Experimental signatures of nodeless multiband superconductivity in a \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\hbox {2H-Pd}_{0.08} \hbox {TaSe}_2$$\end{document}2H-Pd0.08TaSe2 single crystal

In order to understand the superconducting gap nature of a \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\hbox {2H-Pd}_{0.08} \hbox {TaSe}_2$$\end{document}2H-Pd0.08TaSe2 single crystal with \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$T_{c} = 3.13 \text { K}$$\end{document}Tc=3.13K, in-plane thermal conductivity \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\kappa $$\end{document}κ, in-plane London penetration depth \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\lambda _{\text {L}}$$\end{document}λL, and the upper critical fields \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$H_{c2}$$\end{document}Hc2 have been investigated. At zero magnetic field, it is found that no residual linear term \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\kappa _{0}/T$$\end{document}κ0/T exists and \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\lambda _{\text {L}}$$\end{document}λL follows a power-law \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$T^n$$\end{document}Tn (T: temperature) with n = 2.66 at \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$T \le \frac{1}{3}T_c$$\end{document}T≤13Tc, supporting nodeless superconductivity. Moreover, the magnetic-field dependence of \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\kappa _{0}$$\end{document}κ0/T clearly shows a shoulder-like feature at a low field region. The temperature dependent \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$H_{c2}$$\end{document}Hc2 curves for both in-plane and out-of-plane field directions exhibit clear upward curvatures near \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$T_c$$\end{document}Tc, consistent with the shape predicted by the two-band theory and the anisotropy ratio between the \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$H_{c2}$$\end{document}Hc2(T) curves exhibits strong temperature-dependence. All these results coherently suggest that \documentclass[12pt]{minimal} \usepackage{amsmath} \usepackage{wasysym} \usepackage{amsfonts} \usepackage{amssymb} \usepackage{amsbsy} \usepackage{mathrsfs} \usepackage{upgreek} \setlength{\oddsidemargin}{-69pt} \begin{document}$$\hbox {2H-Pd}_{0.08} \hbox {TaSe}_2$$\end{document}2H-Pd0.08TaSe2 is a nodeless, multiband superconductor.

Multiband superconductivity (MBSC), which features multiple superconducting gaps at various Fermi surfaces, has become one of common properties observed in numerous superconductors. The possibility for the MBSC was first discussed in theoretical studies, in which the single-band BCS theory 1 has been generalized into the case of multi-band superconductivity 2,3 . The first experimental signature was indeed found in early 1980s when a tunneling spectroscopy study revealed two superconducting gaps in a doped SrTiO 3 system 4 . Various other experimental probes such as upper critical fields ( H c2 ), heat capacity ( C p ), and thermal conductivity ( κ ) measurements have also verified characteristic signatures of the MBSC in the doped SrTiO 3 system 5 . The discovery of MgB 2 has brought renewed attention on the physics of MBSC as the material exhibits an unusually high superconducting transition temperature ( T c ≃ 39 K ) associated with the two BCS-type superconducting gaps. More recently, experimental signatures for the MBSC have been also observed in iron-based superconductors 6 , in which sign-changing, nodeless gaps exhibit as many as five different electron and hole pockets 7 . Moreover, it has been recently suggested that even sulfur hydrides exhibiting T c ≃ 203 K at a high pressure 155 GPa could be also associated with the MBSC 8,9 . Therefore, investigations on the possible MBSC in various superconducting materials may provide deeper insight for understanding the pairing mechanism and the pairing symmetry, and even a clue to reach a higher T c .
