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# Magnetic anisotropy control by applying an electric field to the side surface of ferromagnetic films

Scientific Reportsvolume 7, Article number: 5618 (2017) | Download Citation

## Abstract

Reducing the power consumption necessary for magnetization reversal is one of the most crucial issues facing spintronics devices. Electric field control of the magnetic anisotropy of ferromagnetic thin films is a promising method to solve this problem. However, the electric field is believed to be effective only within several nanometres of the surface in ferromagnetic metals because of its short Thomas-Fermi screening length, which prevents its practical application to devices. Herein, we successfully modulate the magnetic anisotropy of the entire region of the ferromagnetic layers in the elongated mesas of vertical spin field-effect transistors with widths as large as ~500 nm by applying an electric field to the side surface of the metallic GaMnAs-based mesas through an electric double layer. Our results will open up a new pathway for spintronics devices with ultra-low power consumption.

## Introduction

The electric field control of ferromagnetism is expected to be a key technique for future low-energy, non-volatile spintronics devices1,2,3,4. Recently, the Curie temperature and magnetic anisotropy of ferromagnetic thin films have been shown to be modulated by a gate electric field applied to the top surface of the films. However, the collective modulation of magnetic anisotropy is effective only when the film thickness is extremely thin (~a few nanometres)1, 2, so it is difficult to use this technique in practical applications. Thus, new techniques to overcome this problem are urgently needed.

The vertical spin electric-double-layer transistor (EDLT) used in our study (Fig. 1) is a type of a spin metal-oxide-semiconductor field-effect transistor (spin MOSFET)5, which has ferromagnetic source and drain electrodes and a semiconductor channel. Because of their current-amplification ability and compatibility with mature semiconductor technologies, spin MOSFETs have promising applications, such as low-power reconfigurable logic gates6 and non-volatile power gating7, with novel functions. In spin MOSFETs, a spin-polarized current is injected from the ferromagnetic electrode to the channel and controlled by the magnetization directions of the source and drain. Most of the previous studies were focused on conventional planar spin transistors8,9,10,11,12; however, the obtained magnetoresistance (MR) ratios were only 0.1%8, 0.005%9, and 0.03%10. This is because the carrier spins are quite sensitive to the crystal quality at the interfaces between ferromagnetic layers and semiconductors and because the channel length (~μm) is too long to prevent the influence of spin relaxation.

In this study, we adopt a vertical transistor structure13, which is more practical because it allows for the achievement of a short channel length on the order of nanometres with atomic-level control (Fig. 1a). Thus, we can significantly suppress the spin-relaxation during transport. In theory, we can realize large MR as high as that is obtained in magnetic tunnel junctions in the vertical device. We prepared elongated-mesa vertical EDLTs with a width of 500 nm. In EDLTs14,15,16,17, we can apply a large electric field of up to ~10 MV/cm to the side surface of the mesas using an ionic liquid. We successfully achieved a modulation ratio of the drain-source current I DS up to ~20%, which is much larger than that obtained in the previous study on a vertical spin MOSFET (~0.5%)13, and we also obtained a large MR ratio (~5%) that was 50–1000 times as large as those observed in studies of conventional planar spin field-effect transistors8,9,10. Furthermore, we found that the magnetic anisotropy of the ferromagnetic layers is modulated by the electric field (Fig. 1b,f). Because the electric field penetrates only less than 10 nm into the GaMnAs layers13, and because the collective gate electric field modulations of ferromagnetism of GaMnAs were observed only in extremely thin films, this behaviour was completely unexpected in such wide and elongated mesas with a width of 500 nm. Our results indicate that applying an electric field to the side surface of the ferromagnetic layers may be useful for the collective control of ferromagnetism in spintronics devices.

