The Acadian Orogeny of the Northern Appalachians was caused by accretion of the peri-Gondwanan terranes Avalonia and Meguma to the eastern margin of Laurentia during the Devonian. The lithotectonic relationship between Avalonia and Meguma prior to accretion is uncertain. Radioisotopic dating of detrital zircons from metasedimentary granulite xenoliths from the structural basement to the Meguma terrane indicates that Avalonia and Meguma were proximal and likely contiguous as they transited the Rheic Ocean. The zircon ages range from the Cryogenian to Late Silurian with a minor Paleoproterozoic peak. Mesoproterozoic zircons are also identified and, coupled with the Ordovician to Silurian zircons, distinguish the rocks from those of the Meguma terrane. Furthermore, three distinct metamorphic events are identified at 399.0 ± 2.1 Ma, 376.9 ± 1.6 Ma, and 353.8 ± 3.3 Ma. We conclude that the granulite facies metamorphism experienced by the metasedimentary rocks occurred 10 to 20 million years after deposition of their protoliths during the initial stages of the Acadian Orogeny whereas the younger events are related to syn- and post-collisional episodes. The implication is that Avalonia and the Meguma terrane jointly transited from Gondwana.
The Middle Paleozoic Acadian Orogeny of the Appalachians was largely confined to the current northeastern margin of North America1. The orogeny was the consequence of the accretion of Avalonia and Meguma, two exotic peri-Gondwanan terranes, and possibly a mantle plume2,3,4,5,6. The Avalon terrane is comprised primarily of Neoproterozoic continental margin magmatic rocks and by Cambrian fossil-rich sedimentary rocks. In contrast, the Meguma terrane is composed mainly of flyshoid metasedimentary rocks of the Meguma Supergroup, which includes Cambrian to earliest Ordovician Goldenville Group greywacke and shales and the Lower Ordovician Halifax Group shale2. The Meguma Supergroup is >10 km thick and is overlain by the middle Ordovician to early Devonian Rockville Notch Group that is comprised of subaerial to shallow marine sediments (mainly quartzite and shale) and bimodal rift-related volcanic rocks. Subsequent to accretion, a number of Middle Devonian to Early Carboniferous silicic plutons were emplaced across both terranes7,8. Avalonia and Meguma are juxtaposed in northern mainland Nova Scotia along the Carboniferous Minas fault (Fig. 1)9. The fault likely extends west into the Bay of Fundy and east to the continental shelf.
Avalonia and Meguma have distinct geological and geochemical features and appear to be structurally unrelated terranes7,10 but their lithotectonic relationship prior to accretion is unknown11,12,13. Consequently, the nature of the relationship between Avalonia and Meguma is one of the most debated issues of the Northern Appalachians14. There are two principal models for the pre-accretion lithotectonic relationship between Avalonia and Meguma. On one hand it is suggested that they evolved independently but rifted from Gondwana and jointly transited the Rheic Ocean before accretion. On the other hand, they are considered to be spatially unrelated and transited at separate and distinct intervals2,11,12,13,15. Constraining the pre-accretion relationship between the two terranes is problematic due to the fact that the Meguma terrane is primary comprised of sedimentary rocks but was thrust over Avalonia and may cover a sizeable portion of it16.
Granulite-facies xenoliths are present within a Late Devonian mafic dyke that intrudes the Meguma terrane. The xenoliths are noteworthy because they evidently represent fragments of the structural basement to the Meguma terrane16,17,18. The metaigneous and metasedimentary granulites are entrained as xenoliths in a ~370 million year old, ~15 m wide lamprophyre dyke at Pope’s Harbour (Fig. 1)19. The Pope’s Harbour dyke (PHD) is located ~75 km south of the Minas fault zone and is a member of a suite of NW-striking mafic dykes that cut the Meguma Supergroup on the eastern shore of Nova Scotia. The geochemistry of the dykes shows that they are shoshonitic20. The dykes are variably evolved, but many samples have primitive compositions with a high mg number [>0.70, where mg-number = Mg/(Mg + 0·9 × total Fe) atomic], elevated MgO and Ni concentrations (>10 wt.% and 150 ppm, respectively), and low heavy REE concentrations. The xenoliths include aluminous (“metapelitic”, sensu lato) and orthopyroxene ± garnet-bearing tonalitic gneisses, and dioritic to ultramafic rocks17. The metapelites are most abundant but some were disaggregated and it is common to observe xenocrysts of garnet and aluminosilicate (silliminatized kyanite and sillimanite) minerals in the dyke.
Isotopic evidence from both the metaigneous and metasedimentary xenoliths indicates they are distinct from the overlying Meguma terrane16. The metaigneous granulites have chondritic to moderately radiogenic Sr and Nd values (87Sr/86Sri = 0.70285 to 0.70500; εNd(t) = −2.03 to +5.33) whereas the metasedimentary granulites are moderately unradiogenic to chondritic (87Sr/86Sri = 0.70458 to 0.70916; εNd(t) = +1.53 to −2.56). In contrast, the Sr-Nd isotopes of Meguma rocks are unradiogenic (87Sr/86Sri = 0.7113 to 0.7177; εNd(t) = −8.8 to −11.3) and their middle Proterozoic Nd model ages (TCHUR = 1358 Ma) are significantly older than the early Cambrian (TCHUR = 544 Ma) ages of the metaigneous granulites16. The isotopic data and Nd model ages of the metaigneous granulites are indistinguishable from Avalonia magmatic rocks suggesting the Avalon terrane is the structural basement to Meguma10,16.
The metasedimentary granulites are of particular significance because they contain heavy mineral detritus (zircon, apatite, monazite) that can be dated using U-Pb radioisotopic methods21,22. Detrital zircon geochronology can not only constrain the provenance and depositional age of the host rock but also provides a record of tectonothermal episodes in the catchment area of their sedimentary basin. This is especially important for the metasedimentary granulites as they have not been correlated to surface rocks. Here we use in situ laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) to date detrital zircons from metasedimentary xenoliths of the Pope’s Harbour dyke. Our results show that the tectonothermal history of the granulites provides important constraints on the pre-, syn- and post accretionary development of Avalonia and Meguma. Moreover, the new data provide the basis for a robust re-interpretation of one of the most debated issues concerning the development of the Northern Appalachians.
