Optimization of Performance and Emission Characteristics of Catalytic Coated IC Engine with Biodiesel Using Grey-Taguchi Method

The performance and emission affected by piston catalytic coating have been analyzed in this study. The main contributing factors for improving performance such as load, fuel and speed have been preferred to reduce the emission and improve the performance of an IC engine. These specific standard parameters have been modified with copper alloy coated diesel engine with the aid of design of experiment by Taguchi with grey relational analysis optimization (GRA) method, for improving the IC engine performance and reducing the emissions. The result shows modified copper chromium zirconium (CuCr1Zr) catalytic coated piston produces less emission and improves performance when compared to standard un-coated piston type engine. In this investigation cotton seed oil is used as a bio- diesel and the piston and combustion chamber were coated with copper chromium zirconium material with a thickness of 250 microns. Finally the results of the experiments were compared with un-coated engine and optimized parameters have been identified for catalytic coated modified IC engine using Taguchi with GRA approach.


Methodology.
To find the catalytic coated engine performance and emission parameters the following procedure is followed as shown in Fig. 2. plasma coating. The plasma spray method is basically a thermal spraying coating process. The material to be coated is converted into molten stage by means of heat and sprayed to the surface to be coated and produce a coating. It is shown in Fig. 3 The coating material impacts on the substrate surface and quickly cools forming a coating 9 . The plasma coating method has been shown in Fig. 4. below. piston coating. Today's engines uses an exhaust after gas treatment system which is otherwise called as catalytic converter. This investigation intends to implement a similar kind of technology used in catalytic converter in the engine itself. This is archieved by coating the piston and chamber thereby making it possible to reduce a major amount of pollution emitted by the engine. So, this investigation involves coating of piston and combustion chamber with a catalytic material. Copper-chromium-zirconium alloy is coated on the bottom side of engine cylinder head and the top side of piston crown to a thickness of 250 microns. There are different methods of catalytic coating process for coating the piston and combustion chamber walls as shown in Fig. 3. The plasma spray process is advised by many researchers [9][10][11] because of its performance, economy and eco friendly nature. The properties of coating material values are tabulated in Table 1 The surface roughness of the coating was measured using Mitutyo make Surf test SJ-210 testing machine. The average surface roughness value before coating is Ra = 6.2 ± 0.3 μm and after coating is Ra = 5.9 ± 0.4 μm. Hence the surface roughness after coating has improved.
Kadir Mert Doleker et al. was conducted porosity measurements of thermal barrier coatings. The results showed that that the thermal barrier coatings exhibit higher porosity 12       that improvement of brake thermal efficiency and reduction of SFC, CO, HC emissions 13 . In this investigation the piston is coated with CuCr1Zr to a thickness of 250 microns and it does not affect the compression ratio.

