The improved properties and microstructure of β-solidify TiAl alloys by boron addition and multi steps forging process

A novel forging process has been designed for better mechanical properties of Ti-43Al-6Nb-1Mo-1Cr-(0,0.6)B alloys in this paper. Multi step forging process could provide much finer microstructure, higher room-temperature strength, increased high-temperature strength and elongation with these alloys. The forged alloys without boron exhibit strength and elongation as 676.05 ± 11.37 MPa and 41.32 ± 1.38% at 800 °C, while the average grain size represents as 12.63 ± 3.77 μm. The forged alloys with 0.6 at.% B represent better mechanical properties than the forged alloys without boron, due to the refined microstructure with dispersive borides. Meanwhile, the detailed mechanism of increased strength and elongation caused by finer microstructure were concluded and discussed.

TiAl alloys have obtained interests of researchers on aerospace applications due to light weight and high strength 1,2 . The insufficient mechanical properties 3,4 decides the application and development of TiAl alloys. Therefore, the high Nb-TiAl alloys have been designed 5 for mechanical properties improvement. There are also other methods to improve the mechanical properties of TiAl alloys, such as hot-forged, hot-rolled 6 and alloying 7 . As β stabilizer, Mo [8][9][10][11] or Cr 12-14 addition were effective ways to obtain the excellent oxidation resistance and creep strength. With Cr and Mo addition, a novel composition with Ti-43Al-6Nb-1Mo-1Cr(at.%) was designed for better mechanical properties.
The dynamic recrystallization (DRX) and dynamic recovery (DRV) would influence the mechanical properties of TiAl alloys after hot processing 15,16 . TiAl alloys manufacture through the conventional forming process has posed a challenge for technical applications. Especially, Nb, Mo and Cr addition could improve the mechanical properties of TiAl alloys. However, these refractory elements also increase the deformation resistance to hinder the hot processing 9,10 . Therefore, it is necessary to design an economic manufacturing process for these alloys to guarantee the excellent mechanical properties based on the recent research 17 .
Li 18 et al. found that boron addition could promote the DRX behavior largely to soften the TiAl alloys in hot processing. In addition, boron addition could also improve the mechanical properties of conventional TiAl alloys applied in casting [19][20][21][22] . However, less researches referred to the effect of boron addition on the mechanical properties of forged TiAl alloys. Most β solidified TiAl alloys should also be forged or rolled for better properties or engineering application. Therefore, it is necessary to investigate the effect of boron addition on the properties and microstructure of forged TiAl alloys.
Two main objects focus on the economic manufacturing process and the effect of boron addition on the mechanical properties of forged Ti-43Al-6Nb-1Mo-1Cr alloys in this paper. Based on the recent study 18 , 0.6 at.% boron addition content could promote DRX formation largely, therefore, the boron content would be selected as 0.6 at.%.

Results and Discussion
The microstructure evolution in the forged Ti-43Al-6Nb-1Mo-1Cr alloys. In Fig. 2, the microstructure of casted and forged Ti-43Al-6Nb-1Mo-1Cr alloys could be observed. In Fig. 2(a) 23 , columnar (α 2 + γ) lamellar colonies form in the casted microstructure while the average colonies size is 584.94 ± 269.23 μm measured by OM images. The β/B2 phase distribute on the boundaries of columnar (α 2 + γ) lamellar colonies. The low expansion microstructure and grains distribution of forged alloys are exhibited in Fig. 2(b,c). In Fig. 2(b), finer DRXed grains and (α 2 + γ) lamellar colonies form perpendicular to compression direction while the average grain size is 12.63 ± 3.77 μm, as listed in Table 1. The grain sizes are decreased dramatically after multi-steps forging process. In Fig. 2(c), the equiaxed DRXed grains in alternating with finer (α 2 + γ) lamellar colonies distribute uniformly and form a stable network structure. In Fig. 2(d), the needle shaped γ 0 phase within β/B2 phase form on the (α 2 + γ) lamellar colony boundaries. To ensure the DRXed phase, the corresponding selected area electron diffraction (SAED) patterns and the bright-field TEM images are exhibited in Fig. 3. It can be found that the DRXed β and γ phase appear in the forged microstructure while no orientation relationship occurs between the DRXed grains.
