Abstract
Standard and inverted configuration small molecule OPV cells incorporating bathocuproine (BCP) as electron transport and exciton blocking layer is investigated, demonstrating that 2 mm2 standard and inverted cells display a maximum performance for BCP thicknesses of 10 nm and 1.5 nm, respectively. The reason for the different optimum BCP thicknesses for the two device configurations is the BCP-metal complex formed between the Ag electrode and the BCP layer in the standard configuration OPV devices. Interestingly, at optimum BCP thicknesses, the inverted OPV cells outperform the standard devices. Upon up-scaling of the device area of the cells from 2 mm2 to 10 and 100 mm2, device failure becomes prominent for the inverted OPV cells, due to aggregation of the evaporated BCP layer on the ITO surface. This demonstrates that although BCP can be adopted for efficient ETL in inverted configuration OPV devices on small scale, it is not suitable for device up-scaling due to severely decreasing device yields. In this work, a possible solution where an ultrathin layer of C70 is evaporated between the ITO and BCP layer is proposed. It is demonstrated that the proposed solution holds a strong potential to minimize the device failures of the BCP based inverted OPV cells to a significant extent, while maintaining good device performances.
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Introduction
Organic photovoltaics (OPVs), being eco-friendly and easy-to-produce, are considered to be a prominent sustainable energy source for the future. To date, in the development of highly efficient OPVs, fullerene and their derivatives are dominantly used as electron acceptor layers1,2,3. However, although fullerenes demonstrate excellent electron mobilities, efficient charge extraction in OPV devices still requires an Electron Transport and Exciton Blocking Layer (ETL and EBL, respectively) with well-matched energy levels, that is integrated between the electron acceptor layer and the metal cathode, in order to minimize any interface losses4,5,6,7,8,9. A plain interface between the metal cathode and the fullerene acceptor layer gives rise to multiple losses, be that due to insufficient exciton blocking or recombination effects. Particularly severe non-radiative recombination losses occur when a metal is evaporated on top of fullerene layers, because the metal atoms penetrate into the fullerene film10. In order to enhance the electron collection efficiently in OPVs and to reduce potential exciton losses at the fullerene-metal interface, it is thus common to sandwich proper ETL and EBL in between the fullerene acceptor and metal cathode6,7,8,9,11,12. The combined ETL and EBL may also act as a protective layer for the acceptor from damage during the metal deposition6,10,11,13.
2,9-Dimethyl-4,7-diphenyl-1,10-phenanthroline (Bathocuproine, BCP) is an organic material that is being widely used as ETL in OPV devices to improve electron extraction in the cells14. The molecular structure of BCP shown in Fig. 1d. BCP thin films can be evaporated at very low temperatures and possess a high optical transparency due to BCP’s large bandgap13. BCP has a deep lying Highest Occupied Molecular Orbital (HOMO) level at 7.0 eV, which combined with a Lowest Unoccupied Molecular Orbital (LUMO) at 3.5 eV, provides excellent exciton blocking properties for the most commonly used material systems in OPV12,15,16. Furthermore, Vogel et al. reported that a thin layer of BCP inserted in phthalocyanine (Pc) and C60 based standard configuration OPV cells improves the Power Conversion Efficiency (PCE) of the devices remarkably16. This increase in the PCE is due to a reduction of non-radiative recombination effects at the interface of C60 and Al; without BCP, the non-radiative recombination region extends into the C60 layer due to Al penetration16.
Despite its high bandgap, BCP facilitates efficient electron transport in standard configuration OPV devices17,18,19,20. This transport efficiency is ascribed to the presence of metal-BCP complexes that form when the metal, here Ag, is evaporated on top of the BCP layer. This complex formation requires a strong interaction between the BCP molecule and the metal atom21,22. The LUMO level of the formed Ag-BCP complex aligns with the LUMO level of the fullerene acceptor layers, which facilitates the efficient electron transport seen in the OPV devices22. Inverted OPVs lack this favorable alignment of BCP and fullerene LUMO levels, because metal-BCP complexes are not formed as the BCP layer is deposited directly on top of the bottom electrode in inverted devices. The less favorable LUMO level alignment hampers efficient electron extraction in BCP based inverted OPV devices21. The detailed role of the BCP layer for electron transport in inverted OPV devices is to date, however, not fully investigated.
