Abstract
The present study probed the creation of heat energy and concentrating into Newtonian liquids across vertical 3Dheated plates. The role of the Soret and Dufour theories in concentrating and energy formulas is discussed. The role of hybrid nanoparticles is introduced to illustrate particle efficiency in terms of solute and thermal energy. It is removed a viscous dissipation process and a changing magnetic field. The proposed approach is motivated by the need to maximize solute and thermal energy uses in biological and industrial domains. The constructed system of (partial differential equations) PDEs includes concentration, momentum, and thermal energy equations within various thermal characteristics. Transformations are used to formulate the system of (ordinary differential equations) ODEs for solution. To assess various features vs various variables, a Galerkin finite element approach is used. Motion into nanoscale components is shown to be smaller than motion into hybrid nanoparticles. Furthermore, fluctuations in heat energy and solute particle counts are seen in relation to changes in Soret, Eckert, magnetic, and Dufour numbers. The basic finding is that the generation of thermal energy for hybridized nanomaterials is much higher.
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Introduction
Heat transfer is a thermal engineering subject that entails the manufacture, use, conversion, and alternate of warmth power among transportable structures. Heat transfer is split into diverse approaches, which include thermal conduction, thermal convection, thermal radiation, and energy transfer through section changes. Engineers additionally don't forget to shift an extensive variety of chemical compounds (advection mass switch), both bloodless or hot, to attain a heat switch. Although those techniques have unique characteristics, they generally arise concurrently withinside the identical system. Heat alternate happens while the waft of a huge quantity of liquid (fuel line or liquid) contains its warmth in a liquid. All convective approaches additionally transmit partial warmth to the circulation, as well^{1}. Heat switch is one of the maximum vital commercial approaches. Throughout the economic field, warmth ought to be added, subtracted, or eliminated from the distribution of one technique to another. In theory, the heat dissipated through a hot liquid is in no way precisely similar to the heat received through a cold liquid because of the lack of herbal warmth^{2}. Application for heat transfer in commercial manufacturing 99% of manufacturing makes use of a particular technique to transfer heat. Drying approaches are all types of heat transfer. The commercial makes use of heat transfer fluids vary, from simple, dry layouts to superior sized structures that carry out many features withinside the manufacturing technique. As there are numerous versions withinside the layout and alertness of approaches withinside the use of heat transfer fluids, the quantity of industries that use this technique is likewise huge^{3}. Miniaturization has a large effect on the generation of heat exchangers and turns heat exchangers into an extra compact and extra green. The performance of the heat exchanger has an extremely good effect on the general performance and fitness of the thermal power system. The microchannel heat sink is a brand new device in warmth alternate generation. The benefits of a huge heat transfer area and the excessive cohesiveness of a small channel heat sink make it a green warmth exchanger for the usage of electronic cooling^{4}.
Zahra et al.^{5} investigated the effects of thermal radiation heat transfer with a solar system subjected to flow with nanoparticles. Sheikholeslami and Ganji^{6} discussed heat transfer in ferrofluids with nanoparticles exposed to a magnetic field. Zeeshan and Bhargav^{7} investigated the influence of dispersion of and in fluid on heat transfer in the fluid using the molecular dynamics approach. Sajjad et al.^{8} analyzed the influence of the DarcyForchheimer porous medium and nanoparticles on heat transfer in fluid over a moving surface.