Transition metal dichalcogenides (TMDs) with the chemical formula MX 2 , where M is a transition metal atom (such as Mo, Ta, or Nb) and X is a chalcogen atom (such as Se or S), and have been known since 1960s 10 . Atomically thin layers of TMDs, being mostly direct band-gap insulators, can find applications in novel electronic, optical, and spintronic devices due to their high electron mobility 11 . Physical properties of TMDs can be tuned by various physical parameters to exhibit the interplay and the correlation between various electronic orders 12,13 . As a number of layers increase, the direct band gap quenches and metallic behavior emerges. The most common structural form of the three dimensional TMDs resulted from stacking of thin two dimensional layers has either a octahedral (1T) (such as MoS 2 or WS 2 ) or a trigonal prismatic (2H) (such as NbS 2 , NbSe 2 ,

Results and discussions
Structure and superconducting properties of a 2H-Pd 0.08 TaSe 2 single crystal. Figure 1a presents the 2H-crystal structure of TaSe 2 , in which a pair of two 1H-TaSe 2 layers form one unit cell. In each 1H-TaSe 2 layer, Ta ions are located in the center of a trigonal prism ( D h 3 symmetry) created by six Se ions and form a strong in-plane bonding with neighboring Se ions. In the 2H-structure, each 1H-TaSe 2 layer is rotated by 180 • along the c-axis without in-plane translation, resulting in weak interlayer Se-Se bonding of the van der Waals type along the c-axis. Pd ions are intercalated between the Se-Se ions and join a new bonding between neighboring Se ions (see black dashed line). This bonding can contribute to enhance the interlayer interaction even though both aand c-lattice constants are known to increase due to the steric nature of Pd intercalation 23 . As a result, according to the lattice parameters replotted from our previous work 23 , both a and c increase systematically with the Pd concentration x (Fig. 1b,c). On the other hand, the c/a ratio decreases systematically with x (Fig. 1d).
For the study in this work,a 2H-Pd 0.08 TaSe 2 single crystal has been grown by the chemical vapor transport method, which provides a relatively wide ab-plane with a typical lateral area 1.0 mm × 0.2 mm (see, a photo in the inset of Fig. 1e). When an X-ray beam is shined on the ab-plane, only (00l) reflections from the X-ray diffraction (XRD) pattern (inset of Fig. 1e) are found, indicating that the crystal layers are well formed along the c-axis. To extract accurately the lattice constants of the crystal, many pieces of the 2H-Pd 0.08 TaSe 2 single crystals (a total of ∼ 8 mg) collected from the same growth batch were ground and measured by θ − 2θ scans. An XRD pattern of the ground crystals (black dot) and the Rietveld refinement result (red line) from the FullProf software are shown in Fig. 1e. The refinement considering a preferrential orientation could well reproduce the XRD pattern, resulting in R wp = 22.1 and χ 2 = 4.06. The refined a-and c-values correspond to 3.4408 Å and 12.744 Å, respectively, which are again plotted in Fig. 1b,c together with the calculated c/a value (Fig. 1d). The lattice constants and the c/a ratio (red stars) from the single crystal are close to the expected values in the polycrystalline data, indicating successful intercalation of ∼ 8% Pd into the region between the 1H-TaSe 2 layers. Figure 2a displays temperature-dependence of in-plane resistivity ρ in the 2H-Pd 0.08 TaSe 2 single crystal at zero magnetic field. ρ starts to drop near an onset transition temperature, T on c = 3.3 K and goes to zero below T 0 c = 3.0 K with a transition width δT c = T on c − T 0 c = 0.3 K . T c is defined by the criterion of 0.5ρ N ( ρ N : normalstate resistivity) to reduce the effects of vortex motion (0.1ρ N criterion) and superconducting fluctuation (0.9ρ N criterion) 25 . Note that ρ in a temperature window between 4 and 30 K can be well fitted with a power-law; ρ = ρ 0 + A T 2 with ρ 0 = 0.149 m cm , indicating the Fermi-liquid behavior. Figure 2b shows the temperature dependence of 4πχ measured at H = 10 Oe ( H ab ) upon warming after applying zero-field-cooling (ZFC) and field-cooling (FC) conditions. The onset temperature for a diamagnetic signal ( ∼ 3.0 K) agrees well with T 0 c = 3.0 K. At 1.9 K, 4πχ (chi: magnetic susceptibility)reaches − 0.93, exhibiting a nearly complete Meissner shielding expected in a bulk superconductor.
Evidence for multiband superconductivity from the upper critical fields. General 26 . This is called as the Pauli-limiting effect. At the Pauli-limited upper critical field at zero temperature ( H P c2 (0) ), a Zeeman splitting energy is same as a superconducting condensation energy, i.e. 1 2 Here, 0 is a superconducting gap at T = 0 , χ P = gµ 2 B N F is the Pauli spin susceptibility in the normal state, N F is the density of states at the Fermi energy, and g is the Lande g factor. On the other hand, the orbital-limiting effect is related to supercurrents around the vortices. At the orbital-limited upper critical field at zero temperature ( H orb c2 (0) ), a total kinetic energy of supercurrents around vortex cores exceeds a superconducting condensation energy. This effect is accompanied by an overlap between normal-state vortex cores, leading to µ 0 H orb c2 (0) = φ 0 /2πξ 2 , where φ 0 = 2.07 × 10 −7 Oe cm 2 is the flux quantum and ξ is a coherence length 27 .