A total of 297 zircons were analyzed from four (PHD-1 = 96, PHD-2 = 84, PHD-3 = 95, SEDXENO = 22) metasedimentary xenoliths (Online Supplementary Dataset S1). Individual zircon grains range in size from 50 µm to 200 µm, and generally have anhedral (rounded, fragmented) to euhedral (prismatic) textures (Figs S1 to S4). The entire 206Pb/238U age spectrum ranges from 343 ± 6 Ma (1σ) to 2531 ± 21 Ma (1σ) across all samples but the zircons can be divided into an older group comprised predominantly of igneous (Th/U > 0.1) detrital zircon and a younger group of metamorphic (Th/U < 0.1) zircons23,24. The metamorphic zircons can be further sub-divided into three distinct populations.
The largest group (130) is comprised of zircons with ages ≥415 Ma (415 ± 9 Ma to 2513 ± 43 Ma) although sample PHD-3 did not yield zircons older than 585 ± 13 Ma. The zircons of this group yielded a high average Th/U ratio (0.32 ± 0.5; 2σ) that is typical of an igneous origin. The Proterozoic zircons are comprised of two minor populations with a relatively prominent (12 zircons) Paleoproterozoic group (207Pb/206Pb ages = 1981 ± 18 Ma to 2618 ± 63 Ma) and a smaller (3 zircons) Mesoproterozoic (206Pb/238U ages = 1116 ± 24 Ma to 1225 ± 24 Ma) group (Fig. 2a). The remaining zircons (~90%) are Cryogenian to Late Silurian with clusters at 680–660 Ma, ~630 Ma, ~600 Ma, ~580 Ma, 550–450, and 430–420 Ma (Fig. 2b).
The youngest (<415 Ma) zircons of this study can be separated into three distinct groups. The oldest sub-group comprise 60 zircons and range from 388 ± 8 Ma to 412 ± 9 Ma with a weighted-mean 206Pb/238U age of 399.0 ± 2.1 Ma (MSWD = 0.59; 2σ) which is indistinguishable from the Concordia (398.9 ± 2.2 Ma, MSWD = 0.58; 2σ) intercept age (Fig. 3a). The average Th/U ratio of this group is 0.05 ± 0.01 (2σ). The middle sub-group consists of 86 zircons that range from 364 ± 9 Ma to 387 ± 8 Ma and produced a weighted-mean 206Pb/238U age of 376.9 ± 1.6 Ma (MSWD = 0.69; 2σ) and Concordia intercept age of 377.3 ± 1.8 Ma (Fig. 3b; MSWD = 0.70; 2σ). The average Th/U ratio of the middle sub-group is 0.03 ± 0.01 (2σ). The youngest sub-group is comprised of 18 zircons that range from 343 ± 6 Ma to 363 ± 8 Ma and yields a weighted-mean 206Pb/238U age of 353.8 ± 3.3 Ma (MSWD = 1.00; 2σ) that is within error of the Concordia (353.6 ± 4.1 Ma, MSWD = 1.06; 2σ) intercept age (Fig. 3c). The average Th/U ratio of the youngest zircons is 0.06 ± 0.03 (2σ).
Provenance and depositional age of the Metasedimentary Granulite
The frequency distribution of the detrital zircon ages from the metasedimentary granulites can help to constrain their provenance. Specifically, the ages can confirm whether the rocks are indicative of Avalonia or Meguma sedimentary rocks. The pre-Neoproterozoic detrital zircons are confined to two groups. The Paleoproterozoic zircons (12) are more abundant than the Mesoproterozoic zircons (3) but they have a diffuse age range (207Pb/206Pb ages = 1981 ± 18 Ma to 2618 ± 63 Ma). Half of the Paleoproterozoic zircons are ~2.3 Ga (207Pb/206Pb ages = 2292 ± 17 Ma to 2407 ± 20 Ma) whereas three are ~2.5 Ga (207Pb/206Pb ages = 2520 ± 16 Ma to 2545 ± 63 Ma). The age range of the Paleoproterozoic zircons overlaps with the ages reported for Meguma sedimentary rocks as well as Avalonia sedimentary rocks (Fig. 2a)5,11,12,25. The presence of Mesoproterozoic zircons (206Pb/238U ages = 1116 ± 24 Ma to 1225 ± 24 Ma), although a small population, is more consistent with an Avalonian provenance as this age is uncommon in detrital zircon studies of Meguma sedimentary rocks5,11,12,25.
The post-Mesoproterozoic detrital zircons (≤800 Ma) are the most abundant group and display similar populations identified in Cambrian to Ordovician Avalonia sedimentary sequences from eastern Newfoundland (Avalon, Bonavista, and Burin Peninsulas), the Arisaig and McDonalds Brook Groups of northern Nova Scotia, Mira terrane of eastern Cape Breton and the Broad River Group of southern New Brunswick25,26,27,28,29,30,31,32,33. Moreover, there are Late Silurian (430 Ma to 420 Ma) magmatic zircons that likely represent a contribution of pre- and syn-Laurentia collisional magmatism25,34. In contrast, the youngest detrital zircon from the Meguma Supergroup, which the Pope’s Harbour dyke intrudes, is 529 ± 19 Ma and the age of the uppermost formation (Hellgate Falls Formation) is considered to be Floian (477.7 Ma to 470.0 Ma)12,35. Thus, the new results provide additional support for the Avalonia affinity of the metasedimentary granulites16.
The depositional age of the metasedimentary protoliths is interpreted to be Pridolian as the youngest zircons with high Th/U ratios are ~420 Ma. The Late Silurian zircons are likely derived from some of the last regional magmatic episodes prior to the emplacement of the Middle Devonian granitic batholiths that characterize the main stage of the Acadian Orogeny in the Meguma terrane1,3,25,34,36. Therefore the metasedimentary protoliths were amongst the final pre-Acadian Orogeny sedimentary rocks to be deposited on Avalonia. It is possible that the metasedimentary granulites could be the metamorphic equivalents of Arisaig Group (Antigonish Highlands) sedimentary rocks, specifically the Stonehouse Formation (siltstone and shale) as it is considered to be Pridolian (423 ± 1.5 Ma to 419.2 ± 2.8 Ma), comprised of pelitic rocks, and have similar detrital zircon populations17,25,37.