A hybrid material is a substance that mixes bodily and chemical properties of various substances concurrently and affords those homes in a homogeneous segment. Synthetic hybrid nanomaterials show off firstrate physicochemical homes that don't exist withinside the character components. An enormous quantity of studies has been finished concerning the homes of those composites^{9} and hybrid substances which include carbon nanotubes (CNTs) had been utilized in electrochemical sensors, biosensors, nanocatalysts, etc.^{10} however the use of those hybrid nanomaterials in nanofluids has now no longer advanced as such. Work on hybrid nanofluids could be very restricted and a whole lot of experimental look continues to be being finished. According to Makishima^{11} while or greater substances are blended so that their aggregate has a specific chemical bond entitled “hybrid metals”. In fact, while or greater metals added the homogeneous segment with simultaneous blending named “hybrid nanofluid". This superior elegance of nanofluids confirmed promising enhancement in heat transfer traits and thermophysical and hydrodynamic homes as compared to unitary nanofluids. Hayat and Nadeem^{12} discovered that the hybrid nanofluid finished nicely with a better warmth switch charge as compared to unitary nanofluid even withinside the presence of heat generation, chemical reaction, and thermal radiation. They found this even as investigating the rotating threed consistent waft of Ag–CuO/water hybrid nanofluid. Selimefendigil and Öztop^{13} compared the thermal overall performance of TiO_{2}, Cu, and Al_{2}O_{3} and located that Cu nanofluids furnished relatively higher results. Azmi et al.^{14} deliberated the hybrid nanofluids thermophysical homes, education methods, a current development, and execution outcomes on heat transfer, friction factor, and stress drop. Minea et al.^{15} mentioned the programs of hybrid nanofluids in solar power with the guidance of a few debates on thermophysical homes and mathematical modeling which include numerical details. Nazir et al.^{16} discussed the role of Williamson liquid in thermal energy and concentration involving hybrid nanoparticles toward melting surfaces via nonFourier’s theory. Dogonchi et al.^{17} analyzed the role of hybrid nanoparticles on the thermal efficiency of fluid between two parallel plates subjected to thermal radiation. Chamkha et al.^{18} published on the simultaneous influence of hybrid nanoparticles, magnetic fields, and rotations of walls on the transfer of heat. Masayebidarched et al.^{19} performed theoretical analysis for the thermal enhancement in fluid with hybrid nanoparticles. Similar works published on the role of hybrid nanoparticles on thermal enhancement can be seen in references^{20,21,22,23,24,25,26,27,28,29,30,31,32}.
To conclude, the latest development on the simultaneous transfer of heat and mass has revealed that compositional gradients are a favorable factor for the transfer heat. Similarly, a temperature gradient is supported to enhance mass transfer in fluids. The transfer of heat due to compositional differences of solute is termed the Dufour effect, whereas the transfer of mass due to temperature gradient is called the Soret effect. These effects have been studied theoretically in recent years. For instance, Hayat and Nawaz^{33} studied the combined effects of temperature and concentration gradients on mixed convection heat and mass transport in partially ion, second grade fluid subjected to a magnetic field. Nawaz et al.^{34} studied the Soret and Dufour effects on heat and mass transfer in an axisymmetric flow between two moving surfaces. Subrat et al.^{35} examined the Soret and Dufour effects on the transport phenomenon in thermochemical flow. Iskandar et al.^{36} analyzed the combined effects of Soret and Dufour due to the suspension of nanosized particles on heat and mass transfer in flow over a moving thin needle. Ambreen et al.^{37} also examined the impact of temperature and concentration gradients.