The Werthamer-Helfand-Hohenberg (WHH) model for a single-band, dirty-limit superconductor involving both of these limiting effects can be applied to determine the H c2 -T relationship 27 ; show the evolution of lattice parameters a and c, respectively, with Pd intercalation ratio (x), which are replotted from the results by Bhoi et al. 23 . The corresponding values obtained from the refinement of the XRD data on the ground Pd 0.08 TaSe 2 crystals are also plotted as red stars. (d) The calculated c/a ratio based on the data in (b) and (c). The black dashed lines in (b)-(c) refer to the linear guide to eyes. The inset of (e) shows an XRD pattern measured on the ab-plane of a 2H-Pd 0.08 TaSe 2 single crystal and a photo of the crystal piece ( ∼ 1.0 × 0.2 mm 2 ) lying on a graph paper with one unit of 1 mm. (e) An XRD pattern of the ground crystal (black dot), the Rietveld refinement result (red line) with R wp =22.1 and χ 2 =4.06, and their subtracted pattern (blue line) along with the expected XRD peak positions (green ticks).

Se S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S S
is the Maki parameter, and so is a spin-orbit scattering constant 25,27 . H c2 from Eq. (1) for both field directions exhibit linear temperature-dependence just below T c , followed by a saturating behavior with a concave functional form at low temperatures.
However, H c2 (T) curves of multiband superconductors such as MgB 2 28 and several iron-based superconductors 25,29 display a convex function just below T c . MgB 2 even shows a rapid increase of H c2 near T = 0 28 , which is distinct from the behavior described by Eq. (1). This discrepancy is remedied by the two-band model developed for a dirty-limit superconductor with negligible interband coupling 28 ; w h e r e a 0 = 2( 11 22 − 12 21 ) , 12 21 ] 1/2 , h = H c2 D 1 /2φ 0 T , t = T/T c , and η = D 2 /D 1 . 11 and 22 are intraband BCS coupling constants, 12 and 21 are interband BCS coupling constants, D i is in-plane diffusivity of an ith band, and U(x) = �(x + 1/2) − �(x) where �(x) is the digamma function. This Eq. (2) has successfully described the H c2 behavior of numerous multiband superconductors 28,30 .
(1) www.nature.com/scientificreports/ Application to the experimental data. The ρ curves of 2H-Pd 0.08 TaSe 2 are obtained for magnetic fields parallel to the ab-plane (H ab ) and to the c-axis (H c), as presented in Fig. 3a,b, respectively. In both directions, ρ exhibits negligible magnetoresistance in the normal state so that ρ N stays nearly at the same value 0.149 m cm . With increase in H, the superconducting transition systematically shifts toward lower temperatures in both directions. Moreover, one can observe the broadening of the superconducting transition with increase of H; The increasing rate of the transition width is higher for H c than for H ab . Such anisotroic broadening has been commonly observed in numerous type-II superconductors, indicating that anisotropic thermal fluctuation of the vortex state plays a role in the transition broadening process at a high H region. According to the mean-field theory of type-II superconductors, owing to thermal fluctuation, the vortexlattice to the normal-state transition at H c2 changes into a crossover from the vortex liquid to the normal state, and the vortex-liquid state freezes into the vortex-lattice state at a lower melting field than H c2 31 . In a low field region, the extent of the vortex-liquid region is quantatively characterized by the Ginzburg-Levanyuk number, Gi, which is expressed by the material specific paramters as Gi = 0.5 (8π2 2 L k B T c /φ 2 ξ c0 ) 2 , where k B is the Boltzmann constant, and ξ c0 is a coherence length along the c axis 31 . At sufficiently high H where the cyclotron radius of Cooper pair r 0 = (φ 0 /2πH) 1/2 becomes shorter than the coherence length ξ ab0 32 , situation becomes quite different. In the field range H > GiH ′ c2 T c , the fluctuation broadening is indeed proportional to the fielddependent Ginzburg-Levanyuk number, Gi( Fig. 3c), the field limit of GiH ′ c2 T c is lower in the case of H c so that the transition broadening should become larger. Our experimental results are quite consistent with these theoretical consideration, supporting that the transition broadening at high H region is mainly caused by the thermal fluctuation of vortex states.
