Selective growth of Ti3+/TiO2/CNT and Ti3+/TiO2/C nanocomposite for enhanced visible-light utilization to degrade organic pollutants by lowering TiO2-bandgap

A convenient route was developed for the selective preparation of two stable nanocomposites, Ti3+/TiO2/CNT (labeled as TTOC-1 and TTOC-3) and Ti3+/TiO2/carbon layer (labeled as TTOC-2), from the same precursor by varying the amount of single-walled carbon nanotubes used in the synthesis. TiO2 is an effective photocatalyst; however, its wide bandgap limits its usefulness to the UV region. As a solution to this problem, our prepared nanocomposites exhibit a small bandgap and wide visible-light (VL) absorption because of the introduction of carbonaceous species and Ti3+ vacancies. The photocatalytic efficiency of the nanocomposites was examined via the degradation of methylene blue dye under VL. Excellent photocatalytic activity of 83%, 98%, and 93% was observed for TTOC-1, TTOC-2, and TTOC-3 nanocomposites within 25 min. In addition, the photocatalytic degradation efficiency of TTOC-2 toward methyl orange, phenol, rhodamine B, and congo red was 28%, 69%, 71%, and 91%, respectively, under similar experimental conditions after 25 min. Higher reusability and structural integrity of the as-synthesized photocatalyst were confirmed within five consecutive runs by photocatalytic test and X-ray diffraction analysis, respectively. The resulting nanocomposites provide new insights into the development of VL-active and stable photocatalysts with high efficiencies.

As a result, the development of new TiO 2 photocatalytic systems with enhanced visible-light (VL) absorption is critical and a formidable challenge 18 . To date, several techniques have been used to prolong the separation lifetime of e − /h + pairs and improve the VL absorption of TiO 2 . Among them, heteroelement doping is an excellent approach to addressing these challenges. Cations such as Fe 3+ , Mn 3+ , V 4+ , Re 5+ , Os 3+ , Mo 4+ , and Rh 3+ have been used as dopants in TiO 2 11,14,19 . Doping of nonmetals, resulting in F/TiO 2 , S/TiO 2 , N/TiO 2 , C/TiO 2 , and B/ TiO 2 , has also been reported 14,20 . However, thermal instability and the likelihood of charge recombination both increase with the introduction of heteroelements. To overcome this limitation, appealing approaches based on dopant-free, self-doping Ti 3+ species in TiO 2 have recently been developed. No foreign elements are introduced in Ti 3+ self-doped TiO 2 , which increases convenience. Moreover, numerous oxygen vacancies are beneficial for amplifying absorption in the visible region by reducing the bandgap and increasing electron mobility. Ti 3+ self-doped TiO 2 is easy to prepare compared with common doped forms of TiO 2 11,14,20-23 . Previous research has focused on modifying and preparing TiO 2 with carbon nanotubes (CNTs) as composites to reduce recombination of photoexcited e − /h + pairs. CNTs are composed of sp 2 hybrid carbon atoms, which have a large surface area, exceptional electrical properties, and high charge mobility. TiO 2 nanoparticles (NPs) coupled with CNTs exhibit excellent photocatalytic activity. Carbon functions as an electron trapper, enhancing the conductivity of TiO 2 , minimizing charge recombination, and promoting electron-hole separation. The coupling of TiO 2 with CNTs can increase quantum efficiency because it (1) results in the formation of a heterojunction that hinders e − /h + pair recombination; (2) enables VL absorption by forming Ti-C or Ti-O-C defect sites that act as an impurity; and (3) provides more e − to the conduction band of TiO 2 by creating e − /h + pairs under incident light 13,14,17,[21][22][23][24] .
Here, we report a facile two-step chemical precipitation and calcination method for the selective preparation of Ti 3+ /TiO 2 /CNT and Ti 3+ /TiO 2 /C (C in Ti 3+ /TiO 2 /C is a carbon layer) nanocomposites. All of the reagent amounts (except CNTs) and calcination conditions were the same in the preparation methods. The nanocomposites were characterized and the photocatalytic efficiency of all the nanocomposites was examined through MB dye decomposition under VL, revealing substantial photocatalytic efficiency. The effectiveness of TTOC-2 (Ti 3+ /TiO 2 /C) composite toward the degradation of RhB, CR, MO, and phenol was subsequently evaluated. In the reusability test, no notable activity deterioration was observed after five consecutive runs. The novelty of the present work involves finding a new route for the selective preparation of Ti 3+ /TiO 2 /CNT and Ti 3+ /TiO 2 /C nanocomposites. The process is developed here for the first time, and no previous reports have used identical techniques. Moreover, all the nanocomposites show excellent photocatalytic activity toward organic pollutant degradation and the present method overcomes the shortcomings of TiO 2 as a photocatalyst under visible light.