## Results

### Samples

The device used in this study has a thin GaAs channel (11 nm) between the ferromagnetic Ga0.95Mn0.05As source and drain electrodes (Fig. 1a) (see the Methods section). The ferromagnetic p-type semiconductor GaMnAs is one of the most appropriate materials for a proof-of-concept study of a spin MOSFET because it can be epitaxially grown on a semiconductor GaAs without any dislocations. This can significantly suppress the spin scattering of the tunnelling carriers. We fabricated elongated mesas with a width of 500 nm and a length of 50 μm. The comb-shaped drain electrode is connected to the tops of the 30 mesas. The substrate was used as a source electrode. By applying a gate bias voltage V GS to a Au/Cr gate electrode on an insulating SiO x film next to the mesas, an electric field was applied to the side surface of the mesas through the electrolyte (N,N-diethyl-N-(2-methoxyethyl)-N-methylammonium bis(trifluoromethylsulfonyl-imide), [DEME-TFSI]). Thus, holes are accumulated or depleted at the side surfaces of the mesas by V GS, thereby modulating I DS (Fig. 1b–i). Here we note that the electric field modulation of the band structure is more effective in the intermediate GaAs layer than in the top and bottom GaMnAs layers because there are many holes and thus strong screening in the GaMnAs layers. In the GaMnAs layers, the potential only at the side surface is slightly modulated. Thus, the electric lines of force originating from the side wall of the GaAs layer should go to one of the GaMnAs electrodes, which results in a vertical component of the electric field in GaAs (Fig. 1i). All the measurements were performed at 3.8 K, which is much lower than the Curie temperature (typically ~110–130 K when the Mn content is 6%18 of GaMnAs).

### Spin transistor operation

As shown in Fig. 2a, plotting I DS vs. the drain–source voltage V DS reveals that |I DS| increases or decreases as V GS decreases or increases, as expected. The modulation ratio of I DS, which is defined as [I DS (V GS) − I DS (V GS = 0 V)]/I DS (V GS = 0 V), is 10–20% when V GS is −3.0 V (Fig. 2b). The significant improvement of the modulation ratio relative to that observed in the previous study (~0.5%)13 is achieved by reducing the size of the device and increasing the electric field using the ionic liquid.

For spin transistor operation, the I DS modulation by the magnetization alignment is important. As shown in Fig. 3a, the tunnel resistance is controlled by the magnetization configuration of the two GaMnAs layers; the tunnel resistance is high in the anti-parallel magnetization configuration and low in the parallel one. It is noteworthy that the anti-parallel magnetization configuration is realized because the coercivities of top and bottom GaMnAs layers are different due to the heating during the growth19. Here, the MR ratio is defined as (R AP − R P)/R P, where R P and R AP are the tunnel resistances in the parallel and anti-parallel configurations, respectively. Therefore, in our vertical spin EDLT, current modulation by both the gate electric field and the magnetization alignment is successfully achieved.

### Magnetic anisotropy control

Furthermore, we found that the electric field applied to the side surface of the device influences the magnetic anisotropy of the entire region of the GaMnAs layers in these elongated mesas. The magnetic anisotropy was investigated by measuring the in-plane magnetic-field direction ϕ dependence of the MR (Fig. 4a–e). Here, ϕ is defined as the angle from the in-plane [100] direction (Fig. 3b), and the MR ratio is defined as [R(H) − R(0)]/R(0) at each ϕ, where R(H) is the tunnel resistance when the applied magnetic field is H. The observed anisotropy of MR means that the obtained MR characteristics are originated from tunnel magnetoresistance effects, not from tunnel anisotropic magnetoresistance effects (For the detail, see Supplementary Note 1, and Supplementary Fig. S1). As shown in Fig. 4a–e, both of the MR patterns and the MR ratio are modulated with V GS. When V GS = 0 V, the MR pattern is symmetric with respect to the [$$\bar{1}10$$] axis (Fig. 4c). Meanwhile, when V GS < 0 V, it becomes asymmetric (Fig. 4a); the red-coloured regions, which correspond to the nearly ideal anti-parallel magnetization configuration, extend in the [110] (or [$$\bar{1}\bar{1}0$$]) direction. When V GS > 0 V, the red-coloured regions are broadened, and the pattern has a slight tendency to be four-fold symmetric along the 〈100〉 direction (Fig. 4e).