To find a clue on the pair-breaking mechanism, H c2 values were determined from the results in Fig. 3a,b. Note that the error bars in the determined H c2 values with the 0.5ρ N criterion are less than the symbol size. In our former study, the H c2 (T) curves of a single crystal 2H-Pd 0.08 TaSe 2 were investigaed up to 9 T and down to    Fig. 3c, we first attempted to fit µ 0 H ab c2 (T) and µ 0 H c c2 (T) with Eq. (1), assuming α = 0 (a case for a pure orbital limiting) and so = 0 (a case without the spin-orbit effect). However, the data could not be fitted well (dashed lines). The H c2 curves from Eq. (1) exhibit a linear temperature-dependence just below T c in both field directions, followed by a saturating behavior with a concave shape at lower temperatures. The fitting results are inconsistent with the µ 0 H ab c2 (T) and the µ 0 H c c2 (T) curves, both of which display a convex shape just below T c .
The multiband effect is also corroborated by temperature dependence of the anisotropy ratio between the upper critical fields, γ H = H ab c2 /H c c2 as shown in Fig. 3d. Upon temperature being lowered, the γ H values (solid green triangles) increase rapidly near T c from ∼ 4 to reach a maximum value of ∼ 6.0 at 2.7 K, and slowly decreases to become a nearly constant value of ∼ 5.5 below 1.7 K. This kind of strong temperature dependence in γ H has been similarly observed in other multiband superconductors, e.g. MgB 2 28 and several iron-based superconductors 29,30 , supporting firmly that 2H-Pd 0.08 TaSe 2 is also a multiband superconductor.
Evidence for multiband superconductivity: temperature dependence of in-plane London penetration depth. Magnetic force microscopy (MFM) offers a unique opportunity to extract an absolute value of the in-plane London penetration depth ( L ) 34 . The so-called comparative method measures a repulsive force between a magnetic tip and a sample and compares it with that between the tip and a standard sample (Nb). The force shifts a resonance frequency of the tip, which is depicted in Fig. 4. The magnetic tip was slowly lowered towards the ab surface of the superconducting 2H-Pd 0.08 TaSe 2 crystal at T = 0.5 K , which imposes an increasingly strong repulsive Meissner force onto the tip (blue solid line). This Meissner force curve is then compared to that of a well-characterized Nb film with L,Nb = 110 nm (black solid line), measured under the same condition. Any difference in L manifests itself as a horizontal shift between the two curves. It is found that once shifted to the higher value by 700 nm, the Meissner force curve well overlaps with that for Nb in a wide range of the tip-sample distance (red dashed line). It is estimated that L (0.  www.nature.com/scientificreports/ 0.5 K. A uniform Meissner force is observed in the entire region except a small defect at the upper left corner, indicating homogeneous superfluid density. Temperature dependence of L , L (T) , is presented at low temperatures below 1.25 K in Fig. 4b. We first attempted to fit L (T) with the single-band BCS superconductor model 35 , which is given as . Following a common practice, the fitting was performed up to 1.04 K ( ≃ 1 3 T c ) to minimize the thermal fluctuation effects. The resultant best fit is drawn as a green dashed line, which is clearly inconsistent with the experimental data. Even the obtained parameter 0 = 0.60k B T c is far from the single-band BCS scenario with 0 = 1.76k B T c 1 . Hence, the single-band BCS formula cannot explain the L (T) behavior.
As the single-band BCS fitting is not satisfactory, we carried out a power-law fitting with L (T) = L (0) + AT n (red dashed line), again up to 1.04 K ( ≃ 1 3 T c ). The power law fit resulted in a good match with the experimental data when L (0) = 760 nm and the exponent n = 2.66 . We first discuss the meaning of the obtained exponent. The superconductor with a clean s-wave gap symmetry in the absence of any nodal structure follows the behavior often producing an exponent n >∼ 3 − −4 in the power-law fitting scheme 36 . In the presence of impurities, however, a high value of the power exponent often becomes smaller due to the increased quasiparticle density of states inside the superconducting gap 37 . For example, theoretical studies have shown that such modified density of states due to nonmagnetic impurities change the exponential behavior ( n >∼ 3 − −4 ) to n = 2 in the case of the Fe-based superconductors with sign changing s-wave gaps, i.e, s +− state 36,37 In the experiments of Ba 1−x K x Fe 2 As 2 where a well-defined s +− superconducting gap is likely stabilized, n=∼ 2.7-4 has been indeed observed in the range of 0.32 ≤ x ≤ 0.47 . Even for a conventional BCS superconductor SrPd 2 Ge 2 with T c ≃ 2.7 K comparable to our T c ≃ 3.1 K , the exponent n = 2.7 , being similar to our results, has been found 38 . Therefore, our exponent n = 2.66 support the nodeless superconducting gap structure.