In this work, we assess the impact of BCP as electron transport and exciton blocking layer on the performance of standard and inverted planar heterojunction OPV devices consisting of Tetraphenyldibenzoperiflanthene (DBP) as donor and Fullerene (C70) as acceptor molecules. DBP and C70 solar cells have been extensively studied in the past, reaching power conversion efficiencies of up to 6.4% for single, mixed heterojunction solar cells23,24, whereas the bilayer OPVs with DBP and C70 usually exhibit a device performance of around 3 to 3.5%4,25. We are particularly interested in the change of the OPV device performance when scaling up the device area, in particular when BCP films of different thicknesses are incorporated. We demonstrate that an up-scaling of the device area from 2 mm2 to 10 and 100 mm2 leads to distinctively different device yields for the standard and inverted configuration. The yields of standard configuration OPV devices were not affected by up-scaling to 10 and 100 mm2. However, with up-scaling from 2 mm2 to 10 and 100 mm2 a strongly increasing amount of inverted OPV devices failed due to shunting. We attribute the shunting to extended BCP aggregates that form upon evaporation on Indium-Tin-Oxide (ITO). Device failure due to BCP aggregation strongly reduces the overall OPV device yield. To improve the yield of the inverted devices upon up-scaling, we propose a simple method for reducing the aggregation of BCP on ITO by sandwiching an ultra-thin layer of C70 in between the ITO and BCP layers. The proposed method improves the overall device yield as well as the performance of the fabricated 100 mm2 inverted OPV devices.
Results and Discussion
The JV characteristics of the standard and inverted OPV devices of the 2 mm2 cell area with various thicknesses of the BCP interfacial cathode layer are shown in Fig. 2. The associated performance parameters are listed in Tables 1 and 2, respectively. The energy level diagram of the inverted OPV devices with the BCP layer is shown in Fig. 1c.
For the JV characteristics of the standard OPV devices with various BCP thicknesses (Fig. 2a), the devices with 10 nm of BCP (violet curve) show the highest JSC, FF and PCE. Standard cells without BCP show ‘S-shaped’ JV characteristics (blue curve). The S-shape is likely caused by recombination losses at Ag clusters that penetrated into the C70 layer, reminiscent to the reported case of Al cathodes16. For the standard configuration cells, increasing the BCP thickness up to 15 nm almost doubles the PCE of the devices compared to the devices without BCP; the PCE enhancement is mostly due to increased JSC and FF (Table 1). Increasing the thickness of the BCP layer above 15 nm in the standard configuration cells significantly decreases the device PCE by a factor of 1.7, along with reduced FF and Jsc. The occurrence of optimum performance values around 10–15 nm has also been reported elsewhere6,15,17,26. The reduction in performance beyond 15 nm BCP thickness is presumably caused by the competition between two coexisting sub-regions within the BCP layer, namely a pristine and a metal-permeated BCP region, i.e. a region containing the aforementioned BCP-Ag complex26. The pristine BCP region poses a barrier for electron transport, while the metal-permeated BCP region enables an efficient electron extraction in the devices. When the thickness of the BCP layer increases above 15 nm, the transport occurs in the dominant pristine BCP region, translating into poor FF and PCE values. Thus, an optimized thickness of the BCP layer is crucial for obtaining high device performances.
BCP layers are also crucial for inverted device structures but support the function of the OPV device in a different fashion. In the BCP-free inverted device, JSC as low as 4.1 mA/cm2 (Table 2) and low FF (blue curve in Fig. 2b) are encountered, since exciton blocking is absent and the carrier extraction at the interface between C70 and ITO is inefficient. Inserting the BCP layer as ETL in between ITO and C70 in the inverted OPV devices establishes an improved cathode contact and significantly enhances the short circuit current JSC to more than 5.3 mA/cm2 (Table 2). Since metal-BCP complexes cannot be formed, transport has to be established across a pristine BCP region. The decrease in the device performance with increasing BCP thickness, clearly reflected in the JV characteristics shown in Fig. 2b, appears to predominantly arise due to the resistance of the unaffected BCP layer (Table 2).
