Synthesis of hybrid amorphous/crystalline SnO2 1D nanostructures: investigation of morphology, structure and optical properties

The aim of the study was to prepare SnO2 nanowires via a combination of electrospinning and the sol–gel method from a polyvinylpyrrolidone (PVP)/dimetylformamide (DMF)/ethanol(EtOH)/tin(IV) chloride pentahydrate (SnCl4·5H2O) solution. The morphology, structure and chemical composition of the obtained PVP/SnO2 nanofibers and SnO2 nanowires were examined using transmission electron microscopy (TEM), Fourier transform infrared spectroscopy (FTIR) as well as a scanning electron microscope (SEM) with an energy dispersive spectrometer (EDX). The optical property analysis was performed on the basis of UV–Vis spectra of absorbance as a function of the wavelength, based on which the rated values of band gaps of the fabricated 1D nanostructures were determined. The morphology analysis showed that the obtained amorphous SnO2 nanowires with crystalline protuberances were characterized by a diameter of 50 to 120 nm. Results demonstrated that nanowires with a ratio of 1:1 precursor to polymer in the spinning solution were characterized by the smallest diameter after calcination and the smallest energy gap of 3.3 eV among all investigated samples. The rest of the studied materials were characterized by a larger energy gap (3.8 and 3.9 eV).

In recent years, the attention of scientists in the field of nanotechnology has been attracted by one-dimensional (1D) semiconductor nanomaterials based on metal oxides, which due to the large specific surface area, unique optical and electrical properties, can be applied in chemical sensors, batteries, fuel and solar cells, optic and optoelectronic devices or photocatalysis [1][2][3][4][5][6][7][8] . This group of materials includes SnO 2 , Bi 2 O 3 , TiO 2 , ZnO 9-12 . Among the many methods of their preparation such as the sol-gel method, chemical deposition, hydrothermal methods and magnetron sputtering, electrospinning method stands out [13][14][15][16][17] . The combination of the following two techniques of sol-gel and electrospinning used to prepare inorganic 1D nanostructures from metal oxides is gaining more and more interest due to the high quality of the product, simplicity, low manufacturing costs and a variety of available ceramic materials 18,19 .
In terms of optical properties, tin oxide is one of the most interesting materials. Tin oxide is a semiconductor with a wide energy gap of about 3.1-3.7 eV (Table 1), it is characterized by optical transparency as well as chemical and thermal stability 20,21 . This material is successfully produced in the form of thin layers, nanoparticles or porous microstructures, and is used mainly in gas detection, which owes structural stability, easy accessibility, low costs of manufacturing and high gas sensitivity [22][23][24][25][26][27] .
The first reports on the production of SnO 2 nanofibers by electrospinning from a solution were presented in 2006 by Dharmaraj with his colleagues. The electrospinning process of PVA, DMF, EtOH and SnCl 2 ·2H 2 O solution was carried out using fixed parameters: a distance of 16 cm and a potential difference between the electrodes of 15 kV, resulting in composite PVP/precursor nanofibers. These nanofibers were calcined for 4 h at four different temperatures of 300, 400, 500 and 600 °C to assess the effect of the process temperature on the morphology and structure of the obtained materials. SEM and FTIR analysis showed that only the maximum temperature of 600 °C allowed the polymer to be removed to obtain fully crystalline fibers 36 . Two years later, i.e. in 2008, the work of a Chinese research team was published, in which the preparation of SnO 2 nanofibers by electrospinning was presented and the applicability of this nanomaterial as a gas sensor was indicated. The nanofibers were nanofibers produced by electrospinning. On the basis of the observation of the morphology, structure and BET specific surface measurement, it was noticed that fibers with the addition of P123 have a diameter comparable to undoped ranging from 80 to 150 nm, but also have a much larger surface to volume ratio, hence much better sensory properties 38 . Based on the authors' knowledge and experience, and a review of the literature, it has been noticed that onedimensional nanomaterials characterized by both crystalline and amorphous structure may exhibit different optical, electrochemical properties as compared to those presented by completely crystalline or amorphous nanomaterials 5,12,[39][40][41][42][43][44][45] . Obtaining such a structure depends largely on the calcination temperature. Zhou et al. showed that it is possible to control the crystallinity of Ge 2 O 3 nanofibers using a different range of calcination temperatures-the higher it is, the higher the crystallinity of the nanomaterial 42 . As already mentioned, there is not much research carried out in this particular field so far, however, existing research indicates that such a combination of structures positively affects the energy band gap and the transition of electrons between energy states 12 . Therefore, we strive to pay special attention to these types of materials, because due to their unique properties they can be extremely valuable when used in modern optoelectronic devices.
