Carbonaceous materials with high surface area and a sheet-like structure promote fast ion-transport kinetics, making them an ideal choice to be used in supercapacitors. Few-layer graphene (FLG)-like nanosheets with abundance of micro as well as mesopores are achieved via mechanical exfoliation method from an agricultural waste biomass: peanut shell (PS). A well-known elementary method of probe-sonication, for the achievement of FLG sheets from renewable sources, is introduced in this study for the very first time. The Peanut shell-derived FLG (PS-FLG) possesses remarkably high specific surface area (2070 m2 g−1) with a sufficiently large pore volume of 1.33 cm3 g−1. For the fabrication of a binder-free supercapacitor, the PS-FLG-based electrodes exhibited a high specific capacity of 186 F g−1 without the use of any binder in 1 M H2SO4 as supporting electrolyte. The highest energy density of 58.125 W h Kg−1 and highest power density of 37.5 W Kg−1 was achieved by the material. Surprisingly, the working potential increased to 2.5 V in an organic electrolyte leading to an obvious increase in the energy density to 68 W h Kg−1. Solid-state-supercapacitor was fabricated with this material for the possible use of low-cost, high energy promising energy storage device.
Graphene, an atomically thin layer of carbon, is an extremely promising two-dimensional (2D) nano material1. Since its discovery, initially being regarded only as an ‘academic material,’ graphene emerged as a free-standing 2D planar nano allotrope of elemental carbon, packed in a patterned honeycomb lattice with extremely high carrier mobility suitable for energy applications2,3,4. It has received extensive attention because of its inherent structural flexibility yet substantial mechanical strength, optical transparency and enormous theoretical surface area (2630 m2 g−1)1,5. However, the production of single or few-layer graphene in a simple, efficient, cost-effecitve and scalable pathway is still a massive challaenge in material science.
In the past years, several methods are reported for the synthesis and fabrication of graphene depending upon the applications6. Recent research progresses are thus focused on the scalable production of graphene-related materials for commercial applications. However, high scale preparation of graphene with economically valuable and environmentally sustainable methods is still recognized as a challenging issue. Two-dimensional single and/or few-layered graphene has been synthesized by different methods like, (a) chemical vapor deposition (CVD) from decomposition of methane/acetylene/ethylene on metal surface7,8, (b) micromechanical exfoliation or scotch tape method from graphite1,9, (c) epitaxial growth on electrically insulating surface10, (d) chemical method for the production of graphene or reduced graphene oxide (rGO)11 and (e) carbonization of biomass/waste materials12,13. For the production of graphene without sacrificing the quality of the material; CVD, micromechanical exfoliation, and epitaxial growth have significant roles, but, these methods are not acceptable for economic and large-scale synthesis. However, a chemical process for the production of graphene from exfoliation of graphite oxide can show a route for scalable synthesis, but it involves hazardous and toxic reagents. Moreover, quality of the chemically produced reduced graphene oxide is not suitable for the energy storage device as it suffers from poor electrical conductivity14. Recently, researchers are involved in developing a sustainable technique for the large-scale production of carbon nanomaterials including graphene from natural sources (like plant leaves, biochar, waste corn shell, fungus, eggshell, and even human hair)15,16,17,18.
Bio-waste materials are currently the hotspots because of their abundance, need for recycling and being ample source of carbon. Biomass from plant wastes mainly consists of carbohydrates, fiber, and proteins. Lignin, cellulose, and hemicelluloses are the main components of plant fiber and small amounts of other materials like protein, starches and lipids are also present in there19,20. The management of waste biomass has always been a big challenge in smart cities. Hence, bio-waste can be subjected to conversion into carbonaceous materials to achieve economically-worthwhile products for its emergent applications21. Biomass and waste materials such as food, agricultural waste, wood waste and other stuff have been utilized for the eco-friendly sources for graphene synthesis12,13,22,23. Most of the procedures either used chemical graphitizing agents12 or high-temperature graphite furnace22 together with activating agents to get graphene of high surface area. Some researchers experimented with multi-step processes (like CVD or plasma enhanced CVD)24,25 to grow conductive graphene. These methods are neither scalable nor economical. It is therefore immensely desired to develop a scalable, renewable and cost-effective process for the production of high-quality graphene towards the development of electrode materials for electrical energy storage (EES) devices like supercapacitors and batteries.
Supercapacitors, also known as electrochemical capacitors gained considerable popularity over the last two decades because of their versatile potential in energy storage and delivery. They can store more volumetric or gravimetric energy (energy density) than conventional capacitors; while on the other hand, are able to deliver or accept energy (power density) few orders higher than batteries26. Supercapacitors can be fully charged or discharged within seconds and can withstand tens of thousands of charge-discharge cycles without compromising on its energy storage capacity. They are therefore one of the most sought-after EES devices with a broad application range, from hybrid energy vehicles, memory backup and emergency power supply to microelectronic devices like personal digital assistants27. Currently, new technologies for the applications of supercapacitors are under challenging research since the performance of the device strongly depends on mechanical strength, surface area, porosity and the production cost of the active electrode materials. Carbonaceous materials including CNTs, activated carbon and their derivatives are setting benchmarks in this flourishing field of supercapacitors, due to their natural biocompatibility, chemical stability, mechanical strength, high conductivity, large surface area and therefore evidently an innate ability to store charges28,29,30,31. However, most of these materials face a major drawback regarding low energy density (5–8 W h Kg−1), low specific capacitance and dynamically poor electronic conductivity32. Synthesizing an advanced carbon-based electrode is thus still a significant challenge for the current researchers are dealing with energy storage devices. Graphene stands out to be a better candidate to be employed as an active electrode material for portable supercapacitor devices. State-of-the-art energy-storage devices are thus intrigued with graphene33. Single or few layer graphene can offer low-resistant pathway and short ion diffusion channel, which is perpetual solution for high power delivery of supercapacitors34,35,36.