Pre-Acadian Orogeny tectonomagmatic events
It is suggested that proto-Avalonia developed during the Mesoproterozoic as Sm-Nd depleted mantle model ages of Neoproterozoic basement rocks indicates they were derived from a 1.3 Ga to 0.8 Ga tectonothermal event10,36. The identification of Mesoproterozoic zircons in this study is consistent with a Mesoproterozoic origin of Avalonia but the provenance of the Paleoproterozoic zircons is less certain as rocks of this age are not found in Avalonia. However, it is thought that proto-Avalonia may have formed along the NW margin of Gondwana and bordered Baltica and/or Amazonia as they have rocks that contain zircons of similar ages as those reported here6,10,36,38. More recent studies suggest that detrital zircon Hf isotopes and U-Pb age distributions from Avalonia sedimentary rocks indicate a greater affinity with Baltica specifically, that Avalonia formed as a New Zealand-like ‘ribbon-continent’ that detached from Baltica and accreted to Amazonia by ~670 Ma39. Therefore, it appears that the Paleoproterozoic zircons identified in this study are evidence of an ancient cratonic influence during the creation of proto-Avalonia.
The younger zircon populations at 680–660 Ma, ~630 Ma, ~600 Ma, 580–530 Ma, 520–450 Ma, and 430–420 Ma correlate to distinct magmatic periods that are identified in western Avalonia and more broadly to the entirety of Avalonia (Fig. 2b). The magmatic ‘pulses’ correspond to: (1) Neoproterozoic early (680 Ma to 670 Ma) and main (635 Ma to 570 Ma) arc-related magmatism; (2) intracontinental transtensional magmatism (590 Ma to 540 Ma); (3) rift-related magmatism (520 Ma to 480 Ma) and Rheic Ocean opening; (4) within-plate (back-arc basin?) related magmatism (460 Ma to 440 Ma); and (5) pre-collision arc-related magmatism from 440 Ma to 425 Ma (Fig. 4)4,13,27,33,34,36,40,41,42,43,44,45,46. Regional magmatism likely ended by ~420 Ma as there is a dearth of Lochkovian zircons (417 ± 9 Ma to 411 ± 9 Ma) in the metasedimentary granulites and Arisaig Group sedimentary rocks compared to the Pridolian (430 Ma to 420 Ma) and Emsian (407 ± 2.8 Ma to 397.5 ± 2.7 Ma) populations. Late Silurian magmatism is followed by the earliest effects of regional deformation within the Arisaig Group and Meguma Supergroup by 415–410 Ma14,25,47,48,49,50. Thus there is at least a 5 to 10 million year gap between the cessation of regional subduction-related magmatism and the earliest indication of deformation.
Syn- and post-Acadian Orogeny metamorphism
Previous studies on the metapelitic xenoliths from the Pope’s Harbour dyke identified three metamorphic episodes17. The first (M1) is interpreted to predate the host dyke, and corresponds to a regional, fabric-forming, granulite-facies event. The second (M2) produced undersaturated mineral assemblages (corundum, spinel, sapphirine) that occur within melt blebs that embay biotite and more aluminous M1 phases. Unlike M1 garnets in the metapelite, which have flat compositional profiles typical of granulites, M2 garnet overgrowth rims locally preserve prograde zoning patterns that provide evidence for decompression (i.e., rimward decrease in grossular), despite the high metamorphic grade of this assemblage. This testifies to the rapid quenching of the M2 assemblage, consistent with the skeletal character of some M2 phases, notably spinel, the occurrence of ternary feldspar, and the rare preservation of a corundum-quartz paragenesis. These observations suggest a possible syn-emplacement age for M2. Compositional (e.g., mineral zoning) and textural (e.g., overprinting relations) criteria show that the metamorphic mineral assemblages in the xenoliths are in disequilibrium. Thus, the application of mineral thermobarometers to these rocks is challenging. Assuming domainal-scale equilibration between neighbouring minerals, mineral thermobarometry indicates P-T conditions for M1 in the order of 4.5–6.0 kbar at >600 °C. The sapphirine-spinel thermometer suggests that M2 temperatures approached 800 °C51. M3 is a greenschist-facies overprint that in some samples obscures M1 and M2 assemblages. The three metamorphic episodes outlined above correspond to regional deformation events that affected the Meguma terrane during the Acadian Orogeny and appear to correlate with the three subgroups of metamorphic zircons17,47,49,52.
The oldest group of metamorphic zircons yielded a weighted-mean age of 399.0 ± 2.1 Ma and represents the ‘pre-dyke’ M1 granulite-facies episode. The M1 age is contemporaneous with Early Devonian (~400 Ma) regional greenschist facies deformation within the Meguma terrane1,14,49. There is evidence of older deformation (~415 Ma) within Meguma terrane sedimentary rocks50 but mica and whole rock 40Ar/39Ar ages of Halifax Group and Rockville Notch Group (White Rock Formation) rocks yield ages of ~400 Ma that are interpreted to be due to resetting associated with Acadian Orogeny deformation11,27,53,54,55. Furthermore, Emsian to Eifelian (407.6 Ma to 387.7 Ma) zircons are identified in the Brenton pluton and the youngest (Torbrook Formation) sedimentary rocks of the Rockville Notch Group13,27. Therefore, the M1 episode likely corresponds to the same deformation event that created the granulite facies conditions experienced by the protoliths of the metasedimentary granulites as well as the greenschist facies conditions of the Meguma Supergroup sedimentary rocks. The most plausible explanation for the contemporaneity of the deformation in both terranes with different conditions is thrusting of the Meguma terrane over Avalonia as this could create the P-T conditions estimated for the granulites without inducing similar conditions to the Meguma Supergroup rocks17.