Thus, the essence of the work is to produce hybrid crystalline-amorphous SnO 2 nanowires and to determine the effect of the applied parameters of the electrospinning and calcining process on the morphology and structure of one-dimensional SnO 2 nanostructures, with particular emphasis on the effect of the structure of this nanomaterial on its optical properties. Hence, in this paper the following studies are presented: characterization of the morphology, structure and chemical composition of the obtained nanomaterials using scanning and transmission electron microscopy (SEM and TEM), X-ray energy dispersion spectroscopy (EDX) and FTIR depending on the concentration of the tin oxide precursor and calcination temperature. In addition, the optical properties were analyzed on the basis of the UV-Vis spectrum and the energy gap for the SnO 2 nanowires was calculated.
The first step was to prepare four polyvinylpyrrolidone solutions by adding the polymer powder to ethanol in an amount corresponding to 8% wt. relative to the total weight of the solvents and stirring using a magnetic stirrer for 48 h. At the same time, various amounts of tin oxide precursor were dissolved in DMF and after 48 h of stirring was added to the PVP solutions and mixed for another 24 h to obtain homogeneous solutions with an EtOH:DMF mass ratio of 1:1 and PVP:SnCl 4 ·5H 2 O mass ratio of 2:1, 1:1 and 1:3 (samples were designated as P1, P2 and P3, respectively).
One-dimensional composite PVP/SnCl 4 nanostructures were manufactured using FLOW-Nanotechnology Solutions Electrospinner 2.2.0-500 device, with the following parameters: voltage and distance between electrodes, a flow rate of 22 kV, 15 cm and 0.4 ml·h respectively. To degrade the polymer matrix, the obtained Table 1. Dependence of the energy band gap on the synthesis method and structure of SnO 2 . *Presented work: "Synthesis of hybrid amorphous/crystalline SnO 2 1D nanostructures: investigation of morphology, structure and optical properties". www.nature.com/scientificreports/ composite nanofibers were calcinated in a high-temperature vacuum furnace HT-2100-G-Vac-Graphit-Special, at a 500 °C temperature for 10 h, while the heating rate was 10 °C·min −1 for all samples; after that the samples were left in the furnace to cool. Nanowires corresponding to the ratios mentioned above were designated as S1, S2 and S3, respectively. A scheme summarizing the processes leading to the production of nanowires is shown in Fig. 1.
To investigate the morphology and structure of the produced materials, the (TEM) TITAN 80-300 FEI highresolution transmission electron microscope was used for imaging in the transmission mode with the use of light and dark field (BF, DF), HAADF detector and filtration of energy, in particular using analytical electron microscopy in nanoareas.
Moreover, to study the effect of the heat treatment of composite PVP/SnCl 4 ·5H 2 O nanofibers on the topography of the area and to analyze the chemical composition of the prepared samples, the Zeiss Supra 35 scanning electron microscope (SEM) with the EDAX Trident XM4 series X-ray spectrometer (EDX) were used. Based on SEM images, the diameters of the randomly selected composite and ceramic nanowires were measured using the Digital Micrograph. Fourier-Transform Infrared Spectroscopy (FTIR) spectra of the obtained nanomaterials were carried out by the spectrophotometer FTIR Nicolet 6700/8700. Absorbance measurements have been conducted using the spectrophotometer UV-Vis Evolution 220 by Thermo-Scientific Company.ph software. To investigate the optical properties of the obtained composite and hybrid one-dimensional nanomaterials, the absorbance measurements, as a function of electromagnetic radiation falling on the sample were carried out using UV-Vis Evolution 220 spectrophotometer provided by Thermo-Scientific. Moreover, on the basis of UV-Vis absorption specters, the energy band gap value was determined.

