Abstract
Colloids are essential materials for modern inkjet printing and coating technology. For printing and coating, it is desirable to have a high density of colloids with uniformity. Binary colloids, which consist of different size colloidal particles, have the potential to achieve high coating density and uniformity from size effects. We report a strategy to attain high-density deposits of binary colloids with uniform, crack-free, and symmetric deposits through droplet evaporation on micropillar arrays. We modify surfaces of micropillar arrays with plasma treatment to control their surface energy and investigate how binary colloidal fluids turn into well-controlled deposits during evaporation with X-ray microscopic and tomographic characterizations. We attribute temporary surface energy modification of micropillar arrays to the well-controlled high-density final deposits. This simple, low-cost, and scalable strategy would provide a viable way to get high-quality, high-density deposits of colloids for various applications.
Similar content being viewed by others
Introduction
Colloidal suspensions that consist of insoluble colloidal particles in a solvent are the main component of inkjet printing, a remarkably economical technique used for device manufacturing in several industries (i.e. optoelectronics, energy storage, tissue engineering, biodetection/sensing)1,2,3,4,5,6. Besides the economic advantage of inkjet printing, additional benefits come from the easy control of inkjet materials, delivering exact quantities of nanoinks through single ink droplets on pre-fabricated substrate patterns, and rendering specific structures and properties7. From a physical viewpoint, colloidal suspensions, including insoluble colloidal particles with diameters of approximately 1 nm to several \(\upmu\)m are considered a model of nanoinks8,9. The drying process of colloidal nanoinks is critical in achieving uniform deposition of colloidal particles but challenging in industrial applications because of coffee-ring effect, characterized by solute segregation at the contact line of evaporating colloidal droplets10, and crack formation, which is induced by air invasion into the deposits11,12. Both results cause nonuniform and defective deposition of colloids and eventually degrade the electrical and optical properties of deposits. Additionally, the evaporation of monodispersed colloidal nanoinks inevitably causes the generation of empty spaces among spherical colloidal particles13. The maximum packing density from monodispersed spherical particles is 74% when particles are arranged with face-centered or hexagonal closed packing, a crystalline state. The maximum packing density of a monodisperse particles with random packing is 64%14. In binary colloidal particles with two different diameters, small particles are expected to fill in empty space among large particles, increasing the packing fraction and generating a more physically stable deposition15,16. The increment of packing fraction by using bimodal particles, which leads to highly-dense deposits in the inkjet printing technique, has been shown to enhance electrical and sensing properties of printed devices effectively17,18,19. Finding appropriate deposition condition of binary colloids is crucial to improve coating density and uniformity of colloidal nanoinks deposits.
Achieving uniform deposition of monodispersed colloids through evaporation is essential in recent studies20,21, including a micropillar-guided deposition9. Due to surface roughness, hydrophobicity of substrates22,23,24,25,26 would induce the self-pinning of colloidal fluids on micropillar substrates. A constant contact angle mode (CCA) during droplet evaporation would cause preferential accumulation of colloidal particles at the droplet center and eventually bump formation, as demonstrated in Fig. 1A. The existence of the bump at the droplet center results in the structural nonuniformity and instability responsible for the destruction and dysfunction of deposits. To prevent the bump formation from monodispersed colloids, we suggest a surface-modified micropillar-guided deposition for binary colloids to achieve uniform crack-free high-density deposition. As the surface energy controls droplet dynamics, controlling surface energy can provide opportunities to control deposition. The surface energy of the specimen is increased with plasma treatment, which increases the OH-terminal bonds27,28 and can induce the depinning of colloidal droplets on micropillar substrates, as demonstrated in Fig. 1B. The increasing surface energy spreads the droplet to pass through the pillar barriers, by which colloids can flow outward to the contact line. Eventually, the bump formation is successfully prevented by enhancing the surface wettability of micropillar substrates, as demonstrated in Fig. 1C.
This study demonstrates how to achieve symmetrically uniform crack-free hexagonal dense deposits of binary colloids using a surface-modified micropillar-guided deposition. Using high-resolution X-ray microtomography, we measure real-time dynamics of evaporation and deposition processes for binary colloidal droplets on plasma-modified micropillar substrates. Our findings contributes to identify the optimal conditions that are feasible in inkjet printing technology.