In this work, our objective of using biomass-waste is not only to solve the problem of waste recycling but also to generate value-added materials for renewable energy storage devices like supercapacitors. Peanut shell is a globally-known waste-biomass having no end-use other than being feedstock of animal and building construction materials37. According to the Food and Agriculture Organization (FAO) of the United Nations, India is the second largest country after China in peanut production (6.6 million tons per year)37. Peanut produces a lot of waste as nutshell all over the world that is approximately six million tons per year38. More importantly, peanut shell waste is inexpensive, copious and environmentally benign biological resource. Till now it has been explored only at an research and development scale in the following fields, such as low-cost bio-adsorbent39, metal ion removal and wastewater treatment40,41,42,43, as a catalyst in organic functionalization44, fuel gas (H2) production45, and the hybrid capacitor38. Ding et al. recently reported both cathode and anode material of a hybrid sodium ion capacitor derived from peanut shell38. He et al. developed a supercapacitor with mesoporous carbon derived from peanut biomass using ZnCl2 activation assisted microwave heating46. Activated carbon or mesoporous carbon arising from these methods suffer either from low surface area or high oxygen loading, resulting in a bad conductivity of the materials. It is thus highly anticipated to develop carbon nanomaterials with good conductivity, porous layered structure and high specific surface area, suitable for both fast ion diffusion kinetics and charge storage at the electrochemical double layer for its subsequent applications in supercapacitors. Two-dimensional graphene-like sheets have got the desired morphology, but it has a tendency to restack the layers to get graphite-like structures due to the π-π interaction of the graphene sheets; causing diminished surface area of the resulting materials. Here we have presented a rather common method of mechanical exfoliation in a new perspective by the utilization of no-use peanut shells to obtain value-added few-layer graphene (FLG)-like sheets with an extensively high surface area towards the development of high energy and high-power supercapacitor. Our procedure is highly efficient, environmentally satisfying, economical, scalable and without involving any chemical graphitizing reagent/catalyst.
Materials and Chemicals
Peanut shells, walnut shells and almond shells were obtained from the local market as waste products. Potassium hydroxide (KOH), potassium bromide (KBr), sulphuric acid (H2SO4), and isopropanol were purchased from Merck Chemicals, India limited. Tetraethylammonium tetrafluoroborate (Et4NBF4), ethylene carbonate (EC), N,N-Dimethylformamide (DMF) and Dichloroethane (DCE) were purchased from Sigma-Aldrich. Polyvinyl Alcohol (PVA) was purchased from Alfa-Aesar. All other reagents used in this study were of pure analytical grade and were used without any further purification. All aqueous solution was prepared using mili-Q water.
Fourier transform Infrared (FTIR) spectroscopy was carried out on an Agilent technology Cary 600 series FTIR instrument at room temperature. For FTIR analysis, PS-FLG was mixed with KBr and then finely ground to make a pellet. Raman Spectroscopy was performed on a WITEC Focus Innovations Alpha-300 Raman confocal microscope at a laser wavelength of 532 nm. X-ray Diffraction (XRD) spectroscopic study was carried out on a Bruker D8 Advances instrument using Cu-Κα (λ = 1.5406 Å) radiation in the 2θ range from 5° to 80° with an acceleration voltage of 40 KV. Nitrogen adsorption-desorption analysis was done at 77 K on an Autosorb iQ2 instrumental setup to examine the surface area by Brunauer Emmett Teller (BET) method. The pore size distribution was computed by the nonlocal density functional theory (NLDFT) technique. The samples were degassed at 300 °C for more than 12 h under vacuum conditions. The surface morphology and the elemental composition of the synthesized material were investigated using Scanning Electron Microscopy (SEM Jeol JSMIT300) equipped with a Bruker XFlash 6130 Energy Dispersive X-ray Spectroscopy (EDS) at each stage of synthesis. Probe sonication was performed on a QSonica (Part no.-Q700, USA) ultrasonicator using a replaceable microtip of the diameter of 1/16″ (1.6 mm) at an amplitude of 112 µm (35%). Atomic force microscopy (AFM, Bruker Multimode 8) was used to investigate the surface topologies of the synthesized active material (PS-FLG). Transmission Electron Microscopy (TEM) studies were carried out on a JEM2100 instrument, equipped with digital micrograph software for investigating Selected Area Electron Diffraction (SAED) pattern of the graphene sheets. All electrochemical experiments, like, cyclic voltammetry, galvanostatic charge-discharge and electrochemical impedance spectroscopy (EIS) were performed in 1 M H2SO4 solution aqueous electrolyte and 1 M Et4NBF4 (in 1:1 EC: DCE) organic electrolyte using a CHI 760E electrochemical workstation. Glassy carbon (GC) disc electrode was used to load the active material and studied for their electrochemical behavior. A three-electrode cell setup with a GC working (0.07 cm2), a platinum wire auxiliary and Ag/AgCl (3 M KCl) reference electrodes were used in the voltammetric and chronopotentiometric measurements. A similar setup was organized for electrochemical testing in the organic electrolyte system except for Ag/Ag+, which was taken as the reference electrode. Sigma DC regulated power supply (0–30 V, 0–5 A) was used for charging the solid-state devices to constant potential.
Synthesis of graphene from waste peanut shell
Peanut shell-derived few layer graphene (PS-FLG) was prepared by a simple activation (by KOH) followed by mechanical exfoliation method. Peanut shells wastes were collected from the local market as waste products and purified by the following method. The waste material was copiously washed with distilled water to remove dust and other interfering particles and dried in sunlight for a few days. Then it was dried in a vacuum oven at 80 °C for overnight to remove any moisture content. These shells were crushed into a fine powder which was stored in the completely dried atmosphere. For the synthesis of carbon nanomaterials, the peanut shell precursor (PS-P) powder (5.0 g) was pyrolyzed in a tubular furnace at 800 °C for two hours under an argon atmosphere at a heating rate of 3 °C min−1. The resulting carbonized product of peanut shell (PS-C) was washed thoroughly with isopropanol to remove any unwanted organic deposition. Then the carbon powder was mixed with a well-known porogen KOH (w/w 1:3) and mixed it through mortar-pestle to get a homogeneous mixture. This homogeneous mixture was then heated in a tubular furnace under an argon atmosphere at 800 °C for another two hours to generate the required porosity and functionality to get peanut shell derived activated carbon materials (PS-AC). The activated sample was then washed with 1:1 HCl solution followed by distilled water until the pH reached neutrality and dried for overnight. The exfoliation of the as-prepared PS-AC sample was performed in 10% H2SO4 aqueous solution through probe sonication for 1 hour with a power of 15 W and a pulse on-and-off time of 5 seconds. The tip was dipped well inside the solution for better sonication, but a distance of at least 2 cm was maintained from touching the bottom of the beaker containing the solution. The desired temperature was maintained throughout by using an icebath and by carrying out the experiment in 5 seconds pulses separated by 5 seconds cooling period. Finally, the product was repeatedly washed with isopropanol and deionized water to remove any impurity if present in the sample. The washed samples were centrifuged and dried at 80 °C for overnight. The final product is named as peanut shell derived exfoliated few-layered graphene (PS-FLG). The weight of the PS-FLG material synthesized from peanut shell waste was calculated to be 1.125 g and the corresponding yield was found to be 22.5 wt % with respect to PS-P material. Figure 1 shows the schematic pathway used for the synthesis of PS-FLG from precursor PS-P. Walnut shell-derived carbon (WS-C) and almond shell-derived carbon (AS-C) were prepared from waste walnut shells and almond shells, respectively, for comparison with the capacitive behavior of PS derived material. Same procedures as described above were followed maintaining similar experimental conditions.