To corroborate the hypothesis of a detrimental impact of the BCP layer resistance on the current transport, we inspect the JV characteristics of inverted electron-only devices (EODs), shown in Fig. 3. When operating an EOD, electrons were injected through Ag electrode and collected at the ITO electrode. The JV-characteristics of the EODs follow the same trends as in the OPVs. At the low BCP thickness of 1.5 nm, the EOD clearly shows an improved electron extraction (violet curve) compared to reference devices without BCP (blue) curve, in line with the high device performance of inverted configuration cells with 1.5 nm BCP thickness. An increase in the thickness of BCP above 1.5 nm deteriorates the electron current due to a lessened conductivity through the BCP layer. Hence, inverted cells require much thinner optimal BCP layer thicknesses compared to the standard cells.
Remarkably, the inverted cells with BCP films thinner than 5 nm (red curve in Fig. 2b) outperform the optimized standard configuration cells (BCP thickness 10 nm), even though BCP-Ag complexes, that would favor electron transport, are absent. Also, the BCP-containing inverted cells are superior to inverted cells using ZnO rather than BCP as ETL in an otherwise identical structure4.
To probe whether the OPV devices with their configuration-specifically optimized BCP layers keep their performance also in larger cells, OPV devices with 10 nm and 1.5 nm thick BCP layers for standard and inverted configurations, respectively, were scaled up from cell areas of 2 to 10 and 100 mm2. The JV characteristics of the OPV devices with cells areas of 2, 10 and 100 mm2 are shown in Fig. 4. The related performance parameters including the device yield are listed in Tables 3 and 4. Overall, the PCE of the devices decreases while scaling up the cell area. This decrease in PCE is expected, because the increase in the area of the ITO electrode area causes a larger resistance in ITO and, hence, a reduction in JSC and FF (Tables 3 and 4)1,27.
Importantly, the overall device yield of the standard configuration OPV devices was close to 100% independent of the cell area, i.e., almost all fabricated devices worked successfully. In contrast, the inverted OPV cells with BCP as interlayer showed a remarkably reduced device yield upon up-scaling. As seen from the performance parameters (Table 4) and JV characteristics (Fig. 4), the optimum performance for the inverted OPV cells with small active area (2 mm2) was achieved with 1.5 nm BCP as ETL. The overall device yield for these devices exceeded 90%, i.e., 9 out of 10 fabricated OPV devices worked. When increasing the active area to 10 mm2, the device yield dropped to below 40%, and upon further increasing the OPV cell area to 100 mm2, the device yield dropped to less than 10%. The majority of the failed OPV devices showed strong leakage currents in their JV characteristics. The less than 10% OPV devices that worked demonstrated a strong decrease in the VOC and FF values and, hence, a strongly reduced PCE.
In order to investigate the origin of the decreasing device yield and performance in inverted OPV devices, morphological investigations of the BCP layers were carried out. The optical microscope images of the BCP layer on top of the large area ITO substrates (Fig. 5a) feature spots that correspond to BCP aggregates. Such an aggregation of BCP on ITO is due to a large interfacial energy between ITO and BCP28, leading to a Volmer-Weber type growth29. We suggest that these aggregated BCP structures on ITO are responsible for the shunting of the OPV devices, i.e., for device failure and low device yield.
A possible key to understand the relation between the presence of the BCP clusters and the area-dependent device yield is the time-dependence of the cluster formation. Optical microscopy images of 3 nm BCP on ITO recorded at the same spot over time (shown in Fig. 5) reveal that the BCP clusters on ITO grow further in size over time; this increase in cluster size is consistent with Oswald ripening30,31. The size of the BCP clusters depends on the overall available surface area due a combination of two aspects: Firstly, the cluster size depends on the initial amount of molecules deposited on the surface. Larger areas enable the deposition of a larger number of molecules. Secondly, initially formed clusters need to pick up molecules from their surrounding areas in order to grow. Hence, larger areas imply a larger probability for having clusters that are with several hundred nanometers in height tall enough to shunt the cells.