Materials and methods
We examined two kinds of PDMS (polydimethylsiloxane) substrates for comparison: PDMS with flat surfaces and PDMS with micropillar patterns. The PDMS substrates were fabricated with SYLGARD\(^{\textrm{TM}}\) 184 Silicone Elastomer Kit (Dow, USA) at a 10:1 ratio of polymer base to cross-linking curing agent. The PDMS substrates with micropillar patterns were fabricated using a silicon wafer master mold etched with the negative structure for cylindrical pillars arranged in a hexagonal pattern. The final geometry of the micropillar array was fixed in three dimensions: pillar diameter (\(D_P\)) = 100 \(\upmu\)m; pillar height (\(H_P\)) = 100 \(\upmu\)m; pillar pitch (\(P_P\)) = 100 \(\upmu\)m (see Fig. S1 of Supplemental Material). The pillar dimensions were chosen for optimal wetting modes, Wenzel modes, while ensuring polygonal depositions9,29. For the wettability control, the surface energy was increased by applying oxygen plasma treatment27. The plasma surface activation process was carried out with a Basic Plasma Cleaner (PDC-32G-2, Harrick, USA) at a radio frequency (RF) power setting of low (7.2W). The plasma treatment time (\(t_p\)) was increased from 5 to 25 s to determine the optimum surface energy.
An aqueous binary colloidal suspension was prepared by mixing \(5.0 \pm 0.1\) vol\(\%\) polystyrene particles of 2 \(\upmu\)m (small particles) and 10 \(\upmu\)m (large particles) (Polysciences, USA), showing a size ratio (\(\omega _s\)) to be 5 (large/small). Colloidal suspensions of polystyrene particles are widely used as model systems for inkjet printing studies9,30,31. Their surface chemistry is well controlled to be completely immersed and uniformly dispersed in solvents by the supplier. The basic knowledge taken from model particles would be useful in inkjet printing, despite differences in surface chemistry and ink formulation details. Overcoming a limit of monodispersed colloids, binary colloids with significantly different diameters would contribute to dense packing (Figs. S2, S3 of Supplemental Material). Tiny droplets with the initial volumes of \(1.5 \pm 0.2\) \(\upmu\)L were carefully delivered with a micropipette on the PDMS substrates with different surface energies. The side-view optical images for contact angle measurements were acquired using a drop shape analyzer (DSA25, Krüss, Germany). A digital upright microscope (VHX-700FE, Keyence, Japan) was used to visualize the droplet’s temporal evolution and the final deposited pattern. Scanning electron microscopy (SEM) (S-3000H, Hitachi, Japan) was used to image the final binary colloidal deposits on the pillar substrate.
For in-situ observation of the evaporation process and visualization of the final deposited pattern of binary colloidal drops on micropillar patterned PDMS, high-resolution and high-speed X-ray imaging technique was employed in this study, allowing the acquisition of three-dimensional (3D) images through microtomography. The experiments were carried out at the 6C Bio Medical Imaging (BMI) beamline established in the Pohang Light Source (PLS-II), where the beam is composed of monochromatic synchrotron X-rays with 20 keV energy. A \(\times\) 10 magnification was used, translating into an effective pixel size of 0.65 \(\upmu\)m and a field of view of 1.70 \(\times\) 1.40 mm\(^{2}\). For image acquisition, the sample is penetrated by the beam, followed by X-ray conversion into visible light by the scintillator (LuAG:Ce 50 \(\upmu\)m) and then received by the Scientific Complementary Metal–Oxide–Semiconductor (sCMOS) camera (pco.edge) (see Fig. S4 of Supplementary Material). For 3D image acquisition, 2D projections were acquired from 0 to 180 degrees while the sample was rotating, comprising a total of 900 projections. The Octopus Reconstruction software (Octopus, Belgium) was utilized to originate 2D tomographic slices from the X-ray projection images. The Octopus software also enabled image processing by applying noise and ring filtering. The 2D slices were processed with the visualization Amira Software (Thermo Fisher Scientific, USA) to achieve the three-dimensional volume images presented in this work. The Amira software was used for noise reduction and smoothing by applying a Median Filter to the 2D tomographic slices, the Volume Rendering function for the generation of the 3D images, and the dimensions of the pillars and colloidal deposits for analysis with built-in measurement tools32.
Results and discussion
We successfully achieve highly uniform and dense deposits of binary colloids on surface-modified micropillar substrates, as described below.