Fabrication of supercapacitor electrode
A cleaned Glassy carbon (GC) electrode was used as a conductive current collector for evaluation of the electrochemical performance of the as-developed materials in a three-electrode setup. Before use, the GC electrode was polished with fine alumina powder and repeatedly washed with DI water followed by sonication in water. The active materials (PS-C, PS-AC, and PS-FLG) were dispersed in1:1 isopropanol-water mixture and sonicated for 15 min to get a homogeneous dispersion. The solution was then drop cast on the pre-cleaned GC electrode and dried overnight at room temperature in vacuum. The concentration of all the active materials loaded on GC electrode was 1 mg cm−2. The electrode was subjected to all electrochemical measurements performed in a three-electrode system. Cyclic voltammetry (CV), galvanostatic charging-discharge (GCD) and electrochemical impedance spectroscopy (EIS) were carried out using CHI 760E electrochemical workstation. All the electrochemical measurements were performed between a potential window of −0.4 to 1.1 V in 1 M H2SO4 aqueous electrolyte and −1.3 to 1.2 V in 1 M Et4N-BF4 organic electrolyte.
The solid-state supercapacitor was made with PS-FLG powder coated on ITO sheets and assembled together with gel electrolyte. Briefly, the PS-FLG powder material was first dispersed in DMF solution, and dense ink was made out of it. The ink was then coated onto thin ITO sheet using doctors blade and dried under vacuum overnight. After drying, two of such PS-FLG coated ITO sheets were symmetrically sandwich together with PVA-H2SO4 as an ionogel electrolyte to construct an all-solid-state supercapacitor. The ionogel electrolyte was prepared by adding 1 g of polyvinyl alcohol (PVA) in 10 ml water and stirred at 90 °C until the solution becomes clear. A stoichiometric amount of H2SO4 solution (1 M) was then added to the mixture, and the stirring was continued for another 1 h. The device was allowed to dry at room temperature for 24 h before testing its performance.
Results and Discussions
It is crucial to design advanced electrode materials to meet the rising and urgent demand for high-performance supercapacitors. An inexpensive carbon-based electrode would not only provide a cost advantage but would also maximize the device energy density. Peanut shell-derived few-layer graphene (PS-FLG) was so chosen as the active material for supercapacitor. First, peanut shell precursor was carbonized followed by activation with KOH. Potassium reacts violently to rip apart the layers between carbons. To get the highly dispersed PS-FLG, probe ultrasonication was preferred to accelerate the aqueous exfoliation of PS-AC in H2SO4 because a definite power delivery into the aqueous system can be ensured in this process; entirely different from the variable bath ultrasonication47. Probe sonication was performed on a QSonica (Part no.- Q700, USA) ultrasonicator using a replaceable microtip of a diameter of 1/16″ (1.6 mm) at an amplitude of 112 µm for 1 h with a pulse on-and-off time of 5 seconds.
To check the dispersion of the as derived PS-FLG material in different solutions, several aqueous, as well as organic solvents have been selected. Figure S1 shows the digital photographs of PS-FLG dispersed in various solvents like water, isopropanol, dimethylformamide, dimethyl sulfoxide and carbon tetrachloride. The PS-FLG sample exhibits high dispersibility in polar (aqueous) as well as non-polar (organic) solvents. Fourier-Transform Infra-Red (FT-IR) analysis was conducted to establish the functional group present in PS-FLG material. As can be observed in Fig. S2, an array of both polar and non-polar functional groups is present in PS-FLG. The absorption peak at 3429 cm−1 can be assigned for the -OH stretching vibrations of the hydroxylic group and chemisorbed water48. The skeletal ring vibration of graphene-like sheets can be observed at 1631 cm−1 49,50. The peak at 3160 cm−1 stands for C=C-H stretching mode51. Medium broad vibration observed at 2786 cm−1 is ascribed to the overtones of O-H bending mode which arise from proton tunneling and Fermi resonance interactions52. The peaks at 1397 cm−1 and 1464 cm−1 appears because of the-CH2 and -CH symmetric bending modes53. Presence of both polar and non-polar groups in its structure, makes PS-FLG disperse both in aqueous or organic solvents.
In order to investigate the structural transformations of the as-synthesized PS derived carbon materials, Raman spectral analysis was carried out. Figure 2a records all the Raman peaks corresponding to the PS-derived carbon structures at various stages of synthesis. Raman spectra of graphene-like materials are regularly characterized by two featured bands, D-band & G-band54. The D-band arise due to the breathing mode of k-point phonons of A1g symmetry and G-band is assigned to the first order scattering of E2g phonon of sp2 carbon atoms21,55. As can be observed in Fig. 2a there is a gradual red shift in the D-peak from PS-C (1351 cm−1) to PS-AC (1344 cm−1) to PS-FLG (1342 cm−1); it can be assigned to the gradual attainment of the more ordered structure of the PS-derived material at each stage. The G-band appears because of degenerate in-plane E2g optical mode at the center of the Brillouin zone of graphitic carbon56. PS-derived carbons show a red-shift also in their G-band from PS-C (1593 cm−1) to PS-AC (1590 cm−1) to PS-FLG (1588 cm−1); gradually reaching for the more graphitic character. A characteristic overtone peak (2D band) at 2680 cm−1and (S3 band) at 2909 cm−1 appeared corresponding to PS-FLG, indicating graphitization of the materials57. The degree of crystallinity is directly proportional to the intensity ratio of D & G-peaks. As calculated from the obtained data, IG/ID for PS-FLG is 1.01, gradually increasing from 0.99 for PS-AC & 0.98 for PS-C; suggesting the increase in crystalline nature of the material12.
Wide angle X-ray powder diffraction analysis of the PS-FLG sample was conducted under monochromatized Cu-Kα to study the crystallinity and phase structure. As shown in Fig. 2b, the prominent diffraction peak at 2θ = 30.1° originates because of the characteristic reflection from the (002) graphitic plane. This peak is much sharper than the small peak at 2θ = 43.5° assigned to the (100) plane of distorted graphitic sheets, confirming the high degree of crystallinity of the exfoliated sample58. Figure S3 gives a comparative view of the XRD patterns of WS-C and AS-C. It shows the presence of some turbostratic disordered carbon phase along with the characteristic diffraction peaks for carbonaceous materials, at 2θ = 23.9° corresponding to the (002) plane and 2θ = 43.1° for the (100) plane in both AS-C and WS-C59.