If clusters tend to be larger for larger electrode areas, then the optimum thickness of BCP also depends on the area of the ITO electrodes. In order to demonstrate this thickness dependence, we fabricated 100 mm2 OPV devices in inverted configuration with BCP layer thicknesses reduced further down to 0.7, 0.5, and 0 nm. This reduction improves the overall device yield compared to the 1.5 nm BCP device (cf. Table 5). Their JV characteristics (Fig. 6) and performance values (Table 5) reveal that the device with 0.7 nm BCP (green curve in Fig. 6) has an even larger PCE than the device with 1.5 nm BCP (Table 4). Reducing the BCP thickness beyond 0.7 nm leads to less favorable device performance, which is in line with the behavior previously seen for the 2 mm2 area cells.
The up-scaling of well-performing inverted OPV devices suffers severely from the aggregation of BCP on ITO and thus an increasing probability of device failure. Despite an increased performance, the 100 mm2 devices with 0.7 nm BCP thickness were fabricated with a yield of <50% being almost a factor 2 lower than the for the 2 mm2 devices. To check to which extent the standard configuration devices may be prone to BCP cluster-induced shunting, we compare Atomic Force Microscopy (AFM) images of 3 nm BCP deposited on ITO (Fig. 7a) and 10 nm BCP deposited on C70 (Fig. 7b), corresponding to inverted and standard cell configuration, respectively. While the image in Fig. 7a confirms the formation of BCP clusters on ITO surfaces, no aggregation is discernible on top of C70 layers (Fig. 7b). This lack of clusters explains the high device yield for up-scaled standard configuration BCP based cells, and the low device yield for the inverted devices. In the supplementary information provided, AFM scans demonstrate that BCP clusters peaks through the 50 nm thick DBP/C70 active layer, which explains the origin of the inverted OPV shunting.
Combining the need to suppress the BCP cluster formation and the absence of clusters on C70 surfaces readily suggests a route to improve the structure of inverted OPV devices. An ultrathin layer of C70 was inserted in between the ITO and the BCP layer, as seen in Fig. 8 (left). The performance of the fabricated up-scaled inverted configuration cells is shown in the Fig. 8 (right) and Table 6.
As seen from Table 6, adding 1 nm of C70 between the ITO and BCP layers already improves the performance of the inverted cells compared to 100 mm2 area devices without BCP (Table 4), both in terms of device performance and yield. Increasing the thickness of the C70 layer to 2 nm improves the device yield of the 100 mm2 devices further up to 70%, which is significantly higher compared to the 10% device yield of the inverted OPVs without the C70 interlayer between ITO and BCP (Table 4). Furthermore, the performance of the inverted devices with 2 nm C70 layer sandwiched between ITO and BCP also improves significantly, showing average PCE of 2.49 ± 0.14%, i.e., close to that of a standard configuration device at the same device area. The AFM image of 3 nm BCP on top of a layer stack of glass/ITO/C70 (2 nm) is shown in Fig. 7c, revealing no aggregation of BCP here, although smaller BCP peaks are present. The lack of aggregation explains the improved device performance and yield for this structure. Increasing the thickness of the sandwiched C70 layer further decreases the overall performance of the OPV devices due to increased series resistance, energy level misalignment, and absorption loss in the active layer, which seems to be minimum at the very low C70 layer thicknesses. The results indicate that the proposed method of adding ultrathin films of C70 between ITO and BCP layer could be used for large area inverted cells, as it directly addresses the issues related to the aggregation of BCP on ITO, and thus the following device shunting that hampers both performance and especially device yield for large area inverted cells.
Conclusion
The performance of standard and inverted DBP and C70 based OPV devices incorporating BCP as electron transport layer was investigated while up-scaling the device areas from 2 to 10 and 100 mm2. The maximum PCE for 2 mm2 standard cells was 4.06 ± 0.10%, achieved for BCP thicknesses close to 10 nm, whereas an impressive PCE of 4.48 ± 0.13% for inverted cells was obtained with 1.5 nm BCP, despite the lack of electron-transport mediating metal-complexes inside the BCP layer.