Results and discussion
Characterization of the samples. To demonstrate the surface topography, field-emission scanning electron microscopy (FE-SEM) images of the TTOC-2 nanocomposites at different magnification are presented in Fig. 1a,b. The FE-SEM micrographs show that the as-synthesized compound is composed of irregular sphericalshaped NPs with diameters ranging from ~ 15 to ~ 75 nm and a mean diameter of 43 nm (Fig. 1d). The chemical composition of the TTOC-2 nanocomposite was confirmed from its energy-dispersive X-ray spectrum (EDS) (Fig. 1c). The inset FE-SEM image in Fig. 1c was used for EDS analysis, and the elemental composition is presented in the table (inset). The EDS spectrum affirms the presence of carbon species with Ti and O elements. The precursor CNT was not observed in the FE-SEM analysis; however, the EDS studies confirm the presence of carbon in TTOC-2, indicating breakdown of the CNTs. EDS of the TTOC-2 sample was conducted on the silicon wafer instead of carbon tape for more accurate analysis. A signal of Si at ~ 1.83 keV was observed from the silicon wafer.
Transmission electron microscopy (TEM) analysis was conducted to further analyze the state of the CNTs in the TTOC-2 sample; images at three different magnifications are shown in Fig. 2a-c. The results confirmed the nanostructure of the catalyst and explored the absence of CNTs. The appearance of the nanocomposites suggests the presence of layer around the particles. The crystalline nature of nanoparticles and the amorphous nature of the layer were discernably observed. Both FE-SEM and TEM results indicate the formation of carbon layer from CNTs precursor used in the preparation. The different forms of carbon can be found through TEM imaging. The formation of a thin carbon layer (marked with a red dashed line) was clearly observed in Fig. 2. High-resolution TEM (HR-TEM) analysis was subsequently used to observe the crystal lattice (Fig. 2d), which confirms the existence of two different conjoint planes. The estimated d-spacing matches the interplanar spacing of graphitic carbon 1 , and the d-spacing  Figure S4a shows TEM images of TTOC-1. The spherical NPs with a mean diameter of 51 nm are superimposed on the CNTs. In the HR-TEM image of (Supplementary Figure S4b), the lattice d-spacing of 0.35 nm is assigned to the (101) plane of TiO 2 NPs and that of 0.41 nm is ascribed to the graphitic carbon of CNTs. A TEM image of TTOC-3 is shown in Supplementary Figure S4c; the growth of TiO 2 NPs with a mean diameter of 47 nm is clearly observed. The same lattice fringe spacings observed for TTOC-1, 0.35 nm and 0.41 nm, are also observed for TTOC-3 and are attributed to the TiO 2 NPs and the CNTs, respectively (HR-TEM image, Supplementary Figure S4d).
The structure and phase purity of the photocatalysts was studied by X-ray diffraction (XRD). The XRD plots of the nanocomposites are displayed in Fig. 3. For comparison, the XRD patterns of commercial anatase TiO 2 (CTiO 2 ) and pristine CNTs are also presented. The two characteristic peaks of the CNTs, centered at 2θ angles of 25.28° and 44.27°, are indexed to their (002) and (100) crystal planes, respectively 26 . The first broad peak corresponds to interlayer stacking, and the second, weaker peak is attributed to the interplanar stacking of aromatic systems. The pattern of the commercial TiO 2 shows diffraction peaks at 25.  11 . A Gaussian fitting of the Ti-2p peaks was used to estimate the relative Ti 3+ content of the nanocomposites quantitatively. Small shoulders of the peaks associated with Ti 3+ species compared with the peaks associated with Ti 4+ species are noticeable in the spectra of all of the nanocomposites. The calculated Ti 4+ :Ti 3+ ratio for TTOC-1, TTOC-2, and TTOC-3 is 1:0.55, 1:0.74, and 1:0.57, respectively. These results indicate that Ti 3+ is more prevalent in TTOC-2 than in TTOC-1 and TTOC-3. The large Ti 3+ content in TTOC-2 confirms the high stability of the produced Ti 3+ ions. The stability of Ti 3+ increases because of the presence of a carbon layer around the Ti 3+ /TiO 2 particles in the TTOC-2 nanocomposite. Ti 3+ species are present in the TiO 2 as a lattice Ti 3+ and surface Ti 3+ . The stability of surface Ti 3+ is less stable than a lattice Ti 3+ because of easy oxidation in contact with air. The prospect of Ti 3+ oxidation reduces by the formation of the carbon layer. The carbon layer acts as a shield/barrier for surface Ti 3+ species of TiO 2 , which reduces the Ti 3+ conversion to other forms and helps to maintain the content of Ti 3+ species. In TTOC-1 and TTOC-3, Ti 3+ ions are located on or near the surface of TiO 2 , enabling their easy oxidation to Ti 4+ and thereby reducing the peak area of Ti 3+ ions. The C-1s and O-1s fitting XPS spectra of all the nanocomposites discussed in the Supplementary section 2 ( Supplementary Figures S5 and S6).  Figure S7).