Specially designed layered carbon nanomaterials with a good balance between mesoporosity and microporosity is highly desirable to achieve high energy/power density simultaneously60. Materials with high surface-to-volume ratio and abundance of mesopores promote sufficient charge storage (high energy density) and fast charge transfer kinetics (high power density) respectively which are very significant for applications in advanced energy storage systems. The N2 adsorption-desorption isotherm of PS-FLG shows a mixed type I and type IV curve as observed in Fig. 2c; typical of a material with both microporosity and mesoporosity. A magnified image, of the curve corresponding to PS-FLG shown in the inset of Fig. 2c, shows a typical type IV curve with an H2 type hysteresis loop, inherent of a mesoporous material, in the relative pressure (P/P0) range of 0.4–0.712,60. However, this type of hysteresis loop is absent in the case of PS-C and PS-AC (Fig. 2c), suggesting the presence of only micropores in them. Only micropores are not suitable for either charge storage or propagation12. A steep increase in N2 uptake at lower relative pressure also suggests the presence of micropores in PS-FLG61. Mechanical exfoliation not only separates the graphene sheets, but it is also involved in increasing the porosity, suitable for supercapacitors. Pore size distribution was computed using the adsorption branch of the isotherm by the NLDFT method, showing an average pore size of 1.3 nm in Fig. 2d. Magnified view of the NLDFT pore size distribution plot of PS-FLG (Fig. 2d, inset) reveals achievement of mesopores (2.1–5.4 nm) during exfoliation. Microporous substances with an enhanced surface area is ideal for elevated capacitance and power density in aqueous electrolyte because of high conductivity and smaller ionic size62. But to explore its potential in the organic electrolyte, it is necessary to have a reasonable mesopore volume and their good interconnectivity for the electrolyte ions to effectively realize all the available surface area of the carbon framework63,64. The specific surface area of the PS-FLG is measured to be 2070 m2 g−1, whereas, the surface area of PS-C and PS-AC is estimated to be 645 and 1554 m2 g−1, respectively. This high surface area acknowledged the superiority of the methods used to produce PS-FLG material compared to other methods reported recently for producing graphene-like carbon from biomass13,22,23,65,66 (Table 1). Such a high specific surface area (2070 m2 g−1) with high pore volume (1.33 cm3 g−1) can afford more active sites during the charge-discharge process and thus makes PS-FLG an attractive material for energy storage devices. WS-C and AS-C were also subjected to BET surface area analysis and the specific surface area of the WS-C and AS-C are measured to be 363 and 403 m2 g−1, respectively. Figure S4a gives the comparative N2 adsorption-desorption isotherm plot of PS-FLG with the other two nutshells-derived carbon. Magnified view of WS-C and AS-C are shown in Figure S4b, which represents that both the materials possess type IV curve with an H2 type hysteresis loop, typically observed for mesoporous materials. Though the average pore size of both the material is around 2 nm, the presence of pores with larger diameters (Figure S4c) are also observed, confirming the presence of mesopores in them. Although the materials have mesoporous architecture, their not-so-high specific surface area along with low pore volume (0.047 cm3 g−1 for WS-C and 0.035 cm3 g−1 for AS-C) is responsible for their lower capacitive properties than PS-FLG. Table S1 summarizes all the surface morphological analysis data obtained from the peanut, walnut and almond shell-derived carbon material.
To investigate the microstructures, surface morphology and topology of the as-synthesized materials, SEM and AFM investigations were performed. The morphology of PS-FLG can be attributed to our synthesis strategy which is tailored accordingly to take maximum structural advantage of the peanut shell. SEM images in Fig. 3a–c reveals that the so formed PS-FLG contains a broad distribution of sheet-like structure. Figure S5a shows the distinctive SEM micrograph of the pre-carbonized PS, where the naturally abundant lignocellulosic microfibril networks quantify the rough surface morphology, a characteristic feature of any biomass. Figure S5b and c show the SEM images of the carbonized sample PS-C, and KOH-activated sample PS-AC, respectively. As observed, on activation with KOH at 800 °C the samples transformed to sheet-like morphology. Further, as seen in Fig. 3a–c, on exfoliation the otherwise stacked sheet-like structure was transformed to few layers graphene-like morphology with nearly transparent appearance. SEM images of walnut and almond waste shell based carbon were also captured. As can be observed in Figure S6, both WS-C and AS-C have a porous surface with profoundly broken sheet structures forming agglomerates unlike the continuous few-layer graphene-like nanosheet morphology, observed for PS-FLG in Fig. 3.
EDS was carried out to find out the elemental composition of the as developed PS-FLG, as observed in Fig. S7. The abundance of carbon is clearly seen with almost 94 wt.% of it with the minimal occurrence of oxygen (only about 6 wt.%) confirming the effective carbonization of the active materials. Atomic force microscopic (AFM) measurements were conducted to study the top-view images and cross-sectional thickness of the FLG material. The average cross-sectional thickness of the graphene sheets is found to be around 3.2 nm. Figure 3d reveals the existence of 6–8 layers of graphene sheets, considering the thickness of the monolayer graphene is 0.33 nm67. A detailed three-dimensional mapping of the PS-FLG nanosheets is presented in Fig. S8.
TEM measurement was performed to confirm the morphology of the few-layered graphene materials further. As can be seen in Fig. 4a–c, transparent few-layer graphene-like nanosheets are to be clearly observed at various magnifications on a holey carbon grid. High-resolution TEM (HRTEM) images of selected regions are presented in Fig. 4d and e revealing distorted nanosheets consisting about 5–6 layers of graphene nanosheets. Further, HRTEM confirms the interlayer spacing of ~0.34 nm (Fig. 4e), which corresponds to the (002) plane of few-layered graphene nanosheets. Selected area electron diffraction (SAED) analysis reveals the presence of a hexagonal lattice of crystalline graphene-like sheets with long-range order62. As can be observed from the diffraction pattern in Fig. 4f, there are six well-defined diffraction spots corresponding to a graphene-like lattice, indicating the crystalline nature of the sheets68,69. The active crystal planes of the nanosheets of PS-FLG are calculated to be (002) and (100) planes of the reciprocal lattice, which is in line with the data obtained from XRD measurements (Fig. 2b).
Electrochemical performances were measured to evaluate the potential applications of the PS-derived few layer graphene-like nanosheets as an active electrode material in aqueous as well as organic electrolyte using three electrode setup. Cyclic voltammetric curves obtained in 1 M H2SO4 at different stages of synthesis show the gradual increase in specific capacitance (CSP) from the carbonized sample, PS-C; to the activated sample, PS-AC; and to the exfoliated sample, PS-FLG as exhibited in Fig. 5a. The increase in the CSP of PS-FLG with respect to PS-C and PS-AC is due to the increased specific surface area as well as the better distribution of pores of slightly larger diameter (as shown in Fig. 2d, inset); which favours the charge storage capacity of the exfoliated material. It explains the phenomenon of better ion transport of the PS-FLG materials; which further establishes the need for exfoliation to attain well-separated nanosheets. A distinctive capacitive behavior with quasi-rectangular CV curve was maintained throughout a good range of scan rates from 10 mV s−1 to 1000 mV s−1 for PS-FLG as shown in Fig. 5b, implying quick dynamics of high power behavior of the PS-FLG material. The presence of a bump in CV at slow scan rate indicates a little contribution of redox species to the electrochemical capacitance of the PS-FLG materials. The closely rectangular shape of the CV was maintained above the scan rate of 100 mV s−1, which may be attributed to the optimum amount of combined micropore and mesopore volume as well as good electrical conductivity63. The capacitive potential of the PS-FLG based electrode was further investigated by galvanostatic charge-discharge (GCD) experiments. An expected increase in discharge time was observed in the case of PS-FLG from PS-AC or PS-C at a current density of 1 A g−1 as shown in Fig. 5c.