## Discussion

To understand the mechanism underlying this behaviour, we calculated and reproduced the polar plot of the MR ratio using the Stoner-Wohlfarth coherent rotation model. In this model, the magnetostatic energy E of a ferromagnetic film, which has a magnetization M in the in-plane direction of θ with respect to the in-plane [100] direction (Fig. 3b), is expressed by3, 20

$$\begin{array}{rcl}E & = & \frac{M{H}_{{\rm{B}}}}{8}{\sin }^{2}(2\theta )+\frac{M{H}_{{\rm{U}}[\bar{1}10]}}{2}{\sin }^{2}(\theta -\frac{3\pi }{4})\\ & & +\frac{M{H}_{{\rm{U}}[010]}}{2}{\sin }^{2}(\theta -\frac{\pi }{2})-MH\,\cos (\theta -\varphi ),\end{array}$$
(1)

where H B, $${H}_{U[\bar{1}10]}$$ and H U[010] are the biaxial anisotropy field along 〈100〉 (i.e., [100] and [010]), the uniaxial anisotropy field along [$$\bar{1}10$$] and that along [010], respectively. In this model, θ is determined so that E takes a local minimum. In addition, we allowed the magnetization to be reversed by the nucleation and propagation of the 180° domain wall; in this case, θ moves from one local minimum to another local minimum with a lower energy when the energy difference between these points exceeds the domain nucleation/propagation energy ε. When the relative angle of the magnetization directions of the top and bottom ferromagnetic layers in our device is Δθ, the MR ratio is expressed by21

$$(\text{MR}\,\text{ratio})=\frac{{P}^{2}(1-\,\cos ({\rm{\Delta }}\theta ))}{1+{P}^{2}\,\cos ({\rm{\Delta }}\theta )},$$
(2)

where P is the spin polarization of the ferromagnetic layers.

Using equations (1) and (2) and the values of H B, $${H}_{U[\bar{1}10]}$$ and H U[010] plotted in Fig. 5a,b, we can well reproduce the ϕ dependence of the MR (Fig. 4f–j, see the Methods section, Supplementary Note 2, and Supplementary Fig. S2). The difference in the V GS dependence of the anisotropy fields between the top and bottom GaMnAs layers probably results from the different quality between the two layers. As shown in Fig. 5a,b, the uniaxial anisotropy along [$$\bar{1}10$$] ($${H}_{U[\bar{1}10]}$$) is dominant in both GaMnAs layers. As V GS increases, the biaxial anisotropy (H B) tends to be stronger. This tendency is different from that in the previous report, in which the uniaxial anisotropy increased as the gate electric field applied to the top surface of the GaMnAs layers increased1. This difference may be caused by the difference in the electric field direction (i.e., parallel to the side surface vs. parallel to the top surface) or the film quality.

In our model, domain walls are considered only when the magnetization switch occurs. Thus, in principle, our model is a single-domain model. Therefore, the good agreement between the experimental ϕ dependence of the MR (Fig. 4a–e) and that calculated using this model (Fig. 4f–j) indicates that the magnetic anisotropy of the entire region of the elongated mesas (width: 500 nm) is changed by the gate electric field applied to the side surface (Fig. 5a–d). In particular, as shown in Fig. 5c, the magnetic easy axis of the top GaMnAs layer is rotated by 16° (Fig. 1b,f), which is larger than that (~10°) observed in the previous study1, by the gate electric field. This behaviour is surprising and cannot be explained in the current understanding of the electric field’s control of ferromagnetism, because magnetic anisotropy is modulated in such wide elongated mesas (~500 nm), while the potential is modulated only within ~10 nm of the side surface of the GaMnAs layers. This situation may be similar to the case of the collective metal-insulator transition observed in VO2 induced by the gate electric field applied to the film’s top surface22. In ref. 22, the metal-insulator transition was observed in the entire region of films with thicknesses up to 70 nm, although the charges were accumulated only at the top surface of the films. The collective phase transition occurs because it is favourable to remain in a single phase at length scales less than a domain size to minimize interface energy22. In the analogy of the metal-insulator transition in VO2, the collective modulation of ferromagnetism in GaMnAs can be explained. In GaMnAs, the typical magnetic domain size is a few μm23, and it may not be energetically favourable for a domain wall to form along the longitudinal direction of the elongated mesas. Thus collective control of the magnetic anisotropy is possible just by changing the magnetic properties within 10 nm of the side surface.

Our results indicate that applying an electric field to the side surface of the ferromagnetic layers may be quite effective for the manipulation of magnetization in spintronics devices, and suggest that the shape or size of the mesas is important for the collective control of the ferromagnetism in thin films. Further miniaturization and exploring more appropriate materials will realize the more effective modulation even at room temperature.