In general, scaling up the device areas led to a drop in the performance that is predominantly caused by an increasing ITO resistance. For standard configuration OPV cells, we found no other factors that affect the device performance; the overall device yield remained high. For the inverted OPV cells, however, the overall device yield was strongly affected by scaling up the cell area. This pronounced dependence on the cell area is ascribed to the formation of BCP clusters on the ITO surfaces upon evaporation. The BCP clusters were observed to grow with time (presumably by Ostwald ripening). The clusters reach heights of up to several hundred nanometers and cause inverted OPV devices to fail due to electrical shunting. The larger the area of the ITO electrodes, the higher the probability that clusters large enough to shunt the cells are formed. Lowering the overall BCP thickness and the amount of BCP molecules evaporated onto the surface improved the device performance. Nevertheless, the yield remained close to 50% for these large area cells, showing that cluster formation still hampers device development.
Ultrathin layers of C70 evaporated onto ITO prior to the deposition of the BCP electron transport layers reduced the clustering of BCP on the surface. From the JV characteristics, it was noted that the device performance of 100 mm2 cells improves notably by sandwiching 2 nm of C70 between ITO and BCP, and also the device yield was observed to be larger than 70%, which was the highest observed for this cell area. Therefore, the presented approach has the potential to improve the device yield and performance to a significant extent for the large area inverted OPV cells incorporating BCP as ETL. In the future, co-evaporation of BCP and C70 together as ETL in the fabrication of inverted OPVs could be a promising direction for improving the device yield even further.
Methods
For 2 and 10 mm2 OPVs, 100 nm ITO coated glass wafers (University Wafer, Inc., USA) were patterned by positive photolithography and ITO etching, while for 100 mm2 OPV devices, ITO coated glass substrates (Kintec Company, Hong Kong) were obtained pre-patterned. ITO coated glass substrates were cleaned sequentially in an ultrasonic water bath with Acetone and IPA for 10 min each. Substrates were then dried using N2 gas.
For the inverted (structure shown in Fig. 1a) 2 mm2 OPV devices fabricated on the cleaned ITO substrates, BCP with the thicknesses of X = 0, 1.5, 3 and 5 nm was deposited at a growth rate of 0.2 Å/s. This was followed by 30 nm C70 (Sigma-Aldrich, Germany) at a growth rate of 0.5 Å/s and 20 nm DBP (Luminescence Technology Corp., Taiwan) deposited at 0.3 Å/s by Organic Molecular Beam Deposition (OMBD) at a base pressure of 3 × 10−8 mbar. MoO3 (Sigma-Aldrich, Germany) and Silver (Ag) (AESpump ApS, Denmark) were deposited by thermal evaporation at a base pressure of 5 × 10−7 mbar at a rate of at 0.3 Å/s and 1 Å/s, respectively. For the standard (as per the structure shown in Fig. 1b) 2 mm2 OPV devices, layers with a sequence of MoO3 (10 nm), DBP (20 nm), C70 (30 nm), BCP (Y = 0, 3, 5, 10, 15, 20 and 30 nm) and Ag (100 nm) were evaporated by keeping the deposition parameters the same as for the inverted OPV devices. For the up-scaled devices with the cell area of 10 and 100 mm2, devices for both standard and inverted configuration were fabricated using the optimized BCP thicknesses for the respective small area cell configurations.
The current density-voltage (JV) characteristics of OPV devices were measured in ambient conditions by applying a voltage sweep from +2 to −1 V using a 2400 source measure unit (Keithley Instruments Inc., USA), and a class AAA solar simulator (Sun 3000, Abet Technologies Inc., USA) having a calibrated lamp intensity of 100 mW/cm2. For 2 mm2 Electron-Only-Devices (EODs) (structure shown in the inset of Fig. 3), BCP with the thicknesses of X = 0, 1.5, 3 and 5 nm was deposited on the cleaned ITO substrates, followed by 30 nm C70 and 100 nm Ag keeping the deposition parameters exactly same as for the OPVs. The JV characteristics of EODs were measured in ambient air by applying a voltage sweep from +1 to −1 V using a 2400 source measure unit (Keithley Instruments Inc., USA).