Results
Analysis of morphology and structure. The topographic analysis of composite PVP/SnCl 4 nanofibers marked as P2 and P3 revealed that both nanofibrous samples were free from defects in the form of beads, and their diameter was constant over the entire length of the fiber (Fig. 2b,c). Furthermore, the analysis of the P1 sample revealed a small number of beads, as well as glued fibers, which may be related to the hydrolysis and condensation reactions of the precursor at the mixing stage (Fig. 2a). This is a very common defect and at the same time undesirable, however it can be avoided at the preparation stage of the spinning solution by using anhydrous solutions or drying, as well as during electrospinning by controlling the process parameters appropriately 41 . It was found that all of the composite nanofibers have smooth surfaces and a cylindrical structure with an average diameter of 30-250 nm. This proves the proper viscosity of the spinning solution and the correctly established electrospinning process parameters.
A 100-fold measurement of the obtained PVP/SnCl 4 random nanofibers confirmed that the diameter of the fibers electrospun from the solution with the lowest concentration of oxide precursor (P1) was the smallest compared to other samples and ranged from 30 to 80 nm, with nanofibers with diameters from 55 to 65 forming the largest group-39% (Fig. 2b). The increase in the precursor amount caused an increase in the diameter of the nanofibers, and in the case of sample P2, nanofibers with diameters in the range between 50-115 nm were observed, and the most common diameter values (also 39% of all measured diameters) were in the 65-85 nm range (Fig. 2c). The largest diameter was found in sample P3 obtained from a solution with six times more precursor than the second one. The nanofibers were characterized by diameters in the range of 60 to 250 nm, www.nature.com/scientificreports/ of which the most common values were in the 140-180 nm range (Fig. 2c). Therefore, it can be unequivocally stated that the precursor concentration is not without influence on the morphology of PVP/SnCl 4 nanofibers. S2 and S3 nanowires obtained after calcination at a 500 °C temperature, were characterized by a highly developed, rough surface with a large number of protuberances caused by crystallization on the surface, which is presented in Fig. 2e,f. Based on the significant similarity to the morphology of Ga 2 O 3 nanofibers obtained by Zhou et al., S2 and S3 nanowires were found to be amorphous with SnO 2 crystals on the surface, which is schematically verified and confirmed later by TEM analysis (Figs. 5, 6) 42 . The histograms shown in Fig. 2e,f reveal that in the case of both samples of S2 and S3 spinning solution, a decrease in the diameter of the nanowire was observed compared to the diameter of nanofibers before the heat treatment, which results from the degradation of PVP molecules during calcination 43 . The most numerous group (44%) of nanowires of the second sample were wires with a diameter value in the range of 40-60 nm, while for the third sample, as much as 50% of the measured diameters were in the range of 100-140 nm. In the case of sample S1, large agglomerates of SnO 2 were visible on the wires, which results from defects in the form of beads already present before calcining. Moreover, nanowires were sintered together during calcination (Fig. 2d), so that, compared to nanofibers before calcination, a double increase in diameter was noticeable, of which the most common value-41%-was in the range of 80-120 nm ( Fig. 2d; Table 2).
An analysis of the EDX spectrum of nanofibers obtained from each spinning solution showed the presence of SnCl 4 precursor elements (Fig. 2a-c), while the spectra presented in Fig. 2d-f based on the samples after calcination confirmed obtaining pure SnO 2 nanowires without the presence of undesirable elements (undescribed peaks near 2.0 eV presents Au and Pt, which were sputtered on the samples, Al comes from foil, and C from conductive carbon tape).