The middle zircon group yielded a Frasnian weighted-mean age of 376.9 ± 1.6 Ma that is within error of previous zircon and monzonite U/Pb TIMS dating (378 ± 1 Ma) of the metasedimentary xenoliths18. The Late Devonian age is equivalent to the ‘syn-plutonic’ M2 episode which is contemporaneous with widespread silicic plutonism in the Meguma terrane7. The spatially associated Musquodoboit Batholith (800 km2) was emplaced at 377.5 ± 0.6 Ma (zircon and monazite U/Pb TIMS) and its estimated crystallization temperature is >650 °C to 800 °C56. It is likely that the emplacement of the Musquodoboit Batholith is responsible for the M2 episode as it requires sustained and areally extensive heating to generate melts of sufficient volume. Although the Pope’s Harbour dyke has not been dated, correlative dykes yielded hornblende 40Ar/39Ar ages of 370 ± 2 Ma and 367 ± 2 Ma19. It is likely that the M2 episode corresponds to regional heating associated with the Musquodoboit Batholith and that the metasedimentary xenoliths were entrained in the dyke magma subsequently.
The youngest and also the least abundant metamorphic zircon group yielded a weighted-mean age of 353.8 ± 3.3 Ma which we interpret as the equivalent to the M3 episode. The Early Carboniferous age is contemporaneous with mafic and silicic plutonism in the Cobequid Highlands8 although there are no spatially associated intrusions or volcanic rocks near the Pope’s Harbour dyke. However, the greenschist facies overprint is probably associated with the rapid exhumation of the Middle to Late Devonian S-type granites of the Meguma terrane and the oldest movement along the Minas fault zone1,9,52,57.
The Lithotectonic Relationship between Avalonia and Meguma
The lithotectonic relationship between Avalonia and Meguma prior to collision with Laurentia is debated11,13,14. On the one hand Meguma is thought to have been contiguous with Avalonia whereas on the other hand it is considered to be an unrelated or at least a distal terrane that was deposited in a rift basin between Gondwana (West Africa or Amazonia) and Avalonia2,11,12,13. One of the most important issues for understanding the pre-accretion relationship between Avalonia and Meguma is the origin of the Rockville Notch Group.
Unconformably overlying the Meguma Supergroup is the Ordovician to Silurian (450 Ma to 420 Ma) Rockville Notch Group, which is comprised of rifted-related (within-plate) volcanic and plutonic rocks (White Rock Formation) and siliciclastic (Torbrook Formation) rocks2,13,42,53,58. The volcanic and sedimentary rocks are thought to be either related to the separation of the Meguma terrane from West Africa13,53,59 or an overstep sequence11,27,42,60. The former interpretation implies there is no pre-collision lithotectonic relationship between Avalonia and the Meguma terrane whereas the latter interpretation indicates they may be contiguous and transited the Rheic Ocean together. Detrital zircon ages and isotopic compositions of Meguma Supergroup rocks are distinct from Avalonian rocks due the comparative absence of Mesoproterozoic (1000 Ma to 1600 Ma) and Ordovician to Silurian zircons11,12,13,25,28,59. However, the Rockville Notch Group has a detrital zircon age distribution that is indistinguishable from the Arisaig Group and the rocks of this study13,25. Moreover, the Nd isotopes and depleted mantle model ages of the volcanic and plutonic rocks of the Rockville Notch Group are the same as Avalonian magmatic rocks but different from Meguma7,10,12,27,43,44,53,61,62. The implication is that the Rockville Notch Group demonstrates greater affinity with Avalonian rocks than Meguma rocks.
There are three key issues that suggest the Rockville Notch Group is an overstep sequence of Meguma. Firstly, the location of the rift-related volcanic rocks is inconsistent with Meguma separation from Gondwana. Meguma rocks were deposited to the west of Gondwana and therefore the rifted margin, including the volcanic and intrusive rocks (i.e. Rockville Notch Group) should be on the eastern side of the terrane rather than their current location on the western side. There are three scenarios that could explain the current location of the Rockville Notch Group: (1) the Meguma terrane rotated ~180° after separation from Gondwana, (2) the Rockville Notch Group was transported from eastern Meguma to western Meguma during the Acadian Orogeny (~415 Ma) or (3) the Rockville Notch Group is a passive rift sequence within an amalgamated Avalonia-Meguma terrane (i.e. an overstep sequence). At the moment there is little to no evidence to suggest that Meguma rotated 180° during its migration across the Rheic Ocean. Moreover, the contact between the uppermost Halifax Group and lowermost Rockville Notch Group is an unconformity rather than a thrust fault which supports a depositional relationship rather than a tectonic relationship58,63.
Secondly, the ~440 Ma Brenton pluton, a subvolcanic intrusion correlative with the White Rock Formation volcanic rocks, contains a significant population of inherited zircons with 206Pb/238U ages between 460 ± 11 Ma to 499 Ma ± 12 Ma including a cluster between 472 ± 11 Ma and 485 Ma ± 12 Ma13,27. The implication is that the inherited zircons must be derived from older (>440 Ma) lithologies that contain Early to Middle Ordovician zircons. Early to Middle Ordovician detrital minerals are absent in the Meguma Supergroup5,12,64,65. Thus, either the Meguma terrane had rocks with Early to Middle Ordovician zircons that were removed sometime after the emplacement of the Brenton pluton but before collision with Avalonia or, the magmatic rocks of the Rockville Notch Group were generated from an Avalonian lithospheric source that subsequently erupted on top of, and possibly through, the Meguma Supergroup.
Thirdly, the time interval between rifting of the Meguma terrane from Gondwana and its collision to Laurentia may be too short given the distance. The youngest rift-related magmatic rock of the Rockville Notch Group is the Late Silurian (426 ± 2 Ma) Mavillette gabbro66,67. If rifting from Gondwana began at ~440 Ma and magmatism ceased by ~425 Ma, then the Meguma terrane crossed the Rheic Ocean - a distance estimated to be 4000 km - and collided with Avalonia in only 10–20 Ma68. This scenario would require the Meguma terrane to rotate 180° after separation from Gondwana and then transit the Rheic Ocean at rate of 20–40 cm/year.