It should be also noted that a clean superconductor with line nodes is theoretically predicted to have n = 1 , e.g. high-T c cuprates with the d-wave gap symmetry 39 . When nonmagnetic impurity scattering exists in the superconductors with the line node, the exponent n was indeed varied from 1.0 toward 2.0 but it was mostly less than 2.0. For example, Zn-doped YBa 2 Cu 3 O 6.95 showed gradual changes of n from 1.13 to 1.75 when the Zn doping into the Cu sites changed from 0 to 0.31% 40 . Therefore, our exponent n = 2.66 clearly rules out the possibility of superconducting gap state with the nodal lines 36,41 .
To check the validity of the experimentally obtained L (0) , we herein attempt to calculate L (0) using the parameters obtained from the two-band fitting of H c2 and the heat capacity measurement 23 . The London equation for a two-band superconductor is given by 42 where N 1 and N 2 are the electron densities of states. 1 and 2 are the gap magnitudes. D 1 and D 2 are the intraband diffusivities. N 1 , N 2 , 1 and 2 could be derived from the heat capacity measurements, which yields N 1 = 1.51 states/eV f.u., N 2 = 0.65 states/cell eV f.u., 1 = 0.49 meV, and 2 = 0.16 meV with a unit cell volume of V = 87.7$AA 3 . From the H c2 measurements, the diffusivities are derived as D 1 = 1.54 cm 2 /s, D 2 = 4.59 cm 2 /s, If we combine those parameters, we obtain L (0) ≃ 752 nm, which is similar to the measured L (0) = 760 nm . This results corroborate that the experimentally determined values such as L (0) , diffusivities, superconducting gaps, and density of states are consistent each other. Furthermore, the ratio L (0)/ξ ab0 = 67 ≫ 1 from the fitting parameter L (0) = 760 nm and ξ ab0 = 11.4 nm indicates that type-II superconductivity is realized in 2H-Pd 0.08 TaSe 2 .
Evidence for multiband superconductivity: temperature and magnetic-field dependence of thermal conductivity. General behavior of thermal conductivity of a superconductor. Thermal conductivity of a material κ is described by a sum of each ith heat-transferring carrier κ i , i.e. κ = i κ i . The κ i within a semiclassical approach considering the gapless excitation is generally written as 35 where c i , v i , and l i are specific heat, average velocity, and mean free path of the ith heat-transferring carrier, respectively. Equation (4) can be applicable to any type of heat carriers such as phonons and electrons.
The phononic thermal conductivity κ ph from Eq. (4) is given by where β = 12π 4 zR/5θ 3 D is related to the coefficient from the phononic specific heat as c ph = βT 3 , v ph is a mean velocity of acoustic phonons, θ D is the Debye temperature, z is the number of atoms per formula unit (in this case, z = 3 ), R is the ideal gas constant, and l ph is a phononic mean free path 35 . When phonons are scattered at a rough sample boundary (diffuse scattering limit), it is known that the l ph is limited to the temperature-independent, characteristic sample dimension and thus κ ph /T is proportional to T 243 . However, at low-temperatures, the average phonon wavelength increases to make the surface of given roughness apparently look smoother to result in the so-called specular reflection regime 43 , which renders l ph to be varied with a certain power of T, leading to κ ph /T ≃ T n−143, 44 .
The electronic thermal conductivity κ N is expressed with the specific heat of electrons c e = π 2 N F k 2 B T/3: where c e , v F , l e , τ , n, and m * parameters refer to specific heat, Fermi velocity, mean free path, scattering time, carrier density, and effective mass of electrons, respectively. It is noted that κ N /T is independent of T. According to the Wiedemann-Franz law 35 , ρ N = m * /ne 2 τ leads us to estimate κ N /T = L 0 /ρ N where L 0 = π 2 k 2 B /3e 2 = 2.44 ×10 −8 W /K 2 is the Lorenz number. Then, κ/T is as the sum of T-independent ( κ N /T ) and κ ph /T ≃ T n−1 in the normal state.