In order to investigate the morphology of the SnO 2 nanowires obtained after calcination of PVP/SnCl 4 nanofibers, the transmission electron microscope (TEM) characterization was carried out with the results presented in Figs. 3, 4, 5. Figure 3a,b reveal a smooth surface and the absence of any particles or roughness on a    www.nature.com/scientificreports/ single S1 nanowire, which had a diameter of about 540 nm and a length of 3.5 mm. In the high-resolution mode, no distinct lattice planes fringes in the structure could be seen (Fig. 3c). Moreover, reflections on the diffraction spectrum obtained for a single SnO 2 nanostructure were diffuse rings (Fig. 3d), which clearly indicates their homogenous amorphous structure. Figure 4 presents TEM analysis for nanowires made from a spinning solution with the lowest precursor concentration, and in contrast to the S1 sample, branched and sintered nanowires with particles inside and on the surface of the nanowires were visible; the diameter of a single nanowire was determined to be 240 nm. In Fig. 4c, at high magnification of a single particle of the surface, it has been observed that an amorphous shell covers the polycrystalline particle and crystallographic lattice planes of different orientation were visible. The electronogram obtained from the area visible in Fig. 4c presents the diffraction image derived from a single particle on the surface of the nanowire and reflections in the form of diffraction rings deriving from the following planes with Miller indices: (130), (122), (140), and (132), which correspond to the tetragonal, rutile structure of SnO 2 assigned to the spatial group P 42/m n m no. 136.
In the images taken in the bright and dark fields, two nanowires are visible, their diameter was about 130 nm and their length was about 2 µm, which makes it possible to state that the obtained material could be classified as one-dimensional (Fig. 5a,b). In Fig. 5a, as in the previous sample, dark crystalline protuberances are visible on the light amorphous wire. To further confirm the crystallinities of single surface protuberance, selected area electron diffraction (SAED) patterns were obtained from the area shown in Fig. 5c. Distinct ring patterns were indexed to the polycrystalline tetragonal structure of SnO 2 from the following planes with Miller indices: (121), (221), (031), (131), (140) and (330), which were assigned to the spatial group P 42/m n m no. 136 (Fig. 5d).
It has been demonstrated that the nanowire protuberances seen in SEM images were polycrystalline rutile nanoparticles with diameters up to 90 nm, in which crystallization in the amorphous wire has been stopped 42 . The combination of SEM and TEM analysis allows to state that regardless of the precursor concentration, after calcination at a 500 °C temperature, amorphous SnO 2 and amorphous-crystalline SnO 2 nanowires were obtained (Figs. 2, 3, 4, 5).
In order to determine the structure of the obtained PVP/SnCl 4 and SnO 2 nanowires, an analysis using a Fourier-Transform Infrared spectrometer (FTIR) was performed (Fig. 6). In Fig. 6a, the characteristic absorption peaks of PVP were observed at 1,654, 1,445, 1,370 and 1,295 cm −1 which correspond to the vibration of the carbonyl group C=O, O-H bending and -C-N stretching, respectively (Fig. 6a). The strong peak observed at 2,950 cm −1 can be assigned to asymmetric stretching vibration of C-H bending. Moreover, the band at 550-60 cm −1 corresponds to the -Sn-O bond; higher absorbance in this range for sample P3 is associated with the highest concentration of precursor [46][47][48] . One visible wide peak in the spectrum recorded for SnO 2 nanowires can be observed (Fig. 6b). The band appearing at 630-690 cm −1 is associated with the fundamental -Sn-O bond 36 .
Analysis of optical properties. In order to investigate the optical properties of 1D SnO 2 nanostructures obtained from solutions with three different precursor concentrations, UV-Vis spectral studies were performed. Based on the recorded absorbance spectra as a function of the electromagnetic radiation where the wavelength was in the range of 200-1,100 nm, the optical band gap of the manufactured nanowires was determined.
Spectral characteristics recorded for tin oxide nanowires obtained from the second and third solutions showed the presence of a sharp absorption edge in the middle UV region, with the sharp absorption edge wavelength estimated at of 300 nm (Fig. 7a). The absorption maxima were registered with a wavelength of 288 and 277 nm, respectively. In Fig. 7a, it can be seen that the first sample shows a gradual fall in absorption in the UV region, wherein the absorption maxima could be identified at the characteristic wavelength of about 297 nm. The values Figure 6. FT-IR spectra of as-prepared PVP/SnCl 4 nanofibers and SnO 2 nanowires calcined at 500 °C (the spectrum recorded for the nanowires is presented for the 400-1,200 cm −1 range due to background noise above this range). The results of studies on the interaction of SnO 2 nanowires with electromagnetic radiation in the 200-1,100 nm range clearly indicate very effective absorption of ultraviolet radiation, which can be applied in photocatalytic reactions, manufacturing photovoltaic cells and layers protecting against radiation in this range.