## Methods

### Growth

The heterostructure composed of Ga0.95Mn0.05As (9.2 nm)/GaAs (11 nm)/Ga0.95Mn0.05As (10 nm)/GaAs:Be (100 nm) was grown on a p+GaAs (001) substrate by low-temperature molecular beam epitaxy. The substrate temperatures during the growth of the bottom Ga0.95Mn0.05As, the middle GaAs, and the top Ga0.95Mn0.05As layers were 205 °C, 185 °C and 195 °C, respectively.

### Process

After the growth, we fabricated the vertical spin EDLT structure. We partially etched the grown films, buried the etched area under a SiO x insulating film, and then formed a contact pad for the drain electrode on the insulating film to allow I DS to flow only in the patterned mesa diodes, which have a width of 500 nm and a length of 50 μm. In our measurements, before changing V GS, we increased the sample temperature to 220 K from the measurement temperature of 3.8 K because, at this temperature, the ionic liquid is frozen and the ions in the electrolyte cannot move. After changing V GS, the sample was cooled to 3.8 K while maintaining V GS. Although the Au/Cr drain electrode and the GaAs:Be layer are also covered by the ionic liquid, they are metallic and thus the gate-modulation effect in them are negligibly small (see Supplementary Note 3, and Supplementary Fig. S3).

### Measurements

The I DS-V DS characteristics were measured before H was applied at each V GS. Thus the magnetization direction of every magnetic domain in each GaMnAs layer was not aligned in the same direction, because the sample temperature was increased to ~220 K, which is much higher than the Curie temperature (typically ~110–130 K when the Mn content is 6%) of the GaMnAs layers, to change V GS before the I DS - V DS measurements. To measure the ϕ dependence of the MR, we applied a strong magnetic field of 1 T in the opposite direction of ϕ to first align the magnetization directions, and then we decreased the magnetic field to zero before the measurements. Subsequently, we started to measure the tunnel resistance while increasing the magnetic field from zero in the ϕ direction. The measurements were performed at every 15° step of ϕ. To calculate the ϕ dependence of the MR, P was set to 0.15. During the measurements of the ϕ dependence of the MR, the Joule heating was negligibly small (see the Supplementary Note 4, and Supplementary Fig. S4).

## Additional information

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## References

1. 1.

Chiba, D. et al. Magnetization vector manipulation by electric fields. Nature 455, 515 (2008).

2. 2.

Sawicki, M. et al. Experimental probing of the interplay between ferromagnetism and localization in (Ga, Mn)As. Nature Physics 6, 22 (2010).

3. 3.

Chiba, D. et al. Electrical control of the ferromagnetic phase transition in cobalt at room temperature. Nature Materials 10, 853 (2011).

4. 4.

Anh, L. D., Hai, P. N., Kasahara, Y., Iwasa, Y. & Tanaka, M. Modulation of ferromagnetism in (In, Fe)As quantum wells via electrically controlled deformation of the electron wave functions. Phys. Rev. B 92, 161201(R) (2015).

5. 5.

Sugahara, S. & Tanaka, M. A spin metal-oxide-semiconductor field-effect transistor using half-metallic-ferromagnet contacts for the source and drain. Appl. Phys. Lett. 84, 2307 (2004).

6. 6.

Matsuno, T., Sugahara, S. & Tanaka, M. Novel Reconfigurable Logic Gates Using Spin Metal–Oxide–Semiconductor Field-Effect Transistors. Jpn. J. Appl. Phys. 43, 6032 (2004).

7. 7.

Shuto, Y., Yamamoto, S. & Sugahara, S. Nonvolatile static random access memory based on spin-transistor architecture. J. Appl. Phys. 105, 07C933 (2009).

8. 8.

Nakane, R., Harada, T., Sugiura, K. & Tanaka, M. Magnetoresistance of a Spin Metal-Oxide-Semiconductor Field-Effect Transistor with Ferromagnetic MnAs Source and Drain Contacts. Jpn. J. Appl. Phys. 49, 113001 (2010).

9. 9.

Sasaki, T. et al. Spin Transport in Nondegenerate Si with a Spin MOSFET Structure at Room Temperature. Phys. Rev. Applied 2, 034005 (2014).