In order to study the microstructure evolution during the multi-steps forging process, the EBSD image of the forged microstructure in Fig. 4. Compared to Fig. 4(a,b), with the steps increasing, the fraction of DRXed γ phase increases from 65.7% to 85.8% while the fraction of DRXed α 2 phase decreases from 21.5% to 6.9%. The angles of grain boundaries distribution after second step process are listed in Fig. 4(c), the large angle grain boundaries occupy the fraction more than 95%, which represents that many DRXed grains occur. Meanwhile, the boundary angles 60° and 90° occupy large proportion. The DRXed grain boundaries would tend to 120° through necklace mechanism and boundaries migration 24,25 . When the angles were counted, 60° could be treated as 120° angle, because 60° is the other side of 120°. Additionally, the twinning and atoms rearrangement cause α 2 phase parent lattice being reoriented by 90° around {1012} <1011> 26,27 . Parts of α 2 lamellae phase would deform, resolve or be reoriented between cylinder/base surfaces. Based on 90° rotation and the high stack fault energy, parts of DRXed α 2 grains would grow along the [0001] in the reoriented α 2 phase and form 90° boundaries with original α 2 phase or the other matrix phase. The alloys were forged in (α + γ) phase region while many reoriented α grains formed along the [0001] with 90° boundaries during the thermal deformation. Afterwards, many γ phase nucleating from α grains would also exhibited same direction as matrix α grains with 90° boundaries during the cooling process. Therefore, during the forging process, the boundary angles 60° and 90° between the DRXed grains and remaining α 2 /γ lamellae formed normally.
The microstructure evolution during the multi-steps forging process could be concluded in Fig. 5. When Ti-43Al-6Nb-1Mo-1Cr alloys were heated at 1180 °C, the γ → α transformation occurs and the alloys stay in (α + γ) phase region. The microstructure of alloys would consist of β + (α + γ) phase, as shown in Fig. 5(a,d).   www.nature.com/scientificreports www.nature.com/scientificreports/ The DRX behavior of γ phase dominates hot deformation 28,29 while much DRXed α and γ phase would nucleate 17 . The β, α and γ phase represent A2, D0 19 and L1 0 structure at 1180 °C. The order of the slip systems quantity is β > γ > α [30][31][32][33] . The microstructure evolution in the first step forging process could be obtained in previous (a) 20 40   www.nature.com/scientificreports www.nature.com/scientificreports/ work 18 . When the alloys deform, dislocations slip through the softer β and γ phase and pile-up on the α phase surfaces. Because of four slip systems opening in γ phase, less dislocations pile-up in β phase, which leads to less DRXed β phase nucleation. Due to hard α obstacles, dislocations pile-ups cause much DRXed γ phase nucleation. Afterwards, parts of dislocations slip into α phase and pile-up while DRXed α phase nucleates. Therefore, much DRXed γ phase and less DRXed α phase form in the first step forged microstructure, as shown in Fig. 5 The process annealing would be applied at 1150 °C for 0.5 h. The dislocation movement would be promoted to release stress concentration and to provide enough time for DRXed grains growth. The DRXed grains would grow and absorb dislocations, as shown in Fig. 5(f). In the second step forging process, the α phase would also be obstacles for dislocation movement while dislocations would pile up in the γ phase in front of α phase. The increased dislocation blocks in γ phase promotes the DRXed γ phase nucleation. Meanwhile, a large number of previous DRXed γ are broken to be tiny and equiaxed DRXed γ. Therefore, the content of DRXed γ phase would be further increased with the steps increasing below 1200 °C. The equiaxed DRXed grains in alternating with finer (α 2 + γ) lamellar colonies distribute uniformly and form a stable network shaped structure, as exhibited in Fig. 5(g).
