) plateau for out-of-plane applied field plus an additional plateau for applied field angles between about 45 • and 60 • . We interpret the additional plateau in R xy (θ ) for the L1 0 800 • C CoPt sample as evidence for an additional anisotropy axis, which we propose is perpendicular the [100] direction. The [100] plane has a dihedral angle of 54.75 • with the [111] growth plane. Additional sources of anisotropy in our samples are interface anisotropy at the Pt/CoPt interfaces, which would favour out-of-plane magnetisation for thin layers, and shape anisotropy, which for our thin films would favour in-plane magnetisation. Figure 5 shows the extracted coercive field as a function of in-plane rotator angle for the L1 0 800 • C sample. The data shows a clear six-fold symmetry. This is consistent with an easy axis for the plurality tetragonal L1 0 phase of [001] when grown on {111} planes-the < 100 > directions of the parent cubic structure are inclined at ±45 • from the plane and are coupled with the three fold symmetry of {111} . The magnetometry data therefore strongly suggests that over the sample the [001] L1 0 can be found in any of the three possible < 100 > of the parent cubic structure without a strong preference for which of the possible twins grow.  sheet films is shown in Fig. 6a,b for the L1 1 ( 350 • C ) and L1 0 ( 800 • C ) crystal structures respectively. Hysteresis loops over the full thickness range are given in the Supplemental Information online. The moment/area at saturation (or 6 T) verses nominal CoPt thickness are presented in Fig. 6c,d. We calculate the magnetisation (M) by fitting the moment/area versus nominal CoPt thickness data. In order to account for interfacial contributions to the magnetisation of the CoPt, we model the system as a magnetic slab with possible magnetic dead layers and/or polarised adjacent layers. Magnetic dead layers can form as a result of interdiffusion, oxidation, or at certain interfaces with non-ferromagnetic layers. At some ferromagnet/nonferromagnet interfaces, the ferromagnetic layer can create a polarisation inside the non-ferromagnetic layer by the magnetic proximity effect. Polarisation is particularly common at interfaces with Pt [68][69][70][71][72] . To take these into account, we fit to the expression, where d i is the contribution to M from any magnetic dead layers or polarisation. The resulting best fit and the moment/area versus the nominal CoPt thickness is shown in Fig. 6.

CoPt properties as a function of thickness for
For L1 1 growth at 350 • C , the result of fitting Eq. (1) shown in Fig. 6c gives M = 750 ± 50 emu/cm 3 and d i = 0.38 ± 0.05 nm. From the XRR data and fitting presented in Fig. 2, the interdiffusion of the Pt seed and capping layers and the CoPt layer is minimal at this growth temperature, which is consistent with the small dead layer d i .
For L1 0 growth at 800 • C , the thinnest 1 nm and 2 nm films did not display any magnetic response and are excluded from the analysis in Fig. 6. This suggests the formation of a magnetic dead layer or alternatively a large  www.nature.com/scientificreports/ enough change to the stoichiometry that those films were no longer magnetic. From the XRR data and fitting presented in Fig. 2, there is significant interdiffusion between the Pt seed and capping layers and the CoPt. The result of fitting Eq. (1) shown in Fig. 6d for the samples thicker than 2 nm gives M = 520 ± 50 emu/cm 3 and d i = −2 ± 1 nm. Interestingly, we find a significant difference in M between the two crystal structures, which is consistent with a previous report of CoPt growth on MgO substrates 43 . It is possible that the differences in M corresponds to a true difference in the saturation magnetisation of the two crystal structures. An alternative scenario is that the 6 T applied field is not large enough to fully saturate the L1 0 samples, leading to a reduced measured M. Another possibility is that the interdiffusion of the Pt seed and capping layers during growth at 800 • C modifies the stoichiometry of the resulting L1 0 film, and hence reduces the magnetisation. The thickness dependence of the magnetic switching of the L1 1 samples is well summarised by the squareness ratio shown in Fig 6e. The thickest 40 and 128 nm samples are wasp waisted, as presented in Fig. 3. At reduced thicknesses, between 2 and 8 nm, the L1 1 CoPt no longer displays the wasp waisted switching for out-of-plane field orientation, and now has a square loop shown in Fig. 6a. The 16 nm sample showed an intermediate behaviour. At 1 nm, the magnetic switching showed "S" shaped hysteresis loops for both in-and out-of-plane applied fields with small remanent magnetisation, see Supplemental Information online.
The thickness dependence of the L1 0 crystal structure samples is significantly different to the L1 1 . In the thinnest films of 1 and 2 nm there is no evidence of ferromagnetic ordering in the hystersis loops, see Supplemental Information online. For L1 0 growth at 800 • C , the XRR measurements (Fig. 2) suggests interdiffusion at the Pt/ CoPt interfaces during high growth temperature. The interdiffusion may account for magnetic dead layers, which in the thinnest samples may prevent ferromagnetic ordering. Upon increasing the thickness to 4 nm, a ferromagnetic response was recovered, however the hysteresis loops and extracted squareness ratio (Fig. 6f) indicate that the 4 nm and 8 nm L1 0 samples have in-plane magnetisation. The in-plane magnetisation in the thinner films suggests that the long-range L1 0 ordering may have not established at those thicknesses.
The thickness dependence in both crystal structures suggest that the Pt/CoPt/Pt trilayers grown on Al 2 O 3 substrates are not suitable for applications where ultrathin magnetic layers are required. To improve the magnetic properties of the thinnest samples in this study our future work will focus on replacing the Pt layers with seed and capping layers where interdiffusion may be less.