The highest CSP of 186 F g−1 was obtained at a current density of 0.5 A g−1 for PS-FLG as can be calculated from Fig. 5d. The superior performance of PS-FLG can be ascribed to its porous sheets like structure and the high BET surface area (2070 m2 g−1) which is crucial for better penetration of electrolyte ions and fast charge propagation and storage. Exfoliation promotes a few atomic layered thick graphene sheets, increasing its electrical conductivity dramatically and thus PS-FLG shows a huge increment in capacitive performance as an active electrode material for supercapacitor. The CSP (F g−1) of PS-FLG-based electrode material were calculated at various current densities from 0.5 A g−1 to 50 A g−1 (Fig. 5d). Rate capability is one of the determining parameters that are essential for practical applications of the active electrode material. Here as can be seen, even at a higher current density (50 A g−1), the typical quasi-rectangular shape of the GCD curve is maintained showing appreciable charge-discharge reversibility. As with enhanced current density, limited charge diffusion tends to reduce the specific capacity; Fig. 5e demonstrates how excellently PS-FLG can retain CSP, even with increasing current density.
For the fabrication of highly advanced supercapacitor for practical use, energy density must be improved without sacrificing the power supply. Enhanced CSP with a wide operating potential window is appropriate for increasing the energy density of the supercapacitor material. From the Ragone plot (Fig. 5f), it can be observed that PS-FLG exhibits highest energy density of 58.13 W h Kg−1 against a reasonably good power density of 375 W Kg−1 in a large potential window of 1.5 V (−0.4 V–1.1 V). This is maintained at 15.63 W h Kg−1 even at the highest power density of 37.5 KW Kg−1 in an aqueous electrolyte of 1 M H2SO4. The PS-AC and PS-C show highest energy densities at 6.8 W h Kg−1, and 1.2 W h Kg−1 with highest power densities attained at 15 W Kg−1 and 7.5 W Kg−1, respectively (Fig. 5f).
Electrochemical responses of the walnut and almond shells-derived carbon (WS-C or AS-C) were also studied as potential materials for different carbon sources for comparison. Cyclic voltammetry (Fig. 6a) at a scan rate of 100 mV s−1 and galvanostatic charge-discharge study at 0.5 A g−1 (Fig. 6b) was conducted for WS-C and AS-C to compare the capacitive behavior with PS-FLG material. As can be observed in Fig. 6b, PS-FLG shows a huge CSP of 186 F g−1, much more (about 4.5 times and 2.5 times higher) than that indicated by WS-C (42 F g−1) or AS-C (78 F g−1) at a current density of 0.5 A g−1. Detailed electrochemical performance of WS-C and AS-C are shown in Fig. S9. Fig. S9a and b gives the cyclic voltammetric responses at various scan rates while Fig. S9c and d represent the galvanostatic charge- discharge profile at different scan- rates of WS-C and AS-C based electrodes. As can be seen in Fig. S9c and d, both WS-C and AS-C are stable only up to a current density of 10 A g−1, much lower than PS-FLG which can retain their rate capability even at a much higher discharge current of 50 A g−1.
Electron impedance spectroscopy (EIS) was further done at the open circuit potential (OCP) to ensure that the as developed few-layer graphene-like nanosheets are well equipped to promote fast charge-discharge as well as efficient charge storage12. As demonstrated in Fig. 7a, at lower frequency region, the imaginary part increases more sharply for PS-FLG, than PS-C & PS-AC, indicating diffusion limited electron transfer characteristic of ideal capacitive behavior of the material. A closer view of the mid-frequency region reveals that the line due to Warburg resistance cuts the real axis at the smallest angle for PS-FLG as compared to other PS-based electrode materials. It indicates that the ion diffusion pathways for electrolyte ions to the pores of the electrode surface is shortest for PS-FLG12. A magnified image (inset, Fig. 7a) in the higher frequency region shows the real axis intercept provides equivalent series resistance (ESR, Rs) along with the semicircular impedance loop whose diameter gives the charge transfer resistance (Rct). The Rs value for the PS-FLG material is found to be 6.1 Ω, whereas, it was 6.8 Ω and 25.4 Ω, for PS-AC and PS-C, respectively. The Rs value clearly tells the PS-FLG material has high conductivity and low internal resistance. The nanosheet-like structure allows for fast ion-transfer kinetics between the electrode surface and electrolyte making it most suitable for use as an active material. Figure 7b is the Bode phase plot, which demonstrates that in the low-frequency region when the phase shift approaches −70°, the material performs more like capacitors attends with the diffusion process70,71. The phase angle reaches −45° at the capacitor response frequency of 5.6 Hz, which is much higher than activated carbon (0.15 Hz)72.
Galvanostatic charge-discharge cycling stability is one of the critical parameters to look out for in commercially available supercapacitors. The active material must endure fast charging-discharging at higher current densities and yet maintain its inherent property even after large number of GCD cycles. Figure 7c exhibits a promising 87% CSP retention even after 5000 GCD cycles at a sufficiently higher current density (10 A g−1). Fig. 7d shows the initial and final five GCD cycles having almost similar triangular pattern retained as is expected for good charge propagation of electrolyte ions into PS-FLG electrodes. CV plots before and after GCD cycling test can be observed in Figure S10, showing a slight decrease in the area under the curve but the characteristic CV shape is retained. This confirms the cycling stability of the active material. Figure 7c also shows retaining of coloumbic or faradaic efficiency around 100% indicating an absence of any side reactions or faradaic processes were taking place during GCD cycling test.
The capacitive behavior of PS-FLG material was tested in an organic electrolyte. Briefly, the CV and charge-discharge test were performed in 1 M Et4NBF4 in 1:1 mixture of EC: DCE solvent with a three-electrode setup. Figure 8a exhibits the cyclic voltammetric response of the PS-FLG active electrode material in the organic electrolyte system. A high CSP of 78.3 F g−1 at a current density of 1 A g−1 during galvanostatic charge-discharge study was achieved (Fig. 8b). Introducing organic electrolyte allows an increment of the potential window to 2.5 V, thereby increasing the energy density to 68 W h Kg−1.