The microstructure evolution in the forged Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys. To compare the effect of boron addition on the forged microstructure, the casted and forged microstructure of Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys were observed in Fig. 6. The casted microstructure in previous work is exhibited in Fig. 6(a) 34 , with 0.6 at.% boron addition, the average sizes of (α 2 + γ) lamellar colonies decrease, the β segregation disappear and stripe shaped borides appear, compared to Fig. 2(a). The forged microstructure under large expansion is obtained in Fig. 6(b), with the SAED patterns in ref. 34 , broken TiB distribute perpendicular to compression direction. TiB obstacles hinder dislocation movement to promote the DRXed grains nucleation, as shown in Fig. 6(c). The broken TiB and equiaxed DRXed grains in alternating with finer (α 2 + γ) lamellar colonies distribute uniformly and form a stable network shaped structure in Fig. 6(d).
The as-cast microstructure evolution. In the casted microstructure of Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys, Ti 2 Al phase could be observed on the interface of TiB and γ phase, as shown in Fig. 7. In Fig. 7(a,b) 34 , the TEM image of TiB and γ phase are exhibited, combining with Fig. 7(d), the orientation relationship of Ti 2 Al, TiB and γ phase In ref. 35 Ti3Al . Compared with the orientation relationship of Ti 2 Al, TiB and γ phase in these references, tiny angle between the habit plane occur in this paper. The angle between (2110) Ti2Al and (202) γ is 4.5°, while the angle between (020) TiB and (202) γ represents 16.3°. In comparison, boron addition causes TiB and Ti 2 Al formation and the angle between the crystal faces. This should be discussed to clarify the effect of Ti 2 Al formation on the forging process and thermal deformation of alloys.
(1) Transformation between Ti 2 Al and γ phase He 37 found many Ti 2 Al combining with α 2 separate from supersaturated γ in Ti-51.7Al alloys, which were quenched at 1000 °C for 100 h. Ti 2 Al phase was thought as the transitional phase between α 2 and γ phase while interfaces of Ti 2 Al and γ were parallel to {111} γ or (0001) Ti2Al . The misfit dislocations with 4.2 nm thickness occur on the Ti 2 Al interface, in which a semi-atomic surface parallel to {111} γ occurs and would not form stacking sequence along the interface. The lattice constants of γ phase represent a = b = 0.3976 nm, c = 0.4049 nm. Due to different lattice constants and crystal structure, the lattice misfit would form between Ti 2 Al and γ while the mismatch degree along particular direction can be calculated as follow: (i) when the crystal faces are parallel to each other,  www.nature.com/scientificreports www.nature.com/scientificreports/ (ii) when the angle occurs between the crystal planes, 1  (2) Transformation between Ti 2 Al and α/α 2 phase The α 2 /γ lamellar structure would form in the primary α with A3 structure, while γ separate out with α 2 during the cooling, the phase transformation is α → α 2 → α 2 + γ or α → α + γ → α 2 + γ. The change of stacking fault sequence and composition provides the composition basis for γ phase nucleation. The interface existence of two atoms layers with b = 1/6 < 112 > Burgers vector mainly depends on the partial Shockley dislocation. The α 2 and γ phase transformation mainly depends on the atomic stacking sequence change under element diffusion and Shockley dislocation. α 2 phase is P6 3 /mmc structure with a = b = 0.5793 nm and c = 0.4649 nm and similar to Ti 2 Al structure. The instable Ti 2 Al is the transitional phase between α 2 and γ phase. The essence of Ti 2 Al → α 2 is a complete dislocation decomposing into incomplete dislocations. The incomplete Shockley dislocation starting changes the stacking sequence regular of dense stacking surfaces and cause phase transformation. However, α 2 is dense-hexagonal structure, in which only dense plane (0001)α 2 occur. Therefore, incomplete Shockley dislocation would only start on the plane (0001)α 2 . The stacking model of α 2 phase along <1120> is…ABAB…, while the stacking model of Ti 2 Al phase along <1120> is …ABA'BA'CA….
The phase transformation between α 2 and Ti 2 Al results from the stacking sequence variety caused by the dislocation movement. The lattice constant would change, but the crystal structure, the habit plane and direction of crystal growth would not change. It corresponds to the orientation relationship between α 2 and Ti 2 Al by TEM. Figure 8(a) shows the projection polar graph of (0001)α 2 and (111) Ti2Al , in which α 2 , Ti 2 Al and γ phase exhibit strict orientation relationship in crystal face and lattice constant.