The optical band gap of the obtained one-dimensional tin oxide nanostructures was determined with the help of the Tauc equation (1) 5 : where, α-absorption coefficient, h-Planck constant, υ-electromagnetic radiation frequency, A-constant, hν-photon energy, Eg-energy band gap, ρ-coefficient, the taken value was ½. Figure 7b presents the determination of the optical energy band gap based on the (αhν) 2 -(hν) plots. The optical band gaps of SnO 2 nanowires obtained from the first, second and third solutions were 3.3, 3.8 and 3.9 eV, respectively. The nanowires marked as S2 and S3 were characterized by a much higher energy gap than the gap presented by S1, due to their smaller diameter size and shift of absorption edge. The hybrid SnO 2 nanowires presented in this work have a significantly higher energy gap compared to the gap of other forms of SnO 2 , for example, in comparison to bulk SnO 2 (3.6 eV) or thin films (3.54) 38,50 . The above results indicate a strong quantum confinement effect in SnO 2 one dimensional nanomaterials. This is a typical phenomenon for semiconductor 1D nanostructure in which electrons are free to move in one direction, while quantization occurs in the remaining two directions and it is associated with change in the electronic state of the semiconductor. It leads to the widening of the forbidden band and the decreasing of density of electronic states at the edges of the conduction and valence band. This improves electron transfer between states through the position shift of the conduction band to more negative values 51 . Favorable optical properties makes them extremely desirable in construction of optoelectronic devices such as novel type dye sensitized solar cells (DSSC). The produced one-dimensional SnO 2 nanomaterials can be an alternative to TiO 2 as a DSSC photoanode material due to the large surface area and similar optical properties like energy gap and light absorption range 45 .

conclusions
In summary, hybrid amorphous-crystalline SnO 2 one-dimensional nanomaterials have been successfully prepared by a combination of two techniques: sol-gel and electrospinning from PVP/DMF/EtOH/SnCl 4 ·5H 2 O solution in order to determine the effect of precursor concentration on their structure, morphology and optical properties. Using the following polymer to precursor ratios: 1:1, 2:1, 1:3, composite PVP/SnCl 4 nanofibers were produced in the electrospinning process and then calcined at the temperature of 500 °C for 10 h.
SEM analysis showed that after the heat treatment process, amorphous nanowires with crystalline SnO 2 protuberances on the surface were obtained, but only for samples with higher precursor concentrations. Moreover, an increase in diameter from 55 to 150 nm of composite nanofibers with precursor concentration was observed.
(1) αhυ = A(hυ − E g ) ρ www.nature.com/scientificreports/ The nanowires obtained from the solution with the lowest precursor concentration were sintered and clusters of the ceramic phase were visible, which is the result of the presence of beads already in the composite fibrous mats. TEM analysis allowed to confirm that amorphous and amorphous nanowires with polycrystalline SnO 2 nanoparticles were manufactured. The presence of Sn-O stretching in the IR spectra and no peaks from the precursor on the EDX spectrum on the samples after calcination at a 500 °C temperature confirmed the formation of tin oxide. The analysis of the optical properties of the manufactured nanowires was performed based on the absorbance as a function of the wavelength specters using a UV-Vis spectrophotometer. In the spectrum, a high degree of absorption of electromagnetic radiation of the UV range was noticed in all samples. The band gaps of the calcined fabricated nanowires were calculated from optical spectra and ranged from 3.3 to 3.9 eV; the smallest value was obtained for a sample with a 2:1 PVP to precursor ratio, which is lower than other tin oxide nanostructures. Based on these results, it can be deducted that hybrid SnO 2 nanowires with excellent optical properties could be used for the fabrication of novel types of solar cells, optoelectronic devices and as a photocatalyst in water treatment.