Optical microscope images were taken using an Industrial microscope eclipse LV100D optical microscope (Nikon Corporation, Japan). AFM images of the structures were scanned using a Veeco Dimension 3100 scanning probe microscope.
References
Patil, B. R., Shanmugam, S., Teunissen, J. P. & Galagan, Y. All-solution processed organic solar cells with top illumination. Org. Electron. physics, Mater. Appl. 21, 40–46 (2015).
Galagan, Y., Moet, D. J. D., Hermes, D. C., Blom, P. W. M. & Andriessen, R. Large area ITO-free organic solar cells on steel substrate. Org. Electron. 13(12), 3310–3314 (2012).
Ahmadpour, M., Liu, Y., Rubahn, H. G. & Madsen, M. Current Matching in Multifold DBP/C70 Organic Solar Cells With Open-Circuit Voltages of up to 6.44 V. IEEE J. Photovoltaics 7(5), 1319–1323 (2017).
Patil, B. R., Liu, Y., Qamar, T. & Rubahn, H. 4P-NPD ultra-thin films as efficient exciton blocking layers in DBP/C70 based organic solar cells. J. Phys. D. Appl. Phys. 50, 38 (2017).
Hirade, M. & Adachi, C. Small molecular organic photovoltaic cells with exciton blocking layer at anode interface for improved device performance. Appl. Phys. Lett. 99(15), 10–13 (2011).
Hong, Z. R., Huang, Z. H. & Zeng, X. T. Utilization of copper phthalocyanine and bathocuproine as an electron transport layer in photovoltaic cells with copper phthalocyanine/buckminsterfullerene heterojunctions: Thickness effects on photovoltaic performances. Thin Solid Films 515(5), 3019–3023 (2007).
Zhang, C. et al. Roll-to-roll micro-gravure printed large-area zinc oxide thin film as the electron transport layer for solution-processed polymer solar cells. Org. Electron. physics, Mater. Appl. 45, 190–197 (2017).
Xiong, J. et al. Efficient and stable inverted polymer solar cells using TiO2 nanoparticles and analysized by Mott-Schottky capacitance. Org. Electron. 15(8), 1745–1752 (2014).
Xiong, J. et al. Efficient organic photovoltaics using solution-processed, annealing- free TiO2 nanocrystalline particles as an interface modification layer. vol. 17, pp. 253–261 (2015).
Huang, J., Yu, J., Lin, H. & Jiang, Y. Detailed analysis of bathocuproine layer for organic solar cells based on copper phthalocyanine and C60. J. Appl. Phys. 105(7), 1–6 (2009).
Gommans, H. et al. On the Role of Bathocuproine in Organic Photovoltaic Cells. Adv. Funct. Mater. 18(22), 3686–3691 (2008).
Peumans, P., Bulović, V. & Forrest, S. R. Efficient photon harvesting at high optical intensities in ultrathin organic double-heterostructure photovoltaic diodes. Appl. Phys. Lett. 76(19), 2650–2652 (2000).
Hao, X. et al. Novel cathode buffer layer of Ag-doped bathocuproine for small molecule organic solar cell with inverted structure. Org. Electron. 15(8), 1773–1779 (2014).
Bernède, J. C., Cattin, L., Morsli, M. & Berredjem, Y. Ultra-thin metal layer passivation of the transparent conductive anode in organic solar cells. Sol. Energy Mater. Sol. Cells 92(11), 1508–1515 (2008).
Peumans, P. & Forrest, S. R. Very-high-efficiency double-heterostructure copper phthalocyanine/C60 photovoltaic cells. Appl. Phys. Lett. 79(1), 126–128 (2001).
Vogel, M., Doka, S., Breyer, C., Lux-Steiner, M. C. & Fostiropoulos, K. On the function of a bathocuproine buffer layer in organic photovoltaic cells. Appl. Phys. Lett. 89(16), 1–4 (2006).
Bartynski, A. N. et al. Organic Solar Cells with Open Circuit Voltage over 1.25 v Employing Tetraphenyldibenzoperiflanthene as the Acceptor. J. Phys. Chem. C 120(34), 19027–19034 (2016).