Li 18 et al. found that TiB obstacles cause dislocation piling-ups to promote DRXed grains nucleation. When the alloys are compressed, dislocation movement would change the atomic stacking sequence of Ti 2 Al and promote Ti 2 Al phase to transform to α 2 or γ phase. The Ti 2 Al could provide the DRXed α 2 and γ phase nucleation with chemical foundation. On the other hand, Ti 2 Al phase strengthens the combination of TiB and γ, which would hinder dislocation slipping better to promote the DRX formation. Therefore, the conclusion that Ti 2 Al promotes the DRXed α 2 and γ phase nucleation could be ensured in this section.
The forged microstructure evolution. Many dislocations could be found in the forged microstructure of Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys, as shown in Fig. 9. In Fig. 9(a,b), dislocations pile up on the DRXed grain boundaries, which indicates DRXed grains growth absorbing dislocation block. This absorbing process would cause the dislocations continually slipping into DRXed grains. In Fig. 9(c), dislocation pile-up on the boundaries of DRXed grains. It means that isotropic DRXed grains would hinder dislocation movement to promote the DRXed grains nucleation during the second step forging process.
To ensure the structure and composition variety of TiB after forging process, the broken TiB is analyzed by TEM in Fig. 10. In Fig. 10(a), the stripe shaped TiB is broken, the matrix γ fills into the gap of broken TiB. According to SAED patterns and the chemical composition maps, the crystal structure and composition could be ensured as TiB and γ phase while the Ti 2 Al in casted microstructure disappear after forging. In Fig. 10(b), the HRTEM image of TiB, γ and interfaces could be seen. No dislocations but many Nb and Mo atoms solid solution occur in the TiB. It indicates that dislocations would slip into TiB but dislocation block would cause stress concentration to break TiB.
To compare the phase transformation, the EBSD images of Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys in different steps forging process are exhibited in Fig. 11. With forging steps increasing, the content of DRXed γ phase increase from 57.0% to 80.2% while the DRXed α 2 phase content decrease from 33.6% to 7.9%. Due to forging steps increasing, the TiB are broken again and again which causes the sizes of TiB decrease. The tiny broken TiB are difficult to measured, therefore, the content of TiB (1.1%) in the second step forged microstructure is much less than that (2.0%) in the first step forged microstructure. In Fig. 11(b), the pole maps of point 1,2,3 and 4 indicate that the DRXed γ, β and α 2 exhibit no orientation relationship.
The microstructure evolution of Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys during the forging process could be concluded. The alloys stay in (α + γ) phase and the β content maintains stability at 1180 °C 38,39 . The microstructure evolution in the first step forging process could be obtained in previous work 18  www.nature.com/scientificreports www.nature.com/scientificreports/ quantity is β > γ > α > TiB [30][31][32][33] . When the alloys deform, less dislocations pile-up in β phase due to many slip systems opening in γ and β phase. This causes less DRXed β phase nucleation. Much DRXed γ phase nucleate, because many dislocations pile-up in γ that in front of α and TiB obstacles. Afterwards, parts of dislocations slip into α phase and pile-up in front of TiB surfaces. Then less DRXed α phase would nucleate. Therefore, much DRXed γ phase and less DRXed α phase form along the broken TiB in the first step forged microstructure, as shown in Fig. 11(a).  www.nature.com/scientificreports www.nature.com/scientificreports/ During the process annealing, the DRXed α and γ phase absorb the dislocations and grow along the broken TiB. In the next step forging process, the DRXed α, γ phase and broken TiB are broken are broken again. The α phase would also be obstacles for dislocation movements. Dislocation pile-ups in the γ phase in front of the α surfaces would promote the DRXed γ nucleation and increase the DRXed γ phase content. Therefore, the content of the DRXed γ phase in the second step forging process is increased dramatically. -43Al-6Nb-1Mo-1Cr-(0,0.6) B alloys. The tensile curves of casted and forged Ti-43Al-6Nb-1Mo-1Cr-(0,0.6)B alloys are exhibited in Fig. 12 while the detailed tensile properties are listed in Table 1. It can be found that the forged Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys exhibit larger UTS and elongation than the forged alloys without boron containing, which means boron addition could improve better mechanical properties of forged alloys.