UV-vis absorbance was employed to investigate the optical features of the nanocomposites. Figure 5a-d shows the UV-vis absorbance of pristine CNT, TTOC-1, TTOC-2, and TTOC-3, respectively. The pristine CNT shows a characteristic absorption peak at 263 nm. The absorption edge of TTOC-1, TTOC-2, and TTOC-3 nanocomposites was observed at 718, 761, and 738 nm, respectively. The absorption-edge wavelength (λ g ) was calculated from the intercept between the abscissa coordinate and the tangent of the absorption curve. The absorbance of all the nanocomposites shows almost full-range coverage of VL wavelengths. Among them, the TTOC-2 nanocomposite exhibits the highest λ g . The extended VL absorption range might be dependent on the Ti 3+ oxygen/ vacancy states on the TiO 2 surface. The carbon layer improves the stability of the Ti 3+ in the TTOC-2 composite compared with that in the TTOC-1 and TTOC-3 composites.
The bandgaps of the nanocomposites and pristine CNT were analyzed from the following Tauc equation, (αhv) n = A(hv-E g ); where E g , A, hv, and α are the bandgap energy, constant, incident photon energy, and absorption coefficient, respectively. The value of n depends on the transition feature of electrons (indirect transition: n = 1/2; direct transition: n = 2). E g was calculated from plots (αhʋ) 2 vs. E, where the intercept to the E axis denotes E g where (αhʋ) 2 = 0. Figures S8a-S8d show the Tauc plots of pristine CNT, TTOC-1, TTOC-2, and TTOC-3. The calculated bandgaps of the CNTs and the TTOC-1, TTOC-2, and TTOC-3 nanocomposites are 3.47, 2.08, 1.93, and 2.04 eV, respectively. To ensure the starting at zero levels, the plots of transformed Kubelka-Munk function vs E were also demonstrated. As shown in Supplementary Figure S9(a-c), the E g values of all the nanocomposites matched well with those obtained from absorption data (± 0.07). The bandgap of the nanocomposites is dramatically lowered by the introduction of carbonaceous species and Ti 3+ ions. This smaller bandgap makes the nanocomposites applicable in the visible range, which is one of the criteria for a good photocatalyst. In the case of a small bandgap, low-energy light is sufficient to excite valence-band (VB) electrons into the conduction band (CB). The lowest bandgap of TTOC-2 among the nanocomposites is attributed to the formation of a carbon layer.
The photoluminescence (PL) analysis was used to investigate immigration, transfer or the fate of (e-h) pairs, and efficiency of charge carrier trapping; this is discussed in Supplementary Section 4 (Supplementary Figure S10).
The surface area and pore size were assessed by N 2 absorption-desorption isotherm analysis. The Brunauer-Emmett-Teller (BET) surface area and pore size of the pristine CNTs are 255.39 m 2 /g and 79.79 Å, respectively. The high surface area of the CNTs decreased in all of the TTOC samples, suggesting the formation of composites.