Based on the detrital age spectra, Nd isotope systematics, and geological relationships, it is very likely that the Rockville Notch Group is an overstep sequence that has affinities with Avalonia. It is possible that the Rockville Notch Group volcanic rocks are related to ensialic (passive) rift-related magmatism found in the Antigonish Highlands (McGillivray Brook Formation) as they have similar isotopic compositions (εNd(t) = +0.2 to +6.8), depleted mantle (TDM ≈ 1200 Ma) model ages, and broadly similar emplacement ages (McGillivray Brook = 454 ± 0.7 Ma, Rockville Notch = 443 ± 2; 442 ± 4; 438 + 3/−2 Ma)13,43,53,62. Figure 5 outlines a possible scenario which may explain the lithotectonic association between Avalonia, Rockville Notch Group, and the Meguma terrane. We suggest that the Rockville Notch volcanic rocks erupted within a rift basin that developed near the boundary between Avalonia and Meguma. The cause of rifting is uncertain but it could be related to tensional stress induced by westward subduction of the Iapetus Ocean just prior to the collision between Laurentia and Avalonia (~420 Ma to ~410 Ma) or to a combination of tensional plate stresses related to Iapetan subduction and Rheic extension. Consequently, the most plausible lithotectonic relationship between the Avalonia and Meguma terranes since the opening of the Rheic Ocean is one of contiguity and that they transited together.
The geochronology results of this study show that the majority of detrital zircons have ages between ~420 Ma and ~660 Ma with minor groups at ~1100 Ma and ~2200 Ma. The new results are supportive of an Avalonia provenance of the metasedimentary granulites with possible influence of pre- to syn-Laurentia collision-related magmatic rocks during the Late Silurian. The protoliths depositional ages are interpreted to be ~420 Ma. Younger zircons (<410 Ma) correlate to three distinct tectonomagmatic events: (1) the early period of the Acadian Orogeny (399.0 ± 2.1 Ma), (2) the main period of Acadian Orogeny-related magmatism at 376.9 ± 1.6 Ma, and (3) post-Acadian Orogeny regional exhumation and Minas fault zone movement during the Early Carboniferous (353.8 ± 3.3 Ma). The contrasting nature of the metamorphic conditions experienced by the metasedimentary xenoliths (granulite facies) and Meguma Supergroup (greenschist facies) rocks at the same time can best be explained by collision and thrusting of Meguma over Avalonia at ~400 Ma. The implication is that there was ~20 million years between the deposition of the protolith and peak metamorphic conditions. Consequently, the Meguma terrane was proximal to Avalonia prior to collision and very likely contiguous.
Laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) zircon geochronology
Four metasedimentary xenoliths (2–4 kg each) were collected from the Popes Harbour dyke, Nova Scotia located at 44°46′47.55″N, 62°38′56.88″W. Zircons were separated using magnetic separation and heavy-liquid techniques at the Yu-Neng Rock and Mineral Separation Company (Lanfang, Hebei). Cathodoluminescence (CL) images were taken at the Institute of Earth Sciences, Academia Sinica, Taipei for the examination of the individual crystal internal structures and for selecting suitable positions for U-Pb analyses. Zircon U-Pb isotopic analyses were performed by laser ablation-inductively coupled plasma mass spectrometry (LA-ICP-MS) at the Department of Geosciences, National Taiwan University, Taipei using an Agilent 7500 s Q-ICP-MS and a Photon Machines Analyte G2 193 nm laser ablation system. A spot size of 35 μm with laser repetition rate of 5 Hz was used and the laser energy density was 3.83 to 5.33 J/cm2. Calibration was performed by using the zircon standard GJ-1 (608.5 ± 0.4 Ma)69, 91500 (1065 Ma)70, and zircon Plešovice (337.1 ± 0.4 Ma)71 was also used for data quality control. Measured U-Th-Pb isotope ratios were calculated using the GLITTER 4.4.4 software72 and the relative standard deviations of reference values for GJ-1 were set at 2%. The common lead was corrected using a common lead correction function73, and the weighted mean U-Pb ages, Concordia plots and probability density plots were created using Isoplot v. 4.174.
The reconstructions were created using the open-source software GPlates 2.1 following the model suggested by the Paleomap project database75 provided within: https://www.earthbyte.org/.
The authors declare that all analytical data supporting the findings of this study are available within the paper and its Supplementary Information Files.
Murphy, J. B. & Keppie, J. D. The Acadian Orogeny in the Northern Appalachians. Int. Geol. Rev. 47, 663–687 (2005).
Schenk, P. E. Sequence stratigraphy and provenance on Gondwana’s margin: the Meguma zone (Cambrian to Devonian) of Nova Scotia, Canada. Geol. Soc. Am. Bull. 109, 395–409 (1997).
Hibbard, J. P., van Staal, C. R. & Miller, B. V. Links among Carolinia, Avalonia, and Ganderia in the Appalachian peri-Gondwanan realm. Geol. Soc. Am. Spec. Pap. 433, 291–311 (2007).
Cocks, L. R. M. & Fortey, R. A. Avalonia: a long-lived terrane in the Lower Palaeozoic? Geol. Soc. Lond. Spec. Publ. 325, 141–155 (2009).
Waldron, J. W. F., Schofield, D. I., White, C. E. & Barr, S. M. Cambrian successions of the Meguma terrane, Nova Scotia, and Harlech Dome, North Wales: dispersed fragments of a peri-Gondwanan basin? J. Geol. Soc. Lond. 168, 83–98 (2011).
Murphy, J. B., Nance, R. D., Keppie, J. D. & Dostal, J. Role of Avalonia in the development of tectonic paradigms. Geol. Soc. Lond. Spec. Publ. 470, https://doi.org/10.1144/SP470.12 (2018).
Clarke, D. B., MacDonald, M. A. & Tate, M. C. Late Devonian mafic-felsic magmatism in the Meguma zone, Nova Scotia. Geol. Soc. Am. Mem. 191, 107–127 (1997).