experimental Setup
The experimental set up consists of five different elements. The five various elements are catalytic coated engine, eddy current dynamometer, gas analyzer, personnel computer and data acquisition system. These elements are connected as shown in Figs. 5 and 6. This set up is used for conducting the engine performance test and emission test. The engine can be operated by two fuels either by petrol or diesel. If the engine is operating in petrol fuel, the electronic control unit (ECU) is needed. In this research, the engine is run by diesel fuel. Here, it operated with the help of injector and fuel pump (FIP). The experiments are conducted using diesel and blended diesel 10% and 20%, as shown in Fig. 7.
Bio diesel preparation. In this investigation cotton seed oil is used as blended diesel fuel. Cotton seed oil is produced from the seed of the cotton plant, by crushing or by chemical solvent extraction process. For commercial purpose, cottonseed oil is extracted through solvent extraction process. The properties of cotton seed oil is listed in Table 2. Cotton seed plant (Gossypium hirsutum and Gossypium herbaceum) is grown by farmers for the purpose of feeding animals, make cotton cloths, and produce cotton oil. The seed of cotton has a similar shape to sunflower seed. Both seeds contains oil contaminants inside the hull. Using the chemical extraction process, the cotton seed oil is extracted from the kernel. Now-a-days due to high demand and shortages of crude oil, the cost of automotive vehicle fuel increases day by day 14,15 . So the cottonseed oil can be used as an alternative fuel for automotive    www.nature.com/scientificreports www.nature.com/scientificreports/ vehicles. In this investigation cotton seed oil is blending with diesel fuel with the ratio of 10% to 20% (B10, B20) using transesterification process. In the transesterification process one ester group is converted or interchanged into another ester group. The converting reaction of cotton seed oil into biodiesel is called transesterification process is shown in Fig. 8. In this process, methanol and alcohol combine with the triglyceride oil in the cotton seed under heat and sodium or potassium hydroxide as catalyst. Bio diesel and glycerol is produced through the chemical reaction. Ayegba, et al. 14 describe, the transesterification reaction as shown in Fig. 8. After the sedimentation process, glycerol and bio diesel is separated. The properties of cotton seed oil is compared with diesel fuel in Table 3.
taguchi method. Taguchi with grey relational analysis (GRA) is most suitable technique for multi-performance characteristics with minimum experimental work 16 . In the present investigation, taguchi

S. No
Parameters Values     www.nature.com/scientificreports www.nature.com/scientificreports/ technique with grey rational analysis method is used for finding the optimum engine parameters for coated IC engine. To find the optimum solution of a problem with minimum number of trails, taguchi technique is the most preferable method. This technique uses an orthogonal array concept. In the present study, three factors and three levels L9 orthogonal array is used. Taguchi`s array selector table used for selecting orthogonal array 17 . The identified parameter should be in three levels such as smallest, medium and highest levels. Taguchi technique uses a concept known as signal to noise quantitative relation (S/N) for measuring the standard characteristics.
Grey rational analysis (GRA) method. Goutam Pohit et al. used the grey rational analysis for multi objective problems 18 . The intention of the investigation is to optimize seven response parameters for coated piston and head type IC engine. Out of seven responses, four responses related to engine performance and remaining three responses related to emission. In this, higher S/N ratio is preferred for engine performance and lower S/N ratio for emission characteristic. Therefore, taguchi is not suitable for multi response optimization problem. To overcome this problem, in this investigation taguchi with grey relational analysis is used to find the optimum solution.
Prasanta Sahoo et al. used grey rational technique 19 . The first step is experimental results are normalized as the first step. After normalization, the grey relational coefficients (GRC) are calculated in the second step. In the third step, the overall grey relational grade (GRG) is calculated for each selected response by averaging the grey relational coefficients. Finally, evaluation of the multiple process response is based on the grey relational grade.
Parameters and its levels. In the present investigation three factors and three levels are used. Experiments are conducted considering three input parameters such as Fuel, Load (%) and Speed (rpm). Overall nine experiments are carried out. Table 4 shows the values of various parameters used for experiments.
Minitab-16 statistical software is used in this investigation. The parameter variation levels are updated in Minitab-16 statistical software, and the software suggests that L9 (3*3) orthogonal array as shown in Table 5. The experiments are performed for the diesel and blended bio diesel with the proportion of 10% and 20% bio diesel with 90% and 80% diesel fuel (B10, B20).