Droplet pinning dynamics on a plasma-modified substrate
The initial depinning dynamics, as illustrated in Fig. 2A, is explained by surface energy modification through plasma treatment contribution, which is essential to control the initial pinning and depinning dynamics of binary colloidal fluids. Initial low surface energy or large contact angle of micropillar substrate with no treatment would be favorable for initial pinning of colloidal fluids between pillars, as demonstrated in Fig. 2B (left). Plasma treatment increases surface energy (or decrease contact angle), which is essential to induce initial depinning that makes contact lines pass through pillars, as shown in Fig. 2B (right). The temporal evolutions of pinning with no treatment and depinning with plasma treatment are shown in Fig. 2C. Surface energy modification by plasma treatment is critical for pinning or depinning dynamics at initial times.
The late re-pinning dynamics, as illustrated in Fig. 2A, is attributed to that hydrophilicity or less hydrophobicity by plasma treatment is temporary and recoverable to original hydrophobicity. Contact angle modification with plasma treatment time (\(t_p\)), as summarized in Fig. 3A, demonstrates that initial contact angles decrease by plasma treatment times for both flat and micropillar PDMS substrates. The gradual decrease of contact angles by plasma treatment times turns hydrophobicity (\(\theta > 90^{\circ }\)) into hydrophilicity (\(\theta < 90^{\circ }\)), as demonstrated in Fig. 3B. The transition from hydrophobicity to hydrophilicity appears at \(t_p \sim 5\) s for flat PDMS and at \(t_p \sim 15\) s for micropillar PDMS. Most importantly, hydrophilicity or less hydrophobicity with plasma treatment is not permanent. Hydrophilicity is therefore recovered to hydrophobicity, as observed in Fig. 3C. The recovery of oxygen plasma treatment is well known as aging effect33,34,35,36,37. Original hydrophilicity is favorable for initial depinning, contributing to flattening the upper bump. Late recovery from hydrophilicity to hydrophobicity is favorable for re-pinning, minimizing the final deposit surface area.
The recovery dynamics of oxygen plasma treatment by aging effects is due to air exposure under ambient conditions (\(22 \pm 3\,^\circ\)C room temperature and \(35 \pm 5\)% relative humidity). The longer plasma treatment time leads to a longer recovery time. In particular, micropillar PDMS substrates for \(t_p = 5\) s and \(t_p = 10\) s is fully recovered to \(\theta _0 \sim 120^\circ\), 20 min after plasma treatment. During the evaporation process, the droplet coverage prevents the local hydrophilicity transition on the liquid–solid interface by avoiding the substrate contact with air34. However, the air exposure allows the surrounding substrate to be prone to induce the aging effect, facilitating the recovery dynamics. The recovery dynamics of micropillar substrates are responsible for the late re-pinning dynamics and thus the final minimum deposit surface area.
Achieving highly-dense uniform deposits from binary colloids
The high-density packing of binary colloids requires the uniformity of the deposition. An appropriate mixture of binary colloids is expected to realize a high-density coating if small particles sufficiently fill the space between large particles16. The size ratio (\(\omega _s\)) and the mixing volume ratio (\(\omega _m\)) between small and large particles are essential to obtain the highest packing density. For a colloidal mixture that displays binary particle dynamics, it is necessary to have a size ratio larger than 1.415. We find low-density deposition by monodispersed-like behaviors at small size ratios and size separation (Figs. S3, S5 of Supplemental Material). Size separation for evaporating droplets, including binary colloids, can be induced due to hydrodynamics by diffusion force during evaporation10. We choose the size ratio to be \(\omega _s = 5.0\) (= 5/1 = large/small) and the mixing volume ratio to be \(\omega _m = 0.5\) (= large/total) to achieve dense, uniform and crack-free deposits.
For the specified conditions and without plasma treatment (\(t_p = 0\) s), the bump formation will be present, depicting a higher height (H) of the deposit due to the highly constricted surface area of the hexagonal prism base (S) (Fig. 4A, left). The bump formation, a failure of the uniform deposition, (Fig. 4B, left) induces the low particle density deposition of the bump layer, where large particles surrounded by small particles may behave like single-sized large particles, hindering a high-density deposition. We visualize the discontinuously arranged particles in Fig. 4B (left), which would result in poor electrical property, a weakness for inkjet-printed device fabrication38. Overcoming the bump emergence is possible with plasma treatment, leading to a final pattern with uniform height, distributed through a wider surface area, effectively removing the bump and exposing the pillar top surfaces evenly, in opposition to the absence of plasma treatment (Fig. 4A, right). Here, the size of small particles is sufficiently little to fill voids between the large particles (Fig. 4B, right). Eventually, the deposit pattern can stabilize without a bump and prevent crack formation (Fig. S6 of Supplemental Material).