A comparative study of carbonaceous materials obtained from various waste biomass sources and their capacitive performances are presented in Table 2. A supercapacitor needs to have sufficiently high energy density without sacrificing on its instant power delivery, to be employed for commercialization. It is mostly observed that any material, which is stable even on a more extensive potential range, subsequently has higher energy storage capacity. Mostly reported supercapacitors based on carbon nanostructures are limited to function within a potential range of 1 V in an aqueous electrolyte12,21,73,74,75,76,77. However, our as developed PS-FLG material is shown to be functional in a much higher potential window of 1.5 V. Another key factor lies in the attainment of morphologies suitable for maximum charge storage. The predominant product morphology for the carbonaceous materials from the majority of the waste sources is found to be mostly activated or porous carbon. Only activated carbons from dried corn grains or sugarcane bagasse has got limited energy densities at a range of 10–30 W h Kg−1 75,77. On the other hand, nano or micro porous carbons from various sources like wood sawdust, dead neem leaves or waste coffee beans exhibit slightly better energy densities in the range of 8–55 W h Kg−1 (power densities ranging from 5–12 KW Kg−1) mostly because of the presence of well-distributed pores48,57,78. This establishes the need for a combination of both a layered structure with well-distributed pores and sufficiently high surface area for the achievement of higher energy density. PS-FLG possesses all these qualities along with an enhanced potential window. It shows almost 6 times higher energy density (58.25 W h Kg−1) and 3.75 times higher power density (37.5 KW Kg−1) than a similar morphology of few-layer graphene-like nanosheets achieved from waste coconut shell (9.58 W h Kg−1 at a maximum power delivery of 10 KW Kg−1)12.
Performance evaluation of the fabricated symmetric solid-state supercapacitor
In order to ascertain the commercial application and performance of the developed PS-FLG material, we fabricated a symmetric solid-state device (SSD) by coating the synthesized PS-FLG onto a conducting substrate (ITO) and using PVA-H2SO4 as the gel electrolyte (Fig. 8c, inset and Fig. S11). Microscopic SEM images of the solid-state electrode surface are displayed in Fig. S12, showing the abundance of sheet-structures at low magnification. First, the performance and output deliverance of SSD was characterized and the voltage behavior was monitored using a multimeter (Supporting video, Fig. S13). The discharge voltage with respect to time was monitored as described in Fig. 8c. After charging the device using a constant DC power supply (3 V) for 60 s, the discharge voltage was 1.15 V and monitored for 180 s thereafter. The discharge voltage was noted as 0.70 V, 0.55 V, 0.44 V and 0.41 V after 30 s, 60 s, 120 s, and 180 s, respectively. The voltage retention is around 0.4 V more than 240 s. To further demonstrate the practical application of the device, two devices (PS-FLG/PVA-H2SO4/ITO) were connected in series. The connected devices were charged up to 3 Volts using a constant DC power supply and were then disconnected. The devices in series were able to light a commercial red LED (1.5 V) successfully (Fig. 8d). These results infer that the developed PS-FLG as electrode material exhibits significant possibilities in energy application.
In summary, we have developed a new approach for the synthesis of few-layered graphene from no-value biomass waste peanut shell without using any graphitizing agents. The PS-FLG materials possess remarkably high specific surface area and satisfactorily large pore volume. The adsorption-desorption isotherm of PS-FLG reveals that the materials have both the micropores and mesopores. The PS-FLG material is suitable for application in supercapacitor and shows high specific capacitance of 186 F g−1 without using any binder in 1 M H2SO4 as supporting electrolyte. The PS-FLG exhibits highest energy density of 58.13 W h Kg−1 and highest power density of 37.5 KW Kg−1 in an aqueous electrolyte of 1 M H2SO4. The specific capacitance and energy density of the PS-FLG material was also tested in an organic electrolyte (1 M Et4NBF4 in 1:1 mixture of EC: DCE). The specific capacitance of 78.3 F g−1 at a current density of 1 A g−1 and a sufficiently high energy density of 68 W h Kg−1 was observed. The high specific capacitance and energy density can be explained by the presence of micropores with mesopores and high surface area of the PS-FLG materials. We have also synthesized walnut shell and almond shell derived carbon for comparison purpose, and the PS-FLG possesses approximately four times more specific capacitance than WS-C and two times more than AS-C. A solid-state supercapacitor device was fabricated with the PS-FLG materials with ITO as a current collector to demonstrate the possible application and performance of the material. We have shown that the PS-FLG materials have the potential for application as supercapacitor device.
Geim, A. K. & Novoselov, K. S. The rise of graphene. Nat. Mater. 6, 183–191 (2007).
Avila, J. et al. Exploring electronic structure of one-atom thick polycrystalline graphene films: A nano angle resolved photoemission study. Sci. Rep. 3, 1–8 (2013).
Stoller, M. D. et al. Graphene-Based Ultracapacitors. Nano Lett. 8, 3498–3502 (2008).
Bonaccorso, F. et al. 2D materials. Graphene, related two-dimensional crystals, and hybrid systems for energy conversion and storage. Science 347, 1246501 (2015).
Liu, J., Xue, Y. H., Zhang, M. & Dai, L. M. Graphene-based materials for energy applications. MRS Bull. 37, 1265–1272 (2012).
Park, S. & Ruoff, R. S. Chemical methods for the production of graphenes. Nat. Nanotechnol. 4, 217–224 (2009).
Eizenberg, M. & Blakely, J. M. Carbon monolayer phase condensation on Ni (111). Surf. Sci. 82, 228–236 (1979).
Kunkel, R., Poelsema, B., Verheij, L. K. & Comsa, G. Phys. Rev. 657, 768–771 (1990).
Novoselov, K. S. et al. Electric Field Effect in Atomically Thin Carbon Films. Science 306, 666 (2011).
Berger, C. et al. Electronic Confinement and Coherence in Patterned Epitaxial Graphene. Science 312, 1191–1196 (2006).
Chua, C. K. & Pumera, M. Chemical reduction of graphene oxide: a synthetic chemistry viewpoint. Chem. Soc. Rev. 43, 291–312 (2014).
Sun, L. et al. From coconut shell to porous graphene-like nanosheets for high-power supercapacitors. J. Mater. Chem. A 1, 6462–6470 (2013).
Zhou, H. et al. Transforming waste biomass with an intrinsically porous network structure into porous nitrogen-doped graphene for highly efficient oxygen reduction. Phys. Chem. Chem. Phys. 18, 10392–10399 (2016).
Novoselov, K. S. et al. A roadmap for graphene. Nature 490, 192–200 (2013).
Zhu, H., Wang, X., Yang, F. & Yang, X. Promising carbons for supercapacitors derived from fungi. Adv. Mater. 23, 2745–2748 (2011).
Wang, H., Li, Z. & Mitlin, D. Tailoring Biomass-Derived Carbon Nanoarchitectures for High-Performance Supercapacitors. ChemElectroChem 1, 332–337 (2014).
Qian, W. et al. Human hair-derived carbon flakes for electrochemical supercapacitors. Energy Environ. Sci. 7, 379–386 (2013).