In a superconducting state, we may describe κ/T by a power-law, but the term associated with electrons should be replaced by that for quasiparticles ( κ 0 /T ). The κ 0 of nodeless superconductors is not simply expressed by Eq. (4) as the equation is built on the assumption of gapless states 45 . At T ≪ T c without H, the κ 0 /T is given by (� 0 /T) 2 exp (−� 0 /k B T) , thereby resulting in κ 0 /T → 0 as T approaches 0 K 35 . This is consistent with the observation that heat is not transferred by the cooper pairs as verified in single-band nodeless superconductors, e.g. Nb 46 and multiband nodeless superconductors, e.g. 2H-NbSe 2 17 .
In sharp contrast, nodal superconductors have a non-zero κ 0 /T in the zero temperature limit. This behavior is attributed to the quasiparticles that can be excited at the nodes even at zero temperature 39 . The κ 0 /T is given by are the density of states at energy E 45 . With the presence of non-magnetic impurities, κ 0 /T is known to approach a finite value, irrelevant to the impurity scattering rate. This is experimentally verified in nodal superconductors, e.g. YBa 2 Cu 3 O 6.9 45,47 .
The magnetic-field dependence of κ(H)/T relies especially on the κ 0 (H)/T since κ ph /T is almost unchanged by H. κ 0 (H)/T can be understood by two mechanisms: the Volovik effect 48 and the quasiparticle tunneling effect 49 . The former involves a quasiparticle energy shift δE ≃ v s · p due to supercurrents around vortices, where v s and p are a velocity of the supercurrents and a momentum of the quasiparticles, respectively. On the other hand, the latter is related to intervortex spacing which is given by d = √ φ 0 /H 35 . Smaller d promotes the tunneling of localized quasiparticles between adjacent vortices 48 ; the quasiparticles are then delocalized, leading to a finite κ 0 (H)/T.
In the nodeless single-band superconductors, most of the quasiparticles are confined in a vortex and cannot be subject to the supercurrent outside the vortex. This results in negligible Volovik effect 48 . Therefore, the quasiparticle tunneling effect mainly governs the κ 0 (H)/T behavior of nodeless single-band superconductors. More specifically, the quasiparticle tunneling effect contributes to increase of κ 0 (H)/T under magnetic fields. For example, near H ≃ H c2 , κ 0 (H)/T is sharply increased due to overlapping of vortices and reaches its normal-state value κ N /T . This sharply increasing behavior of κ 0 (H)/T near H ≃ H c2 is often observed in the nodeless singleband superconductors such as Nb 46 and InBi 50 , and is also applied to the multiband nodeless superconductors 51 .
At low H region, on the other hand, nodeless multiband superconductors exhibit a characteristic increase of κ 0 (H)/T , forming a shoulder-like feature 52 . In general, multiband nodeless superconductors can have different gap amplitudes, forming approximately two major gaps S and L , where 'S' and 'L' denote the smaller and the larger gaps. Under H higher than the characteristic field H * ≃ 2 S , the superconductivity due to S is suppressed and the quasiparticles are then delocalized across the S , resulting in the enhanced κ 0 (H)/T due to the Volovik effect of the delocalized quasiparticles. Such an enhanced κ 0 (H)/T at a low H region, forming a shoulder-like feature, has been observed in numerous multiband, nodeless superconductors such as MgB 2 51 and several ironbased superconductors 6,53 .
In contrast, the κ 0 (H)/T of nodal superconductors exhibits behavior distinct from that of nodeless superconductors. The quasiparticles of the nodal superconductors can be stabilized even outside the vortex core because of the gapless quasiparticle excitation at the node. The delocalized quasiparticles then result in shift of their energy and even N(E) by the Volovik effect. For example, this effect yields N(E) → N(E + δE) ≃ (E + δE)N F /� 0 in d-wave superconductors. The energy shift δE averaged around the vortex is approximately given by ≃ √ H 48 , resulting in κ 0 (H)/T ≃ N(0) ≃ √ H . This relation was experimentally confirmed by dirty d-wave superconductors, e.g. Tl m Ba 2 Ca n−1 Cu n O 6+δ (m=2 and n=1) (Tl-2201) 54 .