The BET surface area of the TTOC-1, TTOC-2, and TTOC-3 nanocomposites was 23.53, 29.95, and 24.86 m 2 /g, respectively. The reason for the relatively greater surface area of TTOC-2 compared with those of TTOC-1 and TTOC-2 is the formation of small Ti 3+ /TiO 2 NPs. The carbon layer is the driving force for the formation of small-sized NPs. The average pore size of the TTOC-1, TTOC-2, and TTOC-3 nanocomposites was 264.00, 401.23, and 394.79 Å, respectively. The pore size depends on the Ti 3+ ions; that is, a high content of Ti 3+ indicates  Fig. 6b. The MB degradation percentage was approximately 83%, 98%, and 93% for the TTOC-1, TTOC-2, and TTOC-3 nanocomposites, respectively, after 25 min of VL irradiation. When the reaction time was prolonged to 35 min using TTOC-2, the characteristics peak of MB at λ max = 664 completely disappeared; indicates the ~ 100% removal of MB. The self-deterioration of MB was trivial under irradiation of VL. In addition, the pristine CNTs showed no noticeable photocatalytic activity. The change in MB concentration under dark conditions was also measured at regular time intervals. During the adsorption-desorption period, the reduction of the MB concentration after 25 min was negligible. The reaction rate of the MB decomposition on the pristine CNTs and the TTOC-1, TTOC-2, and TTOC-3 nanocomposites was 0.0083, 0.07, 0.15, and 0.10 min −1 , which is 166%, 1400%, 3000%, and 2000% greater, respectively, than the rate of the WC reaction (0.005 min −1 ). As shown in Supplementary Table S1, the correlation coefficient value (R 2 ) of Fig. 6b signifies the smooth photocatalytic reaction. All of the prepared nanocomposites showed greater photocatalytic activity because of the coexistence of Ti 3+ and carbon species along with TiO 2 . The bandgap of Ti 3+ -TiO 2 differs from that of pure TiO 2 and can utilize a wide wavelength range of VL radiation for exciting the VB electrons. In addition, the carbon species increased the adsorption of pollutants and reduced the e − /h + recombination rate, thus enhancing the photodegradation efficiency. Because of its greater CNT content, TTOC-3 exhibited greater www.nature.com/scientificreports/ photocatalytic activity than TTOC-1. However, the photocatalytic performance of TTOC-2 was better than that of TTOC-1 and TTOC-3. In TTOC-2, the Ti 3+ stability is improved by the presence of a carbon layer around the Ti 3+ -TiO 2 NPs. The carbon layer also substantially decreases the particle size and simultaneously increases the specific surface area. A high specific surface area enhances the photodegradation efficiency because the reaction occurs at the surface. Discoloration images of an MB solution in the presence of the TTOC-1, TTOC-2, and TTOC-3 nanocomposites are presented in Supplementary Figures S12a, S12b, and S12c, respectively. The results confirm the excellent changes in MB concentration within short periods. In addition, the degradation activity of TTOC-2 toward CR, RhB, phenol, and MO was investigated under similar experimental conditions. The photodegradation ratio (C t /C 0 ) over the illumination time was plotted in Supplementary Figure S13a. Within 25 min, only 28% of the MO was degraded, whereas 71% of the RhB was degraded. The non-photosensitizing CR dye and colorless organic pollutant phenol show 91% and 69% photodegradation. The linear relation of ln(C 0 /C t ) vs illumination time (Supplementary Figure S13b) confirms the first-order reaction kinetics. Also, the high coefficient value (R 2 ) (Table S1) of Supplementary Figure S13b confirms the smooth flow of the reaction. The rate constants of the CR, RhB, phenol, and MO degradation reactions were 0.0808, 0.0452, 0.0412, and 0.0147 min −1 , which are 1616%, 904%, 824%, and 307% higher than the rate constants of the corresponding reactions without a catalyst. The low degradation rate of MO is due to the presence of an azo bond, which is difficult to rupture 28,29 .  www.nature.com/scientificreports/

Effect of pH and point of zero charge (PZC) on photocatalytic degradation. The determination
of the pH at the point-of-zero-charge (pH PZC ) and an evaluation of the effect of pH on photodegradation are critical. The pH of the mixture affects the solubility of dyes and the surface chemistry of the adsorbent. The pH PZC demonstrates a sample's surface charge. The drift method was used for pH PZC calculation in the pH range between 2 and 12. HCl and NaOH were employed to control the pH of the solution. Supplementary Figure S14 shows a graph of (pH i − pH f ) vs pH i , where pH i and pH f and the initial and final pH, respectively. The measured pH PZC (where the final pH is equal to the initial value) was 9.31, 9.92, and 9.63 for TTOC-1, TTOC-2, and TTOC-3, respectively. These results imply that the nanocomposites are cationic at pH levels below the pH PZC and anionic at pH levels greater than the pH PZC . To verify this speculation, the effect of pH on the degradation of MB by TTOC-2 was