The mechanical properties of the forged Ti
In Fig. 12(a,b), it can be seen that the forged alloys exhibit the dramatically increased UTS and elongation, compared to the casted alloys at room temperature and 800 °C. In Fig. 12(b), the forged Ti-43Al-6Nb-1Mo-1Cr-(0,0.6)B alloys display higher UTS and elongation than the casted Ti-43Al-6Nb-1Mo-1Cr alloys at 900 °C. However, the UTS of all the forged alloys are lower than casted Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys at 900 °C. The UTS and elongation variety should be explained to investigate the effect of multi steps forging process and boron addition on the mechanical properties at different temperatures.
The microstructure evolution of the stain region on the tensile specimens. The microstructure of strain region on the tensile specimens of casted and forged Ti-43Al-6Nb-1Mo-1Cr alloys are shown in Fig. 13. In Fig. 13(a,b) 23 , the holes form on the weak colonies boundaries and act as the sources of cracks formation in the casted alloys at 900 °C. In Fig. 13(c), the DRXed grains and colonies deform along the tensile direction in the forged alloys at 900 °C. When deformation exceeds the limit value, the DRXed grains break and the holes form on the boundaries at 900 °C, as exhibited in Fig. 13(d). In Fig. 13(e,f), however, the deformation of DRXed grains is less while less holes form on the boundaries at 800 °C. It means that the boundaries would be the weak positions and DRXed grains would deform better to support plastic deformation, with the temperature increasing.
The microstructure of strain region on the tensile specimens of the forged Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys are shown in Fig. 14. In Fig. 14(a), holes form on the boundaries of DRXed grains and colonies while lamellae deform along the tensile direction. In this paper, TiB could also strengthen the forged alloys. In Fig. 14(b,c), dispersive TiB phase through α 2 /γ lamellae or around grain boundaries break, which indicates TiB phase could endure parts of stress and pin the boundaries or interface to hinder cracks formation. Li 34 et al. have reported that TiB could cause many dislocation pile-ups to increase the UTS of TiAl alloys. Based on these two factors, boron addition could cause the strengthening in the forged alloys. The strengthening mechanism in Ti-43Al-6Nb-1Mo-1Cr alloys caused by the multi steps forging process is exhibited in Fig. 15(a). The uniform DRXed grains in alternating with finer (α 2 + γ) lamellar colonies form a stable network structure in the forged microstructure. The strengthening mechanism: (i) The α 2 /γ lamellae obstacles hinder the dislocations movement to strengthen the alloys, as shown in Position 4 and Position 5. The finer grains increase the fraction and orientation diversity of α 2 /γ lamellae, which causes more dislocations pile-ups to strengthen the alloys; (ii) The isotropic grains obstacles cause dislocations pile-ups on the boundaries. Much finer grains increase the content dislocation blocks on the boundaries and to strengthen the alloys; (iii) The finer DRXed grains in alternating with (α 2 + γ) lamellae form a stable triangular structure, as shown on Position 1 and Position 2. In Fig. 4(c), 60° and 90° angles occur between the α 2 /γ lamellae and the neighboring DRXed grains in the forged microstructure. It is all known that triangular structure is stable, while mangy dislocations would pile up in this type structure. Therefore, stress concentrations resulting from dislocation pile-ups are hard to break this structure. Additionally, this type of structure could also pin the α 2 /γ lamellar interfaces to hinder the cracks  www.nature.com/scientificreports www.nature.com/scientificreports/ formation and growth along lamellar interfaces. Therefore, this normal triangular structure provides the stable and increased UTS for the forged alloys.
Based on above discussion, fine-grains strengthening, dislocation strengthening, grains boundaries and lamellar interfaces pinning would strengthen the forged alloys together. These mechanisms cause dramatically increased UTS at room temperature and 800 °C. With the temperature increasing, the combining power of grain boundaries decreasing would weaken the strengthening mechanisms. The finer grains deformation and boundaries slipping support the plastic deformation and increase elongation at higher temperatures.