10. 10.

Tahara, T. et al. Room-temperature operation of Si spin MOSFET with high on/off spin signal ratio. Appl. Phys. Express 8, 113004 (2015).

11. 11.

Koo, H. C. et al. Control of Spin Precession in a Spin-Injected Field Effect Transistor. Science 325, 1515 (2009).

12. 12.

Chuang, P. et al. All-electric all-semiconductor spin field-effect transistors. Nature Nanotechnology 10, 35 (2015).

13. 13.

Kanaki, T., Asahara, H., Ohya, S. & Tanaka, M. Spin-dependent transport properties of a GaMnAs-based vertical spin metal-oxide-semiconductor field-effect transistor structure. Appl. Phys. Lett. 107, 242401 (2015).

14. 14.

Saito, Y. & Iwasa, Y. Ambipolar Insulator-to-Metal Transition in Black Phosphorus by Ionic-Liquid Gating. ACS Nano 9, 3192 (2015).

15. 15.

Saito, Y., Kasahara, Y., Ye, J., Iwasa, Y. & Nojima, T. Metallic ground state in an ion-gated two-dimensional superconductor. Science 23, 409 (2015).

16. 16.

Shimotani, H. et al. Insulator-to-metal transition in ZnO by electric double layer gating. Appl. Phys. Lett. 91, 082106 (2007).

17. 17.

Yamada, Y. et al. Electrically Induced Ferromagnetism at Room Temperature in Cobalt-Doped Titanium Dioxide. Science 332, 1065 (2011).

18. 18.

Muneta, I., Ohya, S., Terada, H. & Tanaka, M. Sudden restoration of the band ordering associated with the ferromagnetic phase transition in a semiconductor. Nature Communications 7, 12013 (2016).

19. 19.

Ohya, S., Muneta, I., Hai, P. N. & Tanaka, M. GaMnAs-based magnetic tunnel junctions with an AlMnAs barrier. Appl. Phys. Lett. 95, 242503 (2009).

20. 20.

Pappert, K. et al. Detailed transport investigation of the magnetic anisotropy of (Ga, Mn)As. New Journal of Physics 9, 354 (2007).

21. 21.

Higo, Y., Shimizu, H. & Tanaka, M. Anisotropic Tunneling Magnetoresistance in GaMnAs/AlAs/GaMnAs Ferromagnetic Semiconductor Tunnel Junctions. J. Appl. Phys. 89, 6745 (2001).

22. 22.

Nakano, M. et al. Collective bulk carrier delocalization driven by electrostatic surface charge accumulation. Nature 487, 459 (2012).

23. 23.

Pross, A. et al. Magnetic domain imaging of ferromagnetic GaMnAs films. J. Appl. Phys. 95, 7399 (2004).

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## Acknowledgements

This work was partially supported by Grants-in-Aid for Scientific Research (No. 16H02095 and 26249039), the Project for Developing Innovation Systems of MEXT, and the Spintronics Research Network of Japan (Spin-RNJ). Part of this work was conducted under the Cooperative Research Project Program of RIEC, Tohoku University. Y. I. was supported by a Grant-in-Aid for specially promoted research (No. 25000003) from JSPS.

## Author information

### Affiliations

1. #### Department of Electrical Engineering and Information Systems, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

• Hiroshi Terada
• , Shinobu Ohya
• , Le Duc Anh
•  & Masaaki Tanaka
2. #### Center for Spintronics Research Network, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

• Shinobu Ohya
•  & Masaaki Tanaka
3. #### Institute of Engineering Innovation, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

• Shinobu Ohya
•  & Le Duc Anh
4. #### QPEC and Department of Applied Physics, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo, 113-8656, Japan

• Yoshihiro Iwasa
5. #### RIKEN Center for Emergent Matter Science, Wako, 351-0198, Japan

• Yoshihiro Iwasa

### Contributions

Device fabrication and experiments: H.T., L.D.A. and Y.I.; data analysis and theory: H.T.; writing and project planning: H.T., S.O. and M.T.

### Competing Interests

The authors declare that they have no competing interests.

### Corresponding author

Correspondence to Masaaki Tanaka.

## About this article

### DOI

https://doi.org/10.1038/s41598-017-05799-8

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