Dunning, G. R. et al. Chronology of Devonian to early Carboniferous rifting and igneous activity in southern Magdalen Basin based on U-Pb (zircon) dating. Can. J. Earth Sci. 39, 1219–1237 (2002).
Murphy, J. B., Waldron, J. W. F., Kontak, D. J., Pe-Piper, G. & Piper, D. J. W. Minas fault zone: late Paleozoic history of an intra-continental orogenic transform fault in the Canadian Appalachians. J. Struct. Geol. 33, 312–328 (2011).
Murphy, J. B., Strachan, R. A., Nance, R. D., Parker, K. D. & Fowler, M. B. Proto-Avalonia: a 1.2–1.0 Ga tectonothermal event and constraints for the evolution of Rodinia. Geology 28, 1071–1074 (2000).
Murphy, J. B., Fernández-Suárez, J., Keppie, J. D. & Jeffries, T. E. Contiguous rather than discrete Paleozoic histories for the Avalon and Meguma terranes based on detrital zircon data. Geology 32, 585–588 (2004).
Waldron, J. W. F., White, C. E., Barr, S. M., Simonetti, A. & Heaman, L. M. Provenance of the Meguma terrane, Nova Scotia: rifted margin of early Paleozoic Gondwana. Can. J. Earth Sci. 46, 1–8 (2009).
White, C. E., Barr, S. M. & Linnemann, U. U-Pb (zircon) ages and provenance of the White Rock Formation of the Rockville Notch Group Meguma terrane, Nova Scotia, Canada: evidence for the “Sardian gap” and West African origin. Can. J. Earth Sci. 55, 589–603 (2018).
van Staal, C. R., Whalen, J. B., Valverde-Vaquero, P., Zagorevski, A. & Rogers, N. Pre-Carboniferous, episodic accretion-related, orogenesis along the Laurentian margin of the northern Appalachians. Geol. Soc. Lond. Spec. Publ. 327, 271–316 (2009).
Robinson, P., Tucker, R. D., Bradley, D., Berry, H. N. IV & Osberg, P. H. Paleozoic orogens in New England, USA. Geol. Foren. Stock. For. 120, 119–148 (1998).
Eberz, G. W., Clarke, D. B., Chatterjee, A. K. & Giles, P. S. Chemical and isotopic composition of the lower crust beneath the Meguma lithotectonic zone, Nova Scotia: evidence from granulite facies xenoliths. Contrib. Mineral. Petrol. 109, 69–88 (1991).
Owen, J. V., Greenough, J. D., Hy, C. & Ruffman, A. Xenoliths in a mafic dyke at Popes Harbour, Nova Scotia: implications for the basement to the Meguma Group. Can. J. Earth Sci. 25, 1464–1471 (1988).
Greenough, J. D., Krogh, T. E., Kamo, S. L., Owen, J. V. & Ruffman, A. Precise U-Pb dating of Meguma basement xenoliths: new evidence for Avalonian underthrusting. Can. J. Earth Sci. 36, 15–22 (1999).
Kempster, R. M. F., Clarke, D. B., Reynolds, P. H. & Chatterjee, A. K. Late Devonian lamprophyric dykes in the Meguma zone of Nova Scotia. Can. J. Earth Sci. 26, 611–613 (1989).
Greenough, J. D., Owen, J. V. & Ruffman, A. Noble metal concentrations in shoshonitic lamprophyres: analysis of the Weekend dykes, eastern shore, Nova Scotia, Canada. J. Petrol. 34, 1247–1269 (1993).
Fedo, C. M., Sircombe, K. N. & Rainbird, R. H. Detrital zircon analysis of the sedimentary record. Rev. Mineral. Geochem. 53, 277–303 (2003).
Andersen, T. Detrital zircons as tracers of sedimentary provenance: limited conditions from statistics and numerical simulation. Chem. Geol. 216, 249–270 (2005).
Hoskin, P. W. O. & Schaltegger, U. The composition of zircon and igneous and metamorphic petrogenesis. Rev. Mineral. Geochem. 53, 27–62 (2003).
Kirkland, C. L., Smithies, R. H., Taylor, R. J. M., Evans, N. & McDonald, B. Zircon Th/U ratios in magmatic environs. Lithos 212–215, 397–414 (2015).
Murphy, J. B., Fernández-Suárez, J. & Jeffries, T. E. Lithogeochemical and Sm-Nd and U-Pb isotope data from the Silurian-Lower Devonian Arisaig group clastic rocks, Avalon terrane, Nova Scotia: a record of terrane accretion in the Appalachian-Caledonide orogeny. Geol. Soc. Am. Bull. 116, 1183–1201 (2004).
Keppie, J. D., Davis, D. W. & Krogh, T. E. U-Pb geochronological constraints on Precambrian stratified units in the Avalon composite terrane of Nova Scotia, Canada: tectonic implications. Can. J. Earth Sci. 35, 222–236 (1998).
Keppie, J. D., Shellnutt, J. G., Dostal, J. & Keppie, D. F. An autochthonous Avalonian basement source for the latest Ordovician Brenton Pluton in the Meguma terrane of Nova Scotia: U-Pb-Hf isotopic constraints and paleogeographic implications. Int. J. Earth Sci. 107, 955–969 (2018).
Murphy, J. B., Fernández-Suárez, J., Jeffries, T. E. & Strachan, R. A. U-Pb (LA-ICP-MS) dating of detrital zircons from Cambrian clastic rocks in Avalonia: erosion of a Neoproterozoic arc along the Northern Gondwanan margin. J. Geol. Soc. Lond. 161, 243–254 (2004).
Pollock, J. C., Hibbard, J. P. & Sylvester, P. J. Early Ordovician rifting of Avalonia and birth of the Rheic Ocean: U-Pb detrital zircon constraints from Newfoundland. J. Geol. Soc. Lond. 166, 501–515 (2009).
Pollock, J. C., Sylvester, P. J. & Barr, S. M. Lu-Hf zircon and Sm-Nd whole-rock isotope constraints on the extent of juvenile arc crust in Avalonia: examples from Newfoundland and Nova Scotia, Canada. Can. J. Earth Sci. 52, 161–181 (2015).