Result and Discussion
The experiments were conducted for the diesel and biodiesel B10, B20 on a coated piston engine and Table 6 shows engine performance results obtained through the experiments.
GRA for performance and emission. The first step of GRA is normalizing the responses. The important engine performance responses are BP, brake thermal efficiency (BTh), and Torque. These are the important responses for coated engine. When the required response is higher the better, then the original sequence is normalized as per the Eq. (1) 20 .   www.nature.com/scientificreports www.nature.com/scientificreports/ Similarly the remaining calculations are made as mentioned above, and it is tabulated in Table 6. (Where i = 1, 2, 3…, 9 experiments and k = 1, 2, 3, 4, 5, 6 and 7 for BP, SFC, BTh, Torque, CO, HC and NOX). The GRA performance and emission results are shown in Table 7 GRc and GRG for performance and emission. The grey relational coefficient (GRC) ξi k ( ) was obtained using Eq. (3). Where, ϕ is taken as 0.5 for equal preference. It is defined as identification coefficient 22 .
The grey relational coefficient ξi k ( ) and Grey relational grade (γi) for the BP of the first experiment. Using the above equation is given below Similarly the remaining calculations were made. After finding the grey rational coefficient (GRC) the average grey rational coefficient (GRG) is calculated from each response. Based on the following equation, the overall grey relational grade (GRG) is calculated and it is tabulated in Table 8 Exp.    The obtained grey relational rank is presented in Table 9 where higher grey relational grade is ranked high. The obtained higher grey rational grade is very closer to the optimum solution.
Since the experimental plan is orthogonal the results of every parameter of grey relational grade are separated in to level. For fuel parameter, the mean of the gray relative grade for the various levels one, two and three are calculated by averaging the gray relational grade (GRG) for the experiments one to three, four to six and seven to nine. Similarly, the GRG for the remaining parameters load and speed are calculated as shown in Table 10.
Based on grey prediction concept, the higher grey rational grade input parameter (A3B3C1) is optimum. Therefore B20 fuel, 100% load and 1460 rpm engine speed is the optimum parameter for catalytic coated piston type diesel engine.