Qian, K., Kumar, A., Zhang, H., Bellmer, D. & Huhnke, R. Recent advances in utilization of biochar. Renew. Sustain. Energy Rev. 42, 1055–1064 (2015).
Anwar, Z., Gulfraz, M. & Irshad, M. Agro-industrial lignocellulosic biomass a key to unlock the future bio-energy: A brief review. J. Radiat. Res. Appl. Sci. 7, 163–173 (2014).
Yang, H., Yan, R., Chen, H., Lee, D. H. & Zheng, C. Characteristics of hemicellulose, cellulose and lignin pyrolysis. Fuel 86, 1781–1788 (2007).
Biswal, M., Banerjee, A., Deo, M. & Ogale, S. From dead leaves to high energy density supercapacitors. Energy Environ. Sci. 6, 1249–1259 (2013).
Chen, F., Yang, J., Bai, T., Long, B. & Zhou, X. Facile synthesis of few-layer graphene from biomass waste and its application in lithium ion batteries. J. Electroanal. Chem. 768, 18–26 (2016).
Jacob, M. V. et al. Catalyst-Free Plasma Enhanced Growth of Graphene from Sustainable Sources. Nano Lett. 15, 5702–5708 (2015).
Seo, D. H., Rider, A. E., Han, Z. J., Kumar, S. & Ostrikov, K. Plasma break-down and re-build: Same functional vertical graphenes from diverse natural precursors. Adv. Mater. 25, 5638–5642 (2013).
Ruan, G., Sun, Z., Peng, Z. & Tour, J. M. Growth of graphene from food, insects, and waste. ACS Nano 5, 7601–7607 (2011).
Lukatskaya, M. R., Dunn, B. & Gogotsi, Y. Multidimensional materials and device architectures for future hybrid energy storage. Nat. Commun. 7, 12647 (2016).
Yu, D. et al. Emergence of fiber supercapacitors. Chem. Soc. Rev. 44, 647–62 (2015).
Wei, X., Wan, S., Jiang, X., Wang, Z. & Gao, S. Peanut-Shell-like Porous Carbon from Nitrogen-Containing Poly- N -phenylethanolamine for High-Performance Supercapacitor. ACS Appl. Mater. Interfaces 7, 22238–22245 (2015).
Zhang, L. L., Zhou, R. & Zhao, X. S. Graphene-based materials as supercapacitor electrodes. J. Mater. Chem. 20, 5983 (2010).
Ghosh, A. & Lee, Y. H. Carbon-based electrochemical capacitors. ChemSusChem 5, 480–499 (2012).
Candelaria, S. L. et al. Nanostructured carbon for energy storage and conversion. Nano Energy 1, 195–220 (2012).
Tang, W. et al. Aqueous supercapacitors of high energy density based on MoO3 nanoplates as anode material. Chem. Commun. 47, 10058–10060 (2011).
Shao, Y. et al. Graphene-based materials for flexible supercapacitors. Chem. Soc. Rev. 44, 3639–3665 (2015).
Allen, M. J., Tung, V. C. & Kaner, R. B. Honeycomb Carbon: A Review of Graphene. Chem. Rev. 110, 132–145 (2010).
Gogotsi, Y. Materials science: Energy storage wrapped up. Nature 509, 568–70 (2014).
Goodenough, J. B., H. D. Abruna, & M. V. Buchanan. Basic Research Needs for Electrical Energy Storage. Report of the Basic Energy Sciences Workshop on Electrical Energy Storage, April 2–4, DOESC (USDOE Office of Science (SC)), (2007).
‘Production data for from FAOSTAT, (Item: “Groundnuts, with shell”, Area: World, Year: 2014)’. FAOSTAT, Food and Agricultural Organization of the United Nations, Statistics Division. 2014. Retrieved 23 November 2016. (2014).
Ding, J. et al. Peanut shell hybrid sodium ion capacitor with extreme energy-power rivals lithium ion capacitors. Energy Environ. Sci. 8, 941–955 (2015).
Witek-Krowiak, A., Szafran, R. G. & Modelski, S. Biosorption of heavy metals from aqueous solutions onto peanut shell as a low-cost biosorbent. Desalination 265, 126–134 (2011).
ALOthman, Z. A., Naushad, M. & Ali, R. Kinetic, equilibrium isotherm and thermodynamic studies of Cr(VI) adsorption onto low-cost adsorbent developed from peanut shell activated with phosphoric acid. Environ. Sci. Pollut. Res. 20, 3351–3365 (2013).
Wilson, K., Yang, H., Seo, C. W. & Marshall, W. E. Select metal adsorption by activated carbon made from peanut shells. Bioresour. Technol. 97, 2266–2270 (2006).
Ahmad, M. et al. Effects of pyrolysis temperature on soybean stover- and peanut shell-derived biochar properties and TCE adsorption in water. Bioresour. Technol. 118, 536–544 (2012).
El-Shafey, E. I. Removal of Se(IV) from aqueous solution using sulphuric acid-treated peanut shell. J. Environ. Manage. 84, 620–627 (2007).
Zhao, W., Yang, B., Yi, C., Lei, Z. & Xu, J. Etherification of glycerol with isobutylene to produce oxygenate additive using sulfonated peanut shell catalyst. Ind. Eng. Chem. Res. 49, 12399–12404 (2010).
Nisamaneenate, J., Atong, D., Sornkade, P. & Sricharoenchaikul, V. Fuel gas production from peanut shell waste using a modular downdraft gasifier with the thermal integrated unit. Renew. Energy 79, 45–50 (2015).
He, X. et al. Efficient preparation of biomass-based mesoporous carbons for supercapacitors with both high energy density and high power density. J. Power Sources 240, 109–113 (2013).
He, P. et al. Urea-assisted aqueous exfoliation of graphite for obtaining high-quality graphene. Chem. Commun. 51, 4651–4654 (2015).
He, X. et al. Rice husk-derived porous carbons with high capacitance by ZnCl2 activation for supercapacitors. Electrochim. Acta 105, 635–641 (2013).
Nethravathi, C. & Rajamathi, M. Chemically modified graphene sheets produced by the solvothermal reduction of colloidal dispersions of graphite oxide. Carbon N. Y. 46, 1994–1998 (2008).
Dey, R. S., Hajra, S., Sahu, R. K., Raj, C. R. & Panigrahi, M. K. A rapid room temperature chemical route for the synthesis of graphene: metal-mediated reduction of graphene oxide. Chem. Commun. 48, 1787 (2012).
Krishnakumar, V. & Balachandran, V. FTIR, FT-Raman spectral analysis and normal coordinate calculations of 2-hydroxy-3-methoxybenzaldehyde thiosemicarbozone. Indian J. Pure Appl. Phys. 42, 313–318 (2004).