Spin polarisation.
To estimate the spin polarisation in the chemically ordered L1 0 and L1 1 CoPt samples, we perform point contact Andreev reflection (PCAR) spectroscopy experiments 30,36,[73][74][75][76] . In the PCAR technique, spin polarisation in the ballistic transport regime can be determined from fitting the bias dependence of the conductance with the a modified Blonder-Tinkham-Klapwijk (BTK) model 77 .
We measure the Al 2 O 3 (sub)/Pt (4 nm)/CoPt(128 nm)/Pt (4 nm) samples grown at 350 • C , corresponding to L1 1 crystal structure, and 800 • C , corresponding to L1 0 crystal structure. The PCAR experiment was performed with a Nb wire tip at 4.2 K. Exemplar conductance spectra with fits to the BTK model are given in Fig. 7a. The interpretation of PCAR data is rife with difficulties 78 and a common issue with the PCAR technique is the presence of degenerate local fitting minima. To ensure that a global best fit is obtained, the fitting code makes use of a differential-evolution algorithm and we then consider the spin polarisation and barrier strength parameter for a large number of independent contacts to the same sample. Figure 7c shows the dependence of the polarisation as a function of the square of the barrier strength, Z 2 . The dashed lines in Fig. 7 are linear fits to the data. The value of the true spin polarisation is is often taken to www.nature.com/scientificreports/ correspond to Z = 0 , however this is strictly nonphysical. Nevertheless, in an all metal system it is possible to produce contacts approaching an ideal case and extrapolating to Z = 0 is close to the (finite) minimum. We find that P = 47 ±3 % for both L1 1 and L1 0 CoPt samples. This compares to ≈ 42 % for L1 0 FePt 30 and ≈ 50 % for L1 0 FePd 36 .

Conclusions
The major conclusions of this work may be summarised as follows. On c-plane For alloy growth, we use the co-sputtering technique. To achieve as close to a Co 50 Pt 50 stoichiometry as possible, first, single layer samples of Co or Pt are grown at room temperature on 10 × 10 mm thermally oxidised Si substrates varying the magnetron power. From this initial study, it is found that a growth rate of 0.05 nm s −1 is achieved for a Co power of 45 W and a Pt power of 25W. These growth powers are fixed for the rest of the study.
For the growth of the CoPt samples, 20 × 20 mm c-plane sapphire substrates are used. The substrates are heated by a ceramic substrate heater mounted directly above the substrate holder. The measured substrate heater temperature is reported. We note that the temperature on the substrate surface is most likely to be below the reported heater temperature. The substrate heater is ramped up from room temperature to the set temperature at a rate of 3-5 • C min −1 . Once at the set temperature, the system is given 30 min to reach equilibrium before starting the sample growth.
Once the system is ready for growth, 4 nm Pt seed layer is deposited. The seed layer is immediately followed by the CoPt layer, which is deposited at a rate of 0.1 nm s −1 by co-sputtering from the two targets at the determined powers. Finally, a 4 nm Pt capping layer is deposited to prevent the samples from oxidising. The final sample structure is Al 2 O 3 (sub)/Pt (4 nm)/CoPt(d CoPt )/Pt (4 nm). Following deposition, the samples are post growth annealed for 10 min at the growth temperature before the substrate heater is ramped down to room temperature at 10 • C min −1 .
Characterisation. Magnetisation loops are measured using a Quantum Design MPMS 3 magnetometer.
Angular dependent magnetization measurements are performed using the Quantum Design Horizontal Rotator option. X-ray diffraction and reflectivity is performed on a Bruker D8 diffractometer with an additional fourbounce monochromator to isolate Cu K-α at a wavelength of 1.5406 Å. Sheet films are patterned into Hall bars of 5 µ m width using conventional photolithography and Ar ion milling. Resulting devices are measured using 4-point-probe transport to measure the Hall resistance of the films using a combined Keithley 6221-2182A current source and nano-voltmeter.

PCAR .
Our experimental setup for performing PCAR measurements is described elsewhere 30,36,[74][75][76] . The Nb tips are prepared from commercial 99.9% pure Nb wires with a diameter of 0.5 mm. An AC lock-in detection technique using Stanford Research Systems SR830 lock-in amplifiers is used for the differential conductance measurements. The tip position is mechanically adjusted by a spring-loaded rod driven by a micrometer screw. The experiment is carried out in liquid He at a fixed temperature of 4.2 K and at zero applied magnetic field.

Data availability
The datasets generated and/or analysed during the current study are available in the University of Leeds repository, https:// doi. org/ 10. 5518/ 1275. www.nature.com/scientificreports/