AnoVA analysis. Raggul 23 et al. stated that the main intension of ANOVA analysis is to identify and investi-
gate the significant factor contribute to the engine emission and performance characteristics of a catalytic coated IC engine. The ANOVA analysis is carried out through the sum of squared deviations of the total mean of the GRG. Based on contribution and error of each factor, the effect of each experimental factor can be separated. The factor that poses the maximum mean square value is identified as the most significant parameter and the factor influences the performance and emission characteristics of a catalytic coated IC engine. The result of ANOVA is shown in Table 11. Patel 24   www.nature.com/scientificreports www.nature.com/scientificreports/ sum of squares and degrees of freedom, and (ρ) is the percentage contribution of each of the design parameters. Degree of freedom for each factor is 2 (Number of level-1).
Therefore the ANOVA of GRG analysis conclude that the second factor load poses the maximum mean square value of 0.0455 and hence it is identified as the highest significant factor that contributes and influences the performance and emission characteristics of a catalytic coated IC engine. The ANOVA mean effect plot and residual plots for GRG are shown in Figs. 9 and 10.
Confirmation test. The final step of taguchi design technique is confirmation test. It is conducted through experimental work once again to validate the improvement of performance and to reduce emission characteristics in the coated piston and head type IC engine run by B20 blended diesel fuel. The identified optimum parameter responses BP, SFC, BTE, Torque, CO, HC, NO X obtained through experimental and GRA are presented in Table 12. This shows the comparison of the experimental results using the initial OA, (A3B3C2-experiment no. 9) and optimal grey theory prediction design (A3B3C1) factor. Based on the confirmation test experimental result comparison, it clearly states that the performance and emission characteristics of a catalytic coated IC engine marginally improved through this study.
The diesel engine combustion takes place in the combustion chamber in three stages, namely, ignition delay period, rapid combustion and controlled combustion. In that, ignition delay period implies higher influence in diesel engine combustion process. The delay period stage is dived into chemical delay and physical delay. The physical delay can be controlled by various factors such as fuel atomization, raise in pressure and temperature etc., The cylinder pressure and temperature rise depends upon speed and load of the engine. So the variation of speed changes from 1480 rpm to 1460 rpm at same load condition. The power output of engine BP and specific fuel consumption has slightly decreased and it is showed in the grey prediction design factor level (A3B3C1) results in Fig. 11. The thermal conductivity of copper chromium and zirconium catalytic cooper alloy material is higher, so the chemical reaction starts faster and then further accelerates to higher combustion rate by means of catalyst material and hence ignition delay period is reduced and complete combustion takes place in the second stage of rapid combustion. The combustion is further controlled up to the third stage when fuel droplets are injected till end. Due to the complete combustion, the CO and HC emission is reduced and NOx increases because of high heat flame temperature.
Based on the confirmation experiments, once again the verification experiments are conducted for comparing the results of both coated and un-coated engine. Based on the optimum parameter condition B20 blended diesel fuel, 100% load and 1460 rpm was maintained, and the new results are tabulated in Table 13. Based on the experimental test coating of piston along with bio diesel has resulting the reduction of CO and HC emission of a diesel engine because the coating and bio diesel leads to increased wall heat losses and lower wall temperature levels. Therefore, the objective of the research work has been fulfilled.
The cylinder pressure and heat release rate was varies depending upon crank angle at 1460 rpm speed and 11.8 kg load of a engine for coated engine as shown in Fig. 12. The maximum cylinder pressure developed in coated engine is 62 bar. The cumulative heat release for a coated engine is 0.95 KJ and it is shown in Fig. 13.  Table 11. ANOVA of GRG. www.nature.com/scientificreports www.nature.com/scientificreports/  www.nature.com/scientificreports www.nature.com/scientificreports/ Ponnusamy et al. 7 investigated the effect of copper coating copper gives improved performance and reduces emission, due to rapid flame propagation and catalytic activation of catalytic coating material present in the engine piston and combustion chamber which leads to reduce the CO and HC emission. Similarly in this investigasation the coated engine showed reduction of CO and HC emission marginally. It is shown in Fig. 14. Microstructure of coated piston. The scanning electron microscope (SEM) piston coating image is shown in Fig. 15. The above image is taken after running the experimental test. The grain structure is varying from 10-20 μm. In this image, some cracks are noticed on the top surface of piston coating area, and it is indicates the impact of thermo mechanical stresses developed during the working of engine. The presence of carbon particle on the black colored surface indicates the result of combustion and it is also noticed that bond coat and catalytic alloy coating material are attached firmly. There is no indication of peeling or melting of coating of top surface of the piston crown due to high engine temperature induced at the peak of combustion.    www.nature.com/scientificreports www.nature.com/scientificreports/ conclusions Taguchi with GRA technique has been very efficiently used in the optimization of the performance and emission characteristics of a copper-chromium-zirconium alloy coated piston type IC engine. The three parameter that improve the performance and reduce the emission are identified as Fuel, Load and Speed. Cottonseed oil blended diesel is used as the fuel and the results are compared to that of the pure diesel. Experiments are conducted based on L9 orthogonal array and the engine parameters are optimized through the Taguchi-GRA experimental design method.

Sum of Squares
In the present investigation, Taguchi-GRA experimental design method is used to convert the multi response (seven responses) optimization problem into a single response problem. Based on the GRG result, B20 fuel, 100% load and 1460 rpm engine speed (A3B3C1) are identified as optimum parameter for copper chromium and zirconium catalytic coated piston type diesel engine.
The seven responses such as BP, BTh, Torque, SFC, CO HC and NOX have been determined for coated and uncoated engines. The brake thermal efficiency (BTh) of copper chromium and zirconium coated engine has marginally improved by 13.33% and CO, HC emissions have significantly decreased by 98.59% and 33.33.% respectively. This reveals that complete combustion takes place inside the combustion chamber due to piston coating on copper chromium and zirconium alloy material. And both engine producing the same brake power (BP) and not much variation in specific fuel consumption (SFC) and NOx emission increased due to engine high temperature.
Instead of diesel fuel operated engine, cotton seed oil -blended diesel (B20) fuel operated coated engine gives better results hence cotton seed oil-bio diesel can be used as an alternative fuel for controlling the emissions like CO, HC of a diesel engine.