Panicker, C. Y., Varghese, H. T., Philip, D. & Nogueira, H. I. S. FT-IR, FT-Raman and SERS spectra of pyridine-3-sulfonic acid. Spectrochim. Acta - Part A Mol. Biomol. Spectrosc. 64, 744–747 (2006).
Guo, P. Z., Ji, Q. Q., Zhang, L. L., Zhao, S. Y. & Zhao, X. S. Preparation and characterization of peanut shell-based microporous carbons as electrode materials for supercapacitors. Acta Phys. Chim. Sin. 27, 2836–2840 (2011).
Lazzarini, A. et al. Graphitization of Activated Carbons: A Molecular-level Investigation by INS, DRIFT, XRD and RamanTechniques. Phys. Procedia 85, 20–26 (2016).
Amarnath, C. A. et al. Efficient synthesis of graphene sheets using pyrrole as a reducing agent. Carbon N. Y. 49, 3497–3502 (2011).
Bokobza, L., Bruneel, J.-L. & Couzi, M. Raman Spectra of Carbon-Based Materials (from Graphite to Carbon Black) and of Some Silicone Composites. C—Journal Carbon Res. 1, 77–94 (2015).
Moon, I. K., Lee, J., Ruoff, R. S. & Lee, H. Reduced graphene oxide by chemical graphitization. Nat. Commun. 1, 73 (2010).
Xu, J. et al. Preparing two-dimensional microporous carbon from Pistachio nutshell with high areal capacitance as supercapacitor materials. Sci. Rep. 4, 5545 (2014).
Kurdyumov, A. V. et al. Structural studies of materials: Structure of intermediate carbon phase formed under shock compression of ultradispersed graphite materials. Powder Metall. Met. Ceram. 45, 86–92 (2006).
Zhu, Z. et al. Dual Tuning of Biomass-Derived Hierarchical Carbon Nanostructures for Supercapacitors: The Role of Balanced Meso/Microporosity and Graphene. Sci. Rep. 5, 15936 (2015).
Jiang, L., Yan, J., Xue, R., Sun, G. & Yi, B. Partially graphitized ordered mesoporous carbons for high-rate supercapacitors. J. Solid State Electrochem. 18, 2175–2182 (2014).
Lee, D. et al. Coffee-Driven Green Activation of Cellulose and Its Use for All-Paper Flexible Supercapacitors. ACS Appl. Mater. Interfaces 9, 22568–22577 (2017).
Bhattacharjya, D. & Yu, J.-S. Activated carbon made from cow dung as electrode material for electrochemical double layer capacitor. J. Power Sources 262, 224–231 (2014).
Bhattacharjya, D., Kim, M. S., Bae, T. S. & Yu, J. S. High performance supercapacitor prepared from hollow mesoporous carbon capsules with hierarchical nanoarchitecture. J. Power Sources 244, 799–805 (2013).
Fang, B. et al. Multimodal porous carbon as a highly efficient electrode material in an electric double layer capacitor. Microporous Mesoporous Mater. 182, 1–7 (2013).
Xu, D., Xie, Y., Song, Y. J. & Deng, W. Q. A green and facile method toward synthesis of waste paper-derived 3D functional porous graphene via in situ activation of cobalt(II). J. Mater. Chem. A 3, 16072–16078 (2015).
Peng, K. J. et al. Dissolution-and-reduction CVD synthesis of few-layer graphene on ultra-thin nickel film lifted off for mode-locking fiber lasers. Sci. Rep. 5, 13689 (2015).
Wang, G. X. et al. Facile Synthesis and Characterization of Graphene Nanosheets. J. Phys. Chem. C 112, 8192–8195 (2008).
Zhang, J. J. et al. Reduction of graphene oxide via L-ascorbic acid. Chem. Commun. 46, 1112–4 (2010).
Sheng, K., Sun, Y., Li, C., Yuan, W. & Shi, G. Ultrahigh-rate supercapacitors based on eletrochemically reduced graphene oxide for ac line-filtering. Sci. Rep. 2, 247 (2012).
Zheng, C., Yoshio, M., Qi, L. & Wang, H. A 4 V-electrochemical capacitor using electrode and electrolyte materials free of metals. J. Power Sources 260, 19–26 (2014).
Miller, J. R., Outlaw, R. A. & Holloway, B. C. Graphene Double-Layer Capacitor with ac Line-Filtering Performance. Science 329, 1637–1639 (2010).
Yin, S. et al. Functional free-standing graphene honeycomb films. Adv. Funct. Mater. 23, 2972–2978 (2013).
Chen, W., Zhang, H., Huang, Y. & Wang, W. A fish scale based hierarchical lamellar porous carbon material obtained using a natural template for high performance electrochemical capacitors. J. Mater. Chem. 20, 4773 (2010).
Wang, Y. et al. Development of Low-Cost DDGS-Based Activated Carbons and Their Applications in Environmental Remediation and High-Performance Electrodes for Supercapacitors. J. Polym. Environ. 23, 595–605 (2015).
Rufford, T. E., Hulicova-Jurcakova, D., Zhu, Z. & Lu, G. Q. Nanoporous carbon electrode from waste coffee beans for high performance supercapacitors. Electrochem. commun. 10, 1594–1597 (2008).
Rufford, T. E., Hulicova-Jurcakova, D., Khosla, K., Zhu, Z. & Lu, G. Q. Microstructure and electrochemical double-layer capacitance of carbon electrodes prepared by zinc chloride activation of sugar cane bagasse. J. Power Sources 195, 912–918 (2010).
Huang, Y. et al. Biobased Nano Porous Active Carbon Fibers for High-Performance Supercapacitors. ACS Appl. Mater. Interfaces 8, 15205–15215 (2016).
TP acknowledges DST INSPIRE and GS acknowledges SERB EMR for providing fellowship. This work was financially supported by the DST INSPIRE (DST/INSPIRE/04/2015/000337) and SERB EMR (EMR/2016/000040). Authors acknowledge INST Mohali for instrumental support.
The authors declare that they have no competing interests.
Publisher's note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
About this article
Cite this article
Purkait, T., Singh, G., Singh, M. et al. Large area few-layer graphene with scalable preparation from waste biomass for high-performance supercapacitor. Sci Rep 7, 15239 (2017). https://doi.org/10.1038/s41598-017-15463-w
Fullerenes, Nanotubes and Carbon Nanostructures (2020)
Production of high-performance biochar using a simple and low-cost method: Optimization of pyrolysis parameters and evaluation for water treatment
Journal of Analytical and Applied Pyrolysis (2020)
Waste-Derived Heteroatom-Doped Activated Carbon/Manganese Dioxide Trio-Composite for Supercapacitor Applications
Energy Technology (2020)
An improved hybrid nanocomposites of rice husk derived graphene (GRHA)/Zeolitic imidazolate framework-8 for hydrogen adsorption
International Journal of Hydrogen Energy (2020)