Barr, S. M., Hamilton, M. A., Samson, S. D., Satkoski, A. M. & White, C. E. Provenance variation in northern Appalachian Avalonia based on detrital zircon age patters in Ediacaran and Cambrian sedimentary rocks, New Brunswick and Nova Scotia, Canada. Can. J. Earth Sci. 49, 533–546 (2012).
Willner, A. P., Barr, S. M., Gerdes, A., Massonne, H. J. & White, C. E. Origin and evolution of Avalonia: evidence from U-Pb and Lu-Hf isotopes in zircon from the Mira terrane, Canada, and the Stavelot-Venn Massif, Belgium. J. Geol. Soc. Lond. 170, 769–784 (2013).
Waldron, J. W. F., Schofield, D. I. & Murphy, J. B. Diachronous Paleozoic accretion of peri-Gondwanan terranes at the Laurentian margin. Geol. Soc. Lond. Spec. Publ. 470, https://doi.org/10.1144/SP470.11 (2018).
Bergström, S. M., Huff, D. H., Kolata, D. R. & Melchin, M. J. Occurrence and significant of Silurian K-bentonite beds at Arisaig, Nova Scotia eastern Canada. Can. J. Earth Sci. 34, 1630–1643 (1997).
White, C. E., Palacios, T., Jensen, S. & Barr, S. M. Cambrian-Ordovician acritarchs in the Meguma terrane, Nova Scotia, Canada: resolution of early Paleozoic stratigraphy and implications for paleogeography. Geol. Soc. Am. Bull. 124, 1773–1792 (2012).
Nance, R. D., Murphy, J. B. & Keppie, J. D. A cordilleran model for the evolution of Avalonia. Tectonophysics 352, 11–31 (2002).
Murphy, J. B. Geological evolution of middle to late Paleozoic rocks in the Avalon terrane of northern mainland Nova Scotia, Canadian Appalachians: a record of tectonothermal activity along the northern margin of the Rheic Ocean in the Appalachian-Caladonide orogeny. Geol. Soc. Am. Spec. Pap. 423, 413–435 (2007).
Linnemann, U., Gerdes, A., Hofmann, M. & Marko, L. The Cadomian Orogen: Neoproterozoic to Early Cambrian crustal growth and orogenic zoning along the periphery of the West African Craton-constraints from U-Pb zircon ages and Hf isotopes (Schwarburg Antiform, Germany). Precambrian Res. 244, 236–278 (2014).
Henderson, B. J., Collins, W. J., Murphy, J. B., Gutierrez-Alonso, G. & Hand, M. Gondwanan basement terranes of the Variscan-Appalachian orogeny: Baltican, Saharan and West African hafnium isotopic fingerprints in Avalonia, Iberia and the Armorican terranes. Tectonophysics 681, 278–304 (2016).
Miller, B. V. et al. Magmatism and metamorphism in a Grenvillian fragment: U-Pb and 40Ar/39Ar ages from the Blair River complex, norther Cape Breton island, Nova Scotia, Canada. Geol. Soc. Am. Bull. 108, 127–140 (1996).
Doig, R., Murphy, J. B., Pe-Piper, G. & Piper, D. J. W. U-Pb geochronology of Late Palaeozoic plutons, Cobequid Highlands, Nova Scotia, Canada: evidence for Late Devonian emplacement adjacent to the Meguma-Avalon terrane boundary in the Canadian Appalachians. Geol. J. 31, 179–188 (1996).
Keppie, J. D. & Krogh, T. E. 440 Ma igneous activity in the Meguma terrane, Nova Scotia, Canada: part of the Appalachian overstep sequence? Am. J. Sci. 300, 528–538 (2000).
Murphy, J. B., Hamilton, M. A. & LeBlanc, B. Tectonic significance of Late Ordovician silicic magmatism, Avalon terrane, northern Antigonish Highlands, Nova Scotia. Can. J. Earth Sci. 49, 346–358 (2012).
Archibald, D. B. et al. Field relationships, petrology, age, and tectonic setting of the Late Cambrian-Ordovician West Barneys River Plutonic Suite, southern Antigonish Highlands, Nova Scotia, Canada. Can. J. Earth Sci. 50, 727–745 (2013).
Pollock, J. C., Hibbard, J. P. & van Staal, C. R. A paleogeographical review of the peri-Gondwanan realm of the Appalachian orogen. Can. J. Earth Sci. 49, 1–30 (2012).
Barr, S. M., van Rooyen, D. & White, C. E. Granitoid plutons in peri-Gondwanan terranes of Cape Breton Island, Nova Scotia, Canada: new U-Pb (zircon) age constraints. Atl. Geol. 54, 21–80 (2018).
Keppie, J. D. & Dallmeyer, R. D. Late Paleozoic collision, delamination, short-lived magmatism, and rapid denudation in the Meguma terrane (Nova Scotia, Canada): constraints from 40Ar/39Ar isotopic data. Can. J. Earth Sci. 32, 644–659 (1995).
Waldron, J. W. F., Murphy, J. B., Melchin, M. J. & Davis, G. Silurian tectonics of Western Avalonia: strain-corrected subsidence history if the Arisaig Group, Nova Scotia. J. Geol. 104, 677–694 (1996).
Hicks, R. J., Jamieson, R. A. & Reynolds, P. H. Detrital and metamorphic 40Ar/39Ar ages from muscovite and whole-rock samples, Meguma Supergroup, southern Nova Scotia. Can. J. Earth Sci. 36, 23–32 (1999).
Reynolds, P. H. & Muecke, G. K. Age studies on slates: applicability of the 40Ar/39Ar stepwise outgassing method. Earth Planet. Sci. Lett. 40, 111–118.
Owen, J. V. & Greenough, J. D. An empirical sapphirine-spinel Mg-Fe exchange thermometer and its application to high grade xenoliths in the Popes Harbour dyke, Nova Scotia, Canada. Lithos 26, 317–332 (1991).