Recently extensive studies paintings have been completed on the fluid’s dynamics withinside the presence of a magnetic field. The effects of the magnetic discipline on fluids are well worth investigating because of its several packages in a huge variety of fields. The examination of the interplay of the magnetic discipline or the electromagnetic discipline on fluids has been documented, e.g., in nuclear fusion, chemical engineering, medication, and transformer cooling. A magnetic nanofluid (ferrofluid) is a magnetic colloidal suspension along with a base liquid and magnetic nanoparticles with a length variety of 5–15 nm in diameter coated with a surfactant layer Sheikholeslami and Rashidi^{38}, Ganguly et al.^{39} studied the impact of a line dipole on warmth switch enhancement. They located that an enhancement withinside the general heat switch relies upon the internet magnetizing cuttingedge in addition to the relative placement of the dipoles. Parsa et al.^{40} investigated the magnetohemodynamic laminar viscous glide of an accomplishing physiological fluid in a semiporous channel beneath neath a transverse magnetic discipline. Sheikholeslami and Ellahi^{41} studied 3dimensional mesoscopic simulation of magnetic discipline impact on herbal convection of nanofluid. They located that thermal boundary layer thickness growth with growth withinside the Lorentz force. The vortex dynamics in the back of diverse magnetic limitations and traits of warmth switches have been investigated by Zhang and Huang^{42}. They located that the stress drop penalty isn't depending on the interplay parameter. Nanofluid glide and heat transfer traits among horizontal parallel plates in a rotating gadget have been investigated by Sheikholeslami et al.^{43}. They located that the Nusselt range will increase with a growth in nanoparticle quantity fraction and the Reynolds range; however, it decreases with a growth withinside the Eckert range, the magnetic and the rotation parameters. Ghofrani et al.^{44} provided experimental research on pressured convection warmth switch of an aqueous ferrofluid glide passing thru a round copper tube withinside the presence of an alternating magnetic discipline. They located that the impact of the magnetic discipline in low Reynolds numbers is higher, and a most of 27.6% enhancement withinside the convection heat transfer is observed. Sheikholeslami et al.^{45} used lattice Boltzmann simulation (LBM) to simulate nanofluid glide and heat transfer outcomes in a horizontal cylindrical enclosure with an internal triangular cylinder. Rashidi et al.^{46} studied the results of magnetic interplay range, slip component, and relative temperature distinction on velocity and temperature profiles in addition to entropy technology in Magnetohydrodynamic (MHD) glide of a fluid over a rotating disk with variable properties^{47,48,49,50,51,52,53,54,55,56,57}. include new additions that consider conventional and hybrid nanofluids with heat and mass transmission in a variety of physical circumstances.
The unique connections among thermophysical parameters, no previous study on thermal enhancement and mass transposition in threedimensional Newtonian liquids flowing across vertical heated plates have been investigated. It is found that the basis liquids of the hybrid nanofluids tested include copper (Cu), silver (Ag), and water (H_{2}O). Following the similarity approach, numerical solutions are obtained using the robust Galerkin finite element technique for the controlling PDEs system. Hybrid nanofluid passes through vertical heated plates and offers a wide range of industrial applications, including coating and suspensions, cooling of metallic plates, heat exchanger technology, and materials processing. Manufacturing of aerodynamically extruded plastic sheets, the production of paper, heattreated materials were going between feed and windingup rolls, and the cooling of an endless metallic plate in a cooling bath.
For this reason, this research comprises five sections, each of which presents a variety of alternative answers. Section "Flow analysis" lays out the specifics of the issue at hand. Meanwhile, an overview of the numerical approach is provided in section "Numerical method and code validation". Section "Results and discussion" discusses the results. Section "Core points and conclusions" wraps up this investigation.
Flow analysis
The features of thermal energy and solute particles in Newtonian liquid inserting hybrid nanostructures toward a heated vertical surface are considered under the impact of a variable magnetic field. A porous surface is taken to characterize the motion and thermal energy of particles along with the Dufour and Soret influences. The composite of \(Ag\) and \(Cu\) is called a hybrid nanostructure, while \(Ag\) is known as a nanoparticle. The thermal properties of \(Ag\) and \(Cu\) are illustrated in Table 1.
Assumptions of the current problem
Following suppositions and requirements are observed for the mathematical model:

Hybrid nanofluid model

Copper (Cu) and silver (Ag) nanoparticles

Water (H_{2}O)as base fluid

Magnetic field

Porous media

Heat source

Vertical 3Dheated plates
The schematic behavior of the current model is presented in Fig. 1.
In Fig. 1, It noticed that xaxis is taken along vertical direction and yaxis is assumed along horizontal direction while magnetic field is inserted along ydirection. Magnetic field parameter reduces motion of particles. The flow region is exposed by taking a uniform transverse magnetic field and the maximum amount of thermal energy is achieved versus argument values of Eckert number, bouncy parameter and magnetic parameter.
PDEs, describing the problem^{58,59}, can be stated as
For system Eqs. (1)–(5) the BCs are (see for details,^{58,59})
In the above equations, the velocity is \(\left[ {u,v,0} \right]\), \(g^{*}\) denotes the gravitational force, \(\rho {\text{is the fluid density}}\), \(\mu\) is the kinematic viscosity, \(\sigma\) is the electrical conductivity, \(c_{p}\) is called the specific heat, \(k\) is the thermal conductivity, \(D\) is the mass diffusion (coefficient), and \(hnf\) is revealed by the hybrid nanostructures. It should be noted that a uniform magnetic field is taken along the zdirection of the surface while the flow runs due to stretching walls.
Table 1 demonstrates the composite relation between hybrid nanostructures and nanomaterials in polymers, which is called the base fluid.
In Table 1 the following denotes
Next, the similarity transformation is
Consequently, using similarity transformation in Eqs. 1–6, we have
where, the following denotes: (Dufour number) \(Du\), (Eckert number) \(Ec\), Soret number (\(Sr\)), (Schmidt number) \(Sc\), (Prandtl number) \(Pr\), (porous medium parameter) (\({K}^{*}\)), (volumetric thermal expansion number) \({\beta }_{hnf}\), (heat generation) \({\beta }^{*}\), (Grashof number) \({\left(Gr\right)}_{c}\) and (magnetic parameter) \(M\). The dimensionless numbers and defined here
The practical proposed model parameters used in this study are summarized in Table 2.
The surface forces are captured as
Nusselt number is
the rate of mass diffusion is
where, \(Re = \frac{{xU_{w} }}{{\nu_{f} }}\), the Reynolds number.
Numerical method and code validation
The GFEM (Galerkin finite element method)^{60,61,62,63,64} is used via COMSOL Multiphysics calculation software to obtain the solution of the presented problem. The working rules of GFEM are given below:

The residual equations are constructed.

The residual is integrated over the typical element of the discretized domain.

The weighted residual integrals are approximated using the Galerkin approach, and stiffness matrices are derived.

The rules of assembly of elements are followed, and a nonlinear system of equations is linearized. The linearized system is solved under computational tolerances \(10^{  3}\).

The convergence is checked, and gridindependent results are obtained. The criterion of error analysis is used.
$$\left {\frac{{\eta_{i + 1}  \eta_{i} }}{{\eta^{i} }}} \right < 10^{  5} .$$(15) 
Table 3 reveals the investigation of meshfree;