evaluated in the range 2 ≤ pH ≤ 12 under similar experimental conditions; the results are presented in Supplementary Figure S15. Superior photodegradation was observed at pH 12, whereas the worst performance was obtained at pH 2 (Supplementary Figure S15a). The photodegradation ratio clearly increases with increasing pH because MB is cationic at pH values greater than 5.8 (pKa = 5.8). In a basic medium, the electrostatic attraction between the cationic MB and the catalyst's negative surface increases. The opposite effect is observed in an acidic medium, and the photocatalytic efficiency is decreased. The results of kinetics studies of the effect of pH on MB degradation are shown in Supplementary Figure S15b. The linear relation between ln(C 0 /C t ) and irradiation time confirms first-order kinetics. The rate constant of the reaction at pH 2, 5, 9, and 12 was 0.0163, 0.0314, 0.0754, and 0.1454 min −1 , respectively. The rate constant of the reaction at pH 12 was 892% greater than that of the reaction at pH 2. The superior photodegradation of the as-synthesized nanocomposites at high pH levels also confirms the presence of negative surface groups when the nanocomposites are in a basic medium. Discoloration images of MB solution at pH 2 (after 25) and pH 12 (after 20 min) are presented in Supplementary Figures S12d and S12e, respectively. In addition to the efficiency of a photocatalyst, its stability and reusability are also essential parameters for evaluating its performance. Reusability experiments were performed using recovered nanocomposites. The degradation ratio over five consecutive cycles is presented in Supplementary Figure S16a. No significant changes were observed throughout the runs. The degradation efficiencies after five cycles were 81.0%, 96.0%, and 90.2% for TTOC-1, TTOC-2, and TTOC-3, respectively. The XRD patterns of the three nanocomposites were collected (Supplementary Figure S16b) after five consecutive runs and showed no obvious differences from the patterns of the fresh samples. The XRD crystal planes of the samples before reaction and after the reaction are consistent. The low-intensity characteristic peaks of the (100) plane of carbon species (2θ = 44.27°) are also observed. These results indicate excellent reusability and stability of the nanocomposites.
The photodegradation activity of the as-synthesized nanocomposites is compared with that of various reported catalysts in Supplementary Table S2. This comparison demonstrates that our composites show substantial photocatalytic activity under VL.  CB and VB edge potential was estimated to illustrate the photocatalytic mechanism of as-synthesized photocatalyst. Proposed mechanism path of photocatalytic performance was discussed in Supplementary Section 6. The schematic reaction mechanism with redox couples and energy band positions is shown in Fig. 7.
Further, scavenger studies were carried out to elucidate the involvement of active species in the photocatalytic reaction mechanism and discussed in Supplementary Section 7 (Supplementary Figure S19).

Conclusions
In summary, we fabricated Ti 3+ /TiO 2 /CNT and Ti 3+ /TiO 2 /C nanocomposites using a straightforward precipitation and calcination process. The amount of CNTs was varied, whereas the loading amount of other precursors was kept constant. The nanocomposites' E g was remarkably low, and their absorbance covers the entire visible-light wavelength range. The average size of the Ti 3+ /TiO 2 particle in all composites was less than 100 nm, resulting in a high specific surface area. The photocatalytic efficiency of the nanocomposites was tested for the degradation of a MB solution under VL. All of the nanocomposites showed high photocatalytic efficiency within 25 min: 83%, 98%, and 93% for the TTOC-1, TTOC-2, and TTOC-3 nanocomposites, respectively. The photocatalytic efficiency enhancement was attributed to the introduction of Ti 3+ and carbon species onto TiO 2 . Among the nanocomposites, TTOC-2 exhibited the highest activity because of its large Ti 3+ content as a result of the formation of a carbon shell. Similar experiments with TTOC-2 for the degradation of CR, RhB, phenol, and MO were performed, resulting in ~ 91%, ~ 71%, ~ 69%, and ~ 28% degradation, respectively. The PZC of the nanocomposites revealed a negative nature of their surface at high pH. The effect of pH on MB degradation using TTOC-2 was also demonstrated. With increasing pH value, the photocatalytic activity increased. Moreover, after five consecutive cycles, no apparent loss of photocatalytic activity was observed and the XRD patterns showed no structural changes, indicating good cycling stability. Therefore, the proposed nanocomposites are suitable for practical application in wastewater treatment because of their high stability and high photocatalytic efficiency. In addition, the selective preparation techniques for the two different nanocomposites might be useful in the preparation of future photocatalysts.