Martel, A. T., McGregor, D. C. & Utting, J. Stratigraphic significance of Upper Devonian and Lower Carboniferous miospores from the type area of the Horton Group, Nova Scotia. Can. J. Earth Sci. 30, 1091–1098 (1993).
MacDonald, L. A., Barr, S. M., White, C. E. & Ketchum, J. W. F. Petrology, age, and tectonic setting of the White Rock Formation, Meguma terrane, Nova Scotia: evidence for Silurian continental rifting. Can. J. Earth Sci. 39, 259–277 (2002).
Muir, C. M. An 40Ar/39Ar study of the Goldenville, Halifax, White Rock, and Torbrook formations of the Digby area, southwest Nova Scotia. B.Sc. Thesis, Dalhousie University, 61 pp (2000).
Keppie, J. D. & Dallmeyer, R. D. Dating transcurrent terrane accretion: an example from the Meguma and Avalon composite terranes in the northern Appalachians. Tectonics 6, 831–847 (1987).
Kontak, D. J., Ham, L. J. & Dunning, G. U-Pb dating of the Musquodoboit Batholith, southern Nova Scotia: evidence for a protracted magmatic-hydrothermal event in a Devonian intrusion. Atl. Geol. 40, 207–216 (2004).
Gibbons, W. et al. Mylonite to megabreccia: tracking fault events within a transcurrent terrane boundary in Nova Scotia, Canada. Geology 24, 411–414 (1996).
Schenk, P. E. Annapolis Belt in Geology of the Appalachian-Caledonian orogeny in Canada and Greenland (ed. Williams, H.) 367–383 (Geological Survey of Canada, 1995).
White, C. E. & Barr, S. M. Stratigraphy and depositional setting of the Silurian-Devonian Rockville Notch Group, Meguma terrane, Nova Scotia, Canada. Atl. Geol. 53, 337–365 (2017).
Chandler, F. W., Sullivan, R. W. & Currie, K. L. The age of the Springdale Group, western Newfoundland, and correlative rocks – evidence for a Llandovery overlap assemblage in the Canadian Appalachians. T. Roy. Soc. Edin.-Earth 78, 41–49 (1987).
Murphy, J. B., Keppie, J. D., Dostal, J., Waldron, J. W. F. & Cude, M. P. Geochemical and isotopic characteristics of Early Silurian clastic sequences in Antigonish Highlands, Nova Scotia, Canada: constraints on the accretion of Avalonia in the Appalachians-Caledonide Orogen. Can. J. Earth Sci. 33, 379–388 (1996).
Keppie, J. D., Dostal, J., Murphy, J. B. & Cousens, B. L. Palaeozoic within-plate volcanic rocks in Nova Scotia (Canada) reinterpreted: isotopic constraints on magmatic source and palaeocontinental reconstructions. Geol. Mag. 134, 425–447 (1997).
Schenk, P. E. Events and sea-level changes on Gondwana’s margin: the Meguma zone (Cambrian to Devonian) of Nova Scotia, Canada. Geol. Soc. Am. Bull. 103, 512–521 (1991).
Krogh, T. E. & Keppie, J. D. Age of detrital zircon and titanite in the Meguma Group, southern Nova Scotia, Canada: clues to the origin of the Meguma terrane. Tectonophysics 177, 307–323 (1990).
Piper, D. J. W., Pe-Piper, G., Tubrett, M., Triantafyllidis, S. & Strathdee, G. Detrital zircon geochronology and polycyclic sediment sources, Upper Jurassic-Lower Cretaceous of the Scotian Basin, southeastern Canada. Can. J. Earth Sci. 49, 1540–1557 (2012).
Calder, L. M. & Barr, S. M. Petrology of the Mavillette intrusion Digby County, Nova Scotia. Atl. Geol. 18, 29–40 (1982).
Warsame, H. S. Paleogeography of Early Paleozoic Laurentia and Meguma, Avalonia terranes via paleomagnetism and faunal review. M.Sc. Thesis, Western University, 170 pp (2017).
Nance, R. D. et al. A brief history of the Rheic Ocean. Geosci. Front. 3, 125–135 (2012).
Jackson, S. E., Pearson, N. J., Griffin, W. L. & Belousova, E. A. The application of laser ablation-inductively coupled plasma-mass spectrometry to in situ U-Pb zircon geochronology. Chem. Geol. 211, 47–69 (2004).
Wiedenbeck, M. et al. Three natural zircon standards for U–Th–Pb, Lu–Hf, trace element and REE analyses. Geostandard Newslett. 19, 1–24 (1995).
Sláma, J. et al. Plešovice zircon - A new natural reference material for U-Pb and Hf isotopic microanalysis. Chem. Geol. 249, 1–35 (2008).
Griffin, W. L., Powell, W. J., Pearson, N. J. & O’Reilly, S. Y. GLITTER: data reduction software for laser ablation ICP-MS. Min. Assoc. Can. Short Course Ser. 40, 308–311 (2008).
Andersen, T. ComPbCorr-Software for common lead correction of U-Th-Pb analyses that do not report 204Pb. Min. Assoc. Can. Short Course Ser. 40, 312–314 (2008).
Ludwig, K. R. Isoplot v. 4.15: a geochronological toolkit for Microsoft Excel. Berkeley Geochron. Center Sp. Publ. 4, 75 (2011).
Scotese, C. R. PALEOMAP PaleoAtlas for GPlates and the PaleoData Plotter Program, PALEOMAP Project (2016).
Li et al. Assembly, configuration, and break-up history of Rodinia: a synthesis. Precambrian Res. 160, 179–210 (2008).
We thank Terri Tang for laboratory assistance. This research was supported by funding provided by MOST (Taiwan) grant #106-2116-M-003-007 to J.G.S.
The authors declare no competing interests.
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Shellnutt, J.G., Owen, J.V., Yeh, MW. et al. Long-lived association between Avalonia and the Meguma terrane deduced from zircon geochronology of metasedimentary granulites. Sci Rep 9, 4065 (2019). https://doi.org/10.1038/s41598-019-40673-9
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