Peumans, P., Yakimov, A. & Forrest, S. R. Small molecular weight organic thin-film photodetectors and solar cells. J. Appl. Phys. 93(7), 3693–3723 (2003).
Steim, R., Kogler, F. R. & Brabec, C. J. Interface materials for organic solar cells. J. Mater. Chem. 20(13), 2499 (2010).
Yoo, S., Domercq, B. & Kippelen, B. Efficient thin-film organic solar cells based on pentacene/C 60 heterojunctions. Appl. Phys. Lett. 85(22), 5427–5429 (2004).
Tong, X., Lassiter, B. E. & Forrest, S. R. Inverted organic photovoltaic cells with high open-circuit voltage. Org. Electron. 11(4), 705–709 (2010).
Yoshida, H. Electron Transport in Bathocuproine Interlayer in Organic Semiconductor Devices. J. Phys. Chem. C 119(43), 24459–24464 (2015).
Xiao, X., Zimmerman, J. D., Lassiter, B. E., Bergemann, K. J. & Forrest, S. R. A hybrid planar-mixed tetraphenyldibenzoperiflanthene/C70 photovoltaic cell. Appl. Phys. Lett. vol. 102, no. 7, (2013).
Zheng, Y. et al. Highly efficient bulk heterojunction photovoltaic cells based on C 70 and tetraphenyldibenzoperiflanthene. Appl. Phys. Lett. 102(14), 143304 (2013).
Wang, Z. et al. Highly efficient organic p-i-n photovoltaic cells based on tetraphenyldibenzoperiflanthene and fullerene C70. Energy Environ. Sci. 6(1), 249–255 (2013).
Wang, J. C., Ren, X. C., Shi, S. Q., Leung, C. W. & Chan, P. K. L. Charge accumulation induced S-shape J–V curves in bilayer heterojunction organic solar cells. Org. Electron. 12(6), 880–885 (2011).
Patil, B. R. et al. ITO with embedded silver grids as transparent conductive electrodes for large area organic solar cells. Nanotechnology vol. 28 (2017).
Mori, T. & Masumoto, Y. Effect of Organic Alloy for Suppression of Polycrystallization in BCP Thin Film. J. Photopolym. Sci. Technol. 19(2), 209–214 (2006).
Turak, A. Dewetting Stability of ITO Surfaces in Organic Optoelectronic Devices. S. L. Pyshkin and J. M. B. T.-O.-A. M. & Ballato, D., Eds Rijeka: In Tech, p. Ch. 10 (2013).
Günes, S., Neugebauer, H. & Sariciftci, N. S. Conjugated Polymer-Based Organic Solar Cells. Chem. Rev. 107(4), 1324–1338 (2007).
Ohring, M. Chapter 7 - Substrate Surfaces and Thin-Film Nucleation BT - Materials Science of Thin Films (Second Edition). San Diego: Academic Press, pp. 357–415 (2002).
Acknowledgements
This work is carried out under the framework of SDU2020 project “Production of Next-Generation Energy Devices”. This project has received funding from the European Union Seventh Framework Programme under grant agreement No. 607232 [THINFACE] and the RollFlex project – part-financed by Interreg Deutschland-Danmark with means from the European Regional Development Fund and the Southern Denmark Growth Forum.
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B.R.P. and M.M. conceived the idea. B.R.P., G.S. and M.M. designed the experiments. M.A. and T.Q. fabricated the 2 mm2 standard and inverted configuration organic solar cells, respectively, and conducted their characterization. A.F.F. conducted characterization of electron-only-devices. The work was carried out under the supervision of K.Z., H.G.R. and M.M. All co-authors participated in the exchange and analyses of the results as well as in the editing the manuscript.
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Patil, B.R., Ahmadpour, M., Sherafatipour, G. et al. Area dependent behavior of bathocuproine (BCP) as cathode interfacial layers in organic photovoltaic cells. Sci Rep 8, 12608 (2018). https://doi.org/10.1038/s41598-018-30826-7
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DOI: https://doi.org/10.1038/s41598-018-30826-7
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