Hexagonal deposit patterns with geometrical uniformity can be expected by the hexagonal prism model9, where the hexagonal deposit volume is obtained as \(V = SH\) and assuming the volume conservation principle for the total particles volumes \(\phi V=\phi _0 V_0\) (the final particle packing fraction \(\phi\), the initial particle volume fraction \(\phi _0\), and the initial droplet volume \(V_0\)). The two main parameters, S and H, are quantified in our experiments in (Fig. 4). H is taken on average from the side-view X-ray imaging, for instance, \(H \sim\) 155 \(\upmu\)m with bump and the average \(H \sim\) 100 \(\upmu\)m without bump (Fig. 1C). S is taken by subtracting the total surface areas of the pillar tops inside the hexagonal prism from the surface area of the hexagonal prism base, for instance, \(S = 0.934\) mm\(^{2}\) (\(= 1.075{-}0.141\)) with bump and \(S = 1.159\) mm\(^{2}\) (\(= 1.536{-}0.377\)) without bump. For both cases, \(V_0 = 1.5\) mm\(^{3}\) and \(\phi _0 = 0.05\). The final packing fraction of the binary colloidal deposit for the two cases can be then expected by
where the bump deposit pattern reveals a lower final packing fraction of \(\phi = 0.52 \bigg ( =\frac{0.05 \times 1.5}{0.934 \times 0.154}\bigg )\) in comparison to the uniform deposit pattern, which accounts for a packing fraction of \(\phi = 0.65 \bigg (=\frac{0.05 \times 1.5}{1.159 \times 0.100} \bigg)\). The estimated \(\phi\) values reinforce the main strength of binary colloids, since \(\phi\) is effectively increased for both cases, compared with the previous value for monodispersed deposits of \(\phi = 0.48\)9.
The symmetric deposition is achieved by initial symmetric pinning, as illustrated in Fig. 5. Initial contact angles determined by plasma treatment times \(t_p\) can be larger than 90\(^{\circ }\), causing initial symmetric pinning by the capillarity predominance. This initial symmetry results in the final bilateral symmetric deposits. We often observe bump formation for \(t_p = 0\) or 5 s and asymmetric deposits for \(t_p = 15\) s. Consequently, initial hydrophobicity and temporal hydrophilicity transition for \(t_p = 10\) s are critical to finally achieving symmetrically uniform crack-free hexagonal deposits. The complete evaporation dynamics affected by the substrate wettability attained for each \(t_p\) is represented in Fig. S7 of Supplemental Material. The attainable symmetric patterns enhance local uniformity of particles distribution, ensuring a steady packing fraction in any direction. Furthermore, this well-controlled evolution of the polygonal contact line is crucial for optimized textured surfaces in printing applications39.
Optimized conditions for high-quality deposit patterns
The optimum mixtures in binary colloids are crucial to achieve highly-dense uniform patterns. The colloidal suspension, being a binary mixture of particles, has two main criteria: particle size ratio (\(\omega _s\) = large particle radius divided by small particle radius) and binary mixing volume ratio (\(\omega _m\) = large particle total volume divided by total particle volume). Regarding the optimum \(\omega _s\) values, to avoid the monodisperse-like behavior of larger particles, the size ratio should be \(\omega _s > 1.4\) in our experiments. Simultaneously, for larger size ratios (\(\omega _s > 6.46\))15, gravity can induce percolation of small particles, leading size separation (Fig. S3 of Supplemental Material). Previous experimental and theoretical studies suggest that a size ratio of \(\omega _s \approx 5\) contributes to a system with more uniform distribution and low mobility allowing increased jamming, corroborating our option14,16. Concerning the mixing volume ratio \(\omega _m\), a volume fraction of large particles to the total volume of dried binary particles, if smaller particles are included in a greater ratio, patterns are more prone to crack due to air invasion at the final evaporation stage (Fig. S5 of Supplemental Material)8,40. Furthermore, a mixture with \(\omega _m \approx 0.7\) would form a packed structure, consistent with previous works15,16. However, the micropillar array hydrophobicity allied to the presence of larger particles would lead to an enhanced movement of smaller particles outwards to the drying interface, constraining the larger particles to stack at the center10,16,41. The size separation at \(\omega _m = 0.75\) can be a setback leading to the bump formation (Fig. S5 of Supplemental Material). Therefore, the approach of \(\omega _m = 0.5\) is justified by the final goal of uniformity of the deposit.