Applications to the experimental data. In-plane thermal conductivity κ of the 2H-Pd 0.08 TaSe 2 single crystal was measured down to 100 mK at various magnetic fields. Figure 5 presents temperature dependence of κ/T . We fit the data with a generic relation κ/T = κ 0 /T + aT n−1 to extract κ 0 /T and n at zero and finite magnetic fields below 200 mK. At zero magnetic field, κ 0 /T = 1.54 ± 4.68 µW/K 2 cm and the exponent n = 2 are obtained. The deviation of the n from 3 immediately supports the occurrence of the specular reflection at the boundary in this low temperature region 43 . More importantly, it should be noted that [κ 0 /T]/[κ N /T] = 1 % is much smaller than the value expected in a nodal superconductor. Here, κ N /T = 163 µW/K 2 cm is the estimated normal state value by the Wiedemann-Franz law and the normal state resistivity ρ N = 1.49 × 10 −4 � cm . Note that the d-wave superconductor Tl-2201 has κ 0 /T = 1.41 mW/K 2 cm which is approximately 36% of κ N /T = 3.95 mW/K 2 cm 54 . Therefore, the negligible κ 0 /T found here thus strongly supports that the superconducting gap of 2H-Pd 0.08 TaSe 2 is nodeless.
When a finite magnetic field ( H c ) is applied, we find that while the power of n ≈ 2 is almost maintained similar to the zero-field result, the y-axis offset corresponding to κ 0 /T is systematically increased. At µ 0 H = 2.5 T , which is higher than to µ 0 H c c2 (0) = 2.45 T , we obtain κ 0 (2.5 T)/T ≈ 162 ± 6 µW/K 2 cm , being comparable to κ N /T = 163 µW/K 2 cm . This observation shows that H ≈ H c c2 (0) restores all the electrons to participate in the heat transfer in accordance with the Wiedemann-Franz law, corroborating that the fully gapped superconducting state is suppressed at the magnetic field close to µ 0 H c c2 (0) 6,55 . In Fig. 6 www.nature.com/scientificreports/ exhibit a shoulder-like feature located at 0.2< H/H c c2 < 0.6. This behavior is originated from the multiband superconductivity as discussed in the previous section. Therefore, the shoulder-like feature observed in Fig. 6 supports multiband superconductivity in 2H-Pd 0.08 TaSe 2 .
It is noted that temperature dependence of κ/T at various fields has been investigated in another piece of sample (sample2) from the same crystal growth batch. The overall behavior is quite similar to the results in Fig. 5 Determination of cleanness and implications of the multiband superconductivity in the electronic structure. To check whether the sample is in a clean or dirty limit, an intrinsic coherence length ξ 0 and l e can be estimated; κ N /T = 1 3T γ 0 Tv F l e = 1 3 γ 0 v F l e in Eq. (6) leads to the estimation of l e = 2.0 nm based on the known values of the normal-state κ N /T = 163 µW/K 2 cm from Fig. 5, the Sommerfeld coefficient γ 0 = 8.56 mJ/K 2 mol from the specific heat measurement 23 , and v F = 1.4 × 10 5 m/s from the ARPES 24 . In a BCS superconductor, ξ 0 is usually close to the BCS coherence length v F /π� 0 56 . Here, we estimate 0 as 0.49 meV from the previous specific heat measurement 23 as 0 is mainly determined by the larger energy gap. Applying these parameters results in ξ 0 = 60 nm, which is longer than the ξ ab0 = 11.6 nm estimated from H c2 measurements. In the presence of strong scattering, the electrons can be localized in the scale of l e and the ξ 0 can be further reduced by the impurity scattering 35 . The ratio ξ 0 /l e thus turns out to be ∼ 30, showing that the 2H-Pd 0.08 TaSe 2 single crystal is in a dirty limit.