The increased elongation of forged Ti-43Al-6Nb-1Mo-1Cr alloys could be explained as follow. The finer DRXed grains in alternating with α 2 /γ lamellae divide dislocations into different parts while the DRX process absorbs dislocations and reduces dislocation fraction. The separated dislocation blocks are difficult to reach the critical values of stress concentration and cracks formation, due to the separated and low energy. In this case, the separated dislocations would slip up continually until the stress concentration cause the cracks formation. The sustained dislocation movement supports the plastic deformation to increase the elongation 40 . In addition, the refined DRXed grains could deform to coordinate the plastic deformation of alloys at high temperatures. Huang 41 et al. also proved that the refined DRXed grains could promote dislocation movement to support plastic deformation. Meanwhile, finer-grains could support plastic deformation better to increase the elongation.
The strengthening mechanisms in the forged Ti-43Al-6Nb-1Mo-1Cr-0.6 alloys. In the tensile curves, it can be found that the alloys with 0.6 at.% boron addition exhibit increased UTS, compared to the alloys without boron addition. The positive effect of boron addition on the high-temperature properties and the strengthening mechanism of casted alloys have been explored in ref. 34 . In this section, the effect of boron addition on the strengthening mechanisms of forged alloys should be clarified, as shown in Fig. 15(b). Relatively similar to the 3 types of strengthening mechanism in section 3.5.1, these strengthening mechanisms also occur in forged Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys. Due to TiB formation around the grain boundaries, the boundaries movement during the forging process and annealing would be hinder while the grains growth could be limited. Combining with the promoted DRXed grains nucleation, the grains sizes in the forged Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys were refined while the finer-grains strengthening was caused. The UTS of the forged Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys was enhanced dramatically, compared to the forged Ti-43Al-6Nb-1Mo-1Cr alloys. With the temperature increasing, the combining power of grain boundaries would be weaker, as shown in Fig. 13(d-f). Dispersive TiB could pin and strengthen the boundaries which maintains strength at high temperatures. In addition, TiB obstacles could also hinder dislocation movement to strengthen the alloys through secondary phase strengthening at room and high temperatures. Therefore, the 0.6 at.% boron addition could increase the UTS of the forged alloys.
The decreased strength of forged alloys at 900 °C. By the multi steps forging process, the UTS and elongations of Ti-43Al-6Nb-1Mo-1Cr-(0,0.6)B alloys have been increased dramatically at room temperatures and 800 °C. With the temperature increasing to 900 °C, however, the elongation of forged Ti-43Al-6Nb-1Mo-1Cr-(0,0.6)B alloys increases, but the UTS decreases dramatically, compared to as-cast Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys. The higher strengths of as-cast Ti-43Al-6Nb-1Mo-1Cr-0.6B alloys have been clarified in ref. 34 . The low strengths of forged Ti-43Al-6Nb-1Mo-1Cr-(0,0.6)B alloys at 900 °C should be discussed. In Table 1, the microstructure could be refined dramatically by the forging process. The combining power of grain boundaries would decrease dramatically, while grain boundaries slip easily with the temperature increasing to 900 °C, as shown in Fig. 13(c,d). The finer grains could deform easily while the increased grains boundaries could slip easily to support the plastic deformation better at 900 °C. Therefore, the refined microstructure increases the plasticity and reduces the deformation resistance dramatically. With the temperature increasing to 900 °C, the soft finer grains and weaker boundaries would weaken the strengthening from fine-grains, dislocations pile-ups and boundaries pinning effect. More dislocations pile-ups would be released in the soft matrix. All these factors lead to dramatically decreased UTS of forged alloys at 900 °C. www.nature.com/scientificreports www.nature.com/scientificreports/ conclusions The finer (α 2 + γ) lamellae with DRXed grains and dispersive TiB form in the forged microstructure of Ti-43Al-6Nb-1Mo-1Cr-(0,0.6)B alloys.
(3) The increased elongation of forged Ti-43Al-6Nb-1Mo-1Cr-(0,0.6)B alloys at high-temperatures results from refined grains. The divided dislocations by refined grains delay the stress concentration and promote the sustained dislocation movement to support plastic deformation. With the temperature increasing, the finer grains could deform easily and the weaker grain boundaries would slip easily to support the plastic deformation.