Finally, we discuss packing fraction differences before and after plasma treatment. Our results indicate that the higher packing fraction is present for the uniform deposit pattern, consistent with the observation in Fig. 4B (right), where the pillars play the role of imprisonment leading to a cohesive pattern. In contrast, the lower packing fraction present in the bump pattern is mainly due to the size separation, displaying a non-desirable monodisperse-like behavior of larger particles (Fig. 4B, left), since smaller particles preferentially move outwards10,16. Theoretically, a reachable final packing density is known as \(\phi = 0.71\) for randomly packed binary colloids15, while the high-density deposits are achieved as \(\phi = 0.65\) in this work. This discrepancy is due to hydrodynamics effects in evaporating droplets, where the flows disturb uniform particle distribution, which can induce colloids to be randomly packed rather than crystallized. We achieved a low packing density of 0.48 from randomly packed monodispersed colloids9. Therefore, binary colloids are more favorable for a high packing density than monodispersed colloids. Our finding on the deposition dynamics will be relevant to the evaporation dynamics of binary colloids, for instance, regarding evaporation dynamics on superhydrophobic surfaces42. Further studies are required to understand evaporation dynamics and to overcome hydrodynamic effects during evaporation to increase deposit densities.
Conclusion
Our study represents a feasible method to achieve high-quality, high-density hexagonal deposits of binary colloids on hexagonal-patterned micropillar substrates. Temporarily turning the substrates hydrophilic with oxygen plasma treatment helps to induce the initial depinning dynamics. The late recovery to hydrophobicity is helpful to induce the re-pinning dynamics of binary colloidal fluids on the substrates. These controlled dynamics would be crucial to achieve symmetric high-density deposits of binary colloids. Additionally, the proposed method forms horizontally uniform heights by removing height differences between the center and the edge of final deposition patterns when using binary colloids and micropillar patterns. The achievable increased packing fraction imply numerous advantages for industrial performances43,44,45. This strategy would help to optimize inkjet printing by proceeding with inexpensive, easy-fabricated, well-controlled high-density deposits of binary colloids for many possible applications, being nearly universal.
Data availability
The data that supports the findings of this study are available within the article and its Supplementary Material.
References
Derby, B. Inkjet printing of functional and structural materials: fluid property requirements, feature stability, and resolution. Annu. Rev. Mater. Res. 40, 395–414 (2010).
Fang, Y. et al. Inkjet-printed vertical organic field-effect transistor arrays and their image sensors. ACS Appl. Mater. Interfaces 10, 30587–30595 (2018).
Pi, X., Zhang, L. & Yang, D. Enhancing the efficiency of multicrystalline silicon solar cells by the inkjet printing of silicon-quantum-dot ink. J. Phys. Chem. C 116, 21240–21243 (2012).
Deiner, L. J., Bezerra, C. A. G., Howell, T. G. & Powell, A. S. Digital printing of solid-state lithium-ion batteries. Adv. Eng. Mater. 21, 1900737 (2019).
Park, J. A. et al. Freeform micropatterning of living cells into cell culture medium using direct inkjet printing. Sci. Rep. 7, 1–11 (2017).
Singh, M., Haverinen, H. M., Dhagat, P. & Jabbour, G. E. Inkjet printing-process and its applications. Adv. Mater. 22, 673–685 (2010).
Park, J. & Moon, J. Control of colloidal particle deposit patterns within picoliter droplets ejected by ink-jet printing. Langmuir 22, 3506–3513 (2006).
Kim, J. Y., Cho, K., Ryu, S., Kim, S. Y. & Weon, B. M. Crack formation and prevention in colloidal drops. Sci. Rep. 5, 1–9 (2015).
Park, H. K., Kim, Y., Min, H., Pang, C. & Weon, B. M. Hexagonal deposits of colloidal particles. Phys. Rev. E 100, 022602 (2019).
Liu, W., Midya, J., Kappl, M., Butt, H.-J. & Nikoubashman, A. Segregation in drying binary colloidal droplets. ACS Nano 13, 4972–4979 (2019).