Experimental methods
Selective preparation of Ti 3+ /TiO 2 /CNT and Ti 3+ /TiO 2 /C nanocomposite. Titanium(IV) isopropoxide (TTIP), sodium borohydride (NaBH 4 ), RhB, CR, phenol, benzoquinone (BQ), isopropyl alcohol (IPA), potassium iodide (KI), and ethanol were sourced from Sigma-Aldrich (USA). The single-walled carbon nanotubes (CNTs, outer diameter: 1-2 nm, length: 5-30 µm) were purchased from US Research 307 Nanomaterials (Houston, USA). MB was obtained from Alfa Aesar (UK). The nanocomposites were prepared using a www.nature.com/scientificreports/ convenient and facile two-step precipitation and calcination process with TTIP and CNT as precursors. In the first step, 5 mg of CNTs was dispersed in 25 mL of ethanol using a sonication bath. Five milliliters of TTIP was then applied to the dispersed CNTs under continuous stirring. A 100 mL aqueous mixture of 0.10 g NaBH 4 was then slowly poured into the solution. The mixture was covered with Al foil and then vigorously stirred for 3 h at 600 rpm on a magnetic stirrer. The precipitate was rinsed with distilled water and dried overnight at 60 °C. Subsequently, in the second step, the precipitate was calcined at 550 °C for 6 h with a ramp rate of 7.5 °C/min to obtain a stable composite. During calcination, the sample was placed in a lid-protected crucible, which further protected in the stainless-steel chamber. The chamber was closed by an airtight UHV seal of clean, highly purified copper gaskets (oxygen-free high conductivity). At the end, the locked chamber was positioned in the furnace. The thus-obtained nanocomposite was labeled as TTOC-1. Three nanocomposites were prepared with different mass loadings of CNTs; the other reaction conditions were unchanged. During dispersion, the volume of ethanol was increased proportionally with increasing amount of CNTs. The obtained products with CNT loadings of 10, 15, and 20 mg were denoted as TTOC-1, TTOC-2, and TTOC-3, respectively. A reaction mechanism is proposed for the preparation of the two different nanocomposites (Supplementary Figure S1). Hydrolysis of TTIP (strong Lewis acid) generally produces TiO 2 -NPs. The highly electronegative isopropoxide (− OCH 3 ) 3 groups undergo protonation reaction, and on the other hand, Ti − OH bond formation occurs. The functional group of Ti-OH provides stronger binding with CNTs. Subsequently, TiO 2 -NPs were produced through hydrolysis and attached to CNTs through chemical bonding. Here, NaBH 4 was used to reduce Ti 4+ ions on the surface of TiO 2 to Ti 3+ ions. The precipitation reaction produced three Ti 3+ /TiO 2 /CNT composites with different CNT loadings. However, after calcination, the CNTs ruptured and produced a carbon layer around the Ti 3+ /TiO 2 -NPs only in the TTOC-2 nanocomposite. The aforementioned analysis indicates that, among the nanocomposites, TTOC-2 exhibits the strongest interaction between the Ti 3+ doped TiO 2 and the CNTs. The characteristics of the titanium oxide and CNTs composites vary depending on individual reaction procedures, synthesis conditions, and the mass ratio of the precursor. The reproducibility of the method was checked by repeating the process several times; in each case, the results were identical. Characterization methods are described in Supplementary Section 1 in detail.
Investigation of photocatalytic activity. The photocatalytic efficiency of the samples was tested via the degradation of MB, RhB, CR, MO, and phenol using a 300 W Xe lamp as a solar-light simulator. A 100 mL aqueous solution containing 10 mg of the pollutant was mixed with 0.05 g of catalyst under ultrasonication for 1 h. The mixture was then placed in the dark for 1 h to ensure that adsorption/desorption equilibrium was achieved. The mixture was irradiated under a Xe lamp for 25 min. A 400 nm UV cutoff filter was used to prevent irradiation with UV light. A fixed amount of solution was collected at regular time intervals, and the absorbance of the solution was monitored using a UV-vis spectrophotometer within the wavelength range 200-750 nm. Characteristic peaks at λ MB = 664, λ RhB = 554, λ CR = 498, λ phenol = 269, and λ MO = 464.5 nm were monitored to evaluate the extent of organic pollutant degradation. After photodegradation, the catalyst was collected, rinsed with distilled water, and dried. The photocatalytic activity test was repeated for five consecutive cycles with reused samples under identical experimental conditions. The photodegradation percentage was estimated using Eq. (1): where C t is the concentration of dye at degradation time t, C 0 is the initial concentration of dye, and Ƞ is the degradation efficiency. The rate constant (k) of the degradation reaction was calculated using Eq. (2):