Convergence analysis is confirmed via 300 elements.
In examples, a parametric study is elaborated to study heat energy and mass transfer in 3D flow of Newtonian fluid, showing the influences of heat generation, porous medium, viscous dissipation, temperature gradient, rate of mass diffusion and Joule heating.
It is remarked that the current study's findings are approximated using GFEM. Table 4 shows a validation of results using the Nusselt number in the case of nanofluids (Table 5).
The Prandtl number decreases with the nano and hybrid particle volume fraction, whereas the Brownian motion parameter and the thermophoresis parameter increase with the nanoparticle volume fraction in Integral treatment for forced convection heat and mass transfer of nanofluids 300. It's interesting to note that the variation of the Lewis number has a varied pattern for different nanoparticles. In the case of Ag and Cu nano and hybrid nanoparticles, the Lewis number decreases as the nanoparticle volume percentage increases. As a result, for a fixed reference temperature (T) and a specified size of nano and hybrid particles. Furthermore, the density of the nanoparticles is usually substantially higher than that of the basic fluid. As a result, adding heavy nanoparticles will increase the density of the resulting hybrid nanofluid, and increasing the volume fraction of nanoparticles will simultaneously increase the dynamic viscosity and density.
Results and discussion
The aspect of heat energy and mass diffusion in Newtonian fluid flow over a surface with temperature (variable) and wall concentration (variable) is modeled, and a coupled mathematical model is solved numerically using the GFEM. The parameter \(\beta\) is called the flow fluid parameter; it determines the rheological behavior under yield stress. Yield stress is the characteristic by which fluid resists deformation until a certain amount of applied stress is reached. As the yield stress increases, the fluid’s ability to resist the applied stress attains its equilibrium state; therefore, a decrease in the velocity field (in both the \(x\) and \(y\) components) is observed (see Figs. 2 and 3).
Various numerical experiments are performed with different samples of parametric values. Some crucial observations are obtained from the numerical experiments. It is important to note that dashed curves are associated with flow, heat transfer and mass diffusion in nanofluids (Cunanofluids), whereas solid curves are associated with flow, heat transfer and mass transport in hybrid nanofluids (Cu Ag nanofluids). The increase in the magnitude of the resistive force is captured first. Obviously, the flow in both the \(x\) and \(y\) directions decelerates; see Figs. 4 and 5). Moreover, the parameter \(k^{*}\) associated with porous medium resistivity against the flow of fluid and its impact on the motion of fluid particles is shown in Figs. 6, and 7 decreasing velocity behavior can be seen in Figs. 6 and 7. These figures also show that the hybrid nanofluid experiences more resistance to the porous medium than the mono nanofluid. The viscous region for nanofluids is wider than that for hybrid nanofluids.
Role of magnetic field versus fluid flow
The direct relation is addressed to the magnetic field and Lorentz force. The influence of the Lorentz force on flow can be determined by the variation in \(M\). The large values of \(M\) increase the opposing effect of the Lorentzian force. Therefore, flow experiences retardation due to the Lorentz force. (See Figs. 6 and 7). Thus, BLT is approached by varying the magnetic field (the intensity of applied). It is also noted that the Lorentz force for the case of flow of the Cu Ag nanofluids is greater than the Lorentz force in the case of flow of the Cunanofluid.
Temperature field versus variation of crucial model parameters
The effects of \(Du, \left( {Gr} \right)_{t} ,M\), \(Pr\), \(\beta^{*}\), and \(Ec\) versus thermal energy for both nanofluids (\(Cu\) nanofluids) and hybrid nanofluids (Cu Ag nanofluids) are examined. The observed influence of these parameters is shown in Figs. 8, 9. The parameter \(Du\) is called Dufour number. It appears in the dimensionless form of the energy equation when the transcript of thermal energy due to the concentration gradient is taken into account. It measures the transfer of heat energy due to compositional differences caused by nanoparticles and solute diffused in the fluid. The effects of \(Du\) on the temperature of the \(Cu\) nanofluid and Cu Ag hybrid nanofluid are shown in Fig. 8. The temperature of both types of fluids has an increasing tendency as a function of \(Du\). The influence of \(Du\) on the temperature of the Cu nanofluid is smaller than that on the temperature of the Cu Ag nanofluids. The effects of the buoyancy force on the temperature of the Cunanofluid and Cu Ag nanofluids are represented by Fig. 9. \(\left( {Gr} \right)_{ \in } > 0\) is the case when the buoyancy force is positive, and flow is assisted by this force. However, \(\left( {Gr} \right)_{t} < 0\) in the case when the buoyancy force is negative, the flow in this case is called opposing flow.
Wall shear stresses, heat transfer rate and mass flux
Numerical data related to wall shear stresses in the \(x\) and \(y\)directions, wall heat transfer rate and wall mass flux for both types of fluids, \(Cu\) fluid (mono nanofluid) and \(Cu\) \(Ag\) fluid (hybrid nanofluid), are investigated versus the variation in key parameters, \(k^{*}\), \(Du\), \(Sr\) and \(Sc\) (see Table 6). The numerical outcomes are summarized in Table 6. It appears that \(k^{*}\) is inversely proportional to the voids present in the porous medium. Hence, the resistive force per unit area (stress) increases. Therefore, wall shear stresses in both the \(x\) and \(y\)directions are increasing functions of \(k^{*}\). The temperature gradient and mass flux are both decreasing functions of \(k^{*}\). It is also observed that wall shear stress increases when \(Du\) is increased. On the other hand, a rise in wall mass flux against \(Du\) is noted. Finally, the temperature gradient on solute particles is determined by \(Sr\), and an increase in \(Sr\) causes a decrease in wall shear stress. However, the opposite trend is noted for \(Sc\).
Core points and conclusions
The features of heat energy and mass diffusion, which play essential roles in the behaviour of nanoparticles and hybrid nanostructures, are addressed over the vertical 3D melting surface. Newtonian fluid is considered under simultaneous influences of heat generation, porous medium, viscous dissipation, temperature gradient, rate of mass diffusion, and Joule heating. The mathematical modelling is solved using the famous FEM. The prime findings are listed below:

1.
The convergence of the proposed problem is confirmed for finite element mesh density equal to 300.

2.
The magnetic field reduces the motion of both nanoparticles and hybrid nanostructures, where the effect on hybrid nanofluid is more significant than on nanofluid.

3.
The Dufour number amplified the temperature of both hybrid nanofluid and nanofluid while the temperature for hybrid nanofluid is higher than nanofluid.

4.
The temperature for both fluids diminish as the buoyancy force acts onto the system.

5.
The joule heating parameter intensified the temperature for both fluids, and hybrid nanofluid is stronger than nanofluid.

6.
The Prandtl number decreases the temperature profile for both fluids, but the temperature for hybrid nanofluid is slightly higher than nanofluid.

7.
The temperature profile for both fluids increases when the heat generation and viscous dissipation act onto the system.

8.
The temperature gradient increased the concentration for both fluids, while the diffusion parameter decreased the concentration for both fluids.

9.
Wall shear stress amplified with the porous medium parameter, Dufour number and diffusion parameter but the wall shear stress decrease for the temperature gradient parameter. The mass wall flux rises with the Dufour number and decreases the wall shear stress, while heat transfer rate and mass flux decrease as the porous medium parameter increases.
The Galerkin finite element method could be applied to a variety of physical and technical challenges in the future^{67,68,69,70,71,72,73,74,75,76,77}.
Change history
15 April 2024
This article has been retracted. Please see the Retraction Notice for more detail: https://doi.org/10.1038/s41598024591241
Abbreviations
 Du :

Dufour number
 T :

Temperature of nanofluid
 T _{∞} :

Ambient temperature
 g*:

Gravitational force
 u, v :

Velocity component in \(x\), \(y\) direction \(\left( {m{ }s^{  1} } \right)\)
 D :

Mass diffusion (coefficient)
 Ec :

Eckert number
 k :

Thermal conductivity
 \(x,y,z\) :

Dimensional space coordinates \(\left( m \right)\)
 Pr :

Prandtl number
 Sr :

Soret number
 Sc :

Schmidt number
 K* :

Porous medium parameter
 C _{fx} :

Surface force
 Re :

Reynolds number
 M :

Magnetic parameter
 GFEM:

Galerkin finite element method
 Nu :

Nusselt number
 PDEs:

Partial differential equations
 Ag:

Silevr
 Cu:

Copper
 Sh :

Rate of mass diffusion
 H_{2}O:

Water
 \(k\) :

Thermal conductivity (W m^{1} K^{1})
 q_{w} :

Wall heat flux
 \(h_{nf}\) :

Hybrid nanoparticles
 ρ :

Density
 β * :

Heat source
 ρc_{p} :

Heat capacity
 ϕ :

Volume fractions
 \(\sigma\) :

Electrically conductivity (Ω m) ^{−1}
 \(D_{hnf}\) :

Thermal diffusivity of the hybrid nanofluid
 \(\beta_{hnf}\) :

Volumetric thermal expansion number
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M.B.H. and M.K. formulated and solved the problem. M.B.H., M.K., H.S., A.A.P. and M.A., computed and scrutinized the results. All the authors equally contributed in writing and proof reading of the paper. All authors reviewed the manuscript.
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Hafeez, M.B., Krawczuk, M., Shahzad, H. et al. RETRACTED ARTICLE: Simulation of hybridized nanofluids flowing and heat transfer enhancement via 3D vertical heated plate using finite element technique. Sci Rep 12, 11658 (2022). https://doi.org/10.1038/s41598022155605
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DOI: https://doi.org/10.1038/s41598022155605
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