Lilin, P. & Bischofberger, I. Criteria for crack formation and air invasion in drying colloidal suspensions. Langmuir 38, 7442 (2022).
Hatton, B., Mishchenko, L., Davis, S., Sandhage, K. H. & Aizenberg, J. Assembly of large-area, highly ordered, crack-free inverse opal films. Proc. Natl. Acad. Sci. 107, 10354–10359 (2010).
Manoharan, V. N. Colloidal matter: Packing, geometry, and entropy. Science 349, 1253751 (2015).
Pillitteri, S., Lumay, G., Opsomer, E. & Vandewalle, N. From jamming to fast compaction dynamics in granular binary mixtures. Sci. Rep. 9, 1–7 (2019).
Pillitteri, S., Opsomer, E., Lumay, G. & Vandewalle, N. How size ratio and segregation affect the packing of binary granular mixtures. Soft Matter 16, 9094–9100 (2020).
Inoue, K. & Inasawa, S. Positive and negative birefringence in packed films of binary spherical colloidal particles. RSC Adv. 10, 2566–2574 (2020).
Hwang, M.-S. et al. Inkjet-printing of nonsintered alumina-resin hybrid films and their dielectric properties. J. Appl. Phys. 108, 102809 (2010).
Fernandez, F. D. M., Bissannagari, M. & Kim, J. Fully inkjet-printed batio3 capacitive humidity sensor: Microstructural engineering of the humidity sensing layer using bimodal ink. Ceram. Int. 47, 24693–24698 (2021).
Buchheit, R., Kuttich, B., González-García, L. & Kraus, T. Hybrid dielectric films of inkjet-printable core-shell nanoparticles. Adv. Mater. 33, 2103087 (2021).
Yu, Y.-S., Wang, M.-C. & Huang, X. Evaporative deposition of polystyrene microparticles on pdms surface. Sci. Rep. 7, 1–9 (2017).
Cui, L. et al. Suppression of the coffee ring effect by hydrosoluble polymer additives. ACS Appl. Mater. Interfaces 4, 2775–2780 (2012).
Lee, M. et al. Water droplet evaporation from sticky superhydrophobic surfaces. Appl. Phys. Lett. 111, 021603 (2017).
Dicuangco, M., Dash, S., Weibel, J. A. & Garimella, S. V. Effect of superhydrophobic surface morphology on evaporative deposition patterns. Appl. Phys. Lett. 104, 201604 (2014).
Jin, H., Li, Y., Zhang, P., Nie, S. & Gao, N. The investigation of the wetting behavior on the red rose petal. Appl. Phys. Lett. 108, 151605 (2016).
Zhang, C. et al. Spectroscopy-assisted label-free molecular analysis of live cell surface with vertically aligned plasmonic nanopillars. Small 17, 2100161 (2021).
Gustafsson, L., Jansson, R., Hedhammar, M. & van der Wijngaart, W. Structuring of functional spider silk wires, coatings, and sheets by self-assembly on superhydrophobic pillar surfaces. Adv. Mater. 30, 1704325 (2018).
Tan, S. H., Nguyen, N.-T., Chua, Y. C. & Kang, T. G. Oxygen plasma treatment for reducing hydrophobicity of a sealed polydimethylsiloxane microchannel. Biomicrofluidics 4, 032204 (2010).
Tabaei, P. S. E. et al. Comparative study between in-plasma and post-plasma chemical processes occurring at the surface of uhmwpe subjected to medium pressure ar and n2 plasma activation. Polymer 193, 122383 (2020).
Lm, S. J. et al. Hydrophobicity evolution on rough surfaces. Langmuir 36, 689–696 (2020).
Sowade, E., Blaudeck, T. & Baumann, R. R. Inkjet printing of colloidal nanospheres: Engineering the evaporation-driven self-assembly process to form defined layer morphologies. Nanoscale Res. Lett. 10, 1–9 (2015).
Oh, G., Jeong, W., Jung, N., Kang, S. H. & Weon, B. M. Evaporation and deposition of colloidal binary droplets. Phys. Rev. Appl. 17, 024010 (2022).
Gonçalves, M. et al. Droplet evaporation on porous fabric materials. Sci. Rep. 12, 1–11 (2022).
Ren, P. et al. Achieving high-resolution electrohydrodynamic printing of nanowires on elastomeric substrates through surface modification. ACS Appl. Electron. Mater. 3, 192–202 (2020).