In a recent ARPES study 24 , it is found that 2H-Pd 0.08 TaSe 2 at the normal state undergoes a Lifshitz transition with Pd intercalation, resulting in a quite different FS topology as compared with that of TaSe 2 . In other words, the electron pockets of a dogbone shape, which are originally well separated in TaSe 2 , have merged to form one connected, bigger Fermi surface in 2H-Pd 0.08 TaSe 2 (see, Fig. 3 in Ref. 24 for details). At the same time, the hole pockets located at the Ŵ and the K points of the crystal momentum in TaSe 2 have overall increased their areas. As a result, the Brillouin zone at the normal state is characterized with well-defined hole-pockets and electronlike Fermi surfaces that almost fill up the areas of the whole Brillouin zone. In comparison with the spectra of 2H-TaSe 2 , both electron and hole FSs have increased their areas to result in increased density of states in both electron and hole channels. In this regard, the T c enhancement with Pd intercalation could be a natural outcome of the increased density of states at the normal states as expected in a BCS superconductor. This further implies that the zone-folding effect caused by the commensurate CDW formation might not affect seriously the overall increase of density of states with Pd intercalation in the underlying electronic structure.
It should be noticed that the resultant FS topology of 2H-Pd 0.08 TaSe 2 becomes qualitatively close to that of 2H-NbSe 2 with T c ≃ 7.2 K, which is also known to exhibit nodeless, multiband superconductivity. It is thus inferred that formation of distinctive electron-and hole-Fermi surfaces with large areas at the normal sate should be favorable to the formation of multiband superconductivity in both 2H-Pd 0.08 TaSe 2 and 2H-NbSe 2 . A higher T c ≃ 7.2 K in 2H-NbSe 2 could be still associated with the difference in the electronic structure. In 2H-NbSe 2 , as compared with the Fermi surface of 2H-Pd 0.08 TaSe 2 , the density of states seems to be further enhanced with the overall bandwidth decrease due to the 4d electrons of Nb. Moreover, a CDW state that can possibly suppress the density of states further is not formed in 2H-NbSe 2 .

Conclusion
In conclusion, we have investigated the superconducting gap structure of a 2H-Pd 0.08 TaSe 2 single crystal from upper critical fields, in-plane London penetration depth measurements and thermal conductivity measurements. The upper critical fields in both magnetic field directions show an upward curvature just below T c , and overall shape can be well fitted by the two-band formula in a dirty limit with negligible interband coupling. Moreover, the upper critical field anisotropy exhibits strong temperature dependence. All these behaviors in the upper critical fields constitute strong evidences for the multiband superconductivity.
The London penetration depth, as measured by the magnetic force microscopy with a comparative method, also supports the multiband superconductivity. At H = 0 , the BCS fitting to L (T) results in 0 = 0.60 k B T c , which is smaller than that expected from the BCS theory, 0 = 1.76 k B T c . A power-law fitting to L (T) at low temperatures below 1/3 T c provides the exponent n = 2.66 , which is consistent with the nodeless multiband superconductivity.
Finally, temperature-and field-dependent measurements of thermal conductivity are also consistent with the presence of the nodeless muitiband superconductivity. A vanishingly small residual linear term ( κ 0 /T ) at zero magnetic field and a shoulder-like feature observed in the plot of [κ 0 (H)/T]/[κ N /T] verify the scenario of a nodeless multiband superconductivity and rule out the possibility of nodal superconductivity. All these results therefore consistently form compelling evidences that nodeless multiband superconductivity is realized in the single crystal of 2H-Pd 0.08 TaSe 2 , as similar to the case of 2H-NbSe 2 .

Methods
Single crystals of 2H-Pd 0.08 TaSe 2 were grown by the chemical vapor transport method using SeCl 4 as a transport agent as described in our previous report 23 . Room temperature XRD of the crystal was performed by a diffractometer ( Empyrean TM , PANalytical). The obtained pattern was refined by the Fullprof software. In-plane resistivity measurements were performed in a Physical Property Measurement System (Quantum Design) by the conventional four probe method. Magnetic susceptibility was measured with a Magnetic Property Measurement System ( PPMS TM , Quantum Design). The absolute value of the in-plane London penetration depth was measured www.nature.com/scientificreports/ in a home-built 3 He-MFM probe, operating inside a 3-axis vector magnet (2-2-9 T in the x-y-z direction) 34 . In-plane thermal conductivity was measured by a standard steady-state two-thermometer, one-heater method in a dilution refrigerator. RuO x thermometers were carefully calibrated in magnetic fields for the κ measurement. For both electrical and thermal transport measurements, contacts were made with silver paste (Dupont 4929N TM ). For κ measurements, heat current was applied along the ab-plane and magnetic field was applied along c-axis. We have used the same piece of crystal for XRD, magnetic susceptibility, ρ , and κ measurements. For L measurements, another piece of a crystal from the same batch was used.