Chen, F. et al. Stability of plasma treated superhydrophobic surfaces under different ambient conditions. J. Colloid Interface Sci. 470, 221–228 (2016).
Murakami, T., Kuroda, S.-I. & Osawa, Z. Dynamics of polymeric solid surfaces treated with oxygen plasma: Effect of aging media after plasma treatment. J. Colloid Interface Sci. 202, 37–44 (1998).
Sanchis, M., Calvo, O., Fenollar, O., Garcia, D. & Balart, R. Characterization of the surface changes and the aging effects of low-pressure nitrogen plasma treatment in a polyurethane film. Polym. Test. 27, 75–83 (2008).
Waters, L. J., Finch, C. V., Bhuiyan, A. M. H., Hemming, K. & Mitchell, J. C. Effect of plasma surface treatment of poly (dimethylsiloxane) on the permeation of pharmaceutical compounds. J. Pharm. Anal. 7, 338–342 (2017).
Qin, Y., Alam, A. U., Howlader, M. M., Hu, N.-X. & Deen, M. J. Morphology and electrical properties of inkjet-printed palladium/palladium oxide. J. Mater. Chem. C 5, 1893–1902 (2017).
Kumar, A. & Raj, R. Droplets on microdecorated surfaces: Evolution of the polygonal contact line. Langmuir 33, 4854–4862 (2017).
Xu, L., Davies, S., Schofield, A. B. & Weitz, D. A. Dynamics of drying in 3d porous media. Phys. Rev. Lett. 101, 094502 (2008).
Patil, N. D., Bhardwaj, R. & Sharma, A. Self-sorting of bidispersed colloidal particles near contact line of an evaporating sessile droplet. Langmuir 34, 12058–12070 (2018).
Hu, Y., Zhao, B., Lin, S., Deng, X. & Chen, L. Evaporation and particle deposition of bi-component colloidal droplets on a superhydrophobic surface. Int. J. Heat Mass Transf. 159, 120063 (2020).
Xu, Y. & Chung, D. Increasing the thermal conductivity of boron nitride and aluminum nitride particle epoxy-matrix composites by particle surface treatments. Compos. Interfaces 7, 243–256 (2000).
Yung, K. C. & Liem, H. Enhanced thermal conductivity of boron nitride epoxy-matrix composite through multi-modal particle size mixing. J. Appl. Polym. Sci. 106, 3587–3591 (2007).
He, G., Zhu, L., Liu, M., Fang, Q. & Zhang, L. Optical and electrical properties of plasma-oxidation derived hfo2 gate dielectric films. Appl. Surf. Sci. 253, 3413–3418 (2007).
Acknowledgements
This research was supported by Basic Science Research Program (2016R1D1A1B01007133) and through the National Research Foundation of Korea (NRF) funded by the Ministry of Education (2019R1A6A1A03033215) and the Korea Evaluation Institute of Industrial Technology funded by the Ministry of Trade, Industry and Energy (20000423, Developing core technology of materials and processes for control of rheological properties of nanoink for printed electronics) and the Global Energy Materials Innovator (20194010000290) funded by the Korea Institute of Energy Technology Evaluation and Planning (KETEP).
Author information
Authors and Affiliations
Contributions
H.K., M.G., and B.M.W. conceived the experiments. H.K. and M.G. conducted the experiments. H.K., M.G., B.M.W., and S.H.K. analyzed the results. H.K., M.G., B.M.W., and S.H.K. wrote the main manuscript. All authors reviewed the manuscript.
Corresponding authors
Ethics declarations
Competing interests
The authors declare no competing interests.
Additional information
Publisher's note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Supplementary Information
Rights and permissions
Open Access This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons licence, and indicate if changes were made. The images or other third party material in this article are included in the article's Creative Commons licence, unless indicated otherwise in a credit line to the material. If material is not included in the article's Creative Commons licence and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this licence, visit http://creativecommons.org/licenses/by/4.0/.
About this article
Cite this article
Kim, H., Gonçalves, M., Kang, S.H. et al. High density deposits of binary colloids. Sci Rep 12, 22307 (2022). https://doi.org/10.1038/s41598-022-26151-9
Received:
Accepted:
Published:
DOI: https://doi.org/10.1038/s41598-022-26151-9
Comments
By submitting a comment you agree to abide by our Terms and Community Guidelines. If you find something abusive or that does not comply with our terms or guidelines please flag it as inappropriate.